catena-Poly[[(1,10-phenanthroline)lead(II)]bis-(μ-5-chloro-2-hy-droxy-benzoato)].

In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))](n), the Pb(II) ion displays a distorted pseudo-octa-hedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chloro-salicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric structure is built up from bridging carboxyl-ate O atoms, forming chains along [100]. The crystal structure is stabilized by π-π inter-actions between the 1,10-phenanthroline and 5-chloro-salicylate ligands, the shortest centroid-centroid separation between neighbouring aromatic rings being 3.652 (1) Å.

Related literature

For related non-polymeric complexes including 5-chloro­salicylate ligands, see: Wen & Ying (2007 ▶); Wen et al. (2008 ▶).

Experimental

Crystal data

[Pb(C7H4ClO3)2(C12H8N2)]

M = 730.51

Triclinic,

a = 8.9100 (1) Å

b = 11.2959 (1) Å

c = 13.5816 (1) Å

α = 75.508 (1)°

β = 86.302 (1)°

γ = 68.342 (1)°

V = 1229.43 (2) Å3

Z = 2

Mo Kα radiation

μ = 7.13 mm−1

T = 296 K

0.28 × 0.25 × 0.24 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T min = 0.156, T max = 0.181

21579 measured reflections

5987 independent reflections

5339 reflections with I > 2σ(I)

R int = 0.029

Refinement

R[F 2 > 2σ(F 2)] = 0.025

wR(F 2) = 0.064

S = 1.05

5987 reflections

334 parameters

H-atom parameters constrained

Δρmax = 1.18 e Å−3

Δρmin = −0.59 e Å−3

Data collection: APEX2 (Bruker, 2001 ▶); cell refinement: SAINT (Bruker, 2001 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810023561/bh2289sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810023561/bh2289Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Pb(C7H4ClO3)2(C12H8N2)]	Z = 2
Mr = 730.51	F(000) = 700
Triclinic, P1	Dx = 1.973 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.9100 (1) Å	Cell parameters from 5987 reflections
b = 11.2959 (1) Å	θ = 2.8–26.9°
c = 13.5816 (1) Å	µ = 7.13 mm−1
α = 75.508 (1)°	T = 296 K
β = 86.302 (1)°	Block, yellow
γ = 68.342 (1)°	0.28 × 0.25 × 0.24 mm
V = 1229.43 (2) Å3

Bruker APEXII CCD diffractometer	5987 independent reflections
Radiation source: fine-focus sealed tube	5339 reflections with I > 2σ(I)
graphite	Rint = 0.029
φ and ω scans	θmax = 28.2°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 2001)	h = −11→11
Tmin = 0.156, Tmax = 0.181	k = −14→14
21579 measured reflections	l = −18→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.025	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.064	H-atom parameters constrained
S = 1.05	w = 1/[σ2(Fo2) + (0.0349P)2 + 0.472P] where P = (Fo2 + 2Fc2)/3
5987 reflections	(Δ/σ)max = 0.001
334 parameters	Δρmax = 1.18 e Å−3
0 restraints	Δρmin = −0.59 e Å−3
0 constraints

	x	y	z	Uiso*/Ueq
Pb1	0.258486 (14)	−0.038882 (12)	−0.001073 (10)	0.03675 (5)
Cl1	1.04796 (14)	−0.31797 (16)	0.36720 (10)	0.0779 (4)
Cl2	−0.2949 (2)	−0.0117 (2)	0.47404 (14)	0.1106 (6)
O5	0.0025 (3)	0.0001 (3)	0.1216 (2)	0.0495 (6)
O1	0.5607 (4)	−0.1240 (3)	0.0939 (2)	0.0548 (7)
O2	0.3533 (3)	−0.1567 (3)	0.1750 (2)	0.0569 (7)
O4	0.1160 (4)	0.1481 (3)	0.1053 (2)	0.0604 (8)
N1	0.2350 (4)	−0.2615 (3)	0.0256 (2)	0.0423 (7)
N2	0.4307 (4)	−0.1896 (3)	−0.1218 (3)	0.0449 (7)
C12	0.2979 (4)	−0.3371 (3)	−0.0407 (3)	0.0394 (8)
O3	0.3774 (4)	−0.2835 (5)	0.3602 (3)	0.0882 (13)
H3B	0.3326	−0.2436	0.3043	0.132*
C11	0.3981 (4)	−0.2980 (4)	−0.1197 (3)	0.0409 (8)
C13	0.5001 (4)	−0.1665 (3)	0.1727 (3)	0.0417 (8)
C14	0.5973 (4)	−0.2334 (4)	0.2701 (3)	0.0421 (8)
C15	0.5322 (5)	−0.2888 (6)	0.3575 (3)	0.0609 (12)
C7	0.4610 (5)	−0.3747 (4)	−0.1912 (3)	0.0509 (10)
C8	0.5574 (6)	−0.3329 (5)	−0.2661 (4)	0.0615 (12)
H8A	0.6005	−0.3804	−0.3148	0.074*
O6	0.0401 (4)	0.3062 (3)	0.2185 (3)	0.0704 (9)
H6B	0.0809	0.2756	0.1702	0.106*
C21	−0.0455 (4)	0.1217 (4)	0.2486 (3)	0.0419 (8)
C4	0.2689 (5)	−0.4538 (4)	−0.0344 (4)	0.0496 (9)
C1	0.1447 (5)	−0.2992 (4)	0.0995 (3)	0.0506 (9)
H1A	0.1000	−0.2465	0.1446	0.061*
C22	−0.0349 (5)	0.2293 (5)	0.2767 (3)	0.0512 (10)
C19	0.7579 (5)	−0.2452 (4)	0.2740 (3)	0.0449 (8)
H19A	0.8040	−0.2107	0.2160	0.054*
C20	0.0289 (4)	0.0873 (4)	0.1522 (3)	0.0447 (9)
C9	0.5890 (6)	−0.2234 (5)	−0.2688 (4)	0.0634 (12)
H9A	0.6523	−0.1946	−0.3191	0.076*
C2	0.1143 (6)	−0.4148 (5)	0.1118 (4)	0.0590 (11)
H2A	0.0533	−0.4396	0.1655	0.071*
C10	0.5239 (5)	−0.1554 (5)	−0.1941 (3)	0.0551 (10)
H10A	0.5475	−0.0814	−0.1952	0.066*
C26	−0.1257 (5)	0.0475 (4)	0.3101 (3)	0.0510 (9)
H26A	−0.1347	−0.0236	0.2916	0.061*
C3	0.1744 (6)	−0.4899 (4)	0.0450 (4)	0.0616 (12)
H3A	0.1529	−0.5660	0.0517	0.074*
C5	0.3351 (6)	−0.5275 (5)	−0.1086 (4)	0.0664 (13)
H5A	0.3147	−0.6033	−0.1054	0.080*
C6	0.4259 (6)	−0.4894 (5)	−0.1825 (4)	0.0660 (13)
H6A	0.4673	−0.5396	−0.2297	0.079*
C25	−0.1914 (6)	0.0793 (5)	0.3981 (3)	0.0638 (12)
C24	−0.1821 (6)	0.1881 (6)	0.4256 (4)	0.0740 (15)
H24A	−0.2285	0.2099	0.4851	0.089*
C23	−0.1051 (6)	0.2610 (6)	0.3650 (4)	0.0688 (13)
H23A	−0.0993	0.3335	0.3830	0.083*
C18	0.8483 (5)	−0.3069 (5)	0.3622 (3)	0.0616 (12)
C17	0.7827 (7)	−0.3620 (7)	0.4485 (4)	0.0867 (19)
H17A	0.8447	−0.4035	0.5085	0.104*
C16	0.6277 (7)	−0.3553 (7)	0.4453 (4)	0.090 (2)
H16A	0.5853	−0.3956	0.5025	0.108*

	U11	U22	U33	U12	U13	U23
Pb1	0.03379 (8)	0.04199 (8)	0.03692 (8)	−0.01778 (5)	0.00344 (5)	−0.00846 (5)
Cl1	0.0494 (6)	0.1113 (10)	0.0641 (8)	−0.0373 (7)	−0.0139 (5)	0.0104 (7)
Cl2	0.1064 (12)	0.1390 (15)	0.0809 (10)	−0.0634 (11)	0.0396 (9)	0.0020 (10)
O5	0.0489 (15)	0.0541 (15)	0.0449 (16)	−0.0154 (13)	−0.0012 (12)	−0.0156 (13)
O1	0.0612 (18)	0.0596 (17)	0.0402 (16)	−0.0272 (15)	−0.0072 (13)	0.0037 (13)
O2	0.0420 (15)	0.0743 (19)	0.0543 (18)	−0.0233 (14)	−0.0065 (13)	−0.0106 (15)
O4	0.0583 (18)	0.072 (2)	0.0588 (19)	−0.0311 (16)	0.0224 (15)	−0.0228 (16)
N1	0.0386 (16)	0.0421 (15)	0.0465 (18)	−0.0169 (13)	0.0001 (13)	−0.0076 (13)
N2	0.0396 (16)	0.0503 (18)	0.0479 (19)	−0.0189 (14)	0.0051 (14)	−0.0144 (15)
C12	0.0337 (17)	0.0355 (17)	0.044 (2)	−0.0068 (14)	−0.0094 (15)	−0.0072 (14)
O3	0.054 (2)	0.168 (4)	0.055 (2)	−0.063 (2)	0.0100 (16)	−0.016 (2)
C11	0.0334 (17)	0.0426 (18)	0.043 (2)	−0.0090 (15)	−0.0082 (15)	−0.0089 (15)
C13	0.0431 (19)	0.0386 (18)	0.046 (2)	−0.0132 (15)	−0.0020 (16)	−0.0157 (16)
C14	0.0409 (19)	0.051 (2)	0.038 (2)	−0.0194 (16)	0.0004 (15)	−0.0123 (16)
C15	0.052 (2)	0.097 (4)	0.042 (2)	−0.037 (2)	0.0066 (19)	−0.017 (2)
C7	0.047 (2)	0.049 (2)	0.048 (2)	−0.0041 (17)	−0.0109 (18)	−0.0144 (18)
C8	0.059 (3)	0.073 (3)	0.045 (2)	−0.010 (2)	0.003 (2)	−0.023 (2)
O6	0.068 (2)	0.075 (2)	0.085 (3)	−0.0421 (18)	0.0217 (18)	−0.0284 (19)
C21	0.0324 (17)	0.054 (2)	0.0364 (19)	−0.0137 (16)	−0.0002 (14)	−0.0095 (16)
C4	0.050 (2)	0.0374 (19)	0.058 (2)	−0.0137 (17)	−0.0157 (19)	−0.0045 (17)
C1	0.050 (2)	0.051 (2)	0.050 (2)	−0.0226 (18)	0.0022 (18)	−0.0045 (18)
C22	0.038 (2)	0.065 (3)	0.052 (2)	−0.0196 (19)	0.0005 (17)	−0.016 (2)
C19	0.0416 (19)	0.052 (2)	0.039 (2)	−0.0193 (17)	0.0012 (16)	−0.0035 (16)
C20	0.0338 (18)	0.055 (2)	0.040 (2)	−0.0095 (16)	−0.0021 (15)	−0.0103 (17)
C9	0.053 (3)	0.079 (3)	0.055 (3)	−0.020 (2)	0.010 (2)	−0.017 (2)
C2	0.054 (2)	0.058 (3)	0.061 (3)	−0.029 (2)	0.000 (2)	0.005 (2)
C10	0.050 (2)	0.064 (3)	0.056 (3)	−0.026 (2)	0.014 (2)	−0.018 (2)
C26	0.044 (2)	0.061 (2)	0.046 (2)	−0.0218 (19)	0.0014 (17)	−0.0048 (18)
C3	0.061 (3)	0.046 (2)	0.078 (3)	−0.027 (2)	−0.011 (2)	−0.003 (2)
C5	0.072 (3)	0.045 (2)	0.085 (4)	−0.019 (2)	−0.014 (3)	−0.021 (2)
C6	0.073 (3)	0.054 (2)	0.069 (3)	−0.010 (2)	−0.007 (3)	−0.029 (2)
C25	0.052 (2)	0.088 (3)	0.043 (2)	−0.028 (2)	0.0101 (19)	0.000 (2)
C24	0.061 (3)	0.111 (4)	0.047 (3)	−0.022 (3)	0.012 (2)	−0.030 (3)
C23	0.065 (3)	0.087 (3)	0.063 (3)	−0.028 (3)	0.011 (2)	−0.036 (3)
C18	0.049 (2)	0.090 (3)	0.044 (2)	−0.033 (2)	−0.0051 (19)	−0.001 (2)
C17	0.068 (3)	0.146 (6)	0.042 (3)	−0.053 (4)	−0.011 (2)	0.010 (3)
C16	0.078 (4)	0.157 (6)	0.040 (3)	−0.067 (4)	0.001 (2)	0.006 (3)

Pb1—O2	2.458 (3)	C8—H8A	0.9300
Pb1—O5	2.703 (3)	O6—C22	1.358 (6)
Pb1—O4	2.734 (3)	O6—H6B	0.8200
Pb1—O5i	2.768 (3)	C21—C26	1.388 (6)
Pb1—O1	2.785 (3)	C21—C22	1.399 (6)
Pb1—O1ii	2.887 (3)	C21—C20	1.502 (5)
Pb1—N1	2.534 (3)	C4—C3	1.398 (7)
Pb1—N2	2.662 (3)	C4—C5	1.426 (7)
Cl1—C18	1.742 (4)	C1—C2	1.397 (6)
Cl2—C25	1.737 (5)	C1—H1A	0.9300
O5—C20	1.259 (5)	C22—C23	1.382 (6)
O5—Pb1i	2.768 (3)	C19—C18	1.364 (6)
O1—C13	1.235 (5)	C19—H19A	0.9300
O1—Pb1ii	2.887 (3)	C9—C10	1.393 (7)
O2—C13	1.270 (5)	C9—H9A	0.9300
O4—C20	1.261 (5)	C2—C3	1.348 (7)
N1—C1	1.331 (5)	C2—H2A	0.9300
N1—C12	1.350 (5)	C10—H10A	0.9300
N2—C10	1.321 (5)	C26—C25	1.366 (6)
N2—C11	1.353 (5)	C26—H26A	0.9300
C12—C4	1.416 (5)	C3—H3A	0.9300
C12—C11	1.439 (5)	C5—C6	1.336 (8)
O3—C15	1.357 (5)	C5—H5A	0.9300
O3—H3B	0.8200	C6—H6A	0.9300
C11—C7	1.415 (5)	C25—C24	1.402 (8)
C13—C14	1.495 (5)	C24—C23	1.354 (8)
C14—C19	1.390 (5)	C24—H24A	0.9300
C14—C15	1.395 (6)	C23—H23A	0.9300
C15—C16	1.386 (7)	C18—C17	1.385 (7)
C7—C8	1.394 (7)	C17—C16	1.358 (7)
C7—C6	1.417 (7)	C17—H17A	0.9300
C8—C9	1.358 (7)	C16—H16A	0.9300
O2—Pb1—N1	74.00 (10)	O2—C13—C14	116.7 (4)
O2—Pb1—N2	107.51 (10)	O1—C13—Pb1	68.5 (2)
N1—Pb1—N2	63.52 (10)	O2—C13—Pb1	53.5 (2)
O2—Pb1—O5	70.89 (9)	C14—C13—Pb1	170.2 (3)
N1—Pb1—O5	81.85 (9)	C19—C14—C15	118.5 (4)
N2—Pb1—O5	143.50 (9)	C19—C14—C13	120.0 (3)
O2—Pb1—O4	76.94 (10)	C15—C14—C13	121.5 (3)
N1—Pb1—O4	128.10 (10)	O3—C15—C16	117.5 (4)
N2—Pb1—O4	168.25 (9)	O3—C15—C14	122.5 (4)
O5—Pb1—O4	48.05 (9)	C16—C15—C14	120.0 (4)
O2—Pb1—O5i	135.16 (9)	C8—C7—C11	117.1 (4)
N1—Pb1—O5i	73.83 (9)	C8—C7—C6	123.7 (4)
N2—Pb1—O5i	84.71 (9)	C11—C7—C6	119.2 (4)
O5—Pb1—O5i	74.36 (9)	C9—C8—C7	120.6 (4)
O4—Pb1—O5i	99.85 (9)	C9—C8—H8A	119.7
O2—Pb1—O1	48.91 (9)	C7—C8—H8A	119.7
N1—Pb1—O1	97.78 (9)	C22—O6—H6B	109.5
N2—Pb1—O1	81.42 (10)	C26—C21—C22	119.5 (4)
O5—Pb1—O1	116.23 (9)	C26—C21—C20	120.4 (4)
O4—Pb1—O1	94.20 (10)	C22—C21—C20	120.1 (4)
O5i—Pb1—O1	165.95 (9)	C3—C4—C12	117.3 (4)
O2—Pb1—O1ii	111.66 (9)	C3—C4—C5	123.5 (4)
N1—Pb1—O1ii	145.69 (10)	C12—C4—C5	119.2 (4)
N2—Pb1—O1ii	83.09 (9)	N1—C1—C2	122.6 (4)
O5—Pb1—O1ii	132.42 (9)	N1—C1—H1A	118.7
O4—Pb1—O1ii	85.17 (9)	C2—C1—H1A	118.7
O5i—Pb1—O1ii	112.58 (8)	O6—C22—C23	118.4 (4)
O1—Pb1—O1ii	68.01 (9)	O6—C22—C21	121.9 (4)
O2—Pb1—C13	24.55 (10)	C23—C22—C21	119.7 (4)
N1—Pb1—C13	85.87 (10)	C18—C19—C14	120.6 (4)
N2—Pb1—C13	94.97 (10)	C18—C19—H19A	119.7
O5—Pb1—C13	93.59 (10)	C14—C19—H19A	119.7
O4—Pb1—C13	84.95 (10)	O5—C20—O4	122.8 (4)
O5i—Pb1—C13	157.51 (10)	O5—C20—C21	119.4 (4)
O1—Pb1—C13	24.36 (9)	O4—C20—C21	117.8 (4)
O1ii—Pb1—C13	89.63 (10)	O5—C20—Pb1	62.0 (2)
O2—Pb1—C20	68.44 (10)	O4—C20—Pb1	63.4 (2)
N1—Pb1—C20	103.98 (11)	C21—C20—Pb1	163.5 (2)
N2—Pb1—C20	167.39 (11)	C8—C9—C10	118.2 (5)
O5—Pb1—C20	24.29 (10)	C8—C9—H9A	120.9
O4—Pb1—C20	24.36 (10)	C10—C9—H9A	120.9
O5i—Pb1—C20	90.21 (9)	C3—C2—C1	119.2 (4)
O1—Pb1—C20	102.90 (9)	C3—C2—H2A	120.4
O1ii—Pb1—C20	109.53 (11)	C1—C2—H2A	120.4
C13—Pb1—C20	85.33 (10)	N2—C10—C9	124.0 (5)
O2—Pb1—Pb1i	104.32 (7)	N2—C10—H10A	118.0
N1—Pb1—Pb1i	74.65 (7)	C9—C10—H10A	118.0
N2—Pb1—Pb1i	116.10 (7)	C25—C26—C21	119.7 (4)
O5—Pb1—Pb1i	37.70 (6)	C25—C26—H26A	120.1
O4—Pb1—Pb1i	72.18 (7)	C21—C26—H26A	120.1
O5i—Pb1—Pb1i	36.66 (6)	C2—C3—C4	120.3 (4)
O1—Pb1—Pb1i	152.88 (6)	C2—C3—H3A	119.8
O1ii—Pb1—Pb1i	131.46 (6)	C4—C3—H3A	119.8
C13—Pb1—Pb1i	128.72 (8)	C6—C5—C4	121.2 (4)
C20—Pb1—Pb1i	55.75 (7)	C6—C5—H5A	119.4
C20—O5—Pb1	93.7 (2)	C4—C5—H5A	119.4
C20—O5—Pb1i	126.0 (2)	C5—C6—C7	121.9 (4)
Pb1—O5—Pb1i	105.64 (9)	C5—C6—H6A	119.0
C13—O1—Pb1	87.2 (2)	C7—C6—H6A	119.0
C13—O1—Pb1ii	145.9 (3)	C26—C25—C24	120.7 (4)
Pb1—O1—Pb1ii	111.99 (9)	C26—C25—Cl2	119.8 (4)
C13—O2—Pb1	101.9 (3)	C24—C25—Cl2	119.5 (4)
C20—O4—Pb1	92.2 (2)	C23—C24—C25	119.5 (4)
C1—N1—C12	118.6 (3)	C23—C24—H24A	120.3
C1—N1—Pb1	119.9 (3)	C25—C24—H24A	120.3
C12—N1—Pb1	121.1 (2)	C24—C23—C22	120.9 (5)
C10—N2—C11	117.9 (4)	C24—C23—H23A	119.6
C10—N2—Pb1	124.7 (3)	C22—C23—H23A	119.6
C11—N2—Pb1	116.5 (2)	C19—C18—C17	120.4 (4)
N1—C12—C4	121.9 (4)	C19—C18—Cl1	120.3 (3)
N1—C12—C11	118.9 (3)	C17—C18—Cl1	119.3 (4)
C4—C12—C11	119.2 (4)	C16—C17—C18	119.9 (5)
C15—O3—H3B	109.5	C16—C17—H17A	120.1
N2—C11—C7	122.2 (4)	C18—C17—H17A	120.1
N2—C11—C12	118.5 (3)	C17—C16—C15	120.5 (5)
C7—C11—C12	119.3 (4)	C17—C16—H16A	119.8
O1—C13—O2	122.0 (4)	C15—C16—H16A	119.8
O1—C13—C14	121.3 (3)