Aqua-(trifluoro-methane-sulfonato)-bis-(1,3,7-trimethyl-purine-2,6-dione)silver(I).

In the title compound, [Ag(CF(3)SO(3))(C(8)H(10)N(4)O(2))(2)(H(2)O)], the Ag(I) atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water mol-ecule and the trifluoro-methane-sulfonate anion, resulting in an AgN(2)O(2) seesaw geometry. The caffeine mol-ecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, mol-ecules self-assemble into a linear supra-molecular chain along the c axis via O-H⋯O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C-H⋯O inter-actions.

Related literature

For structural diversity in the supra­molecular structures of silver salts, see: Kundu et al. (2010 ▶). For a related Ag structure, see: Arman et al. (2010 ▶).

Experimental

Crystal data

[Ag(CF3SO3)(C8H10N4O2)2(H2O)]

M = 663.36

Triclinic,

a = 8.9012 (10) Å

b = 10.0408 (8) Å

c = 15.457 (2) Å

α = 72.091 (7)°

β = 85.444 (9)°

γ = 63.672 (6)°

V = 1175.6 (2) Å3

Z = 2

Mo Kα radiation

μ = 1.03 mm−1

T = 98 K

0.42 × 0.27 × 0.10 mm

Data collection

Rigaku AFC12/SATURN724 diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.568, T max = 1

7271 measured reflections

5323 independent reflections

5140 reflections with I > 2σ(I)

R int = 0.020

Refinement

R[F 2 > 2σ(F 2)] = 0.034

wR(F 2) = 0.092

S = 1.14

5323 reflections

355 parameters

3 restraints

H-atom parameters constrained

Δρmax = 0.63 e Å−3

Δρmin = −0.86 e Å−3

Data collection: CrystalClear (Molecular Structure Corporation & Rigaku, 2005 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810035300/hb5627sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810035300/hb5627Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(CF3SO3)(C8H10N4O2)2(H2O)]	Z = 2
Mr = 663.36	F(000) = 668
Triclinic, P1	Dx = 1.874 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71069 Å
a = 8.9012 (10) Å	Cell parameters from 3724 reflections
b = 10.0408 (8) Å	θ = 2.4–40.6°
c = 15.457 (2) Å	µ = 1.03 mm−1
α = 72.091 (7)°	T = 98 K
β = 85.444 (9)°	Block, colorless
γ = 63.672 (6)°	0.42 × 0.27 × 0.10 mm
V = 1175.6 (2) Å3

Rigaku AFC12K/SATURN724 diffractometer	5323 independent reflections
Radiation source: fine-focus sealed tube	5140 reflections with I > 2σ(I)
graphite	Rint = 0.020
ω scans	θmax = 27.5°, θmin = 2.4°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −11→11
Tmin = 0.568, Tmax = 1	k = −13→11
7271 measured reflections	l = −20→19

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.092	H-atom parameters constrained
S = 1.14	w = 1/[σ2(Fo2) + (0.0466P)2 + 1.1737P] where P = (Fo2 + 2Fc2)/3
5323 reflections	(Δ/σ)max = 0.001
355 parameters	Δρmax = 0.63 e Å−3
3 restraints	Δρmin = −0.86 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Ag	0.92178 (2)	0.48844 (2)	0.188475 (12)	0.01653 (8)
S1	1.24387 (8)	0.07772 (7)	0.21533 (4)	0.01613 (13)
F1	1.1161 (2)	−0.1212 (2)	0.27088 (15)	0.0355 (4)
F2	1.3860 (2)	−0.2279 (2)	0.27639 (14)	0.0331 (4)
F3	1.2548 (3)	−0.1155 (2)	0.37600 (12)	0.0356 (4)
O1	1.2942 (2)	0.5290 (2)	0.54121 (13)	0.0215 (4)
O2	0.7737 (3)	0.9110 (2)	0.41597 (14)	0.0233 (4)
O3	0.5572 (2)	0.5224 (2)	−0.19291 (13)	0.0217 (4)
O4	0.3195 (2)	0.9238 (2)	−0.06788 (13)	0.0200 (4)
O1w	0.6921 (2)	0.4768 (3)	0.28220 (13)	0.0225 (4)
H1w	0.6922	0.4669	0.3382	0.034*
H2w	0.6035	0.4812	0.2635	0.034*
O5	1.2439 (3)	0.0652 (3)	0.12484 (14)	0.0292 (5)
O6	1.3918 (3)	0.0794 (2)	0.24474 (17)	0.0295 (5)
O7	1.0872 (2)	0.1910 (2)	0.23664 (13)	0.0196 (4)
N1	1.0320 (3)	0.7175 (3)	0.47948 (15)	0.0161 (4)
N2	0.9007 (3)	0.7135 (3)	0.35260 (15)	0.0160 (4)
N3	1.0696 (3)	0.4918 (3)	0.29602 (15)	0.0170 (4)
N4	1.2894 (3)	0.3795 (3)	0.39758 (15)	0.0160 (4)
N5	0.4349 (3)	0.7199 (3)	−0.12752 (15)	0.0160 (4)
N6	0.5649 (3)	0.7186 (3)	0.00204 (14)	0.0155 (4)
N7	0.8288 (3)	0.4857 (3)	0.06071 (15)	0.0172 (4)
N8	0.8324 (3)	0.3657 (3)	−0.04021 (15)	0.0166 (4)
C1	1.1779 (3)	0.5806 (3)	0.48418 (17)	0.0156 (5)
C2	1.0253 (4)	0.7989 (3)	0.54543 (18)	0.0208 (5)
H2A	1.1136	0.8343	0.5346	0.031*
H2B	1.0427	0.7275	0.6075	0.031*
H2C	0.9153	0.8892	0.5381	0.031*
C3	0.8935 (3)	0.7894 (3)	0.41529 (18)	0.0169 (5)
C4	0.7618 (3)	0.7835 (3)	0.28352 (19)	0.0206 (5)
H4A	0.7994	0.8207	0.2235	0.031*
H4B	0.6682	0.8714	0.2978	0.031*
H4C	0.7247	0.7052	0.2829	0.031*
C5	1.0406 (3)	0.5789 (3)	0.35362 (17)	0.0143 (5)
C6	1.2221 (3)	0.3717 (3)	0.32635 (18)	0.0168 (5)
H6	1.2761	0.2898	0.2997	0.020*
C7	1.4535 (3)	0.2678 (3)	0.44590 (19)	0.0207 (5)
H7A	1.5136	0.1906	0.4138	0.031*
H7B	1.4372	0.2147	0.5081	0.031*
H7C	1.5193	0.3234	0.4481	0.031*
C8	1.1738 (3)	0.5129 (3)	0.41647 (17)	0.0147 (5)
C9	0.5606 (3)	0.5776 (3)	−0.13270 (17)	0.0154 (5)
C10	0.2981 (3)	0.8070 (3)	−0.19966 (19)	0.0207 (5)
H10A	0.3385	0.8553	−0.2556	0.031*
H10B	0.2040	0.8883	−0.1803	0.031*
H10C	0.2605	0.7354	−0.2111	0.031*
C11	0.4333 (3)	0.7971 (3)	−0.06454 (17)	0.0154 (5)
C12	0.5725 (3)	0.7927 (3)	0.06883 (18)	0.0202 (5)
H12A	0.6628	0.8253	0.0554	0.030*
H12B	0.5948	0.7182	0.1302	0.030*
H12C	0.4651	0.8842	0.0655	0.030*
C13	0.6907 (3)	0.5769 (3)	0.00148 (17)	0.0149 (5)
C14	0.9101 (3)	0.3590 (3)	0.03247 (17)	0.0174 (5)
H14	1.0126	0.2734	0.0613	0.021*
C15	0.8874 (4)	0.2440 (3)	−0.08522 (19)	0.0203 (5)
H15A	1.0015	0.1650	−0.0615	0.030*
H15B	0.8865	0.2908	−0.1511	0.030*
H15C	0.8110	0.1950	−0.0731	0.030*
C16	0.6894 (3)	0.5071 (3)	−0.06174 (17)	0.0159 (5)
C17	1.2518 (3)	−0.1069 (3)	0.28803 (19)	0.0200 (5)

	U11	U22	U33	U12	U13	U23
Ag	0.01694 (11)	0.01610 (12)	0.01605 (11)	−0.00609 (8)	−0.00257 (7)	−0.00519 (8)
S1	0.0131 (3)	0.0120 (3)	0.0189 (3)	−0.0024 (2)	0.0012 (2)	−0.0038 (2)
F1	0.0277 (9)	0.0307 (10)	0.0546 (12)	−0.0190 (8)	0.0034 (9)	−0.0122 (9)
F2	0.0281 (9)	0.0136 (8)	0.0456 (11)	−0.0009 (7)	0.0068 (8)	−0.0071 (8)
F3	0.0466 (12)	0.0338 (10)	0.0181 (8)	−0.0151 (9)	0.0034 (8)	−0.0013 (7)
O1	0.0206 (10)	0.0245 (10)	0.0188 (9)	−0.0079 (8)	−0.0022 (8)	−0.0080 (8)
O2	0.0214 (10)	0.0174 (10)	0.0259 (10)	−0.0028 (8)	−0.0015 (8)	−0.0078 (8)
O3	0.0203 (9)	0.0267 (11)	0.0209 (10)	−0.0088 (8)	−0.0008 (8)	−0.0129 (8)
O4	0.0192 (9)	0.0153 (9)	0.0216 (9)	−0.0038 (7)	−0.0007 (7)	−0.0060 (7)
O1w	0.0198 (10)	0.0333 (11)	0.0189 (9)	−0.0131 (9)	0.0027 (8)	−0.0122 (9)
O5	0.0284 (11)	0.0232 (11)	0.0189 (10)	0.0030 (9)	0.0027 (8)	−0.0059 (8)
O6	0.0157 (9)	0.0203 (10)	0.0511 (14)	−0.0071 (8)	−0.0003 (9)	−0.0095 (10)
O7	0.0154 (9)	0.0161 (9)	0.0239 (10)	−0.0021 (7)	0.0002 (7)	−0.0089 (8)
N1	0.0174 (10)	0.0149 (10)	0.0145 (10)	−0.0062 (9)	−0.0006 (8)	−0.0037 (8)
N2	0.0144 (10)	0.0118 (10)	0.0184 (10)	−0.0037 (8)	−0.0032 (8)	−0.0024 (8)
N3	0.0152 (10)	0.0150 (10)	0.0205 (11)	−0.0066 (9)	−0.0003 (8)	−0.0051 (9)
N4	0.0135 (10)	0.0146 (10)	0.0192 (10)	−0.0049 (8)	−0.0003 (8)	−0.0061 (8)
N5	0.0164 (10)	0.0142 (10)	0.0153 (10)	−0.0059 (8)	−0.0016 (8)	−0.0027 (8)
N6	0.0179 (10)	0.0136 (10)	0.0138 (10)	−0.0053 (8)	0.0002 (8)	−0.0048 (8)
N7	0.0161 (10)	0.0168 (11)	0.0139 (10)	−0.0037 (9)	−0.0013 (8)	−0.0032 (8)
N8	0.0169 (10)	0.0129 (10)	0.0165 (10)	−0.0041 (8)	0.0009 (8)	−0.0037 (8)
C1	0.0161 (12)	0.0153 (12)	0.0160 (11)	−0.0084 (10)	0.0016 (9)	−0.0035 (9)
C2	0.0258 (14)	0.0180 (13)	0.0182 (12)	−0.0079 (11)	0.0015 (10)	−0.0078 (10)
C3	0.0169 (12)	0.0150 (12)	0.0184 (12)	−0.0082 (10)	0.0005 (10)	−0.0025 (10)
C4	0.0163 (12)	0.0160 (12)	0.0250 (13)	−0.0027 (10)	−0.0067 (10)	−0.0049 (10)
C5	0.0135 (11)	0.0141 (11)	0.0163 (11)	−0.0071 (9)	0.0006 (9)	−0.0042 (9)
C6	0.0161 (12)	0.0159 (12)	0.0188 (12)	−0.0065 (10)	0.0004 (9)	−0.0062 (10)
C7	0.0118 (11)	0.0196 (13)	0.0239 (13)	−0.0009 (10)	−0.0030 (10)	−0.0059 (11)
C8	0.0143 (11)	0.0123 (11)	0.0169 (11)	−0.0052 (9)	0.0008 (9)	−0.0046 (9)
C9	0.0141 (11)	0.0153 (12)	0.0164 (11)	−0.0068 (9)	0.0027 (9)	−0.0044 (9)
C10	0.0181 (12)	0.0188 (13)	0.0227 (13)	−0.0065 (10)	−0.0062 (10)	−0.0037 (11)
C11	0.0164 (11)	0.0142 (12)	0.0141 (11)	−0.0068 (9)	0.0007 (9)	−0.0022 (9)
C12	0.0216 (13)	0.0179 (13)	0.0186 (12)	−0.0053 (10)	−0.0015 (10)	−0.0070 (10)
C13	0.0155 (11)	0.0148 (12)	0.0138 (11)	−0.0074 (10)	0.0018 (9)	−0.0025 (9)
C14	0.0157 (12)	0.0163 (12)	0.0162 (12)	−0.0044 (10)	−0.0013 (9)	−0.0033 (10)
C15	0.0230 (13)	0.0165 (12)	0.0213 (13)	−0.0067 (10)	0.0034 (10)	−0.0093 (10)
C16	0.0155 (12)	0.0128 (11)	0.0158 (11)	−0.0036 (9)	0.0014 (9)	−0.0039 (9)
C17	0.0183 (12)	0.0155 (12)	0.0232 (13)	−0.0054 (10)	0.0031 (10)	−0.0054 (10)

Ag—N7	2.213 (2)	N6—C11	1.388 (3)
Ag—N3	2.218 (2)	N6—C12	1.467 (3)
Ag—O1w	2.4347 (19)	N7—C14	1.344 (3)
Ag—O7	2.5591 (19)	N7—C13	1.361 (3)
S1—O6	1.436 (2)	N8—C14	1.335 (3)
S1—O5	1.442 (2)	N8—C16	1.386 (3)
S1—O7	1.4482 (19)	N8—C15	1.468 (3)
S1—C17	1.822 (3)	C1—C8	1.423 (4)
F1—C17	1.334 (3)	C2—H2A	0.9800
F2—C17	1.322 (3)	C2—H2B	0.9800
F3—C17	1.338 (3)	C2—H2C	0.9800
O1—C1	1.227 (3)	C4—H4A	0.9800
O2—C3	1.216 (3)	C4—H4B	0.9800
O3—C9	1.229 (3)	C4—H4C	0.9800
O4—C11	1.213 (3)	C5—C8	1.371 (4)
O1w—H1w	0.8401	C6—H6	0.9500
O1w—H2w	0.8400	C7—H7A	0.9800
N1—C1	1.397 (3)	C7—H7B	0.9800
N1—C3	1.411 (3)	C7—H7C	0.9800
N1—C2	1.473 (3)	C9—C16	1.422 (4)
N2—C5	1.369 (3)	C10—H10A	0.9800
N2—C3	1.388 (3)	C10—H10B	0.9800
N2—C4	1.463 (3)	C10—H10C	0.9800
N3—C6	1.349 (3)	C12—H12A	0.9800
N3—C5	1.365 (3)	C12—H12B	0.9800
N4—C6	1.333 (3)	C12—H12C	0.9800
N4—C8	1.381 (3)	C13—C16	1.370 (4)
N4—C7	1.468 (3)	C14—H14	0.9500
N5—C9	1.392 (3)	C15—H15A	0.9800
N5—C11	1.415 (3)	C15—H15B	0.9800
N5—C10	1.471 (3)	C15—H15C	0.9800
N6—C13	1.368 (3)
N7—Ag—N3	165.48 (8)	H4A—C4—H4C	109.5
N7—Ag—O1w	98.70 (8)	H4B—C4—H4C	109.5
N3—Ag—O1w	95.81 (7)	N3—C5—N2	127.2 (2)
N7—Ag—O7	90.01 (7)	N3—C5—C8	110.6 (2)
N3—Ag—O7	88.93 (7)	N2—C5—C8	122.2 (2)
O1w—Ag—O7	92.39 (7)	N4—C6—N3	113.1 (2)
O6—S1—O5	115.21 (14)	N4—C6—H6	123.5
O6—S1—O7	114.71 (13)	N3—C6—H6	123.5
O5—S1—O7	114.71 (12)	N4—C7—H7A	109.5
O6—S1—C17	104.22 (13)	N4—C7—H7B	109.5
O5—S1—C17	103.14 (13)	H7A—C7—H7B	109.5
O7—S1—C17	102.51 (12)	N4—C7—H7C	109.5
Ag—O1w—H1w	123.9	H7A—C7—H7C	109.5
Ag—O1w—H2w	125.1	H7B—C7—H7C	109.5
H1W—O1w—H2w	111.1	C5—C8—N4	106.2 (2)
S1—O7—Ag	136.78 (12)	C5—C8—C1	122.5 (2)
C1—N1—C3	126.5 (2)	N4—C8—C1	131.3 (2)
C1—N1—C2	116.8 (2)	O3—C9—N5	122.4 (2)
C3—N1—C2	116.7 (2)	O3—C9—C16	125.2 (2)
C5—N2—C3	119.6 (2)	N5—C9—C16	112.4 (2)
C5—N2—C4	121.2 (2)	N5—C10—H10A	109.5
C3—N2—C4	119.1 (2)	N5—C10—H10B	109.5
C6—N3—C5	103.9 (2)	H10A—C10—H10B	109.5
C6—N3—Ag	119.15 (18)	N5—C10—H10C	109.5
C5—N3—Ag	136.34 (18)	H10A—C10—H10C	109.5
C6—N4—C8	106.3 (2)	H10B—C10—H10C	109.5
C6—N4—C7	126.5 (2)	O4—C11—N6	122.3 (2)
C8—N4—C7	127.3 (2)	O4—C11—N5	121.0 (2)
C9—N5—C11	126.4 (2)	N6—C11—N5	116.6 (2)
C9—N5—C10	117.3 (2)	N6—C12—H12A	109.5
C11—N5—C10	116.0 (2)	N6—C12—H12B	109.5
C13—N6—C11	119.6 (2)	H12A—C12—H12B	109.5
C13—N6—C12	120.8 (2)	N6—C12—H12C	109.5
C11—N6—C12	119.6 (2)	H12A—C12—H12C	109.5
C14—N7—C13	104.0 (2)	H12B—C12—H12C	109.5
C14—N7—Ag	119.11 (17)	N7—C13—N6	127.1 (2)
C13—N7—Ag	136.45 (18)	N7—C13—C16	110.8 (2)
C14—N8—C16	106.0 (2)	N6—C13—C16	122.1 (2)
C14—N8—C15	126.0 (2)	N8—C14—N7	113.2 (2)
C16—N8—C15	127.9 (2)	N8—C14—H14	123.4
O1—C1—N1	121.8 (2)	N7—C14—H14	123.4
O1—C1—C8	125.7 (2)	N8—C15—H15A	109.5
N1—C1—C8	112.5 (2)	N8—C15—H15B	109.5
N1—C2—H2A	109.5	H15A—C15—H15B	109.5
N1—C2—H2B	109.5	N8—C15—H15C	109.5
H2A—C2—H2B	109.5	H15A—C15—H15C	109.5
N1—C2—H2C	109.5	H15B—C15—H15C	109.5
H2A—C2—H2C	109.5	C13—C16—N8	106.0 (2)
H2B—C2—H2C	109.5	C13—C16—C9	122.8 (2)
O2—C3—N2	122.2 (2)	N8—C16—C9	131.2 (2)
O2—C3—N1	121.2 (2)	F2—C17—F1	108.1 (2)
N2—C3—N1	116.6 (2)	F2—C17—F3	107.9 (2)
N2—C4—H4A	109.5	F1—C17—F3	107.0 (2)
N2—C4—H4B	109.5	F2—C17—S1	112.01 (19)
H4A—C4—H4B	109.5	F1—C17—S1	110.82 (19)
N2—C4—H4C	109.5	F3—C17—S1	110.9 (2)
O6—S1—O7—Ag	66.6 (2)	O1—C1—C8—C5	−178.7 (2)
O5—S1—O7—Ag	−70.1 (2)	N1—C1—C8—C5	0.9 (3)
C17—S1—O7—Ag	178.87 (16)	O1—C1—C8—N4	0.7 (5)
N7—Ag—O7—S1	78.84 (17)	N1—C1—C8—N4	−179.7 (2)
N3—Ag—O7—S1	−86.68 (17)	C11—N5—C9—O3	−175.7 (2)
O1w—Ag—O7—S1	177.55 (17)	C10—N5—C9—O3	−2.2 (4)
N7—Ag—N3—C6	−62.4 (4)	C11—N5—C9—C16	4.1 (4)
O1w—Ag—N3—C6	115.84 (19)	C10—N5—C9—C16	177.6 (2)
O7—Ag—N3—C6	23.54 (19)	C13—N6—C11—O4	−179.2 (2)
N7—Ag—N3—C5	128.5 (3)	C12—N6—C11—O4	−2.8 (4)
O1w—Ag—N3—C5	−53.3 (3)	C13—N6—C11—N5	2.8 (3)
O7—Ag—N3—C5	−145.6 (2)	C12—N6—C11—N5	179.2 (2)
N3—Ag—N7—C14	67.4 (4)	C9—N5—C11—O4	177.6 (2)
O1w—Ag—N7—C14	−110.8 (2)	C10—N5—C11—O4	4.1 (4)
O7—Ag—N7—C14	−18.4 (2)	C9—N5—C11—N6	−4.3 (4)
N3—Ag—N7—C13	−121.7 (3)	C10—N5—C11—N6	−177.8 (2)
O1w—Ag—N7—C13	60.1 (3)	C14—N7—C13—N6	178.6 (2)
O7—Ag—N7—C13	152.5 (3)	Ag—N7—C13—N6	6.8 (4)
C3—N1—C1—O1	178.0 (2)	C14—N7—C13—C16	−0.5 (3)
C2—N1—C1—O1	1.0 (4)	Ag—N7—C13—C16	−172.28 (19)
C3—N1—C1—C8	−1.7 (3)	C11—N6—C13—N7	179.3 (2)
C2—N1—C1—C8	−178.6 (2)	C12—N6—C13—N7	2.9 (4)
C5—N2—C3—O2	178.4 (2)	C11—N6—C13—C16	−1.7 (4)
C4—N2—C3—O2	1.6 (4)	C12—N6—C13—C16	−178.1 (2)
C5—N2—C3—N1	−2.3 (3)	C16—N8—C14—N7	0.1 (3)
C4—N2—C3—N1	−179.2 (2)	C15—N8—C14—N7	−178.3 (2)
C1—N1—C3—O2	−178.3 (2)	C13—N7—C14—N8	0.2 (3)
C2—N1—C3—O2	−1.4 (4)	Ag—N7—C14—N8	173.80 (17)
C1—N1—C3—N2	2.4 (4)	N7—C13—C16—N8	0.5 (3)
C2—N1—C3—N2	179.3 (2)	N6—C13—C16—N8	−178.7 (2)
C6—N3—C5—N2	−179.1 (2)	N7—C13—C16—C9	−179.1 (2)
Ag—N3—C5—N2	−8.8 (4)	N6—C13—C16—C9	1.7 (4)
C6—N3—C5—C8	0.6 (3)	C14—N8—C16—C13	−0.3 (3)
Ag—N3—C5—C8	170.88 (18)	C15—N8—C16—C13	178.0 (2)
C3—N2—C5—N3	−178.5 (2)	C14—N8—C16—C9	179.2 (3)
C4—N2—C5—N3	−1.7 (4)	C15—N8—C16—C9	−2.5 (4)
C3—N2—C5—C8	1.8 (4)	O3—C9—C16—C13	177.1 (2)
C4—N2—C5—C8	178.6 (2)	N5—C9—C16—C13	−2.7 (4)
C8—N4—C6—N3	0.5 (3)	O3—C9—C16—N8	−2.4 (5)
C7—N4—C6—N3	−179.7 (2)	N5—C9—C16—N8	177.8 (3)
C5—N3—C6—N4	−0.7 (3)	O6—S1—C17—F2	−62.1 (2)
Ag—N3—C6—N4	−172.98 (17)	O5—S1—C17—F2	58.6 (2)
N3—C5—C8—N4	−0.4 (3)	O7—S1—C17—F2	178.0 (2)
N2—C5—C8—N4	179.4 (2)	O6—S1—C17—F1	177.1 (2)
N3—C5—C8—C1	179.2 (2)	O5—S1—C17—F1	−62.2 (2)
N2—C5—C8—C1	−1.1 (4)	O7—S1—C17—F1	57.3 (2)
C6—N4—C8—C5	0.0 (3)	O6—S1—C17—F3	58.5 (2)
C7—N4—C8—C5	−179.9 (2)	O5—S1—C17—F3	179.17 (19)
C6—N4—C8—C1	−179.5 (3)	O7—S1—C17—F3	−61.4 (2)
C7—N4—C8—C1	0.6 (4)

D—H···A	D—H	H···A	D···A	D—H···A
O1w—H1w···O1i	0.84	1.89	2.724 (3)	170
O1w—H2w···O3ii	0.84	1.89	2.701 (3)	163
C10—H10c···O1wii	0.98	2.55	3.428 (4)	149
C15—H15c···O4ii	0.98	2.60	3.382 (4)	137
C4—H4b···O6iii	0.98	2.41	3.252 (4)	144
C12—H12c···O5iii	0.98	2.36	3.278 (4)	155

Ag—N7	2.213 (2)
Ag—N3	2.218 (2)
Ag—O1w	2.4347 (19)
Ag—O7	2.5591 (19)

N7—Ag—N3	165.48 (8)
N7—Ag—O1w	98.70 (8)
N3—Ag—O1w	95.81 (7)
N7—Ag—O7	90.01 (7)
N3—Ag—O7	88.93 (7)
O1w—Ag—O7	92.39 (7)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1w—H1w⋯O1i	0.84	1.89	2.724 (3)	170
O1w—H2w⋯O3ii	0.84	1.89	2.701 (3)	163
C10—H10c⋯O1wii	0.98	2.55	3.428 (4)	149
C15—H15c⋯O4ii	0.98	2.60	3.382 (4)	137
C4—H4b⋯O6iii	0.98	2.41	3.252 (4)	144
C12—H12c⋯O5iii	0.98	2.36	3.278 (4)	155

Symmetry codes: (i) ; (ii) ; (iii) .