Literature DB >> 21623433

Arylation of α-pivaloxyl ketones with arylboronic reagents via Ni-catalyzed sp3 C-O activation.

Kun Huang1, Gang Li, Wei-Ping Huang, Da-Gang Yu, Zhang-Jie Shi.   

Abstract

A Suzuki-Miyaura coupling of α-pivaloxyl ketones via Ni-catalyzed sp(3) C-O activation to produce α-aryl ketones is developed. This study offers a convenient method to construct α-arylation products from readily available α-hydroxyl carbonyl compounds. This journal is © The Royal Society of Chemistry 2011

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Year:  2011        PMID： 21623433     DOI： 10.1039/c1cc11193k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Well-defined nickel and palladium precatalysts for cross-coupling.

Authors:  Nilay Hazari; Patrick R Melvin; Megan Mohadjer Beromi
Journal:  Nat Rev Chem       Date:  2017-03-01       Impact factor: 34.035

2.  Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: stereospecific formation of diarylalkanes and triarylmethanes.

Authors:  Qi Zhou; Harathi D Srinivas; Srimoyee Dasgupta; Mary P Watson
Journal:  J Am Chem Soc       Date:  2013-02-20       Impact factor: 15.419

3.  Nanonickel-catalyzed Suzuki-Miyaura cross-couplings in water.

Authors:  Sachin Handa; Eric D Slack; Bruce H Lipshutz
Journal:  Angew Chem Int Ed Engl       Date:  2015-08-25       Impact factor: 15.336

4.  Selective α-Methylation of Aryl Ketones Using Quaternary Ammonium Salts as Solid Methylating Agents.

Authors:  Johanna Templ; Michael Schnürch
Journal:  J Org Chem       Date:  2022-03-07       Impact factor: 4.354
  4 in total

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