(±)-2-Methyl-piperazin-1-ium perchlorate.

In the title compound, C(5)H(13)N(2) (+)·ClO(4) (-), the monoprotonated piperazine ring adopts a chair conformation. In the crystal structure, cations and anions are linked by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds into layers parallel to (01).

Related literature

For the properties of simple mol­ecular–ionic crystals, see: Czupiński et al. (2002 ▶); Katrusiak & Szafrański (1999 ▶, 2006 ▶).

Experimental

Crystal data

C5H13N2 +·ClO4 −

M = 200.62

Monoclinic,

a = 6.8977 (5) Å

b = 8.1292 (6) Å

c = 16.2201 (11) Å

β = 98.614 (3)°

V = 899.25 (11) Å3

Z = 4

Mo Kα radiation

μ = 0.41 mm−1

T = 293 K

0.30 × 0.25 × 0.20 mm

Data collection

Rigaku SCXmini diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku, 2005 ▶) T min = 0.80, T max = 0.90

8953 measured reflections

2055 independent reflections

1541 reflections with I > 2σ(I)

R int = 0.040

Refinement

R[F 2 > 2σ(F 2)] = 0.075

wR(F 2) = 0.224

S = 1.05

2055 reflections

109 parameters

H-atom parameters constrained

Δρmax = 0.86 e Å−3

Δρmin = −0.56 e Å−3

Data collection: CrystalClear (Rigaku, 2005 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S160053681002862X/rz2472sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053681002862X/rz2472Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C5H13N2+·ClO4−	F(000) = 424
Mr = 200.62	Dx = 1.482 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71075 Å
Hall symbol: -P 2yn	Cell parameters from 1541 reflections
a = 6.8977 (5) Å	θ = 3.1–27.5°
b = 8.1292 (6) Å	µ = 0.41 mm−1
c = 16.2201 (11) Å	T = 293 K
β = 98.614 (3)°	Block, colourless
V = 899.25 (11) Å3	0.30 × 0.25 × 0.20 mm
Z = 4

Rigaku SCXmini diffractometer	2055 independent reflections
Radiation source: fine-focus sealed tube	1541 reflections with I > 2σ(I)
graphite	Rint = 0.040
Detector resolution: 13.6612 pixels mm-1	θmax = 27.5°, θmin = 3.1°
ω scans	h = −8→8
Absorption correction: multi-scan (CrystalClear; Rigaku, 2005)	k = −10→10
Tmin = 0.80, Tmax = 0.90	l = −21→20
8953 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.075	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.224	H-atom parameters constrained
S = 1.05	w = 1/[σ2(Fo2) + (0.1123P)2 + 1.4914P] where P = (Fo2 + 2Fc2)/3
2055 reflections	(Δ/σ)max < 0.001
109 parameters	Δρmax = 0.86 e Å−3
0 restraints	Δρmin = −0.56 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.4992 (5)	0.6921 (5)	0.6807 (2)	0.0414 (8)
H1B	0.5975	0.7730	0.7019	0.050*
H1A	0.5525	0.6233	0.6407	0.050*
C2	0.4487 (5)	0.5875 (5)	0.7518 (2)	0.0406 (8)
H2A	0.5644	0.5267	0.7759	0.049*
H2B	0.4118	0.6591	0.7947	0.049*
C3	0.1170 (5)	0.5531 (5)	0.6809 (2)	0.0389 (8)
H3A	0.0599	0.6227	0.7194	0.047*
H3B	0.0205	0.4703	0.6603	0.047*
C4	0.1591 (5)	0.6579 (5)	0.6075 (2)	0.0384 (8)
H4A	0.2062	0.5856	0.5664	0.046*
C5	−0.0190 (7)	0.7490 (7)	0.5654 (3)	0.0646 (13)
H5A	0.0152	0.8117	0.5196	0.097*
H5B	−0.0656	0.8218	0.6048	0.097*
H5C	−0.1201	0.6716	0.5452	0.097*
Cl1	0.56264 (14)	0.19954 (12)	0.59443 (6)	0.0442 (4)
N1	0.2890 (5)	0.4712 (4)	0.7261 (2)	0.0392 (7)
H1C	0.3305	0.3941	0.6929	0.047*
N2	0.3194 (4)	0.7764 (3)	0.63945 (18)	0.0352 (7)
H2D	0.3494	0.8369	0.5966	0.042*
H2C	0.2761	0.8453	0.6761	0.042*
O1	0.3667 (7)	0.1613 (7)	0.6079 (3)	0.1041 (16)
O2	0.5363 (11)	0.2923 (9)	0.5226 (3)	0.154 (3)
O3	0.6614 (5)	0.2921 (5)	0.6628 (2)	0.0759 (11)
O4	0.6557 (9)	0.0550 (9)	0.5835 (6)	0.215 (5)

	U11	U22	U33	U12	U13	U23
C1	0.0355 (18)	0.044 (2)	0.046 (2)	−0.0020 (15)	0.0098 (15)	0.0026 (16)
C2	0.0404 (19)	0.0397 (19)	0.0410 (19)	0.0043 (15)	0.0037 (15)	0.0042 (15)
C3	0.0395 (19)	0.0380 (18)	0.0401 (18)	−0.0068 (15)	0.0095 (15)	−0.0047 (15)
C4	0.043 (2)	0.0402 (19)	0.0315 (17)	−0.0016 (15)	0.0028 (14)	−0.0028 (14)
C5	0.054 (3)	0.079 (3)	0.056 (3)	0.010 (2)	−0.007 (2)	0.004 (2)
Cl1	0.0500 (6)	0.0457 (6)	0.0378 (5)	0.0080 (4)	0.0094 (4)	−0.0044 (4)
N1	0.0481 (18)	0.0298 (14)	0.0415 (16)	0.0004 (13)	0.0130 (13)	0.0016 (12)
N2	0.0422 (16)	0.0319 (15)	0.0329 (15)	−0.0012 (12)	0.0103 (12)	0.0013 (12)
O1	0.089 (3)	0.149 (4)	0.080 (3)	−0.040 (3)	0.034 (2)	−0.028 (3)
O2	0.196 (7)	0.199 (7)	0.067 (3)	−0.086 (5)	0.017 (3)	0.048 (4)
O3	0.072 (2)	0.076 (2)	0.074 (2)	0.0078 (18)	−0.0083 (19)	−0.0251 (19)
O4	0.132 (5)	0.151 (5)	0.318 (11)	0.089 (4)	−0.105 (6)	−0.155 (7)

C1—N2	1.485 (5)	C4—C5	1.507 (6)
C1—C2	1.514 (5)	C4—H4A	0.9800
C1—H1B	0.9700	C5—H5A	0.9600
C1—H1A	0.9700	C5—H5B	0.9600
C2—N1	1.465 (5)	C5—H5C	0.9600
C2—H2A	0.9700	Cl1—O4	1.363 (5)
C2—H2B	0.9700	Cl1—O2	1.377 (5)
C3—N1	1.459 (5)	Cl1—O3	1.426 (4)
C3—C4	1.526 (5)	Cl1—O1	1.436 (4)
C3—H3A	0.9700	N1—H1C	0.8998
C3—H3B	0.9700	N2—H2D	0.9000
C4—N2	1.500 (5)	N2—H2C	0.9000
N2—C1—C2	109.3 (3)	C3—C4—H4A	108.5
N2—C1—H1B	109.8	C4—C5—H5A	109.5
C2—C1—H1B	109.8	C4—C5—H5B	109.5
N2—C1—H1A	109.8	H5A—C5—H5B	109.5
C2—C1—H1A	109.8	C4—C5—H5C	109.5
H1B—C1—H1A	108.3	H5A—C5—H5C	109.5
N1—C2—C1	113.3 (3)	H5B—C5—H5C	109.5
N1—C2—H2A	108.9	O4—Cl1—O2	111.5 (6)
C1—C2—H2A	108.9	O4—Cl1—O3	112.1 (3)
N1—C2—H2B	108.9	O2—Cl1—O3	110.9 (3)
C1—C2—H2B	108.9	O4—Cl1—O1	107.8 (5)
H2A—C2—H2B	107.7	O2—Cl1—O1	103.9 (4)
N1—C3—C4	114.3 (3)	O3—Cl1—O1	110.3 (2)
N1—C3—H3A	108.7	C3—N1—C2	111.6 (3)
C4—C3—H3A	108.7	C3—N1—H1C	109.0
N1—C3—H3B	108.7	C2—N1—H1C	109.1
C4—C3—H3B	108.7	C1—N2—C4	112.5 (3)
H3A—C3—H3B	107.6	C1—N2—H2D	109.1
N2—C4—C5	110.5 (3)	C4—N2—H2D	109.1
N2—C4—C3	107.8 (3)	C1—N2—H2C	109.1
C5—C4—C3	113.0 (4)	C4—N2—H2C	109.1
N2—C4—H4A	108.5	H2D—N2—H2C	107.8
C5—C4—H4A	108.5
N2—C1—C2—N1	54.6 (4)	C1—C2—N1—C3	−52.3 (4)
N1—C3—C4—N2	−54.1 (4)	C2—C1—N2—C4	−57.7 (4)
N1—C3—C4—C5	−176.4 (3)	C5—C4—N2—C1	−179.4 (3)
C4—C3—N1—C2	52.7 (4)	C3—C4—N2—C1	56.8 (4)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1C···O1	0.90	2.38	3.258 (6)	166
N1—H1C···O3	0.90	2.54	3.250 (5)	136
N2—H2D···O2i	0.90	2.43	2.998 (7)	121
N2—H2C···N1ii	0.90	1.99	2.883 (4)	169

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1C⋯O1	0.90	2.38	3.258 (6)	166
N1—H1C⋯O3	0.90	2.54	3.250 (5)	136
N2—H2D⋯O2i	0.90	2.43	2.998 (7)	121
N2—H2C⋯N1ii	0.90	1.99	2.883 (4)	169

Symmetry codes: (i) ; (ii) .