Literature DB >> 21589246

Poly[[diaqua-(μ(2)-5,5-dioxodibenzo[b,d]thio-phene-3,7-dicarboxyl-ato)(μ(2)-ethyl-ene glycol)manganese(II)] dimethyl-acetamide solvate].

Abstract

In the title complex, {[Mn(C(14)H(6)O(6)S)(C(2)H(6)O(2))(H(2)O)(2)]·C(4)H(9)NO}(n), the Mn(II) ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thio-phene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethyl-ene glycol (EG) mol-ecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O-H⋯O hydrogen bonds.

Entities: Chemical Disease Gene

Year: 2010 PMID： 21589246 PMCID： PMC3011537 DOI： 10.1107/S1600536810045411

Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN： 1600-5368

Related literature

For the use of H2 L ligands in the construction of coordination polymers, including metal-organic frameworks with functionalized pores, see: Neofotistou et al. (2010 ▶). Kanaizuka et al. (2010 ▶). Yan et al. (2009 ▶). For the ligand synthesis, see: Neofotistou et al. (2009 ▶).

Experimental

Crystal data

[Mn(C14H6O6S)(C2H6O2)(H2O)2]·C4H9NO M = 542.41 Monoclinic, a = 7.0564 (3) Å b = 11.8142 (4) Å c = 28.0008 (10) Å β = 100.544 (1)° V = 2294.89 (15) Å3 Z = 4 Mo Kα radiation μ = 0.73 mm−1 T = 296 K 0.30 × 0.20 × 0.10 mm

Data collection

Bruker APEXII CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2008 ▶) T min = 0.811, T max = 0.931 30673 measured reflections 5716 independent reflections 5221 reflections with I > 2σ(I) R int = 0.025

Refinement

R[F 2 > 2σ(F 2)] = 0.030 wR(F 2) = 0.083 S = 1.07 5716 reflections 335 parameters 4 restraints H atoms treated by a mixture of independent and constrained refinement Δρmax = 0.32 e Å−3 Δρmin = −0.36 e Å−3 Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL. Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810045411/fk2028sup1.cif Structure factors: contains datablocks I. DOI: 10.1107/S1600536810045411/fk2028Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Mn(C₁₄H₆O₆S)(C₂H₆O₂)(H₂O)₂]·C₄H₉NO	F(000) = 1124
M_r = 542.41	D_x = 1.570 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 9208 reflections
a = 7.0564 (3) Å	θ = 2.3–26°
b = 11.8142 (4) Å	µ = 0.73 mm⁻¹
c = 28.0008 (10) Å	T = 296 K
β = 100.544 (1)°	Columnar, colourless
V = 2294.89 (15) Å³	0.30 × 0.20 × 0.10 mm
Z = 4

Bruker APEXII CCD area-detector diffractometer	5716 independent reflections
Radiation source: fine-focus sealed tube	5221 reflections with I > 2σ(I)
graphite	R_int = 0.025
φ and ω scans	θ_max = 28.4°, θ_min = 1.5°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −9→7
T_min = 0.811, T_max = 0.931	k = −15→14
30673 measured reflections	l = −37→36

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: geom and difmap
R[F² > 2σ(F²)] = 0.030	H atoms treated by a mixture of independent and constrained refinement
wR(F²) = 0.083	w = 1/[σ²(F_o²) + (0.0425P)² + 1.0021P] where P = (F_o² + 2F_c²)/3
S = 1.07	(Δ/σ)_max = 0.001
5716 reflections	Δρ_max = 0.32 e Å⁻³
335 parameters	Δρ_min = −0.36 e Å⁻³
4 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0011 (3)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	U_iso*/U_eq
Mn1	0.22688 (3)	0.673463 (17)	0.267191 (7)	0.02227 (7)
C1	0.43784 (19)	0.86846 (12)	0.33374 (5)	0.0236 (3)
C2	0.53981 (19)	0.90349 (12)	0.38359 (5)	0.0225 (3)
C3	0.5765 (2)	1.01741 (12)	0.39461 (5)	0.0249 (3)
H3A	0.5433	1.0713	0.3703	0.030*
C4	0.5922 (2)	0.82195 (11)	0.41959 (5)	0.0247 (3)
H4A	0.5704	0.7454	0.4130	0.030*
C5	0.6613 (2)	1.05261 (12)	0.44092 (5)	0.0247 (3)
H5A	0.6842	1.1290	0.4476	0.030*
C6	0.67736 (19)	0.85829 (12)	0.46533 (5)	0.0229 (3)
C7	0.71153 (19)	0.97220 (11)	0.47712 (5)	0.0216 (2)
C8	0.79778 (19)	0.98999 (11)	0.52870 (5)	0.0213 (2)
C9	0.8502 (2)	1.09104 (11)	0.55269 (5)	0.0244 (3)
H9A	0.8314	1.1596	0.5362	0.029*
C10	0.8262 (2)	0.88924 (11)	0.55495 (5)	0.0229 (3)
C11	0.9316 (2)	1.08823 (12)	0.60187 (5)	0.0242 (3)
H11A	0.9687	1.1557	0.6180	0.029*
C12	0.90422 (19)	0.88466 (12)	0.60378 (5)	0.0235 (3)
H12A	0.9199	0.8161	0.6203	0.028*
C13	0.95877 (18)	0.98663 (11)	0.62747 (5)	0.0215 (3)
C14	1.05227 (19)	0.98394 (12)	0.68052 (5)	0.0224 (3)
O1	0.39522 (15)	0.76549 (9)	0.32753 (4)	0.0290 (2)
O2	0.39864 (18)	0.94438 (10)	0.30224 (4)	0.0366 (3)
O3	1.05942 (16)	0.88879 (9)	0.70073 (4)	0.0316 (2)
O4	1.11941 (17)	1.07339 (9)	0.70058 (4)	0.0339 (2)
O5	0.5980 (2)	0.71159 (11)	0.53019 (4)	0.0437 (3)
O6	0.92266 (19)	0.70701 (10)	0.51083 (4)	0.0411 (3)
S1	0.75616 (5)	0.77206 (3)	0.516692 (12)	0.02602 (9)
C15	−0.2116 (2)	0.65002 (14)	0.28938 (6)	0.0334 (3)
H15A	−0.2780	0.6571	0.3167	0.040*
H15B	−0.1888	0.5702	0.2847	0.040*
C16	−0.3383 (2)	0.69648 (15)	0.24442 (6)	0.0334 (3)
H16A	−0.3629	0.7761	0.2490	0.040*
H16B	−0.2730	0.6894	0.2169	0.040*
O7	−0.03049 (15)	0.70750 (10)	0.30054 (4)	0.0312 (2)
H7	−0.052 (3)	0.777 (2)	0.3005 (8)	0.048 (6)*
O8	−0.51664 (16)	0.63629 (11)	0.23467 (5)	0.0381 (3)
H8	−0.495 (3)	0.5748 (15)	0.2233 (8)	0.052 (6)*
O9	0.1821 (2)	0.83273 (10)	0.23213 (5)	0.0471 (3)
H9C	0.135 (3)	0.854 (2)	0.2043 (6)	0.056 (7)*
H9B	0.246 (3)	0.8828 (18)	0.2484 (7)	0.057 (7)*
O10	0.24423 (19)	0.49977 (10)	0.29494 (5)	0.0352 (3)
H10C	0.182 (3)	0.474 (2)	0.3150 (9)	0.057 (7)*
H10B	0.210 (4)	0.463 (2)	0.2701 (10)	0.072 (9)*
C17	−0.0751 (4)	1.0498 (2)	0.08416 (8)	0.0639 (6)
H17A	−0.1888	1.0591	0.0981	0.096*
H17B	−0.1115	1.0281	0.0507	0.096*
H17C	−0.0053	1.1199	0.0863	0.096*
C18	0.0504 (3)	0.95932 (15)	0.11144 (6)	0.0391 (4)
C19	0.3395 (3)	0.8464 (2)	0.12584 (8)	0.0578 (5)
H19A	0.2600	0.7865	0.1344	0.087*
H19B	0.4142	0.8782	0.1548	0.087*
H19C	0.4244	0.8168	0.1057	0.087*
C20	0.2899 (5)	0.9857 (2)	0.05873 (11)	0.0830 (9)
H20A	0.2025	1.0437	0.0443	0.125*
H20B	0.3005	0.9288	0.0349	0.125*
H20C	0.4144	1.0184	0.0703	0.125*
O11	−0.0072 (2)	0.90934 (12)	0.14522 (4)	0.0461 (3)
N1	0.2175 (2)	0.93427 (13)	0.09933 (6)	0.0440 (3)

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Mn1	0.02329 (11)	0.02213 (11)	0.01900 (11)	−0.00047 (7)	−0.00245 (8)	−0.00162 (7)
C1	0.0221 (6)	0.0278 (7)	0.0191 (6)	−0.0016 (5)	−0.0007 (5)	−0.0006 (5)
C2	0.0211 (6)	0.0267 (6)	0.0184 (6)	−0.0021 (5)	0.0002 (5)	−0.0018 (5)
C3	0.0283 (7)	0.0253 (7)	0.0193 (6)	−0.0009 (5)	−0.0004 (5)	0.0015 (5)
C4	0.0268 (7)	0.0227 (6)	0.0228 (6)	−0.0024 (5)	−0.0006 (5)	−0.0026 (5)
C5	0.0302 (7)	0.0217 (6)	0.0207 (6)	−0.0010 (5)	0.0009 (5)	−0.0008 (5)
C6	0.0244 (6)	0.0235 (6)	0.0190 (6)	0.0005 (5)	−0.0006 (5)	0.0014 (5)
C7	0.0212 (6)	0.0247 (6)	0.0177 (6)	−0.0004 (5)	0.0005 (5)	−0.0012 (5)
C8	0.0216 (6)	0.0236 (6)	0.0178 (6)	0.0000 (5)	0.0013 (5)	−0.0002 (5)
C9	0.0301 (7)	0.0212 (6)	0.0204 (6)	0.0001 (5)	0.0010 (5)	0.0014 (5)
C10	0.0255 (6)	0.0211 (6)	0.0206 (6)	−0.0014 (5)	0.0006 (5)	−0.0020 (5)
C11	0.0276 (6)	0.0225 (6)	0.0209 (6)	−0.0011 (5)	0.0004 (5)	−0.0026 (5)
C12	0.0257 (6)	0.0231 (6)	0.0203 (6)	0.0011 (5)	0.0003 (5)	0.0020 (5)
C13	0.0203 (6)	0.0255 (6)	0.0176 (6)	0.0015 (5)	0.0002 (5)	−0.0005 (5)
C14	0.0213 (6)	0.0256 (6)	0.0187 (6)	0.0031 (5)	−0.0004 (5)	−0.0007 (5)
O1	0.0348 (5)	0.0260 (5)	0.0221 (5)	−0.0033 (4)	−0.0054 (4)	−0.0028 (4)
O2	0.0494 (7)	0.0311 (6)	0.0234 (5)	−0.0091 (5)	−0.0092 (5)	0.0045 (4)
O3	0.0397 (6)	0.0270 (5)	0.0222 (5)	−0.0004 (4)	−0.0094 (4)	0.0035 (4)
O4	0.0472 (6)	0.0264 (5)	0.0234 (5)	−0.0010 (5)	−0.0062 (4)	−0.0033 (4)
O5	0.0572 (8)	0.0372 (6)	0.0347 (6)	−0.0207 (6)	0.0036 (5)	0.0026 (5)
O6	0.0543 (7)	0.0313 (6)	0.0340 (6)	0.0154 (5)	−0.0022 (5)	−0.0037 (5)
S1	0.03603 (19)	0.01997 (16)	0.01953 (16)	−0.00206 (13)	−0.00157 (13)	−0.00020 (11)
C15	0.0273 (7)	0.0319 (7)	0.0406 (8)	−0.0013 (6)	0.0048 (6)	0.0038 (6)
C16	0.0256 (7)	0.0369 (8)	0.0372 (8)	−0.0023 (6)	0.0044 (6)	−0.0012 (6)
O7	0.0269 (5)	0.0278 (5)	0.0375 (6)	0.0006 (4)	0.0022 (4)	−0.0058 (4)
O8	0.0257 (5)	0.0373 (6)	0.0516 (7)	−0.0023 (5)	0.0076 (5)	−0.0186 (5)
O9	0.0779 (10)	0.0270 (6)	0.0266 (6)	−0.0056 (6)	−0.0164 (6)	0.0035 (5)
O10	0.0474 (7)	0.0284 (6)	0.0280 (6)	−0.0012 (5)	0.0018 (5)	0.0029 (5)
C17	0.0792 (16)	0.0631 (14)	0.0481 (12)	0.0237 (12)	0.0083 (11)	0.0178 (10)
C18	0.0535 (10)	0.0349 (8)	0.0253 (7)	0.0019 (7)	−0.0021 (7)	−0.0032 (6)
C19	0.0607 (13)	0.0621 (13)	0.0526 (12)	0.0184 (11)	0.0155 (10)	0.0050 (10)
C20	0.103 (2)	0.0651 (16)	0.095 (2)	0.0174 (15)	0.0574 (18)	0.0312 (15)
O11	0.0525 (8)	0.0550 (8)	0.0298 (6)	0.0113 (6)	0.0049 (5)	0.0074 (5)
N1	0.0569 (10)	0.0382 (8)	0.0377 (8)	0.0020 (7)	0.0109 (7)	−0.0011 (6)

Mn1—O9	2.1191 (12)	C14—O3	1.2553 (17)
Mn1—O3ⁱ	2.1437 (10)	O3—Mn1ⁱⁱⁱ	2.1437 (10)
Mn1—O1	2.1710 (10)	O5—S1	1.4329 (13)
Mn1—O10	2.1897 (12)	O6—S1	1.4382 (13)
Mn1—O8ⁱⁱ	2.2138 (12)	C15—O7	1.4303 (18)
Mn1—O7	2.2253 (11)	C15—C16	1.508 (2)
C1—O2	1.2529 (17)	C15—H15A	0.9700
C1—O1	1.2576 (18)	C15—H15B	0.9700
C1—C2	1.5066 (18)	C16—O8	1.4275 (19)
C2—C3	1.3943 (19)	C16—H16A	0.9700
C2—C4	1.3945 (19)	C16—H16B	0.9700
C3—C5	1.3889 (19)	O7—H7	0.84 (2)
C3—H3A	0.9300	O8—Mn1^iv	2.2138 (11)
C4—C6	1.3799 (18)	O8—H8	0.818 (16)
C4—H4A	0.9300	O9—H9C	0.827 (15)
C5—C7	1.3871 (18)	O9—H9B	0.827 (15)
C5—H5A	0.9300	O10—H10C	0.83 (3)
C6—C7	1.3961 (19)	O10—H10B	0.82 (3)
C6—S1	1.7671 (14)	C17—C18	1.504 (3)
C7—C8	1.4762 (17)	C17—H17A	0.9600
C8—C9	1.3864 (18)	C17—H17B	0.9600
C8—C10	1.3941 (18)	C17—H17C	0.9600
C9—C11	1.3919 (18)	C18—O11	1.245 (2)
C9—H9A	0.9300	C18—N1	1.318 (2)
C10—C12	1.3784 (18)	C19—N1	1.461 (3)
C10—S1	1.7648 (13)	C19—H19A	0.9600
C11—C13	1.3932 (19)	C19—H19B	0.9600
C11—H11A	0.9300	C19—H19C	0.9600
C12—C13	1.3950 (19)	C20—N1	1.462 (3)
C12—H12A	0.9300	C20—H20A	0.9600
C13—C14	1.5114 (17)	C20—H20B	0.9600
C14—O4	1.2488 (17)	C20—H20C	0.9600

O9—Mn1—O3ⁱ	83.73 (4)	C1—O1—Mn1	132.45 (9)
O9—Mn1—O1	85.98 (4)	C14—O3—Mn1ⁱⁱⁱ	131.98 (9)
O3ⁱ—Mn1—O1	169.61 (4)	O5—S1—O6	117.10 (8)
O9—Mn1—O10	172.07 (5)	O5—S1—C10	112.10 (7)
O3ⁱ—Mn1—O10	88.43 (4)	O6—S1—C10	110.15 (7)
O1—Mn1—O10	101.89 (4)	O5—S1—C6	110.96 (7)
O9—Mn1—O8ⁱⁱ	92.82 (6)	O6—S1—C6	110.93 (7)
O3ⁱ—Mn1—O8ⁱⁱ	86.40 (4)	C10—S1—C6	93.06 (6)
O1—Mn1—O8ⁱⁱ	92.72 (4)	O7—C15—C16	112.28 (13)
O10—Mn1—O8ⁱⁱ	87.89 (5)	O7—C15—H15A	109.1
O9—Mn1—O7	88.29 (6)	C16—C15—H15A	109.1
O3ⁱ—Mn1—O7	93.65 (4)	O7—C15—H15B	109.1
O1—Mn1—O7	87.44 (4)	C16—C15—H15B	109.1
O10—Mn1—O7	91.00 (5)	H15A—C15—H15B	107.9
O8ⁱⁱ—Mn1—O7	178.89 (5)	O8—C16—C15	110.22 (14)
O2—C1—O1	125.37 (12)	O8—C16—H16A	109.6
O2—C1—C2	117.52 (12)	C15—C16—H16A	109.6
O1—C1—C2	117.09 (12)	O8—C16—H16B	109.6
C3—C2—C4	119.54 (12)	C15—C16—H16B	109.6
C3—C2—C1	120.53 (12)	H16A—C16—H16B	108.1
C4—C2—C1	119.90 (12)	C15—O7—Mn1	125.99 (10)
C5—C3—C2	121.77 (13)	C15—O7—H7	108.4 (15)
C5—C3—H3A	119.1	Mn1—O7—H7	109.7 (16)
C2—C3—H3A	119.1	C16—O8—Mn1^iv	125.51 (10)
C6—C4—C2	117.96 (12)	C16—O8—H8	107.4 (16)
C6—C4—H4A	121.0	Mn1^iv—O8—H8	123.9 (16)
C2—C4—H4A	121.0	Mn1—O9—H9C	134.6 (16)
C7—C5—C3	119.08 (13)	Mn1—O9—H9B	111.1 (16)
C7—C5—H5A	120.5	H9C—O9—H9B	113 (2)
C3—C5—H5A	120.5	Mn1—O10—H10C	125.2 (17)
C4—C6—C7	123.13 (12)	Mn1—O10—H10B	102 (2)
C4—C6—S1	126.50 (11)	H10C—O10—H10B	106 (2)
C7—C6—S1	110.38 (10)	C18—C17—H17A	109.5
C5—C7—C6	118.52 (12)	C18—C17—H17B	109.5
C5—C7—C8	128.45 (12)	H17A—C17—H17B	109.5
C6—C7—C8	113.03 (12)	C18—C17—H17C	109.5
C9—C8—C10	118.68 (12)	H17A—C17—H17C	109.5
C9—C8—C7	128.49 (12)	H17B—C17—H17C	109.5
C10—C8—C7	112.83 (12)	O11—C18—N1	121.38 (16)
C8—C9—C11	118.95 (12)	O11—C18—C17	118.61 (18)
C8—C9—H9A	120.5	N1—C18—C17	120.01 (18)
C11—C9—H9A	120.5	N1—C19—H19A	109.5
C12—C10—C8	123.32 (12)	N1—C19—H19B	109.5
C12—C10—S1	126.02 (11)	H19A—C19—H19B	109.5
C8—C10—S1	110.64 (10)	N1—C19—H19C	109.5
C9—C11—C13	121.50 (12)	H19A—C19—H19C	109.5
C9—C11—H11A	119.2	H19B—C19—H19C	109.5
C13—C11—H11A	119.2	N1—C20—H20A	109.5
C10—C12—C13	117.59 (12)	N1—C20—H20B	109.5
C10—C12—H12A	121.2	H20A—C20—H20B	109.5
C13—C12—H12A	121.2	N1—C20—H20C	109.5
C11—C13—C12	119.96 (12)	H20A—C20—H20C	109.5
C11—C13—C14	121.20 (12)	H20B—C20—H20C	109.5
C12—C13—C14	118.82 (12)	C18—N1—C19	120.01 (16)
O4—C14—O3	125.06 (12)	C18—N1—C20	124.28 (18)
O4—C14—C13	119.06 (12)	C19—N1—C20	115.66 (19)
O3—C14—C13	115.87 (12)

D—H···A	D—H	H···A	D···A	D—H···A
O7—H7···O4^v	0.84 (2)	1.83 (2)	2.6623 (16)	175 (2)
O8—H8···O2^vi	0.82 (2)	1.88 (2)	2.6865 (16)	169 (2)
O9—H9C···O11	0.83 (2)	1.89 (2)	2.7086 (17)	171 (2)
O9—H9B···O2	0.83 (2)	1.84 (2)	2.6135 (16)	156 (2)
O10—H10C···O11^vi	0.83 (3)	1.96 (3)	2.7877 (19)	172 (2)
O10—H10B···O4ⁱ	0.82 (3)	1.98 (3)	2.7663 (16)	161 (3)

Table 1

Selected bond lengths (Å)

Mn1—O9	2.1191 (12)
Mn1—O3ⁱ	2.1437 (10)
Mn1—O1	2.1710 (10)
Mn1—O10	2.1897 (12)
Mn1—O8ⁱⁱ	2.2138 (12)
Mn1—O7	2.2253 (11)

Symmetry codes: (i) ; (ii) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O7—H7⋯O4ⁱⁱⁱ	0.84 (2)	1.83 (2)	2.6623 (16)	175 (2)
O8—H8⋯O2^iv	0.82 (2)	1.88 (2)	2.6865 (16)	169 (2)
O9—H9C⋯O11	0.83 (2)	1.89 (2)	2.7086 (17)	171 (2)
O9—H9B⋯O2	0.83 (2)	1.84 (2)	2.6135 (16)	156 (2)
O10—H10C⋯O11^iv	0.83 (3)	1.96 (3)	2.7877 (19)	172 (2)
O10—H10B⋯O4ⁱ	0.82 (3)	1.98 (3)	2.7663 (16)	161 (3)

Symmetry codes: (i) ; (iii) ; (iv) .

2 in total

1. A short history of SHELX.

Authors: George M Sheldrick
Journal: Acta Crystallogr A Date: 2007-12-21 Impact factor: 2.290

2. Unprecedented sulfone-functionalized metal-organic frameworks and gas-sorption properties.

Authors: Eleftheria Neofotistou; Christos D Malliakas; Pantelis N Trikalitis
Journal: Chemistry Date: 2009 Impact factor: 5.236

2 in total