Literature DB >> 21591641

Highly enantioselective partial hydrogenation of simple pyrroles: a facile access to chiral 1-pyrrolines.

Duo-Sheng Wang1, Zhi-Shi Ye, Qing-An Chen, Yong-Gui Zhou, Chang-Bin Yu, Hong-Jun Fan, Ying Duan.   

Abstract

A highly enantioselective Pd-catalyzed partial hydrogenation of simple 2,5-disubstituted pyrroles with a Brønsted acid as an activator has been successfully developed, providing chiral 2,5-disubstituted 1-pyrrolines with up to 92% ee.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID： 21591641     DOI： 10.1021/ja203190t

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Catalytic Asymmetric Synthesis of Chiral γ-Amino Ketones via Umpolung Reactions of Imines.

Authors:  Lin Hu; Yongwei Wu; Zhe Li; Li Deng
Journal:  J Am Chem Soc       Date:  2016-11-30       Impact factor: 15.419

2.  Pd-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols via capture of active tautomers.

Authors:  Zhang-Pei Chen; Mu-Wang Chen; Lei Shi; Chang-Bin Yu; Yong-Gui Zhou
Journal:  Chem Sci       Date:  2015-03-31       Impact factor: 9.825

3.  Catalytic asymmetric hydrogenation of 3-substituted benzisoxazoles.

Authors:  Ryuhei Ikeda; Ryoichi Kuwano
Journal:  Molecules       Date:  2012-06-06       Impact factor: 4.411

4.  Tin(iv) chloride mediated (3 + 2) annulation of trans-2-aroyl-3-styrylcyclopropane-1,1-dicarboxylates with nitriles: diastereoselective access to 5-vinyl-1-pyrroline derivatives.

Authors:  Murugesan Thangamani; Subaramaniam Thangamalar; Kannupal Srinivasan
Journal:  RSC Adv       Date:  2021-04-21       Impact factor: 3.361

5.  Redox-neutral manganese-catalyzed synthesis of 1-pyrrolines.

Authors:  Tingting Feng; Canxiang Liu; Zhen Wu; Xinxin Wu; Chen Zhu
Journal:  Chem Sci       Date:  2022-02-09       Impact factor: 9.825

6.  Catalytic asymmetric synthesis of a nitrogen heterocycle through stereocontrolled direct photoreaction from electronically excited state.

Authors:  Xiaoqiang Huang; Xinyao Li; Xiulan Xie; Klaus Harms; Radostan Riedel; Eric Meggers
Journal:  Nat Commun       Date:  2017-12-21       Impact factor: 14.919

Review 7.  Selective Arene Hydrogenation for Direct Access to Saturated Carbo- and Heterocycles.

Authors:  Mario P Wiesenfeldt; Zackaria Nairoukh; Toryn Dalton; Frank Glorius
Journal:  Angew Chem Int Ed Engl       Date:  2019-04-29       Impact factor: 15.336
  7 in total

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