Literature DB >> 21618998

Synthesis and characterization of iron(II) and ruthenium(II) hydrido hydrazine complexes.

Leslie D Field1, Hsiu L Li, Scott J Dalgarno, Paul Jensen, Ruaraidh D McIntosh.   

Abstract

Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N(2)H(4))(dmpe)(2)](+) which have been characterized by NMR spectroscopy ((1)H, (31)P, and (15)N). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N(2)H(x) complexes, including several unstable hydrido hydrazido complexes.
© 2011 American Chemical Society

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Year:  2011        PMID： 21618998     DOI： 10.1021/ic102519f

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

Review 1.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

2.  A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4Ligand.

Authors:  Bryan D Stubbert; Javier Vela; William W Brennessel; Patrick L Holland
Journal:  Z Anorg Allg Chem       Date:  2013-07-01       Impact factor: 1.492

3.  Mononuclear five- and six-coordinate iron hydrazido and hydrazine species.

Authors:  Caroline T Saouma; Connie C Lu; Jonas C Peters
Journal:  Inorg Chem       Date:  2012-09-05       Impact factor: 5.165
  3 in total

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