Literature DB >> 21587811

1,1'-(Ethane-1,2-di-yl)bis-(indoline-2,3-dione).

Yao Wang1, Sheng-Li Cao, Chong-Qing Wan, Jing-Li Yuan.   

Abstract

The mol-ecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The mol-ecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethyl-ene group at each N atom. In the crystal, the mol-ecules stack in columns along the b axis. There are two such columns in the structure. The mol-ecules within each column are parallel; however, the mol-ecules in the two columns differ in the respective orientation of the indoline-2,3-dione fragments. In one column, they are approximately parallel to (112), while in the other they are approximately parallel to (12). The inter-planar angle between the indoline-2,3-dione fragments in the two columns is 80.83 (3)°. The mol-ecules within each column are related by mutual displacement of their centres of symmetry, that is (0, ±1/2, ±1/2). The packing between the mol-ecules is provided by weak inter-actions only, viz. C-H⋯O hydrogen bonds and π-π [centroid-centroid distance = 3.8745 (8) Å] and C=O⋯π inter-actions.

Entities:  

Year:  2010        PMID: 21587811      PMCID: PMC3006689          DOI: 10.1107/S1600536810018957

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  6 in total

1.  The Cambridge Structural Database: a quarter of a million crystal structures and rising.

Authors:  Frank H Allen
Journal:  Acta Crystallogr B       Date:  2002-05-29

2.  Potential anticonvulsants. 11. Synthesis and anticonvulsant activity of spiro[1,3-dioxolane-2,3'-indolin]-2'-ones and structural analogues.

Authors:  M Rajopadhye; F D Popp
Journal:  J Med Chem       Date:  1988-05       Impact factor: 7.446

3.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

4.  Selective inhibition of carboxylesterases by isatins, indole-2,3-diones.

Authors:  Janice L Hyatt; Teri Moak; M Jason Hatfield; Lyudmila Tsurkan; Carol C Edwards; Monika Wierdl; Mary K Danks; Randy M Wadkins; Philip M Potter
Journal:  J Med Chem       Date:  2007-03-23       Impact factor: 7.446

5.  Structure validation in chemical crystallography.

Authors:  Anthony L Spek
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2009-01-20

6.  Simple and efficient microwave assisted N-alkylation of isatin.

Authors:  María Sol Shmidt; Ana María Reverdito; Lautaro Kremenchuzky; Isabel Amalia Perillo; María Mercedes Blanco
Journal:  Molecules       Date:  2008-04-10       Impact factor: 4.411

  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.