Literature DB >> 21590822

Squaramides: bridging from molecular recognition to bifunctional organocatalysis.

José Alemán1, Alejandro Parra, Hao Jiang, Karl Anker Jørgensen.   

Abstract

In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to their recent advances as powerful bifunctional hydrogen-bonding catalysts in asymmetric organocatalysis. The main features of the squaramido functionality and the direct comparison with the analogous ureas and thioureas are also discussed.
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2011        PMID: 21590822     DOI: 10.1002/chem.201003694

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  30 in total

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4.  Organocatalytic asymmetric addition of malonates to unsaturated 1,4-diketones.

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5.  High-affinity anion binding by steroidal squaramide receptors.

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6.  Quantification of electrophilic activation by hydrogen-bonding organocatalysts.

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7.  Asymmetric synthesis of functionalized cyclohexanes bearing five stereocenters via a one-pot organocatalytic Michael-Michael-1,2-addition sequence.

Authors:  Pankaj Chauhan; Gregor Urbanietz; Gerhard Raabe; Dieter Enders
Journal:  Chem Commun (Camb)       Date:  2014-07-04       Impact factor: 6.222

8.  Asymmetric domino synthesis of indanes bearing four contiguous stereocentres catalyzed by sub-mol% loadings of a squaramide in minutes.

Authors:  Charles C J Loh; Daniel Hack; Dieter Enders
Journal:  Chem Commun (Camb)       Date:  2013-11-11       Impact factor: 6.222

9.  Asymmetric synthesis of highly functionalized tetrahydropyrans via a one-pot organocatalytic Michael/Henry/ketalization sequence.

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Journal:  Org Lett       Date:  2014-06-27       Impact factor: 6.005

10.  Organocatalytic and enantioselective Michael reaction between α-nitroesters and nitroalkenes. Syn/anti-selectivity control using catalysts with the same absolute backbone chirality.

Authors:  Jose I Martínez; Uxue Uria; Maria Muñiz; Efraím Reyes; Luisa Carrillo; Jose L Vicario
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