Literature DB >> 21614354

Lewis acid-activated oxidation of alcohols by permanganate.

Hongxia Du1, Po-Kam Lo, Zongmin Hu, Haojun Liang, Kai-Chung Lau, Yi-Ning Wang, William W Y Lam, Tai-Chu Lau.   

Abstract

The oxidation of alcohols by KMnO(4) is greatly accelerated by various Lewis acids. Notably the rate is increased by 4 orders of magnitude in the presence of Ca(2+). The mechanisms of the oxidation of CH(3)OH and PhCH(OH)CH(3) by MnO(4)(-) and BF(3)·MnO(4)(-) have also been studied computationally by the DFT method. This journal is © The Royal Society of Chemistry 2011

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Year:  2011        PMID： 21614354     DOI： 10.1039/c1cc12024g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic Mn3MO4 Cubane and Fe3MO(OH) and Mn3MO(OH) Clusters.

Authors:  Davide Lionetti; Sandy Suseno; Emily Y Tsui; Luo Lu; Troy A Stich; Kurtis M Carsch; Robert J Nielsen; William A Goddard; R David Britt; Theodor Agapie
Journal:  Inorg Chem       Date:  2019-02-07       Impact factor: 5.165

2.  Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid Complexes.

Authors:  Jan Paulo T Zaragoza; Regina A Baglia; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2015-05-12       Impact factor: 15.419

3.  Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.

Authors:  Heejung Yoon; Yong-Min Lee; Xiujuan Wu; Kyung-Bin Cho; Ritimukta Sarangi; Wonwoo Nam; Shunichi Fukuzumi; Shunichi Fuhkuzumi
Journal:  J Am Chem Soc       Date:  2013-06-06       Impact factor: 15.419

4.  A Mononuclear Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Metal Ions.

Authors:  Yong-Min Lee; Suhee Bang; Yun Mi Kim; Jaeheung Cho; Seungwoo Hong; Takashi Nomura; Takashi Ogura; Oliver Troeppner; Ivana Ivanović-Burmazović; Ritimukta Sarangi; Shunichi Fukuzumi; Wonwoo Nam
Journal:  Chem Sci       Date:  2013-07-23       Impact factor: 9.825

5.  Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.

Authors:  Jieun Jung; Heather M Neu; Pannee Leeladee; Maxime A Siegler; Kei Ohkubo; David P Goldberg; Shunichi Fukuzumi
Journal:  Inorg Chem       Date:  2016-03-14       Impact factor: 5.165

6.  Sc3+ (or HClO4) Activation of a Nonheme FeIII-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene.

Authors:  Subhasree Kal; Apparao Draksharapu; Lawrence Que
Journal:  J Am Chem Soc       Date:  2018-04-17       Impact factor: 15.419

7.  Mechanism of Permanganate-Promoted Dihydroxylation of Complex Diketopiperazines: Critical Roles of Counter-cation and Ion-Pairing.

Authors:  Brandon E Haines; Brandon M Nelson; Jessica M Grandner; Justin Kim; K N Houk; Mohammad Movassaghi; Djamaladdin G Musaev
Journal:  J Am Chem Soc       Date:  2018-10-08       Impact factor: 15.419

8.  Identifying MnVII-oxo Species during Electrochemical Water Oxidation by Manganese Oxide.

Authors:  Biaobiao Zhang; Quentin Daniel; Lizhou Fan; Tianqi Liu; Qijun Meng; Licheng Sun
Journal:  iScience       Date:  2018-05-30

Review 9.  Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions.

Authors:  Mian Guo; Teresa Corona; Kallol Ray; Wonwoo Nam
Journal:  ACS Cent Sci       Date:  2018-12-18       Impact factor: 14.553

10.  Cooperative activating effects of metal ion and Brønsted acid on a metal oxo species.

Authors:  Gui Chen; Li Ma; Po-Kam Lo; Chi-Keung Mak; Kai-Chung Lau; Tai-Chu Lau
Journal:  Chem Sci       Date:  2020-10-21       Impact factor: 9.825
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