Bis(dimethyl sulfoxide)-hydridobis(triphenyl-phosphane)cobalt(I).

The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl-phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol-yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.

Related literature

For the hydro­formyl­ation of alkenes, see: Roelen (1938 ▶). Derivatives of the title compound, starting from Co2(CO)8, have been synthesized by reaction with hydrogen, see: Hieber & Leutert (1931 ▶). A related compound, [HCo(P(OEt)3)4], obtained by reaction of cobalt halides and sodium borohydride has been reported by Kruse & Atalla (1968 ▶). Its mol­ecular structure in the crystal was determined by Choi & Park (2003 ▶).

Experimental

Crystal data

[CoH(C18H15P)2(C2H6OS)2]

M = 740.73

Monoclinic,

a = 10.5625 (2) Å

b = 21.4211 (3) Å

c = 15.8427 (4) Å

β = 93.4988 (18)°

V = 3577.88 (13) Å3

Z = 4

Mo Kα radiation

μ = 0.72 mm−1

T = 200 K

0.50 × 0.27 × 0.12 mm

Data collection

Stoe IPDS II diffractometer

Absorption correction: numerical (X-SHAPE and X-RED32; Stoe & Cie, 2005 ▶) T min = 0.786, T max = 0.918

59344 measured reflections

8221 independent reflections

6773 reflections with I > 2σ(I)

R int = 0.032

Refinement

R[F 2 > 2σ(F 2)] = 0.026

wR(F 2) = 0.070

S = 0.96

8221 reflections

432 parameters

3 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.37 e Å−3

Δρmin = −0.25 e Å−3

Data collection: X-AREA (Stoe & Cie, 2005 ▶); cell refinement: X-AREA; data reduction: X-AREA; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: XP in SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810029466/bt5307sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810029466/bt5307Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[CoH(C18H15P)2(C2H6OS)2]	F(000) = 1552
Mr = 740.73	Dx = 1.375 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 11909 reflections
a = 10.5625 (2) Å	θ = 1.6–28.4°
b = 21.4211 (3) Å	µ = 0.72 mm−1
c = 15.8427 (4) Å	T = 200 K
β = 93.4988 (18)°	Prism, orange
V = 3577.88 (13) Å3	0.50 × 0.27 × 0.12 mm
Z = 4

Stoe IPDS II diffractometer	8221 independent reflections
Radiation source: fine-focus sealed tube	6773 reflections with I > 2σ(I)
graphite	Rint = 0.032
ω scans	θmax = 27.5°, θmin = 1.6°
Absorption correction: numerical (X-SHAPE and X-RED32; Stoe & Cie, 2005)	h = −13→13
Tmin = 0.786, Tmax = 0.918	k = −27→26
59344 measured reflections	l = −20→20

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.026	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.070	H atoms treated by a mixture of independent and constrained refinement
S = 0.96	w = 1/[σ2(Fo2) + (0.0493P)2] where P = (Fo2 + 2Fc2)/3
8221 reflections	(Δ/σ)max = 0.001
432 parameters	Δρmax = 0.37 e Å−3
3 restraints	Δρmin = −0.24 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.84405 (12)	0.29130 (6)	0.07852 (8)	0.0229 (3)
C2	0.84028 (15)	0.28531 (7)	−0.00879 (9)	0.0304 (3)
H2A	0.8703	0.2481	−0.0334	0.036*
C3	0.79306 (18)	0.33323 (6)	−0.06027 (10)	0.0415 (4)
H3A	0.7904	0.3285	−0.1200	0.050*
C4	0.74978 (17)	0.38784 (7)	−0.02578 (11)	0.0401 (4)
H4A	0.7141	0.4198	−0.0614	0.048*
C5	0.75878 (17)	0.39566 (8)	0.06092 (11)	0.0382 (4)
H5A	0.7324	0.4337	0.0852	0.046*
C6	0.80645 (16)	0.34784 (7)	0.11226 (10)	0.0328 (3)
H6A	0.8137	0.3537	0.1718	0.039*
C7	1.02598 (12)	0.26634 (6)	0.21005 (8)	0.0222 (3)
C8	1.04236 (13)	0.26494 (7)	0.29762 (9)	0.0258 (3)
H8A	0.9809	0.2445	0.3292	0.031*
C9	1.14670 (15)	0.29276 (7)	0.33999 (10)	0.0316 (3)
H9A	1.1553	0.2921	0.4000	0.038*
C10	1.23767 (15)	0.32124 (7)	0.29451 (11)	0.0348 (3)
H10A	1.3111	0.3387	0.3230	0.042*
C11	1.22190 (14)	0.32440 (7)	0.20740 (11)	0.0324 (3)
H11A	1.2838	0.3448	0.1762	0.039*
C12	1.11604 (14)	0.29798 (7)	0.16529 (9)	0.0271 (3)
H12A	1.1047	0.3014	0.1055	0.033*
C13	0.96617 (13)	0.17149 (6)	0.08568 (8)	0.0228 (3)
C14	1.09483 (14)	0.15752 (7)	0.09201 (9)	0.0289 (3)
H14A	1.1501	0.1804	0.1301	0.035*
C15	1.14359 (16)	0.11037 (8)	0.04310 (10)	0.0349 (3)
H15A	1.2316	0.1011	0.0485	0.042*
C16	1.06507 (16)	0.07706 (7)	−0.01308 (10)	0.0336 (3)
H16A	1.0988	0.0451	−0.0467	0.040*
C17	0.93693 (16)	0.09046 (7)	−0.02010 (10)	0.0327 (3)
H17A	0.8824	0.0678	−0.0590	0.039*
C18	0.88760 (14)	0.13677 (7)	0.02925 (9)	0.0270 (3)
H18A	0.7991	0.1451	0.0247	0.032*
C19	0.91922 (13)	0.05062 (7)	0.25711 (8)	0.0249 (3)
C20	1.03066 (13)	0.08500 (7)	0.26426 (10)	0.0303 (3)
H20A	1.0268	0.1289	0.2727	0.036*
C21	1.14762 (14)	0.05622 (7)	0.25922 (10)	0.0365 (4)
H21A	1.2230	0.0805	0.2642	0.044*
C22	1.15513 (16)	−0.00756 (8)	0.24693 (10)	0.0382 (4)
H22A	1.2351	−0.0272	0.2425	0.046*
C23	1.04497 (17)	−0.04240 (8)	0.24121 (11)	0.0405 (4)
H23A	1.0492	−0.0863	0.2337	0.049*
C24	0.92830 (15)	−0.01364 (7)	0.24641 (10)	0.0336 (3)
H24A	0.8533	−0.0382	0.2426	0.040*
C25	0.66405 (13)	0.02838 (7)	0.21015 (9)	0.0254 (3)
C26	0.67228 (14)	0.02436 (7)	0.12283 (9)	0.0295 (3)
H26A	0.7227	0.0536	0.0948	0.035*
C27	0.60789 (15)	−0.02173 (8)	0.07636 (10)	0.0344 (3)
H27A	0.6162	−0.0245	0.0171	0.041*
C28	0.53165 (16)	−0.06371 (8)	0.11571 (11)	0.0391 (4)
H28A	0.4861	−0.0948	0.0836	0.047*
C29	0.52226 (16)	−0.06019 (8)	0.20204 (11)	0.0385 (4)
H29A	0.4700	−0.0890	0.2294	0.046*
C30	0.58849 (14)	−0.01489 (7)	0.24947 (10)	0.0313 (3)
H30A	0.5822	−0.0134	0.3090	0.038*
C31	0.73647 (14)	0.07445 (6)	0.37623 (9)	0.0254 (3)
C32	0.83543 (15)	0.06171 (7)	0.43584 (9)	0.0316 (3)
H32A	0.9193	0.0574	0.4181	0.038*
C33	0.81317 (16)	0.05521 (8)	0.52067 (9)	0.0395 (4)
H33A	0.8819	0.0474	0.5608	0.047*
C34	0.69134 (18)	0.06003 (8)	0.54708 (10)	0.0419 (4)
H34A	0.6757	0.0542	0.6050	0.050*
C35	0.59222 (18)	0.07343 (8)	0.48892 (11)	0.0404 (4)
H35A	0.5083	0.0771	0.5069	0.049*
C36	0.61515 (15)	0.08156 (8)	0.40458 (10)	0.0329 (3)
H36A	0.5469	0.0922	0.3653	0.040*
C37	0.6986 (2)	0.32495 (8)	0.32085 (12)	0.0444 (4)
H37A	0.6635	0.3422	0.2671	0.067*
H37B	0.7906	0.3314	0.3255	0.067*
H37C	0.6601	0.3460	0.3679	0.067*
C38	0.73396 (19)	0.23176 (9)	0.43020 (10)	0.0417 (4)
H38A	0.6910	0.2588	0.4694	0.063*
H38B	0.8243	0.2424	0.4318	0.063*
H38C	0.7242	0.1881	0.4469	0.063*
C39	0.51716 (16)	0.26409 (8)	0.12418 (12)	0.0420 (4)
H39A	0.5786	0.2918	0.0993	0.063*
H39B	0.4946	0.2810	0.1787	0.063*
H39C	0.4408	0.2610	0.0861	0.063*
C40	0.44968 (15)	0.15096 (9)	0.17929 (12)	0.0426 (4)
H40A	0.3759	0.1580	0.1399	0.064*
H40B	0.4332	0.1686	0.2346	0.064*
H40C	0.4653	0.1060	0.1851	0.064*
Co1	0.745804 (16)	0.186494 (8)	0.230342 (11)	0.01983 (5)
O1	0.52521 (11)	0.24091 (7)	0.33284 (8)	0.0494 (3)
O2	0.59499 (11)	0.16332 (6)	0.05273 (7)	0.0386 (3)
P1	0.88875 (3)	0.227945 (16)	0.15380 (2)	0.01951 (7)
P2	0.76289 (3)	0.089222 (16)	0.26405 (2)	0.02134 (8)
S1	0.66484 (3)	0.242824 (18)	0.32462 (2)	0.02783 (8)
S2	0.58576 (3)	0.187931 (18)	0.13968 (2)	0.02729 (8)
H1	0.8514 (17)	0.1820 (8)	0.2884 (11)	0.035 (5)*

	U11	U22	U33	U12	U13	U23
C1	0.0224 (6)	0.0223 (7)	0.0240 (6)	−0.0013 (5)	0.0017 (5)	0.0019 (5)
C2	0.0411 (8)	0.0257 (7)	0.0238 (7)	0.0012 (6)	−0.0018 (6)	−0.0012 (6)
C3	0.0641 (11)	0.0329 (9)	0.0259 (7)	−0.0003 (8)	−0.0092 (7)	0.0024 (6)
C4	0.0504 (10)	0.0278 (8)	0.0402 (9)	0.0013 (7)	−0.0127 (7)	0.0079 (7)
C5	0.0479 (10)	0.0264 (8)	0.0403 (9)	0.0079 (7)	0.0031 (7)	0.0019 (7)
C6	0.0429 (9)	0.0286 (8)	0.0273 (7)	0.0058 (6)	0.0052 (6)	0.0000 (6)
C7	0.0208 (6)	0.0200 (6)	0.0255 (6)	0.0012 (5)	0.0007 (5)	−0.0022 (5)
C8	0.0268 (7)	0.0240 (7)	0.0264 (7)	−0.0020 (5)	0.0000 (5)	0.0014 (5)
C9	0.0338 (8)	0.0287 (8)	0.0311 (7)	−0.0007 (6)	−0.0079 (6)	0.0005 (6)
C10	0.0261 (7)	0.0296 (8)	0.0474 (9)	−0.0040 (6)	−0.0098 (6)	0.0003 (7)
C11	0.0246 (7)	0.0279 (8)	0.0451 (9)	−0.0040 (6)	0.0044 (6)	0.0013 (6)
C12	0.0268 (7)	0.0263 (7)	0.0285 (7)	−0.0013 (6)	0.0041 (5)	0.0000 (6)
C13	0.0277 (7)	0.0206 (6)	0.0207 (6)	0.0002 (5)	0.0051 (5)	0.0011 (5)
C14	0.0287 (7)	0.0288 (8)	0.0295 (7)	0.0029 (6)	0.0031 (6)	−0.0024 (6)
C15	0.0328 (8)	0.0348 (9)	0.0379 (8)	0.0091 (6)	0.0083 (6)	−0.0022 (7)
C16	0.0464 (9)	0.0236 (7)	0.0322 (8)	0.0047 (6)	0.0136 (7)	−0.0025 (6)
C17	0.0454 (9)	0.0255 (8)	0.0275 (7)	−0.0054 (6)	0.0052 (6)	−0.0037 (6)
C18	0.0302 (7)	0.0250 (7)	0.0260 (7)	−0.0018 (6)	0.0047 (5)	−0.0008 (6)
C19	0.0265 (7)	0.0261 (7)	0.0223 (6)	0.0034 (5)	0.0024 (5)	0.0006 (5)
C20	0.0278 (7)	0.0292 (8)	0.0337 (8)	0.0023 (6)	0.0012 (6)	0.0042 (6)
C21	0.0253 (7)	0.0457 (10)	0.0385 (8)	0.0025 (7)	0.0015 (6)	0.0067 (7)
C22	0.0328 (8)	0.0494 (10)	0.0325 (8)	0.0174 (7)	0.0018 (6)	0.0003 (7)
C23	0.0428 (9)	0.0337 (9)	0.0443 (9)	0.0143 (7)	−0.0029 (7)	−0.0081 (7)
C24	0.0321 (8)	0.0277 (8)	0.0406 (8)	0.0038 (6)	−0.0007 (6)	−0.0051 (6)
C25	0.0250 (6)	0.0204 (7)	0.0306 (7)	−0.0001 (5)	0.0004 (5)	−0.0010 (5)
C26	0.0309 (7)	0.0274 (8)	0.0301 (7)	0.0001 (6)	0.0017 (6)	−0.0010 (6)
C27	0.0368 (8)	0.0326 (8)	0.0331 (8)	0.0043 (6)	−0.0039 (6)	−0.0061 (6)
C28	0.0367 (8)	0.0307 (8)	0.0485 (10)	−0.0040 (7)	−0.0100 (7)	−0.0081 (7)
C29	0.0358 (8)	0.0292 (8)	0.0502 (10)	−0.0096 (7)	−0.0002 (7)	0.0005 (7)
C30	0.0317 (7)	0.0280 (8)	0.0343 (8)	−0.0053 (6)	0.0022 (6)	0.0020 (6)
C31	0.0322 (7)	0.0191 (7)	0.0252 (6)	−0.0012 (5)	0.0036 (5)	0.0002 (5)
C32	0.0365 (8)	0.0297 (8)	0.0285 (7)	0.0002 (6)	0.0012 (6)	−0.0015 (6)
C33	0.0547 (10)	0.0365 (9)	0.0266 (7)	0.0011 (8)	−0.0033 (7)	0.0005 (7)
C34	0.0655 (12)	0.0356 (9)	0.0258 (7)	−0.0020 (8)	0.0118 (7)	−0.0004 (7)
C35	0.0469 (10)	0.0380 (9)	0.0383 (9)	0.0000 (8)	0.0182 (7)	−0.0003 (7)
C36	0.0347 (8)	0.0332 (8)	0.0316 (8)	0.0014 (6)	0.0072 (6)	0.0011 (6)
C37	0.0690 (12)	0.0262 (8)	0.0396 (9)	0.0034 (8)	0.0161 (8)	−0.0043 (7)
C38	0.0618 (11)	0.0378 (9)	0.0260 (7)	0.0032 (8)	0.0071 (7)	−0.0050 (7)
C39	0.0346 (8)	0.0396 (10)	0.0505 (10)	0.0120 (7)	−0.0082 (7)	−0.0003 (8)
C40	0.0218 (7)	0.0516 (11)	0.0540 (10)	−0.0054 (7)	−0.0001 (7)	−0.0013 (8)
Co1	0.01897 (9)	0.02004 (10)	0.02051 (9)	0.00010 (7)	0.00147 (6)	−0.00072 (7)
O1	0.0312 (6)	0.0681 (9)	0.0503 (7)	0.0022 (6)	0.0149 (5)	−0.0158 (6)
O2	0.0350 (6)	0.0497 (7)	0.0301 (6)	0.0051 (5)	−0.0059 (4)	−0.0082 (5)
P1	0.02040 (15)	0.01970 (16)	0.01851 (15)	−0.00003 (12)	0.00179 (12)	−0.00071 (12)
P2	0.02156 (16)	0.01971 (17)	0.02289 (16)	−0.00094 (13)	0.00256 (13)	−0.00041 (13)
S1	0.02933 (17)	0.02839 (19)	0.02654 (17)	0.00214 (14)	0.00784 (13)	−0.00359 (14)
S2	0.02106 (16)	0.03158 (19)	0.02882 (17)	0.00215 (13)	−0.00186 (13)	−0.00197 (14)

C1—C2	1.3873 (19)	C25—C26	1.394 (2)
C1—C6	1.392 (2)	C25—C30	1.395 (2)
C1—P1	1.8489 (14)	C25—P2	1.8464 (14)
C2—C3	1.3850 (16)	C26—C27	1.385 (2)
C2—H2A	0.9500	C26—H26A	0.9500
C3—C4	1.3808 (17)	C27—C28	1.381 (2)
C3—H3A	0.9500	C27—H27A	0.9500
C4—C5	1.381 (2)	C28—C29	1.379 (3)
C4—H4A	0.9500	C28—H28A	0.9500
C5—C6	1.384 (2)	C29—C30	1.390 (2)
C5—H5A	0.9500	C29—H29A	0.9500
C6—H6A	0.9500	C30—H30A	0.9500
C7—C8	1.3879 (19)	C31—C36	1.392 (2)
C7—C12	1.3963 (19)	C31—C32	1.392 (2)
C7—P1	1.8477 (13)	C31—P2	1.8431 (14)
C8—C9	1.389 (2)	C32—C33	1.3853 (16)
C8—H8A	0.9500	C32—H32A	0.9500
C9—C10	1.378 (2)	C33—C34	1.3811 (18)
C9—H9A	0.9500	C33—H33A	0.9500
C10—C11	1.382 (2)	C34—C35	1.382 (3)
C10—H10A	0.9500	C34—H34A	0.9500
C11—C12	1.387 (2)	C35—C36	1.383 (2)
C11—H11A	0.9500	C35—H35A	0.9500
C12—H12A	0.9500	C36—H36A	0.9500
C13—C14	1.389 (2)	C37—S1	1.7967 (17)
C13—C18	1.397 (2)	C37—H37A	0.9800
C13—P1	1.8449 (14)	C37—H37B	0.9800
C14—C15	1.391 (2)	C37—H37C	0.9800
C14—H14A	0.9500	C38—S1	1.7995 (17)
C15—C16	1.378 (2)	C38—H38A	0.9800
C15—H15A	0.9500	C38—H38B	0.9800
C16—C17	1.381 (2)	C38—H38C	0.9800
C16—H16A	0.9500	C39—S2	1.7958 (17)
C17—C18	1.384 (2)	C39—H39A	0.9800
C17—H17A	0.9500	C39—H39B	0.9800
C18—H18A	0.9500	C39—H39C	0.9800
C19—C20	1.387 (2)	C40—S2	1.7881 (17)
C19—C24	1.391 (2)	C40—H40A	0.9800
C19—P2	1.8559 (14)	C40—H40B	0.9800
C20—C21	1.3873 (16)	C40—H40C	0.9800
C20—H20A	0.9500	Co1—S1	2.1387 (4)
C21—C22	1.3831 (17)	Co1—S2	2.1507 (4)
C21—H21A	0.9500	Co1—P2	2.1559 (4)
C22—C23	1.381 (3)	Co1—P1	2.1823 (4)
C22—H22A	0.9500	Co1—H1	1.405 (18)
C23—C24	1.385 (2)	O1—S1	1.4891 (12)
C23—H23A	0.9500	O2—S2	1.4837 (11)
C24—H24A	0.9500
C2—C1—C6	118.17 (13)	C27—C28—H28A	120.3
C2—C1—P1	124.47 (11)	C28—C29—C30	120.67 (15)
C6—C1—P1	117.30 (10)	C28—C29—H29A	119.7
C3—C2—C1	120.40 (14)	C30—C29—H29A	119.7
C3—C2—H2A	119.8	C29—C30—C25	120.36 (15)
C1—C2—H2A	119.8	C29—C30—H30A	119.8
C4—C3—C2	120.72 (15)	C25—C30—H30A	119.8
C4—C3—H3A	119.6	C36—C31—C32	118.06 (13)
C2—C3—H3A	119.6	C36—C31—P2	119.27 (11)
C3—C4—C5	119.47 (14)	C32—C31—P2	122.42 (11)
C3—C4—H4A	120.3	C33—C32—C31	120.86 (14)
C5—C4—H4A	120.3	C33—C32—H32A	119.6
C4—C5—C6	119.69 (15)	C31—C32—H32A	119.6
C4—C5—H5A	120.2	C34—C33—C32	120.19 (16)
C6—C5—H5A	120.2	C34—C33—H33A	119.9
C5—C6—C1	121.37 (14)	C32—C33—H33A	119.9
C5—C6—H6A	119.3	C33—C34—C35	119.70 (14)
C1—C6—H6A	119.3	C33—C34—H34A	120.1
C8—C7—C12	118.10 (13)	C35—C34—H34A	120.1
C8—C7—P1	121.25 (10)	C34—C35—C36	119.99 (16)
C12—C7—P1	120.65 (11)	C34—C35—H35A	120.0
C7—C8—C9	121.37 (13)	C36—C35—H35A	120.0
C7—C8—H8A	119.3	C35—C36—C31	121.12 (15)
C9—C8—H8A	119.3	C35—C36—H36A	119.4
C10—C9—C8	119.69 (14)	C31—C36—H36A	119.4
C10—C9—H9A	120.2	S1—C37—H37A	109.5
C8—C9—H9A	120.2	S1—C37—H37B	109.5
C9—C10—C11	119.89 (14)	H37A—C37—H37B	109.5
C9—C10—H10A	120.1	S1—C37—H37C	109.5
C11—C10—H10A	120.1	H37A—C37—H37C	109.5
C10—C11—C12	120.33 (14)	H37B—C37—H37C	109.5
C10—C11—H11A	119.8	S1—C38—H38A	109.5
C12—C11—H11A	119.8	S1—C38—H38B	109.5
C11—C12—C7	120.52 (14)	H38A—C38—H38B	109.5
C11—C12—H12A	119.7	S1—C38—H38C	109.5
C7—C12—H12A	119.7	H38A—C38—H38C	109.5
C14—C13—C18	118.17 (13)	H38B—C38—H38C	109.5
C14—C13—P1	124.44 (11)	S2—C39—H39A	109.5
C18—C13—P1	117.14 (10)	S2—C39—H39B	109.5
C13—C14—C15	120.67 (14)	H39A—C39—H39B	109.5
C13—C14—H14A	119.7	S2—C39—H39C	109.5
C15—C14—H14A	119.7	H39A—C39—H39C	109.5
C16—C15—C14	120.47 (15)	H39B—C39—H39C	109.5
C16—C15—H15A	119.8	S2—C40—H40A	109.5
C14—C15—H15A	119.8	S2—C40—H40B	109.5
C15—C16—C17	119.50 (14)	H40A—C40—H40B	109.5
C15—C16—H16A	120.2	S2—C40—H40C	109.5
C17—C16—H16A	120.2	H40A—C40—H40C	109.5
C16—C17—C18	120.28 (15)	H40B—C40—H40C	109.5
C16—C17—H17A	119.9	S1—Co1—S2	97.289 (15)
C18—C17—H17A	119.9	S1—Co1—P2	113.785 (15)
C17—C18—C13	120.90 (14)	S2—Co1—P2	103.285 (15)
C17—C18—H18A	119.5	S1—Co1—P1	118.569 (16)
C13—C18—H18A	119.5	S2—Co1—P1	99.515 (15)
C20—C19—C24	118.09 (13)	P2—Co1—P1	118.725 (15)
C20—C19—P2	120.81 (11)	S1—Co1—H1	85.2 (7)
C24—C19—P2	121.09 (11)	S2—Co1—H1	176.8 (7)
C19—C20—C21	120.89 (14)	P2—Co1—H1	73.8 (7)
C19—C20—H20A	119.6	P1—Co1—H1	80.9 (7)
C21—C20—H20A	119.6	C13—P1—C7	102.20 (6)
C22—C21—C20	120.41 (15)	C13—P1—C1	102.05 (6)
C22—C21—H21A	119.8	C7—P1—C1	98.42 (6)
C20—C21—H21A	119.8	C13—P1—Co1	113.87 (4)
C23—C22—C21	119.20 (14)	C7—P1—Co1	117.52 (4)
C23—C22—H22A	120.4	C1—P1—Co1	119.93 (4)
C21—C22—H22A	120.4	C31—P2—C25	102.13 (7)
C22—C23—C24	120.34 (16)	C31—P2—C19	99.69 (6)
C22—C23—H23A	119.8	C25—P2—C19	97.94 (6)
C24—C23—H23A	119.8	C31—P2—Co1	112.92 (5)
C23—C24—C19	121.05 (15)	C25—P2—Co1	122.09 (5)
C23—C24—H24A	119.5	C19—P2—Co1	118.51 (5)
C19—C24—H24A	119.5	O1—S1—C37	103.26 (9)
C26—C25—C30	118.31 (13)	O1—S1—C38	105.24 (8)
C26—C25—P2	115.77 (11)	C37—S1—C38	95.15 (9)
C30—C25—P2	125.83 (11)	O1—S1—Co1	119.07 (5)
C27—C26—C25	120.88 (14)	C37—S1—Co1	116.15 (6)
C27—C26—H26A	119.6	C38—S1—Co1	114.71 (6)
C25—C26—H26A	119.6	O2—S2—C40	105.56 (8)
C28—C27—C26	120.35 (15)	O2—S2—C39	104.16 (8)
C28—C27—H27A	119.8	C40—S2—C39	97.12 (9)
C26—C27—H27A	119.8	O2—S2—Co1	121.43 (5)
C29—C28—C27	119.41 (15)	C40—S2—Co1	112.03 (6)
C29—C28—H28A	120.3	C39—S2—Co1	113.48 (6)
C6—C1—C2—C3	−3.8 (2)	C2—C1—P1—C13	15.96 (14)
P1—C1—C2—C3	173.25 (13)	C6—C1—P1—C13	−166.97 (12)
C1—C2—C3—C4	0.4 (3)	C2—C1—P1—C7	120.44 (13)
C2—C3—C4—C5	2.8 (3)	C6—C1—P1—C7	−62.49 (12)
C3—C4—C5—C6	−2.5 (3)	C2—C1—P1—Co1	−110.94 (12)
C4—C5—C6—C1	−1.0 (3)	C6—C1—P1—Co1	66.13 (12)
C2—C1—C6—C5	4.1 (2)	S1—Co1—P1—C13	171.96 (5)
P1—C1—C6—C5	−173.17 (13)	S2—Co1—P1—C13	−84.28 (5)
C12—C7—C8—C9	−1.6 (2)	P2—Co1—P1—C13	26.67 (5)
P1—C7—C8—C9	178.77 (11)	S1—Co1—P1—C7	52.55 (5)
C7—C8—C9—C10	−1.4 (2)	S2—Co1—P1—C7	156.30 (5)
C8—C9—C10—C11	2.9 (2)	P2—Co1—P1—C7	−92.75 (5)
C9—C10—C11—C12	−1.2 (2)	S1—Co1—P1—C1	−66.82 (5)
C10—C11—C12—C7	−1.8 (2)	S2—Co1—P1—C1	36.93 (5)
C8—C7—C12—C11	3.2 (2)	P2—Co1—P1—C1	147.88 (5)
P1—C7—C12—C11	−177.15 (11)	C36—C31—P2—C25	−63.39 (13)
C18—C13—C14—C15	0.2 (2)	C32—C31—P2—C25	122.43 (13)
P1—C13—C14—C15	174.30 (12)	C36—C31—P2—C19	−163.76 (12)
C13—C14—C15—C16	0.6 (2)	C32—C31—P2—C19	22.06 (14)
C14—C15—C16—C17	−0.5 (2)	C36—C31—P2—Co1	69.52 (13)
C15—C16—C17—C18	−0.4 (2)	C32—C31—P2—Co1	−104.66 (12)
C16—C17—C18—C13	1.2 (2)	C26—C25—P2—C31	−175.08 (11)
C14—C13—C18—C17	−1.1 (2)	C30—C25—P2—C31	1.57 (14)
P1—C13—C18—C17	−175.62 (11)	C26—C25—P2—C19	−73.32 (12)
C24—C19—C20—C21	1.2 (2)	C30—C25—P2—C19	103.32 (13)
P2—C19—C20—C21	179.90 (12)	C26—C25—P2—Co1	57.69 (12)
C19—C20—C21—C22	0.0 (2)	C30—C25—P2—Co1	−125.66 (12)
C20—C21—C22—C23	−1.1 (2)	C20—C19—P2—C31	−97.04 (12)
C21—C22—C23—C24	1.0 (3)	C24—C19—P2—C31	81.58 (13)
C22—C23—C24—C19	0.2 (3)	C20—C19—P2—C25	159.12 (12)
C20—C19—C24—C23	−1.4 (2)	C24—C19—P2—C25	−22.25 (13)
P2—C19—C24—C23	179.98 (13)	C20—C19—P2—Co1	25.80 (13)
C30—C25—C26—C27	−0.5 (2)	C24—C19—P2—Co1	−155.58 (11)
P2—C25—C26—C27	176.40 (12)	S1—Co1—P2—C31	−12.08 (5)
C25—C26—C27—C28	1.6 (2)	S2—Co1—P2—C31	−116.35 (5)
C26—C27—C28—C29	−1.4 (2)	P1—Co1—P2—C31	134.80 (5)
C27—C28—C29—C30	0.1 (3)	S1—Co1—P2—C25	110.23 (6)
C28—C29—C30—C25	1.0 (3)	S2—Co1—P2—C25	5.96 (6)
C26—C25—C30—C29	−0.8 (2)	P1—Co1—P2—C25	−102.89 (6)
P2—C25—C30—C29	−177.34 (12)	S1—Co1—P2—C19	−128.03 (5)
C36—C31—C32—C33	1.1 (2)	S2—Co1—P2—C19	127.70 (5)
P2—C31—C32—C33	175.39 (12)	P1—Co1—P2—C19	18.85 (5)
C31—C32—C33—C34	1.4 (3)	S2—Co1—S1—O1	30.74 (7)
C32—C33—C34—C35	−2.1 (3)	P2—Co1—S1—O1	−77.29 (7)
C33—C34—C35—C36	0.4 (3)	P1—Co1—S1—O1	135.77 (7)
C34—C35—C36—C31	2.2 (3)	S2—Co1—S1—C37	−93.69 (8)
C32—C31—C36—C35	−2.9 (2)	P2—Co1—S1—C37	158.28 (8)
P2—C31—C36—C35	−177.33 (13)	P1—Co1—S1—C37	11.35 (8)
C14—C13—P1—C7	10.10 (14)	S2—Co1—S1—C38	156.68 (7)
C18—C13—P1—C7	−175.78 (11)	P2—Co1—S1—C38	48.64 (7)
C14—C13—P1—C1	111.59 (13)	P1—Co1—S1—C38	−98.29 (7)
C18—C13—P1—C1	−74.28 (12)	S1—Co1—S2—O2	170.37 (6)
C14—C13—P1—Co1	−117.68 (12)	P2—Co1—S2—O2	−73.02 (7)
C18—C13—P1—Co1	56.44 (12)	P1—Co1—S2—O2	49.69 (7)
C8—C7—P1—C13	−120.84 (12)	S1—Co1—S2—C40	−63.72 (7)
C12—C7—P1—C13	59.52 (12)	P2—Co1—S2—C40	52.90 (7)
C8—C7—P1—C1	134.81 (12)	P1—Co1—S2—C40	175.60 (7)
C12—C7—P1—C1	−44.83 (12)	S1—Co1—S2—C39	45.04 (7)
C8—C7—P1—Co1	4.58 (13)	P2—Co1—S2—C39	161.66 (7)
C12—C7—P1—Co1	−175.07 (10)	P1—Co1—S2—C39	−75.64 (7)