| Literature DB >> 21615183 |
Francisco J Pulido1, Asunción Barbero, Pilar Castreño.
Abstract
A useful strategy for cycloheptane annulations from oxo- and epoxyallylsilanes, prepared by silylcupration of allenes, has been developed, and their application to the stereoselective synthesis of 4-methylenecycloheptan-1-ols is of great potential in the construction of seven-membered ring natural products presented.Entities:
Year: 2011 PMID： 21615183 DOI： 10.1021/jo200705u
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354