4-Decyl-phenyl 4-benz-yloxy-3-methyl-benzoate.

In the title compound, C(31)H(38)O(3), the central benzene ring makes dihedral angles of 66.06 (9) and 65.21 (8)°, respectively, with the benzyl and 4-decyl-phenyl rings.

Related literature

For general background to benzyl­oxybenzoate, see: Laschat (2009 ▶); Meter & Klanderman (1973 ▶); Young et al. (1974 ▶); Tinn et al. (1982 ▶). For the synthesis, see: Sadashiva & Subba (1975 ▶); Sadashiva (1979 ▶); Hari et al. (2009 ▶). For related structures, see: Blake et al. (1996 ▶); Chin & Goodby (1986 ▶).

Experimental

Crystal data

C31H38O3

M = 458.61

Triclinic,

a = 9.3684 (16) Å

b = 11.168 (2) Å

c = 15.204 (3) Å

α = 68.588 (11)°

β = 87.274 (11)°

γ = 65.578 (10)°

V = 1338.3 (4) Å3

Z = 2

Mo Kα radiation

μ = 0.07 mm−1

T = 295 K

0.22 × 0.15 × 0.12 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: ψ scan (SADABS; Sheldrick, 2004 ▶) T min = 0.987, T max = 0.992

23986 measured reflections

6737 independent reflections

3840 reflections with I > 2σ(I)

R int = 0.034

Refinement

R[F 2 > 2σ(F 2)] = 0.053

wR(F 2) = 0.183

S = 1.04

6737 reflections

308 parameters

6 restraints

H-atom parameters constrained

Δρmax = 0.37 e Å−3

Δρmin = −0.28 e Å−3

Data collection: SMART (Bruker, 2001 ▶); cell refinement: SAINT (Bruker, 2001 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810028965/gw2084sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810028965/gw2084Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C31H38O3	Z = 2
Mr = 458.61	F(000) = 496
Triclinic, P1	Dx = 1.138 Mg m−3
Hall symbol: -P 1	Melting point: 339 K
a = 9.3684 (16) Å	Mo Kα radiation, λ = 0.71073 Å
b = 11.168 (2) Å	Cell parameters from 6737 reflections
c = 15.204 (3) Å	θ = 1.5–28.5°
α = 68.588 (11)°	µ = 0.07 mm−1
β = 87.274 (11)°	T = 295 K
γ = 65.578 (10)°	Plate, colourless
V = 1338.3 (4) Å3	0.22 × 0.15 × 0.12 mm

Bruker SMART CCD area-detector diffractometer	6737 independent reflections
Radiation source: fine-focus sealed tube	3840 reflections with I > 2σ(I)
graphite	Rint = 0.034
ω and φ scans	θmax = 28.5°, θmin = 1.5°
Absorption correction: ψ scan (SADABS; Sheldrick, 2004)	h = −12→12
Tmin = 0.987, Tmax = 0.992	k = −14→14
23986 measured reflections	l = −19→20

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.053	H-atom parameters constrained
wR(F2) = 0.183	w = 1/[σ2(Fo2) + (0.0834P)2 + 0.1711P] where P = (Fo2 + 2Fc2)/3
S = 1.04	(Δ/σ)max < 0.001
6737 reflections	Δρmax = 0.37 e Å−3
308 parameters	Δρmin = −0.28 e Å−3
6 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.009 (2)

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	1.29391 (13)	0.71764 (13)	0.39798 (8)	0.0596 (3)
O2	0.76009 (16)	0.85364 (16)	0.66658 (10)	0.0782 (4)
O3	0.66987 (13)	0.76081 (12)	0.58579 (8)	0.0587 (3)
C1	1.7436 (2)	0.6890 (3)	0.21401 (16)	0.0773 (6)
H1	1.8161	0.6725	0.1710	0.093*
C2	1.7328 (2)	0.5776 (2)	0.28609 (18)	0.0808 (6)
H2	1.7987	0.4849	0.2926	0.097*
C3	1.6246 (2)	0.6016 (2)	0.34940 (15)	0.0734 (5)
H3	1.6178	0.5249	0.3983	0.088*
C4	1.52641 (19)	0.73813 (19)	0.34098 (13)	0.0563 (4)
C5	1.5386 (2)	0.85005 (19)	0.26763 (14)	0.0654 (5)
H5	1.4728	0.9431	0.2605	0.078*
C6	1.6476 (2)	0.8246 (2)	0.20518 (15)	0.0770 (6)
H6	1.6560	0.9006	0.1565	0.092*
C8	1.16997 (18)	0.74083 (16)	0.45050 (11)	0.0493 (4)
C7	1.4092 (2)	0.7663 (2)	0.40939 (14)	0.0703 (5)
H7A	1.4619	0.7163	0.4741	0.084*
H7B	1.3582	0.8672	0.3967	0.084*
C9	1.05899 (18)	0.69493 (15)	0.43409 (11)	0.0478 (4)
C10	0.93050 (18)	0.71552 (16)	0.48486 (11)	0.0490 (4)
H10	0.8552	0.6864	0.4746	0.059*
C11	0.91080 (18)	0.77889 (16)	0.55122 (11)	0.0493 (4)
C12	1.0225 (2)	0.82287 (19)	0.56523 (12)	0.0578 (4)
H12	1.0102	0.8657	0.6090	0.069*
C13	1.1519 (2)	0.80452 (19)	0.51555 (12)	0.0589 (4)
H13	1.2262	0.8347	0.5257	0.071*
C14	1.0830 (2)	0.6250 (2)	0.36370 (14)	0.0680 (5)
H14A	1.1784	0.6208	0.3362	0.102*
H14B	0.9950	0.6789	0.3144	0.102*
H14C	1.0908	0.5304	0.3955	0.102*
C15	0.77674 (19)	0.80247 (17)	0.60752 (12)	0.0538 (4)
C16	0.53999 (18)	0.77559 (18)	0.63921 (11)	0.0512 (4)
C17	0.5292 (2)	0.65529 (18)	0.70043 (13)	0.0611 (5)
H17	0.6060	0.5660	0.7067	0.073*
C18	0.4030 (2)	0.66829 (18)	0.75268 (13)	0.0604 (4)
H18	0.3958	0.5864	0.7943	0.072*
C19	0.28666 (19)	0.79952 (17)	0.74503 (11)	0.0501 (4)
C20	0.30000 (19)	0.91846 (17)	0.68052 (12)	0.0561 (4)
H20	0.2225	1.0082	0.6727	0.067*
C21	0.42535 (19)	0.90750 (18)	0.62747 (12)	0.0553 (4)
H21	0.4318	0.9888	0.5843	0.066*
C22	0.1539 (2)	0.80822 (18)	0.80631 (13)	0.0608 (4)
H22A	0.0896	0.7711	0.7865	0.073*
H22B	0.1997	0.7462	0.8716	0.073*
C23	0.0474 (2)	0.95323 (19)	0.80478 (13)	0.0612 (5)
H23A	−0.0087	1.0130	0.7413	0.073*
H23B	0.1116	0.9952	0.8184	0.073*
C24	−0.0723 (2)	0.9519 (2)	0.87570 (13)	0.0650 (5)
H24A	−0.1399	0.9143	0.8601	0.078*
H24B	−0.0164	0.8883	0.9388	0.078*
C25	−0.1748 (2)	1.0969 (2)	0.87793 (13)	0.0634 (5)
H25A	−0.2347	1.1594	0.8157	0.076*
H25B	−0.1073	1.1365	0.8908	0.076*
C26	−0.2886 (2)	1.0926 (2)	0.95230 (13)	0.0632 (5)
H26A	−0.3508	1.0468	0.9419	0.076*
H26B	−0.2280	1.0347	1.0147	0.076*
C27	−0.4000 (2)	1.23739 (19)	0.95192 (13)	0.0639 (5)
H27A	−0.3383	1.2817	0.9654	0.077*
H27B	−0.4578	1.2970	0.8889	0.077*
C28	−0.5169 (2)	1.23037 (19)	1.02399 (13)	0.0641 (5)
H28A	−0.5745	1.1819	1.0119	0.077*
H28B	−0.4582	1.1731	1.0870	0.077*
C29	−0.6347 (2)	1.3720 (2)	1.02406 (14)	0.0687 (5)
H29A	−0.5781	1.4193	1.0389	0.082*
H29B	−0.6917	1.4310	0.9607	0.082*
C30	−0.7516 (2)	1.3592 (2)	1.09440 (16)	0.0803 (6)
H30A	−0.6939	1.2939	1.1567	0.096*
H30B	−0.8133	1.3183	1.0764	0.096*
C31	−0.8634 (3)	1.4982 (3)	1.1015 (2)	0.1154 (9)
H31A	−0.9338	1.4814	1.1475	0.173*
H31B	−0.9235	1.5629	1.0406	0.173*
H31C	−0.8039	1.5386	1.1210	0.173*

	U11	U22	U33	U12	U13	U23
O1	0.0546 (7)	0.0750 (8)	0.0666 (7)	−0.0390 (6)	0.0209 (6)	−0.0339 (6)
O2	0.0796 (9)	0.1107 (11)	0.0799 (9)	−0.0556 (8)	0.0335 (7)	−0.0593 (9)
O3	0.0524 (7)	0.0696 (7)	0.0669 (7)	−0.0305 (6)	0.0233 (6)	−0.0365 (6)
C1	0.0557 (11)	0.0991 (17)	0.0911 (15)	−0.0335 (11)	0.0254 (10)	−0.0522 (14)
C2	0.0535 (11)	0.0668 (13)	0.1176 (18)	−0.0144 (10)	0.0078 (12)	−0.0426 (13)
C3	0.0661 (12)	0.0579 (11)	0.0869 (14)	−0.0293 (10)	0.0077 (11)	−0.0141 (10)
C4	0.0497 (9)	0.0661 (11)	0.0632 (10)	−0.0336 (8)	0.0118 (8)	−0.0257 (9)
C5	0.0630 (11)	0.0566 (10)	0.0798 (12)	−0.0285 (9)	0.0197 (10)	−0.0272 (10)
C6	0.0774 (13)	0.0784 (14)	0.0781 (13)	−0.0423 (11)	0.0282 (11)	−0.0246 (11)
C8	0.0475 (8)	0.0491 (9)	0.0492 (9)	−0.0228 (7)	0.0098 (7)	−0.0143 (7)
C7	0.0669 (11)	0.0982 (15)	0.0767 (12)	−0.0548 (11)	0.0256 (10)	−0.0456 (11)
C9	0.0482 (8)	0.0435 (8)	0.0505 (9)	−0.0206 (7)	0.0084 (7)	−0.0156 (7)
C10	0.0464 (8)	0.0461 (8)	0.0543 (9)	−0.0219 (7)	0.0086 (7)	−0.0167 (7)
C11	0.0470 (8)	0.0468 (9)	0.0483 (9)	−0.0183 (7)	0.0071 (7)	−0.0138 (7)
C12	0.0614 (10)	0.0672 (11)	0.0534 (9)	−0.0313 (9)	0.0119 (8)	−0.0283 (8)
C13	0.0579 (10)	0.0720 (11)	0.0612 (10)	−0.0376 (9)	0.0123 (8)	−0.0297 (9)
C14	0.0688 (11)	0.0793 (12)	0.0822 (13)	−0.0439 (10)	0.0274 (10)	−0.0466 (11)
C15	0.0533 (9)	0.0544 (10)	0.0533 (9)	−0.0239 (8)	0.0114 (8)	−0.0193 (8)
C16	0.0487 (9)	0.0589 (10)	0.0524 (9)	−0.0245 (8)	0.0147 (7)	−0.0272 (8)
C17	0.0562 (10)	0.0496 (10)	0.0747 (12)	−0.0189 (8)	0.0180 (9)	−0.0260 (9)
C18	0.0635 (11)	0.0488 (9)	0.0668 (11)	−0.0254 (8)	0.0186 (9)	−0.0191 (8)
C19	0.0526 (9)	0.0529 (9)	0.0463 (8)	−0.0235 (8)	0.0113 (7)	−0.0200 (7)
C20	0.0555 (10)	0.0482 (9)	0.0569 (10)	−0.0177 (8)	0.0141 (8)	−0.0176 (8)
C21	0.0565 (10)	0.0521 (9)	0.0539 (9)	−0.0239 (8)	0.0157 (8)	−0.0165 (8)
C22	0.0629 (10)	0.0609 (10)	0.0570 (10)	−0.0274 (9)	0.0208 (8)	−0.0212 (8)
C23	0.0589 (10)	0.0642 (11)	0.0607 (10)	−0.0265 (9)	0.0209 (8)	−0.0252 (9)
C24	0.0634 (11)	0.0686 (12)	0.0645 (11)	−0.0301 (9)	0.0266 (9)	−0.0268 (9)
C25	0.0613 (10)	0.0698 (12)	0.0623 (10)	−0.0303 (9)	0.0229 (9)	−0.0275 (9)
C26	0.0605 (10)	0.0658 (11)	0.0616 (10)	−0.0261 (9)	0.0214 (9)	−0.0249 (9)
C27	0.0634 (11)	0.0632 (11)	0.0679 (11)	−0.0285 (9)	0.0213 (9)	−0.0275 (9)
C28	0.0654 (11)	0.0616 (11)	0.0658 (11)	−0.0271 (9)	0.0217 (9)	−0.0261 (9)
C29	0.0682 (12)	0.0637 (11)	0.0731 (12)	−0.0270 (9)	0.0228 (10)	−0.0279 (10)
C30	0.0715 (12)	0.0821 (14)	0.0890 (14)	−0.0307 (11)	0.0319 (11)	−0.0393 (12)
C31	0.0906 (17)	0.108 (2)	0.138 (2)	−0.0207 (15)	0.0451 (16)	−0.0656 (18)

O1—C8	1.3664 (18)	C18—C19	1.384 (2)
O1—C7	1.436 (2)	C18—H18	0.9300
O2—C15	1.2021 (19)	C19—C20	1.384 (2)
O3—C15	1.363 (2)	C19—C22	1.510 (2)
O3—C16	1.4161 (18)	C20—C21	1.381 (2)
C1—C6	1.362 (3)	C20—H20	0.9300
C1—C2	1.363 (3)	C21—H21	0.9300
C1—H1	0.9300	C22—C23	1.502 (2)
C2—C3	1.377 (3)	C22—H22A	0.9700
C2—H2	0.9300	C22—H22B	0.9700
C3—C4	1.377 (3)	C23—C24	1.519 (2)
C3—H3	0.9300	C23—H23A	0.9700
C4—C5	1.381 (2)	C23—H23B	0.9700
C4—C7	1.494 (2)	C24—C25	1.515 (2)
C5—C6	1.375 (3)	C24—H24A	0.9700
C5—H5	0.9300	C24—H24B	0.9700
C6—H6	0.9300	C25—C26	1.518 (2)
C8—C13	1.382 (2)	C25—H25A	0.9700
C8—C9	1.402 (2)	C25—H25B	0.9700
C7—H7A	0.9700	C26—C27	1.517 (2)
C7—H7B	0.9700	C26—H26A	0.9700
C9—C10	1.382 (2)	C26—H26B	0.9700
C9—C14	1.500 (2)	C27—C28	1.517 (2)
C10—C11	1.396 (2)	C27—H27A	0.9700
C10—H10	0.9300	C27—H27B	0.9700
C11—C12	1.380 (2)	C28—C29	1.509 (2)
C11—C15	1.472 (2)	C28—H28A	0.9700
C12—C13	1.380 (2)	C28—H28B	0.9700
C12—H12	0.9300	C29—C30	1.507 (2)
C13—H13	0.9300	C29—H29A	0.9700
C14—H14A	0.9600	C29—H29B	0.9700
C14—H14B	0.9600	C30—C31	1.512 (3)
C14—H14C	0.9600	C30—H30A	0.9700
C16—C17	1.368 (2)	C30—H30B	0.9700
C16—C21	1.369 (2)	C31—H31A	0.9600
C17—C18	1.380 (2)	C31—H31B	0.9600
C17—H17	0.9300	C31—H31C	0.9600
C8—O1—C7	117.75 (13)	C21—C20—H20	119.1
C15—O3—C16	116.52 (12)	C19—C20—H20	119.1
C6—C1—C2	119.72 (19)	C16—C21—C20	119.21 (15)
C6—C1—H1	120.1	C16—C21—H21	120.4
C2—C1—H1	120.1	C20—C21—H21	120.4
C1—C2—C3	120.29 (19)	C23—C22—C19	116.47 (14)
C1—C2—H2	119.9	C23—C22—H22A	108.2
C3—C2—H2	119.9	C19—C22—H22A	108.2
C2—C3—C4	120.56 (18)	C23—C22—H22B	108.2
C2—C3—H3	119.7	C19—C22—H22B	108.2
C4—C3—H3	119.7	H22A—C22—H22B	107.3
C3—C4—C5	118.56 (16)	C22—C23—C24	113.59 (14)
C3—C4—C7	121.33 (17)	C22—C23—H23A	108.8
C5—C4—C7	120.12 (17)	C24—C23—H23A	108.8
C6—C5—C4	120.29 (17)	C22—C23—H23B	108.8
C6—C5—H5	119.9	C24—C23—H23B	108.8
C4—C5—H5	119.9	H23A—C23—H23B	107.7
C1—C6—C5	120.58 (19)	C25—C24—C23	113.85 (15)
C1—C6—H6	119.7	C25—C24—H24A	108.8
C5—C6—H6	119.7	C23—C24—H24A	108.8
O1—C8—C13	123.80 (14)	C25—C24—H24B	108.8
O1—C8—C9	115.06 (14)	C23—C24—H24B	108.8
C13—C8—C9	121.13 (14)	H24A—C24—H24B	107.7
O1—C7—C4	108.23 (14)	C24—C25—C26	113.16 (15)
O1—C7—H7A	110.1	C24—C25—H25A	108.9
C4—C7—H7A	110.1	C26—C25—H25A	108.9
O1—C7—H7B	110.1	C24—C25—H25B	108.9
C4—C7—H7B	110.1	C26—C25—H25B	108.9
H7A—C7—H7B	108.4	H25A—C25—H25B	107.8
C10—C9—C8	117.95 (14)	C27—C26—C25	114.33 (15)
C10—C9—C14	122.26 (14)	C27—C26—H26A	108.7
C8—C9—C14	119.78 (14)	C25—C26—H26A	108.7
C9—C10—C11	121.69 (15)	C27—C26—H26B	108.7
C9—C10—H10	119.2	C25—C26—H26B	108.7
C11—C10—H10	119.2	H26A—C26—H26B	107.6
C12—C11—C10	118.62 (14)	C28—C27—C26	113.14 (15)
C12—C11—C15	117.55 (14)	C28—C27—H27A	109.0
C10—C11—C15	123.83 (15)	C26—C27—H27A	109.0
C13—C12—C11	121.27 (15)	C28—C27—H27B	109.0
C13—C12—H12	119.4	C26—C27—H27B	109.0
C11—C12—H12	119.4	H27A—C27—H27B	107.8
C12—C13—C8	119.34 (16)	C29—C28—C27	115.36 (16)
C12—C13—H13	120.3	C29—C28—H28A	108.4
C8—C13—H13	120.3	C27—C28—H28A	108.4
C9—C14—H14A	109.5	C29—C28—H28B	108.4
C9—C14—H14B	109.5	C27—C28—H28B	108.4
H14A—C14—H14B	109.5	H28A—C28—H28B	107.5
C9—C14—H14C	109.5	C30—C29—C28	113.17 (16)
H14A—C14—H14C	109.5	C30—C29—H29A	108.9
H14B—C14—H14C	109.5	C28—C29—H29A	108.9
O2—C15—O3	122.27 (15)	C30—C29—H29B	108.9
O2—C15—C11	124.65 (16)	C28—C29—H29B	108.9
O3—C15—C11	113.08 (14)	H29A—C29—H29B	107.8
C17—C16—C21	120.86 (14)	C29—C30—C31	114.4 (2)
C17—C16—O3	118.55 (14)	C29—C30—H30A	108.7
C21—C16—O3	120.56 (14)	C31—C30—H30A	108.7
C16—C17—C18	119.10 (15)	C29—C30—H30B	108.7
C16—C17—H17	120.5	C31—C30—H30B	108.7
C18—C17—H17	120.5	H30A—C30—H30B	107.6
C17—C18—C19	121.97 (16)	C30—C31—H31A	109.5
C17—C18—H18	119.0	C30—C31—H31B	109.5
C19—C18—H18	119.0	H31A—C31—H31B	109.5
C18—C19—C20	117.03 (14)	C30—C31—H31C	109.5
C18—C19—C22	119.99 (15)	H31A—C31—H31C	109.5
C20—C19—C22	122.97 (14)	H31B—C31—H31C	109.5
C21—C20—C19	121.78 (15)
C6—C1—C2—C3	0.5 (3)	C16—O3—C15—C11	177.94 (13)
C1—C2—C3—C4	−0.2 (3)	C12—C11—C15—O2	−2.2 (3)
C2—C3—C4—C5	0.2 (3)	C10—C11—C15—O2	178.07 (17)
C2—C3—C4—C7	−179.54 (17)	C12—C11—C15—O3	177.47 (14)
C3—C4—C5—C6	−0.5 (3)	C10—C11—C15—O3	−2.3 (2)
C7—C4—C5—C6	179.25 (17)	C15—O3—C16—C17	−112.35 (17)
C2—C1—C6—C5	−0.8 (3)	C15—O3—C16—C21	69.6 (2)
C4—C5—C6—C1	0.8 (3)	C21—C16—C17—C18	−1.8 (3)
C7—O1—C8—C13	−1.9 (2)	O3—C16—C17—C18	−179.82 (15)
C7—O1—C8—C9	178.12 (15)	C16—C17—C18—C19	0.0 (3)
C8—O1—C7—C4	−176.37 (14)	C17—C18—C19—C20	1.6 (3)
C3—C4—C7—O1	−65.5 (2)	C17—C18—C19—C22	−177.81 (16)
C5—C4—C7—O1	114.78 (18)	C18—C19—C20—C21	−1.4 (2)
O1—C8—C9—C10	−179.88 (13)	C22—C19—C20—C21	177.94 (16)
C13—C8—C9—C10	0.1 (2)	C17—C16—C21—C20	2.0 (3)
O1—C8—C9—C14	0.6 (2)	O3—C16—C21—C20	179.92 (14)
C13—C8—C9—C14	−179.41 (16)	C19—C20—C21—C16	−0.3 (3)
C8—C9—C10—C11	−0.5 (2)	C18—C19—C22—C23	170.77 (16)
C14—C9—C10—C11	179.02 (16)	C20—C19—C22—C23	−8.6 (3)
C9—C10—C11—C12	0.6 (2)	C19—C22—C23—C24	−173.87 (15)
C9—C10—C11—C15	−179.63 (14)	C22—C23—C24—C25	177.16 (16)
C10—C11—C12—C13	−0.4 (3)	C23—C24—C25—C26	−177.39 (15)
C15—C11—C12—C13	179.87 (15)	C24—C25—C26—C27	−176.29 (16)
C11—C12—C13—C8	0.0 (3)	C25—C26—C27—C28	177.49 (16)
O1—C8—C13—C12	−179.87 (15)	C26—C27—C28—C29	−177.76 (16)
C9—C8—C13—C12	0.1 (3)	C27—C28—C29—C30	177.89 (17)
C16—O3—C15—O2	−2.4 (2)	C28—C29—C30—C31	175.6 (2)

D—H···A	D—H	H···A	D···A	D—H···A
C10—H10···O3	0.93	2.47	2.786 (2)	100
C14—H14A···O1	0.96	2.24	2.726 (3)	110