Undeca-carbonyl-1κC,2κC,3κC-[tris-(2-chloro-eth-yl) phosphite-1κP]-triangulo-triruthenium(0).

In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the mol-ecules are linked into a one-dimensional column along [100] by inter-molecular C-H⋯O hydrogen bonds.

Related literature

For general background to triangulo-triruthenium derivatives, see: Bruce et al. (1985 ▶, 1988a ▶,b ▶). For the synthesis, see: Bruce et al. (1987 ▶). For related structures, see: Shawkataly et al. (1991 ▶, 2010 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

Experimental

Crystal data

[Ru3(C6H12Cl3O3P)(CO)11]

M = 880.80

Triclinic,

a = 7.8592 (9) Å

b = 12.5979 (14) Å

c = 14.8393 (17) Å

α = 109.442 (3)°

β = 93.791 (3)°

γ = 90.763 (3)°

V = 1381.4 (3) Å3

Z = 2

Mo Kα radiation

μ = 2.03 mm−1

T = 100 K

0.20 × 0.19 × 0.03 mm

Data collection

Bruker APEXII DUO CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T min = 0.691, T max = 0.936

32458 measured reflections

11981 independent reflections

9935 reflections with I > 2σ(I)

R int = 0.037

Refinement

R[F 2 > 2σ(F 2)] = 0.030

wR(F 2) = 0.120

S = 1.07

11981 reflections

343 parameters

H-atom parameters constrained

Δρmax = 1.36 e Å−3

Δρmin = −1.36 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810033891/hy2343sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810033891/hy2343Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ru3(C6H12Cl3O3P)(CO)11]	Z = 2
Mr = 880.80	F(000) = 848
Triclinic, P1	Dx = 2.117 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 7.8592 (9) Å	Cell parameters from 9961 reflections
b = 12.5979 (14) Å	θ = 2.6–34.9°
c = 14.8393 (17) Å	µ = 2.03 mm−1
α = 109.442 (3)°	T = 100 K
β = 93.791 (3)°	Plate, orange
γ = 90.763 (3)°	0.20 × 0.19 × 0.03 mm
V = 1381.4 (3) Å3

Bruker APEXII DUO CCD diffractometer	11981 independent reflections
Radiation source: fine-focus sealed tube	9935 reflections with I > 2σ(I)
graphite	Rint = 0.037
φ and ω scans	θmax = 35.0°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Bruker, 2001)	h = −12→11
Tmin = 0.691, Tmax = 0.936	k = −20→20
32458 measured reflections	l = −23→23

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.120	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0712P)2] where P = (Fo2 + 2Fc2)/3
11981 reflections	(Δ/σ)max = 0.001
343 parameters	Δρmax = 1.36 e Å−3
0 restraints	Δρmin = −1.36 e Å−3

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

	x	y	z	Uiso*/Ueq
Ru1	0.71803 (3)	0.328125 (16)	0.260791 (13)	0.01152 (5)
Ru2	0.70797 (3)	0.443891 (16)	0.125659 (14)	0.01282 (5)
Ru3	0.90548 (3)	0.247218 (16)	0.093890 (14)	0.01285 (5)
Cl1	1.27297 (12)	0.29528 (8)	0.52857 (7)	0.0393 (2)
Cl2	0.44453 (13)	−0.08078 (8)	0.26311 (8)	0.0408 (2)
Cl3	0.87744 (12)	0.12562 (8)	0.59050 (6)	0.03316 (18)
P1	0.81185 (9)	0.19414 (5)	0.32030 (5)	0.01243 (11)
O1	0.4173 (3)	0.1665 (2)	0.15829 (18)	0.0261 (5)
O2	0.4589 (3)	0.4615 (2)	0.39455 (16)	0.0272 (5)
O3	1.0116 (3)	0.48098 (19)	0.38775 (16)	0.0243 (4)
O4	1.0024 (4)	0.6040 (2)	0.24393 (19)	0.0312 (5)
O5	0.4624 (4)	0.6254 (2)	0.2229 (2)	0.0353 (6)
O6	0.4026 (3)	0.2931 (2)	0.01285 (18)	0.0264 (5)
O7	0.8072 (3)	0.4917 (2)	−0.05275 (17)	0.0285 (5)
O8	0.6085 (3)	0.0883 (2)	−0.02193 (18)	0.0286 (5)
O9	1.0676 (3)	0.03923 (18)	0.11984 (17)	0.0237 (4)
O10	1.2121 (3)	0.3946 (2)	0.21192 (18)	0.0246 (4)
O11	1.0379 (3)	0.2483 (2)	−0.09539 (17)	0.0296 (5)
O12	1.0146 (3)	0.20752 (17)	0.34233 (15)	0.0185 (4)
O13	0.7651 (3)	0.06914 (16)	0.25139 (14)	0.0167 (3)
O14	0.7425 (3)	0.18383 (16)	0.41609 (13)	0.0156 (3)
C1	0.5297 (4)	0.2259 (2)	0.1906 (2)	0.0170 (5)
C2	0.5606 (4)	0.4129 (2)	0.34655 (19)	0.0176 (5)
C3	0.9063 (4)	0.4263 (2)	0.33632 (19)	0.0162 (4)
C4	0.8986 (4)	0.5401 (2)	0.2013 (2)	0.0197 (5)
C5	0.5525 (4)	0.5573 (2)	0.1872 (2)	0.0213 (5)
C6	0.5187 (4)	0.3433 (2)	0.0568 (2)	0.0186 (5)
C7	0.7704 (4)	0.4744 (2)	0.0129 (2)	0.0190 (5)
C8	0.7114 (4)	0.1509 (2)	0.0235 (2)	0.0195 (5)
C9	1.0079 (4)	0.1172 (2)	0.1112 (2)	0.0176 (5)
C10	1.0934 (4)	0.3452 (2)	0.1710 (2)	0.0178 (5)
C11	0.9900 (4)	0.2496 (2)	−0.0249 (2)	0.0191 (5)
C12	1.1191 (4)	0.1307 (2)	0.3739 (2)	0.0201 (5)
H12A	1.1351	0.0632	0.3201	0.024*
H12B	1.0627	0.1090	0.4217	0.024*
C13	1.2881 (4)	0.1874 (3)	0.4157 (2)	0.0251 (6)
H13A	1.3346	0.2200	0.3715	0.030*
H13B	1.3661	0.1316	0.4238	0.030*
C14	0.7869 (4)	−0.0323 (2)	0.2750 (2)	0.0206 (5)
H14A	0.7794	−0.0160	0.3433	0.025*
H14B	0.8982	−0.0619	0.2585	0.025*
C15	0.6486 (4)	−0.1176 (2)	0.2195 (2)	0.0241 (6)
H15A	0.6760	−0.1907	0.2237	0.029*
H15B	0.6449	−0.1235	0.1525	0.029*
C16	0.7696 (4)	0.2759 (2)	0.50584 (19)	0.0183 (5)
H16A	0.6951	0.3368	0.5060	0.022*
H16B	0.8869	0.3046	0.5150	0.022*
C17	0.7303 (4)	0.2308 (3)	0.5846 (2)	0.0211 (5)
H17A	0.6149	0.1984	0.5727	0.025*
H17B	0.7374	0.2919	0.6455	0.025*

	U11	U22	U33	U12	U13	U23
Ru1	0.01204 (9)	0.01129 (8)	0.01162 (8)	0.00113 (6)	0.00190 (6)	0.00414 (6)
Ru2	0.01309 (9)	0.01271 (8)	0.01366 (9)	0.00183 (6)	0.00155 (6)	0.00559 (6)
Ru3	0.01169 (9)	0.01307 (9)	0.01344 (9)	0.00218 (6)	0.00272 (6)	0.00355 (6)
Cl1	0.0261 (4)	0.0352 (4)	0.0420 (5)	0.0005 (3)	−0.0078 (4)	−0.0045 (4)
Cl2	0.0277 (4)	0.0341 (4)	0.0615 (6)	0.0012 (3)	0.0209 (4)	0.0140 (4)
Cl3	0.0348 (4)	0.0420 (4)	0.0343 (4)	0.0164 (4)	0.0094 (3)	0.0264 (4)
P1	0.0123 (3)	0.0118 (2)	0.0135 (3)	0.0009 (2)	0.0010 (2)	0.0046 (2)
O1	0.0173 (10)	0.0285 (11)	0.0295 (11)	−0.0045 (8)	−0.0009 (8)	0.0065 (9)
O2	0.0225 (11)	0.0326 (12)	0.0220 (10)	0.0072 (9)	0.0069 (8)	0.0018 (9)
O3	0.0253 (11)	0.0209 (9)	0.0222 (10)	−0.0057 (8)	−0.0020 (8)	0.0023 (8)
O4	0.0335 (14)	0.0245 (11)	0.0345 (13)	−0.0079 (10)	−0.0086 (11)	0.0108 (10)
O5	0.0309 (14)	0.0253 (11)	0.0446 (15)	0.0083 (10)	0.0135 (11)	0.0026 (10)
O6	0.0194 (11)	0.0268 (11)	0.0283 (11)	−0.0004 (9)	−0.0045 (9)	0.0044 (9)
O7	0.0285 (12)	0.0391 (13)	0.0258 (11)	0.0016 (10)	0.0059 (9)	0.0205 (10)
O8	0.0215 (11)	0.0243 (10)	0.0319 (12)	0.0010 (9)	0.0000 (9)	−0.0013 (9)
O9	0.0224 (11)	0.0202 (9)	0.0298 (11)	0.0062 (8)	0.0044 (8)	0.0093 (8)
O10	0.0159 (10)	0.0268 (11)	0.0281 (11)	−0.0014 (8)	0.0003 (8)	0.0054 (9)
O11	0.0287 (12)	0.0397 (13)	0.0222 (10)	0.0015 (10)	0.0085 (9)	0.0117 (9)
O12	0.0127 (8)	0.0203 (9)	0.0260 (10)	0.0015 (7)	0.0007 (7)	0.0125 (8)
O13	0.0218 (10)	0.0126 (7)	0.0158 (8)	−0.0002 (7)	0.0008 (7)	0.0050 (6)
O14	0.0175 (9)	0.0153 (8)	0.0138 (8)	−0.0015 (7)	0.0026 (7)	0.0046 (6)
C1	0.0152 (11)	0.0186 (11)	0.0176 (11)	0.0021 (9)	0.0017 (9)	0.0063 (9)
C2	0.0178 (12)	0.0191 (11)	0.0164 (10)	0.0013 (9)	0.0015 (9)	0.0064 (9)
C3	0.0179 (12)	0.0143 (10)	0.0170 (10)	−0.0007 (9)	0.0031 (9)	0.0056 (8)
C4	0.0179 (12)	0.0191 (11)	0.0235 (12)	0.0007 (9)	−0.0005 (10)	0.0093 (10)
C5	0.0212 (13)	0.0180 (11)	0.0234 (12)	0.0006 (10)	0.0048 (10)	0.0047 (10)
C6	0.0180 (12)	0.0169 (11)	0.0212 (12)	0.0027 (9)	0.0031 (9)	0.0065 (9)
C7	0.0171 (12)	0.0210 (11)	0.0215 (12)	0.0029 (9)	0.0018 (9)	0.0103 (10)
C8	0.0145 (11)	0.0198 (11)	0.0235 (12)	0.0027 (9)	0.0046 (9)	0.0056 (10)
C9	0.0148 (11)	0.0180 (11)	0.0188 (11)	0.0007 (9)	0.0043 (9)	0.0042 (9)
C10	0.0150 (11)	0.0198 (11)	0.0184 (11)	0.0023 (9)	0.0019 (9)	0.0059 (9)
C11	0.0174 (12)	0.0208 (11)	0.0183 (11)	0.0024 (9)	0.0034 (9)	0.0053 (9)
C12	0.0168 (12)	0.0188 (11)	0.0245 (12)	0.0054 (9)	−0.0009 (10)	0.0074 (10)
C13	0.0143 (12)	0.0297 (14)	0.0306 (15)	0.0042 (11)	0.0002 (11)	0.0092 (12)
C14	0.0266 (14)	0.0119 (10)	0.0230 (12)	0.0020 (9)	−0.0004 (11)	0.0057 (9)
C15	0.0252 (14)	0.0147 (11)	0.0292 (14)	0.0003 (10)	0.0065 (11)	0.0023 (10)
C16	0.0223 (13)	0.0160 (10)	0.0147 (10)	0.0022 (9)	0.0022 (9)	0.0022 (8)
C17	0.0204 (13)	0.0283 (13)	0.0156 (11)	0.0073 (11)	0.0020 (9)	0.0084 (10)

Ru1—C2	1.905 (3)	O5—C5	1.131 (4)
Ru1—C3	1.945 (3)	O6—C6	1.135 (4)
Ru1—C1	1.946 (3)	O7—C7	1.120 (4)
Ru1—P1	2.2609 (7)	O8—C8	1.135 (4)
Ru1—Ru2	2.8431 (4)	O9—C9	1.136 (4)
Ru1—Ru3	2.8610 (4)	O10—C10	1.133 (4)
Ru2—C5	1.922 (3)	O11—C11	1.130 (4)
Ru2—C7	1.929 (3)	O12—C12	1.450 (3)
Ru2—C6	1.936 (3)	O13—C14	1.443 (3)
Ru2—C4	1.949 (3)	O14—C16	1.446 (3)
Ru2—Ru3	2.8622 (4)	C12—C13	1.493 (4)
Ru3—C9	1.919 (3)	C12—H12A	0.9700
Ru3—C11	1.934 (3)	C12—H12B	0.9700
Ru3—C8	1.945 (3)	C13—H13A	0.9700
Ru3—C10	1.950 (3)	C13—H13B	0.9700
Cl1—C13	1.784 (3)	C14—C15	1.509 (4)
Cl2—C15	1.779 (3)	C14—H14A	0.9700
Cl3—C17	1.790 (3)	C14—H14B	0.9700
P1—O13	1.589 (2)	C15—H15A	0.9700
P1—O14	1.600 (2)	C15—H15B	0.9700
P1—O12	1.601 (2)	C16—C17	1.507 (4)
O1—C1	1.122 (4)	C16—H16A	0.9700
O2—C2	1.148 (4)	C16—H16B	0.9700
O3—C3	1.137 (3)	C17—H17A	0.9700
O4—C4	1.135 (4)	C17—H17B	0.9700
C2—Ru1—C3	90.61 (12)	C12—O12—P1	124.95 (18)
C2—Ru1—C1	88.67 (12)	C14—O13—P1	126.29 (18)
C3—Ru1—C1	176.82 (11)	C16—O14—P1	120.43 (17)
C2—Ru1—P1	106.42 (9)	O1—C1—Ru1	173.4 (3)
C3—Ru1—P1	88.17 (8)	O2—C2—Ru1	176.4 (3)
C1—Ru1—P1	89.06 (8)	O3—C3—Ru1	173.4 (2)
C2—Ru1—Ru2	99.93 (8)	O4—C4—Ru2	173.8 (3)
C3—Ru1—Ru2	91.10 (8)	O5—C5—Ru2	178.8 (3)
C1—Ru1—Ru2	92.08 (8)	O6—C6—Ru2	172.8 (3)
P1—Ru1—Ru2	153.641 (19)	O7—C7—Ru2	179.6 (3)
C2—Ru1—Ru3	159.81 (8)	O8—C8—Ru3	173.9 (3)
C3—Ru1—Ru3	93.38 (8)	O9—C9—Ru3	178.8 (3)
C1—Ru1—Ru3	88.35 (8)	O10—C10—Ru3	173.8 (3)
P1—Ru1—Ru3	93.50 (2)	O11—C11—Ru3	178.3 (3)
Ru2—Ru1—Ru3	60.236 (9)	O12—C12—C13	109.3 (2)
C5—Ru2—C7	106.72 (13)	O12—C12—H12A	109.8
C5—Ru2—C6	90.60 (12)	C13—C12—H12A	109.8
C7—Ru2—C6	93.05 (12)	O12—C12—H12B	109.8
C5—Ru2—C4	89.78 (13)	C13—C12—H12B	109.8
C7—Ru2—C4	90.49 (12)	H12A—C12—H12B	108.3
C6—Ru2—C4	176.17 (12)	C12—C13—Cl1	112.2 (2)
C5—Ru2—Ru1	97.66 (9)	C12—C13—H13A	109.2
C7—Ru2—Ru1	155.59 (9)	Cl1—C13—H13A	109.2
C6—Ru2—Ru1	87.85 (9)	C12—C13—H13B	109.2
C4—Ru2—Ru1	88.32 (9)	Cl1—C13—H13B	109.2
C5—Ru2—Ru3	157.76 (9)	H13A—C13—H13B	107.9
C7—Ru2—Ru3	95.47 (9)	O13—C14—C15	108.5 (2)
C6—Ru2—Ru3	86.84 (8)	O13—C14—H14A	110.0
C4—Ru2—Ru3	91.37 (9)	C15—C14—H14A	110.0
Ru1—Ru2—Ru3	60.191 (8)	O13—C14—H14B	110.0
C9—Ru3—C11	103.01 (12)	C15—C14—H14B	110.0
C9—Ru3—C8	88.67 (12)	H14A—C14—H14B	108.4
C11—Ru3—C8	90.45 (12)	C14—C15—Cl2	112.2 (2)
C9—Ru3—C10	91.35 (12)	C14—C15—H15A	109.2
C11—Ru3—C10	92.68 (12)	Cl2—C15—H15A	109.2
C8—Ru3—C10	176.78 (12)	C14—C15—H15B	109.2
C9—Ru3—Ru1	101.60 (8)	Cl2—C15—H15B	109.2
C11—Ru3—Ru1	155.38 (9)	H15A—C15—H15B	107.9
C8—Ru3—Ru1	90.80 (9)	O14—C16—C17	107.3 (2)
C10—Ru3—Ru1	86.04 (8)	O14—C16—H16A	110.2
C9—Ru3—Ru2	161.17 (8)	C17—C16—H16A	110.2
C11—Ru3—Ru2	95.82 (9)	O14—C16—H16B	110.2
C8—Ru3—Ru2	91.17 (9)	C17—C16—H16B	110.2
C10—Ru3—Ru2	87.77 (9)	H16A—C16—H16B	108.5
Ru1—Ru3—Ru2	59.573 (8)	C16—C17—Cl3	110.5 (2)
O13—P1—O14	98.19 (10)	C16—C17—H17A	109.5
O13—P1—O12	108.50 (12)	Cl3—C17—H17A	109.5
O14—P1—O12	104.15 (11)	C16—C17—H17B	109.5
O13—P1—Ru1	113.83 (8)	Cl3—C17—H17B	109.5
O14—P1—Ru1	120.97 (8)	H17A—C17—H17B	108.1
O12—P1—Ru1	110.01 (8)
C2—Ru1—Ru2—C5	1.98 (12)	C4—Ru2—Ru3—C9	88.2 (3)
C3—Ru1—Ru2—C5	−88.83 (12)	Ru1—Ru2—Ru3—C9	0.9 (3)
C1—Ru1—Ru2—C5	91.00 (12)	C5—Ru2—Ru3—C11	175.3 (3)
P1—Ru1—Ru2—C5	−176.92 (10)	C7—Ru2—Ru3—C11	−1.28 (12)
Ru3—Ru1—Ru2—C5	177.91 (9)	C6—Ru2—Ru3—C11	91.49 (12)
C2—Ru1—Ru2—C7	179.0 (2)	C4—Ru2—Ru3—C11	−91.90 (12)
C3—Ru1—Ru2—C7	88.2 (2)	Ru1—Ru2—Ru3—C11	−179.18 (9)
C1—Ru1—Ru2—C7	−92.0 (2)	C5—Ru2—Ru3—C8	84.8 (3)
P1—Ru1—Ru2—C7	0.1 (2)	C7—Ru2—Ru3—C8	−91.85 (13)
Ru3—Ru1—Ru2—C7	−5.1 (2)	C6—Ru2—Ru3—C8	0.91 (12)
C2—Ru1—Ru2—C6	−88.33 (12)	C4—Ru2—Ru3—C8	177.52 (12)
C3—Ru1—Ru2—C6	−179.15 (11)	Ru1—Ru2—Ru3—C8	90.24 (9)
C1—Ru1—Ru2—C6	0.68 (11)	C5—Ru2—Ru3—C10	−92.2 (3)
P1—Ru1—Ru2—C6	92.76 (9)	C7—Ru2—Ru3—C10	91.19 (12)
Ru3—Ru1—Ru2—C6	87.59 (9)	C6—Ru2—Ru3—C10	−176.05 (11)
C2—Ru1—Ru2—C4	91.53 (12)	C4—Ru2—Ru3—C10	0.56 (12)
C3—Ru1—Ru2—C4	0.72 (11)	Ru1—Ru2—Ru3—C10	−86.72 (8)
C1—Ru1—Ru2—C4	−179.46 (12)	C5—Ru2—Ru3—Ru1	−5.5 (2)
P1—Ru1—Ru2—C4	−87.38 (10)	C7—Ru2—Ru3—Ru1	177.90 (9)
Ru3—Ru1—Ru2—C4	−92.55 (9)	C6—Ru2—Ru3—Ru1	−89.33 (9)
C2—Ru1—Ru2—Ru3	−175.93 (9)	C4—Ru2—Ru3—Ru1	87.28 (9)
C3—Ru1—Ru2—Ru3	93.26 (8)	C2—Ru1—P1—O13	117.48 (13)
C1—Ru1—Ru2—Ru3	−86.91 (8)	C3—Ru1—P1—O13	−152.42 (12)
P1—Ru1—Ru2—Ru3	5.17 (4)	C1—Ru1—P1—O13	29.15 (12)
C2—Ru1—Ru3—C9	−168.0 (3)	Ru2—Ru1—P1—O13	−63.64 (10)
C3—Ru1—Ru3—C9	90.97 (12)	Ru3—Ru1—P1—O13	−59.14 (9)
C1—Ru1—Ru3—C9	−86.36 (12)	C2—Ru1—P1—O14	0.96 (13)
P1—Ru1—Ru3—C9	2.60 (9)	C3—Ru1—P1—O14	91.05 (12)
Ru2—Ru1—Ru3—C9	−179.70 (9)	C1—Ru1—P1—O14	−87.38 (12)
C2—Ru1—Ru3—C11	13.7 (3)	Ru2—Ru1—P1—O14	179.83 (8)
C3—Ru1—Ru3—C11	−87.4 (2)	Ru3—Ru1—P1—O14	−175.67 (9)
C1—Ru1—Ru3—C11	95.3 (2)	C2—Ru1—P1—O12	−120.51 (12)
P1—Ru1—Ru3—C11	−175.7 (2)	C3—Ru1—P1—O12	−30.41 (12)
Ru2—Ru1—Ru3—C11	2.0 (2)	C1—Ru1—P1—O12	151.16 (12)
C2—Ru1—Ru3—C8	−79.2 (3)	Ru2—Ru1—P1—O12	58.37 (10)
C3—Ru1—Ru3—C8	179.78 (11)	Ru3—Ru1—P1—O12	62.86 (9)
C1—Ru1—Ru3—C8	2.45 (12)	O13—P1—O12—C12	−49.8 (2)
P1—Ru1—Ru3—C8	91.41 (9)	O14—P1—O12—C12	54.1 (2)
Ru2—Ru1—Ru3—C8	−90.89 (9)	Ru1—P1—O12—C12	−174.9 (2)
C2—Ru1—Ru3—C10	101.4 (3)	O14—P1—O13—C14	−41.8 (3)
C3—Ru1—Ru3—C10	0.41 (11)	O12—P1—O13—C14	66.2 (3)
C1—Ru1—Ru3—C10	−176.92 (11)	Ru1—P1—O13—C14	−171.0 (2)
P1—Ru1—Ru3—C10	−87.96 (9)	O13—P1—O14—C16	174.3 (2)
Ru2—Ru1—Ru3—C10	89.74 (9)	O12—P1—O14—C16	62.8 (2)
C2—Ru1—Ru3—Ru2	11.7 (2)	Ru1—P1—O14—C16	−61.5 (2)
C3—Ru1—Ru3—Ru2	−89.33 (8)	P1—O12—C12—C13	−162.5 (2)
C1—Ru1—Ru3—Ru2	93.34 (8)	O12—C12—C13—Cl1	71.2 (3)
P1—Ru1—Ru3—Ru2	−177.703 (19)	P1—O13—C14—C15	148.7 (2)
C5—Ru2—Ru3—C9	−4.6 (4)	O13—C14—C15—Cl2	−71.2 (3)
C7—Ru2—Ru3—C9	178.8 (3)	P1—O14—C16—C17	−166.17 (19)
C6—Ru2—Ru3—C9	−88.4 (3)	O14—C16—C17—Cl3	64.2 (3)

D—H···A	D—H	H···A	D···A	D—H···A
C17—H17B···O4i	0.97	2.58	3.297 (4)	131
C17—H17B···O5ii	0.97	2.54	3.307 (4)	136

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C17—H17B⋯O4i	0.97	2.58	3.297 (4)	131
C17—H17B⋯O5ii	0.97	2.54	3.307 (4)	136

Symmetry codes: (i) ; (ii) .