| Literature DB >> 21629945 |
Kai Gao1, Chang-Bin Yu, Wei Li, Yong-Gui Zhou, Xumu Zhang.
Abstract
Highly enantioselective hydrogenation of seven-membered cyclic imines, substituted dibenzo[b,f][1,4]oxazepines, was achieved, with up to 94% ee, by using the [Ir(COD)Cl](2)/(S)-Xyl-C(3)*-TunePhos complex as the catalyst in the presence of morpholine-HCl.Entities:
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Year: 2011 PMID： 21629945 DOI： 10.1039/c1cc12263k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222