Literature DB >> 21630689

Ruthenium-catalyzed hydrovinylation of N-acetylenamines leading to amines with a quaternary carbon center.

Qiu-Shi Wang1, Jian-Hua Xie, Wei Li, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou.   

Abstract

A catalytic hydrovinylation of N-acetylenamines with ethylene is reported. This new hydrovinylation reaction is catalyzed by a ruthenium hydride complex, RuHCl(CO)(PCy(3))(2), providing a series of N-acetylamines with a quaternary carbon center with up to 99% yield.

Entities:  

Year:  2011        PMID: 21630689     DOI: 10.1021/ol201142v

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Transition-metal-catalyzed laboratory-scale carbon-carbon bond-forming reactions of ethylene.

Authors:  Vaneet Saini; Benjamin J Stokes; Matthew S Sigman
Journal:  Angew Chem Int Ed Engl       Date:  2013-09-17       Impact factor: 15.336

2.  Cobalt-Catalysed Asymmetric Hydrovinylation of 1,3-Dienes.

Authors:  Yam N Timsina; Rakesh K Sharma; T V RajanBabu
Journal:  Chem Sci       Date:  2015-04-23       Impact factor: 9.825

  2 in total

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