| Literature DB >> 21595434 |
Stéphanie Ortial1, Jean-Luc Montchamp.
Abstract
The stereocontrolled synthesis of Z-alkenylphosphine-borane complexes is easily accomplished via the hydroalumination or carbocupration of alkynyl precursors. Z/E ratios are generally higher than 95/5. These reactions are stereocomplementary to our olefination approach.Entities:
Year: 2011 PMID： 21595434 DOI： 10.1021/ol2010374
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005