A tetra-silver(I)ditungsten(VI) cluster with sulfide and bis-(diphenyl-phosphino)methane ligands.

The asymmetric unit of the title complex, [Ag(4)W(2)S(8)(C(25)H(22)P(2))(3)]·2C(3)H(7)NO, tris-[μ(2)-bis-(diphenyl-phosphino)meth-ane]-3:6κ(2)P:P';4:5κ(2)P:P';5:6κ(2)P:P'-μ(5)-sulfido-2:3:4:5:6κ(5)S-μ(3)-sulfido-1:3:4κ(3)S-tetra-μ(2)-sulfido-1:3κ(2)S;1:4κ(2)S;2:5κ(2)S;2:6κ(2)S-disulfido-1κS,2κS-tetra-silver(I)ditungsten(VI) N,N-dimethyl-formamide disolvate, contains two [WS(4)](2-) anions, four silver cations, three bidentate-bridging bis-(diphenyl-phosphino)methane (dppm) ligands and two N,N-dimethyl-formamide (DMF) solvent mol-ecules. The coordination geometry of each Ag atom is distorted tetra-hedral. Two Ag ions are coordinated by μ(2)-S and μ(5)-S atoms, and by two P atoms from two dppm ligands, while the other two Ag atoms are coordinated by μ(2)-S, μ(3)-S and μ(5)-S atoms, and by one P atom from a dppm ligand.

Related literature

For related structures, see: Yu et al. (2001 ▶). For general background to Mo(W)—Cu(Ag)—S clusters derived from tetra­thio­tungstate and tetra­thio­molybdate [MS4]2−(M = Mo, W) synthons, see: George et al.(2000 ▶, 2003 ▶); Hong et al. (1997 ▶); Lang et al. (2006 ▶); Niu et al. (2005 ▶); Ren et al. (2006 ▶); Shi et al. (1995 ▶); Yu et al. (2001 ▶); Zhang et al. (2000 ▶, 2004 ▶).

Experimental

Crystal data

[Ag4W2S8(C25H22P2)3]·2C3H7NO

M = 2354.95

Monoclinic,

a = 22.931 (2) Å

b = 14.0395 (12) Å

c = 27.855 (3) Å

β = 107.224 (1)°

V = 8565.6 (14) Å3

Z = 4

Mo Kα radiation

μ = 3.93 mm−1

T = 93 K

0.47 × 0.43 × 0.43 mm

Data collection

Rigaku R-AXIS RAPID diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.262, T max = 0.281

69256 measured reflections

19520 independent reflections

18777 reflections with I > 2σ(I)

R int = 0.045

Refinement

R[F 2 > 2σ(F 2)] = 0.039

wR(F 2) = 0.089

S = 1.14

19520 reflections

950 parameters

H-atom parameters constrained

Δρmax = 1.20 e Å−3

Δρmin = −1.36 e Å−3

Data collection: RAPID-AUTO (Rigaku, 2004 ▶); cell refinement: RAPID-AUTO; data reduction: RAPID-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEPIII (Burnett & Johnson, 1996 ▶) and ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810034197/dn2590sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810034197/dn2590Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag4W2S8(C25H22P2)3]·2C3H7NO	F(000) = 4600
Mr = 2354.95	Dx = 1.826 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 27248 reflections
a = 22.931 (2) Å	θ = 3.0–27.5°
b = 14.0395 (12) Å	µ = 3.93 mm−1
c = 27.855 (3) Å	T = 93 K
β = 107.224 (1)°	Block, yellow
V = 8565.6 (14) Å3	0.47 × 0.43 × 0.43 mm
Z = 4

Rigaku R-AXIS RAPID diffractometer	19520 independent reflections
Radiation source: Rotating Anode	18777 reflections with I > 2σ(I)
graphite	Rint = 0.045
ω scans	θmax = 27.5°, θmin = 3.0°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −29→20
Tmin = 0.262, Tmax = 0.281	k = −18→18
69256 measured reflections	l = −35→36

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.089	H-atom parameters constrained
S = 1.14	w = 1/[σ2(Fo2) + (0.0341P)2 + 13.8363P] where P = (Fo2 + 2Fc2)/3
19520 reflections	(Δ/σ)max = 0.009
950 parameters	Δρmax = 1.20 e Å−3
0 restraints	Δρmin = −1.36 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
W1	0.685156 (8)	0.527538 (12)	0.590934 (6)	0.00959 (5)
W2	0.828154 (8)	0.329261 (13)	0.458854 (7)	0.01383 (5)
Ag1	0.701283 (16)	0.55717 (2)	0.490031 (13)	0.01578 (7)
Ag2	0.797387 (15)	0.41531 (2)	0.598751 (13)	0.01418 (7)
Ag3	0.776781 (15)	0.20725 (2)	0.532723 (12)	0.01373 (7)
Ag4	0.693052 (15)	0.34050 (2)	0.401396 (12)	0.01168 (7)
S1	0.60897 (5)	0.52790 (8)	0.52055 (4)	0.0157 (2)
S2	0.77015 (5)	0.59208 (8)	0.57931 (4)	0.0129 (2)
S3	0.70064 (5)	0.37936 (8)	0.62017 (4)	0.0136 (2)
S4	0.65859 (5)	0.61359 (8)	0.64489 (4)	0.0154 (2)
S5	0.75460 (5)	0.37745 (8)	0.49394 (4)	0.0136 (2)
S6	0.84065 (6)	0.17432 (9)	0.46535 (5)	0.0247 (3)
S7	0.79958 (5)	0.36970 (9)	0.37903 (4)	0.0156 (2)
S8	0.91157 (6)	0.40177 (12)	0.49661 (5)	0.0332 (3)
P1	0.70165 (5)	0.64377 (8)	0.41615 (4)	0.0122 (2)
P2	0.90214 (5)	0.37198 (8)	0.63471 (4)	0.0119 (2)
P3	0.86722 (5)	0.16721 (8)	0.60311 (4)	0.0123 (2)
P4	0.68282 (5)	0.11687 (8)	0.49608 (4)	0.0110 (2)
P5	0.65584 (5)	0.17597 (8)	0.38414 (4)	0.0100 (2)
P6	0.64487 (5)	0.47428 (8)	0.34787 (4)	0.0112 (2)
C1	0.7730 (2)	0.7088 (3)	0.42479 (17)	0.0187 (10)
C2	0.8271 (2)	0.6582 (4)	0.4461 (2)	0.0272 (12)
H2	0.8255	0.5942	0.4567	0.033*
C3	0.8832 (3)	0.7019 (5)	0.4518 (2)	0.0370 (15)
H3	0.9200	0.6673	0.4655	0.044*
C4	0.8853 (3)	0.7961 (5)	0.4374 (2)	0.0437 (18)
H4	0.9236	0.8258	0.4412	0.052*
C5	0.8326 (3)	0.8468 (5)	0.4178 (2)	0.0433 (17)
H5	0.8345	0.9118	0.4090	0.052*
C6	0.7761 (3)	0.8030 (4)	0.4107 (2)	0.0288 (12)
H6	0.7396	0.8377	0.3962	0.035*
C7	0.6402 (2)	0.7312 (3)	0.39761 (17)	0.0153 (9)
C8	0.6100 (2)	0.7549 (3)	0.43287 (19)	0.0203 (10)
H8	0.6220	0.7256	0.4651	0.024*
C9	0.5629 (3)	0.8202 (4)	0.4214 (2)	0.0282 (12)
H9	0.5431	0.8370	0.4457	0.034*
C10	0.5449 (2)	0.8609 (4)	0.3743 (2)	0.0281 (12)
H10	0.5121	0.9051	0.3661	0.034*
C11	0.5742 (3)	0.8380 (4)	0.3387 (2)	0.0257 (11)
H11	0.5612	0.8665	0.3064	0.031*
C12	0.6221 (2)	0.7741 (3)	0.35032 (18)	0.0191 (10)
H12	0.6426	0.7594	0.3262	0.023*
C13	0.6964 (2)	0.5780 (3)	0.35824 (16)	0.0130 (9)
H13A	0.7378	0.5560	0.3592	0.016*
H13B	0.6820	0.6220	0.3293	0.016*
C14	0.5696 (2)	0.5181 (3)	0.34616 (17)	0.0141 (9)
C15	0.5491 (2)	0.5052 (3)	0.38825 (17)	0.0155 (9)
H15	0.5748	0.4752	0.4174	0.019*
C16	0.4916 (2)	0.5358 (3)	0.38777 (19)	0.0201 (10)
H16	0.4786	0.5278	0.4168	0.024*
C17	0.4532 (2)	0.5778 (3)	0.3455 (2)	0.0224 (11)
H17	0.4136	0.5978	0.3453	0.027*
C18	0.4728 (2)	0.5907 (4)	0.30313 (19)	0.0236 (11)
H18	0.4464	0.6193	0.2738	0.028*
C19	0.5311 (2)	0.5619 (3)	0.30380 (19)	0.0196 (10)
H19	0.5446	0.5722	0.2751	0.024*
C20	0.6363 (2)	0.4418 (3)	0.28259 (18)	0.0152 (9)
C21	0.6730 (2)	0.4792 (3)	0.25509 (17)	0.0169 (9)
H21	0.7017	0.5278	0.2694	0.020*
C22	0.6680 (2)	0.4458 (4)	0.20679 (19)	0.0234 (11)
H22	0.6928	0.4719	0.1882	0.028*
C23	0.6265 (2)	0.3743 (4)	0.18612 (19)	0.0256 (11)
H23	0.6230	0.3515	0.1533	0.031*
C24	0.5905 (3)	0.3362 (4)	0.21297 (19)	0.0269 (12)
H24	0.5630	0.2860	0.1989	0.032*
C25	0.5941 (2)	0.3709 (3)	0.26080 (18)	0.0201 (10)
H25	0.5678	0.3462	0.2785	0.024*
C26	0.57227 (19)	0.1766 (3)	0.36167 (16)	0.0112 (8)
C27	0.5416 (2)	0.2602 (3)	0.36530 (18)	0.0173 (9)
H27	0.5644	0.3144	0.3807	0.021*
C28	0.4787 (2)	0.2666 (4)	0.3470 (2)	0.0244 (11)
H28	0.4587	0.3248	0.3496	0.029*
C29	0.4448 (2)	0.1873 (4)	0.32495 (19)	0.0215 (10)
H29	0.4016	0.1913	0.3118	0.026*
C30	0.4751 (2)	0.1017 (3)	0.32236 (18)	0.0189 (10)
H30	0.4522	0.0465	0.3087	0.023*
C31	0.5378 (2)	0.0973 (3)	0.33959 (17)	0.0173 (9)
H31	0.5580	0.0395	0.3364	0.021*
C32	0.6776 (2)	0.1222 (3)	0.33224 (16)	0.0114 (8)
C33	0.6938 (2)	0.1824 (3)	0.29875 (17)	0.0162 (9)
H33	0.6965	0.2491	0.3049	0.019*
C34	0.7063 (2)	0.1462 (4)	0.25613 (18)	0.0201 (10)
H34	0.7169	0.1880	0.2333	0.024*
C35	0.7029 (2)	0.0485 (4)	0.24736 (18)	0.0209 (10)
H35	0.7113	0.0236	0.2184	0.025*
C36	0.6874 (2)	−0.0127 (3)	0.28086 (18)	0.0200 (10)
H36	0.6848	−0.0793	0.2747	0.024*
C37	0.6757 (2)	0.0242 (3)	0.32364 (18)	0.0183 (10)
H37	0.6664	−0.0178	0.3471	0.022*
C38	0.6761 (2)	0.0792 (3)	0.43110 (16)	0.0134 (9)
H38A	0.7154	0.0511	0.4304	0.016*
H38B	0.6446	0.0288	0.4212	0.016*
C39	0.6064 (2)	0.1611 (3)	0.49084 (16)	0.0119 (8)
C40	0.5981 (2)	0.2566 (3)	0.50130 (18)	0.0187 (10)
H40	0.6324	0.2970	0.5143	0.022*
C41	0.5393 (2)	0.2920 (4)	0.4926 (2)	0.0233 (11)
H41	0.5335	0.3568	0.4998	0.028*
C42	0.4894 (2)	0.2340 (4)	0.4736 (2)	0.0248 (11)
H42	0.4494	0.2594	0.4672	0.030*
C43	0.4970 (2)	0.1386 (4)	0.46372 (18)	0.0193 (10)
H43	0.4624	0.0985	0.4513	0.023*
C44	0.5557 (2)	0.1020 (3)	0.47208 (17)	0.0159 (9)
H44	0.5612	0.0370	0.4650	0.019*
C45	0.6863 (2)	0.0014 (3)	0.52730 (17)	0.0144 (9)
C46	0.7188 (2)	−0.0738 (3)	0.51465 (18)	0.0198 (10)
H46	0.7371	−0.0662	0.4885	0.024*
C47	0.7243 (3)	−0.1603 (4)	0.54060 (19)	0.0254 (11)
H47	0.7460	−0.2117	0.5318	0.030*
C48	0.6979 (2)	−0.1708 (4)	0.57924 (19)	0.0245 (11)
H48	0.7016	−0.2295	0.5968	0.029*
C49	0.6666 (2)	−0.0966 (4)	0.59207 (19)	0.0246 (11)
H49	0.6486	−0.1044	0.6185	0.030*
C50	0.6608 (2)	−0.0102 (4)	0.56679 (18)	0.0204 (10)
H50	0.6395	0.0410	0.5763	0.024*
C51	0.9045 (2)	0.0612 (3)	0.58746 (16)	0.0156 (9)
C52	0.8728 (3)	−0.0241 (4)	0.5823 (2)	0.0297 (12)
H52	0.8345	−0.0265	0.5890	0.036*
C53	0.8965 (3)	−0.1062 (4)	0.5675 (2)	0.0377 (15)
H53	0.8744	−0.1643	0.5638	0.045*
C54	0.9519 (3)	−0.1034 (4)	0.5582 (2)	0.0327 (13)
H54	0.9682	−0.1597	0.5483	0.039*
C55	0.9841 (3)	−0.0190 (4)	0.5631 (2)	0.0297 (12)
H55	1.0223	−0.0171	0.5563	0.036*
C56	0.9603 (2)	0.0633 (4)	0.5781 (2)	0.0246 (11)
H56	0.9826	0.1212	0.5819	0.030*
C57	0.8633 (2)	0.1414 (3)	0.66613 (17)	0.0137 (9)
C58	0.9155 (2)	0.1100 (3)	0.70346 (17)	0.0182 (10)
H58	0.9518	0.0962	0.6950	0.022*
C59	0.9142 (2)	0.0992 (4)	0.75240 (18)	0.0200 (10)
H59	0.9496	0.0777	0.7775	0.024*
C60	0.8614 (2)	0.1197 (4)	0.76500 (18)	0.0209 (10)
H60	0.8610	0.1132	0.7989	0.025*
C61	0.8097 (2)	0.1492 (3)	0.72898 (19)	0.0188 (10)
H61	0.7737	0.1628	0.7379	0.023*
C62	0.8100 (2)	0.1593 (3)	0.67889 (18)	0.0170 (9)
H62	0.7739	0.1783	0.6538	0.020*
C63	0.92682 (19)	0.2589 (3)	0.61403 (16)	0.0116 (8)
H63A	0.9638	0.2360	0.6399	0.014*
H63B	0.9377	0.2695	0.5826	0.014*
C64	0.9232 (2)	0.3680 (3)	0.70338 (17)	0.0138 (9)
C65	0.9833 (2)	0.3707 (4)	0.73330 (18)	0.0212 (10)
H65	1.0153	0.3700	0.7181	0.025*
C66	0.9974 (2)	0.3745 (4)	0.78542 (19)	0.0251 (11)
H66	1.0388	0.3787	0.8055	0.030*
C67	0.9514 (3)	0.3723 (4)	0.80778 (19)	0.0286 (12)
H67	0.9612	0.3739	0.8434	0.034*
C68	0.8912 (3)	0.3677 (4)	0.77874 (19)	0.0277 (12)
H68	0.8595	0.3658	0.7943	0.033*
C69	0.8771 (2)	0.3658 (3)	0.72647 (18)	0.0191 (10)
H69	0.8357	0.3630	0.7065	0.023*
C70	0.9557 (2)	0.4595 (3)	0.62351 (17)	0.0142 (9)
C71	1.0132 (2)	0.4363 (3)	0.61976 (17)	0.0153 (9)
H71	1.0264	0.3718	0.6227	0.018*
C72	1.0514 (2)	0.5073 (3)	0.61178 (17)	0.0173 (9)
H72	1.0904	0.4913	0.6087	0.021*
C73	1.0329 (2)	0.6012 (4)	0.60827 (18)	0.0205 (10)
H73	1.0593	0.6496	0.6030	0.025*
C74	0.9756 (2)	0.6252 (4)	0.61239 (19)	0.0226 (11)
H74	0.9633	0.6900	0.6108	0.027*
C75	0.9368 (2)	0.5540 (3)	0.61882 (19)	0.0193 (10)
H75	0.8970	0.5699	0.6200	0.023*
O1	0.71217 (18)	0.7272 (3)	0.26992 (15)	0.0286 (9)
N1	0.78968 (19)	0.6532 (3)	0.24912 (16)	0.0215 (9)
C76	0.7377 (2)	0.7023 (3)	0.2391 (2)	0.0230 (11)
H76	0.7188	0.7196	0.2050	0.028*
C77	0.8220 (2)	0.6244 (4)	0.3001 (2)	0.0287 (12)
H77A	0.8074	0.6621	0.3239	0.043*
H77B	0.8659	0.6350	0.3065	0.043*
H77C	0.8145	0.5567	0.3044	0.043*
C78	0.8173 (3)	0.6276 (4)	0.2097 (2)	0.0303 (12)
H78A	0.7921	0.6525	0.1773	0.045*
H78B	0.8199	0.5581	0.2078	0.045*
H78C	0.8583	0.6550	0.2177	0.045*
O2	0.9365 (2)	0.6952 (4)	0.83007 (18)	0.0508 (13)
N2	0.8745 (2)	0.6405 (3)	0.75669 (18)	0.0266 (10)
C79	0.8866 (3)	0.6654 (4)	0.8036 (2)	0.0352 (14)
H79	0.8546	0.6604	0.8186	0.042*
C80	0.9225 (3)	0.6454 (5)	0.7310 (3)	0.0405 (15)
H80A	0.9587	0.6772	0.7530	0.061*
H80B	0.9072	0.6815	0.6997	0.061*
H80C	0.9334	0.5808	0.7235	0.061*
C81	0.8168 (3)	0.6078 (5)	0.7255 (3)	0.0424 (16)
H81A	0.7874	0.6068	0.7448	0.064*
H81B	0.8213	0.5434	0.7135	0.064*
H81C	0.8021	0.6507	0.6966	0.064*

	U11	U22	U33	U12	U13	U23
W1	0.00959 (9)	0.01051 (8)	0.00897 (8)	0.00050 (6)	0.00322 (7)	0.00076 (6)
W2	0.01041 (9)	0.02124 (10)	0.00953 (9)	−0.00198 (7)	0.00248 (7)	0.00324 (7)
Ag1	0.01769 (18)	0.01876 (17)	0.01144 (16)	0.00004 (13)	0.00515 (13)	0.00419 (13)
Ag2	0.00979 (16)	0.01623 (16)	0.01571 (17)	0.00196 (12)	0.00253 (13)	0.00284 (13)
Ag3	0.01196 (17)	0.01387 (16)	0.01320 (16)	−0.00216 (12)	0.00038 (13)	0.00199 (12)
Ag4	0.01172 (16)	0.01111 (15)	0.01114 (15)	−0.00089 (12)	0.00175 (12)	0.00073 (12)
S1	0.0119 (5)	0.0230 (6)	0.0107 (5)	−0.0008 (4)	0.0009 (4)	0.0018 (4)
S2	0.0118 (5)	0.0124 (5)	0.0151 (5)	−0.0015 (4)	0.0049 (4)	0.0014 (4)
S3	0.0149 (5)	0.0121 (5)	0.0154 (5)	0.0014 (4)	0.0069 (4)	0.0030 (4)
S4	0.0166 (6)	0.0149 (5)	0.0165 (5)	0.0016 (4)	0.0077 (4)	−0.0022 (4)
S5	0.0178 (6)	0.0134 (5)	0.0100 (5)	−0.0002 (4)	0.0047 (4)	0.0002 (4)
S6	0.0313 (7)	0.0250 (6)	0.0236 (6)	0.0131 (5)	0.0168 (6)	0.0079 (5)
S7	0.0139 (6)	0.0241 (6)	0.0093 (5)	−0.0017 (4)	0.0043 (4)	0.0032 (4)
S8	0.0199 (7)	0.0608 (10)	0.0151 (6)	−0.0208 (6)	−0.0006 (5)	0.0056 (6)
P1	0.0146 (6)	0.0116 (5)	0.0102 (5)	−0.0019 (4)	0.0036 (4)	0.0007 (4)
P2	0.0103 (5)	0.0127 (5)	0.0118 (5)	−0.0002 (4)	0.0019 (4)	0.0012 (4)
P3	0.0126 (6)	0.0123 (5)	0.0105 (5)	−0.0008 (4)	0.0012 (4)	0.0014 (4)
P4	0.0119 (5)	0.0107 (5)	0.0099 (5)	−0.0015 (4)	0.0026 (4)	0.0009 (4)
P5	0.0110 (5)	0.0100 (5)	0.0089 (5)	−0.0003 (4)	0.0027 (4)	0.0002 (4)
P6	0.0111 (6)	0.0112 (5)	0.0111 (5)	0.0000 (4)	0.0032 (4)	0.0017 (4)
C1	0.024 (3)	0.021 (2)	0.014 (2)	−0.0047 (19)	0.0099 (19)	−0.0057 (19)
C2	0.020 (3)	0.031 (3)	0.030 (3)	−0.004 (2)	0.006 (2)	−0.009 (2)
C3	0.021 (3)	0.056 (4)	0.034 (3)	−0.010 (3)	0.007 (2)	−0.016 (3)
C4	0.039 (4)	0.067 (5)	0.032 (3)	−0.035 (3)	0.020 (3)	−0.021 (3)
C5	0.050 (4)	0.041 (4)	0.040 (4)	−0.030 (3)	0.016 (3)	−0.005 (3)
C6	0.034 (3)	0.027 (3)	0.025 (3)	−0.015 (2)	0.009 (2)	0.003 (2)
C7	0.018 (2)	0.011 (2)	0.017 (2)	−0.0027 (17)	0.0049 (19)	0.0010 (17)
C8	0.025 (3)	0.016 (2)	0.021 (2)	−0.0004 (19)	0.010 (2)	−0.0008 (19)
C9	0.032 (3)	0.022 (3)	0.036 (3)	0.004 (2)	0.019 (3)	0.004 (2)
C10	0.024 (3)	0.022 (3)	0.039 (3)	0.004 (2)	0.009 (2)	0.005 (2)
C11	0.029 (3)	0.019 (2)	0.029 (3)	0.002 (2)	0.008 (2)	0.006 (2)
C12	0.028 (3)	0.015 (2)	0.015 (2)	0.0009 (19)	0.008 (2)	0.0018 (18)
C13	0.014 (2)	0.014 (2)	0.010 (2)	−0.0012 (17)	0.0027 (17)	0.0031 (17)
C14	0.015 (2)	0.014 (2)	0.015 (2)	−0.0031 (17)	0.0063 (18)	−0.0027 (17)
C15	0.015 (2)	0.015 (2)	0.016 (2)	−0.0023 (17)	0.0044 (18)	−0.0044 (18)
C16	0.018 (3)	0.024 (3)	0.019 (2)	−0.0012 (19)	0.008 (2)	−0.003 (2)
C17	0.015 (2)	0.020 (2)	0.034 (3)	0.0037 (19)	0.009 (2)	−0.001 (2)
C18	0.020 (3)	0.026 (3)	0.021 (3)	0.004 (2)	0.000 (2)	0.004 (2)
C19	0.019 (3)	0.021 (2)	0.021 (2)	0.0055 (19)	0.008 (2)	0.006 (2)
C20	0.014 (2)	0.010 (2)	0.020 (2)	0.0033 (17)	0.0036 (18)	0.0031 (18)
C21	0.013 (2)	0.022 (2)	0.015 (2)	0.0022 (18)	0.0031 (18)	0.0002 (18)
C22	0.023 (3)	0.032 (3)	0.016 (2)	0.009 (2)	0.007 (2)	0.001 (2)
C23	0.031 (3)	0.028 (3)	0.014 (2)	0.003 (2)	0.001 (2)	−0.003 (2)
C24	0.042 (3)	0.015 (2)	0.017 (2)	−0.005 (2)	−0.002 (2)	−0.0003 (19)
C25	0.025 (3)	0.016 (2)	0.016 (2)	−0.0064 (19)	0.000 (2)	0.0033 (18)
C26	0.009 (2)	0.017 (2)	0.0078 (19)	0.0001 (16)	0.0029 (16)	0.0040 (16)
C27	0.018 (2)	0.016 (2)	0.019 (2)	−0.0002 (18)	0.0084 (19)	0.0023 (18)
C28	0.019 (3)	0.020 (2)	0.037 (3)	0.005 (2)	0.012 (2)	0.000 (2)
C29	0.011 (2)	0.033 (3)	0.022 (3)	−0.002 (2)	0.0048 (19)	0.002 (2)
C30	0.018 (2)	0.021 (2)	0.017 (2)	−0.0063 (19)	0.0049 (19)	−0.0068 (19)
C31	0.019 (2)	0.018 (2)	0.014 (2)	−0.0008 (18)	0.0030 (19)	−0.0003 (18)
C32	0.013 (2)	0.012 (2)	0.0088 (19)	0.0016 (16)	0.0031 (16)	−0.0014 (16)
C33	0.018 (2)	0.014 (2)	0.017 (2)	0.0010 (17)	0.0056 (19)	0.0008 (18)
C34	0.020 (3)	0.026 (3)	0.017 (2)	−0.003 (2)	0.010 (2)	0.002 (2)
C35	0.024 (3)	0.027 (3)	0.013 (2)	0.000 (2)	0.007 (2)	−0.004 (2)
C36	0.028 (3)	0.011 (2)	0.020 (2)	0.0032 (19)	0.006 (2)	−0.0052 (18)
C37	0.025 (3)	0.017 (2)	0.014 (2)	0.0002 (19)	0.007 (2)	0.0025 (18)
C38	0.016 (2)	0.012 (2)	0.012 (2)	−0.0024 (17)	0.0048 (18)	−0.0011 (17)
C39	0.011 (2)	0.017 (2)	0.0081 (19)	−0.0030 (16)	0.0038 (16)	0.0013 (16)
C40	0.018 (2)	0.017 (2)	0.019 (2)	−0.0022 (18)	0.0034 (19)	−0.0039 (19)
C41	0.023 (3)	0.017 (2)	0.033 (3)	0.003 (2)	0.013 (2)	−0.002 (2)
C42	0.018 (3)	0.033 (3)	0.025 (3)	0.003 (2)	0.009 (2)	−0.003 (2)
C43	0.015 (2)	0.023 (2)	0.019 (2)	−0.0064 (19)	0.0053 (19)	−0.005 (2)
C44	0.017 (2)	0.017 (2)	0.015 (2)	−0.0040 (18)	0.0071 (18)	−0.0027 (18)
C45	0.013 (2)	0.018 (2)	0.012 (2)	−0.0051 (17)	0.0032 (17)	0.0018 (17)
C46	0.028 (3)	0.017 (2)	0.015 (2)	−0.0001 (19)	0.006 (2)	0.0006 (18)
C47	0.037 (3)	0.017 (2)	0.018 (2)	0.000 (2)	0.001 (2)	−0.001 (2)
C48	0.030 (3)	0.018 (2)	0.019 (3)	−0.006 (2)	−0.003 (2)	0.002 (2)
C49	0.027 (3)	0.030 (3)	0.017 (2)	−0.006 (2)	0.007 (2)	0.009 (2)
C50	0.024 (3)	0.024 (2)	0.015 (2)	0.001 (2)	0.007 (2)	0.0054 (19)
C51	0.019 (2)	0.014 (2)	0.010 (2)	0.0035 (18)	−0.0017 (18)	0.0002 (17)
C52	0.028 (3)	0.023 (3)	0.037 (3)	0.000 (2)	0.008 (3)	−0.003 (2)
C53	0.044 (4)	0.015 (3)	0.051 (4)	−0.004 (2)	0.008 (3)	−0.012 (3)
C54	0.050 (4)	0.024 (3)	0.020 (3)	0.011 (3)	0.003 (3)	−0.008 (2)
C55	0.034 (3)	0.027 (3)	0.029 (3)	0.013 (2)	0.011 (2)	0.004 (2)
C56	0.027 (3)	0.020 (2)	0.029 (3)	0.004 (2)	0.011 (2)	0.003 (2)
C57	0.014 (2)	0.013 (2)	0.013 (2)	−0.0018 (17)	0.0026 (17)	0.0019 (17)
C58	0.015 (2)	0.026 (2)	0.014 (2)	−0.0007 (19)	0.0050 (18)	0.0014 (19)
C59	0.019 (3)	0.025 (3)	0.013 (2)	0.001 (2)	0.0019 (19)	0.0066 (19)
C60	0.026 (3)	0.024 (2)	0.014 (2)	−0.002 (2)	0.009 (2)	0.0015 (19)
C61	0.018 (2)	0.018 (2)	0.024 (3)	−0.0007 (18)	0.013 (2)	0.0030 (19)
C62	0.014 (2)	0.015 (2)	0.022 (2)	−0.0009 (17)	0.0066 (19)	0.0015 (18)
C63	0.008 (2)	0.016 (2)	0.012 (2)	−0.0002 (16)	0.0050 (16)	0.0009 (17)
C64	0.017 (2)	0.0093 (19)	0.013 (2)	−0.0019 (17)	0.0017 (18)	−0.0012 (16)
C65	0.018 (3)	0.027 (3)	0.016 (2)	0.002 (2)	0.0018 (19)	0.001 (2)
C66	0.020 (3)	0.030 (3)	0.019 (2)	−0.002 (2)	−0.005 (2)	−0.001 (2)
C67	0.035 (3)	0.036 (3)	0.011 (2)	−0.002 (2)	0.001 (2)	−0.005 (2)
C68	0.034 (3)	0.036 (3)	0.017 (3)	−0.005 (2)	0.013 (2)	−0.006 (2)
C69	0.018 (2)	0.021 (2)	0.018 (2)	−0.0015 (19)	0.0045 (19)	−0.0052 (19)
C70	0.012 (2)	0.017 (2)	0.012 (2)	−0.0031 (17)	0.0015 (17)	0.0004 (17)
C71	0.013 (2)	0.017 (2)	0.014 (2)	−0.0020 (17)	0.0021 (18)	0.0007 (18)
C72	0.016 (2)	0.024 (2)	0.015 (2)	−0.0050 (19)	0.0088 (19)	−0.0020 (19)
C73	0.021 (3)	0.023 (2)	0.016 (2)	−0.008 (2)	0.004 (2)	0.0018 (19)
C74	0.021 (3)	0.017 (2)	0.027 (3)	−0.0029 (19)	0.004 (2)	0.004 (2)
C75	0.010 (2)	0.018 (2)	0.028 (3)	−0.0020 (18)	0.0035 (19)	−0.001 (2)
O1	0.031 (2)	0.0237 (19)	0.035 (2)	0.0058 (16)	0.0170 (18)	0.0087 (17)
N1	0.020 (2)	0.022 (2)	0.023 (2)	−0.0003 (17)	0.0074 (18)	0.0044 (18)
C76	0.021 (3)	0.017 (2)	0.031 (3)	0.0007 (19)	0.009 (2)	0.012 (2)
C77	0.022 (3)	0.034 (3)	0.026 (3)	−0.001 (2)	0.001 (2)	0.008 (2)
C78	0.029 (3)	0.028 (3)	0.037 (3)	0.006 (2)	0.014 (3)	0.004 (2)
O2	0.026 (2)	0.071 (3)	0.043 (3)	−0.006 (2)	−0.008 (2)	−0.016 (3)
N2	0.017 (2)	0.028 (2)	0.032 (3)	0.0030 (18)	0.0038 (19)	−0.007 (2)
C79	0.029 (3)	0.043 (4)	0.032 (3)	0.004 (3)	0.005 (3)	−0.001 (3)
C80	0.039 (4)	0.045 (4)	0.043 (4)	0.001 (3)	0.020 (3)	−0.006 (3)
C81	0.027 (3)	0.034 (3)	0.056 (4)	−0.002 (3)	−0.003 (3)	−0.016 (3)

W1—S4	2.1523 (11)	C32—C33	1.390 (6)
W1—S1	2.2062 (11)	C32—C37	1.395 (6)
W1—S3	2.2240 (11)	C33—C34	1.396 (6)
W1—S2	2.2579 (11)	C33—H33	0.9500
W1—Ag2	2.9701 (4)	C34—C35	1.391 (7)
W1—Ag1	2.9707 (5)	C34—H34	0.9500
W2—S8	2.1470 (13)	C35—C36	1.390 (7)
W2—S6	2.1945 (13)	C35—H35	0.9500
W2—S7	2.1985 (11)	C36—C37	1.396 (6)
W2—S5	2.2878 (11)	C36—H36	0.9500
W2—Ag4	3.0410 (4)	C37—H37	0.9500
W2—Ag3	3.1609 (4)	C38—H38A	0.9900
Ag1—P1	2.3924 (12)	C38—H38B	0.9900
Ag1—S1	2.5374 (12)	C39—C40	1.396 (6)
Ag1—S2	2.5677 (12)	C39—C44	1.398 (6)
Ag1—S5	2.7919 (12)	C40—C41	1.390 (7)
Ag2—P2	2.3914 (12)	C40—H40	0.9500
Ag2—S3	2.5132 (11)	C41—C42	1.376 (7)
Ag2—S2	2.5772 (11)	C41—H41	0.9500
Ag2—S5	2.8412 (12)	C42—C43	1.389 (7)
Ag3—P4	2.4478 (12)	C42—H42	0.9500
Ag3—P3	2.4602 (12)	C43—C44	1.394 (7)
Ag3—S5	2.6096 (12)	C43—H43	0.9500
Ag3—S6	2.7403 (13)	C44—H44	0.9500
Ag4—P6	2.4485 (12)	C45—C46	1.396 (7)
Ag4—P5	2.4601 (11)	C45—C50	1.400 (6)
Ag4—S5	2.5984 (12)	C46—C47	1.400 (7)
Ag4—S7	2.7248 (12)	C46—H46	0.9500
P1—C1	1.826 (5)	C47—C48	1.390 (8)
P1—C7	1.824 (5)	C47—H47	0.9500
P1—C13	1.831 (4)	C48—C49	1.371 (8)
P2—C70	1.829 (5)	C48—H48	0.9500
P2—C64	1.830 (5)	C49—C50	1.389 (7)
P2—C63	1.835 (4)	C49—H49	0.9500
P3—C57	1.820 (5)	C50—H50	0.9500
P3—C51	1.831 (5)	C51—C56	1.380 (7)
P3—C63	1.836 (4)	C51—C52	1.387 (7)
P4—C39	1.823 (5)	C52—C53	1.390 (8)
P4—C45	1.830 (5)	C52—H52	0.9500
P4—C38	1.848 (4)	C53—C54	1.369 (9)
P5—C32	1.826 (4)	C53—H53	0.9500
P5—C26	1.832 (4)	C54—C55	1.381 (8)
P5—C38	1.847 (4)	C54—H54	0.9500
P6—C14	1.820 (5)	C55—C56	1.394 (7)
P6—C20	1.828 (5)	C55—H55	0.9500
P6—C13	1.844 (4)	C56—H56	0.9500
C1—C6	1.387 (7)	C57—C62	1.395 (6)
C1—C2	1.399 (7)	C57—C58	1.403 (6)
C2—C3	1.392 (8)	C58—C59	1.381 (6)
C2—H2	0.9500	C58—H58	0.9500
C3—C4	1.386 (10)	C59—C60	1.387 (7)
C3—H3	0.9500	C59—H59	0.9500
C4—C5	1.369 (10)	C60—C61	1.371 (7)
C4—H4	0.9500	C60—H60	0.9500
C5—C6	1.394 (8)	C61—C62	1.404 (7)
C5—H5	0.9500	C61—H61	0.9500
C6—H6	0.9500	C62—H62	0.9500
C7—C12	1.395 (6)	C63—H63A	0.9900
C7—C8	1.400 (6)	C63—H63B	0.9900
C8—C9	1.380 (7)	C64—C69	1.389 (6)
C8—H8	0.9500	C64—C65	1.385 (7)
C9—C10	1.376 (8)	C65—C66	1.392 (7)
C9—H9	0.9500	C65—H65	0.9500
C10—C11	1.388 (8)	C66—C67	1.375 (8)
C10—H10	0.9500	C66—H66	0.9500
C11—C12	1.381 (7)	C67—C68	1.380 (8)
C11—H11	0.9500	C67—H67	0.9500
C12—H12	0.9500	C68—C69	1.395 (7)
C13—H13A	0.9900	C68—H68	0.9500
C13—H13B	0.9900	C69—H69	0.9500
C14—C19	1.390 (7)	C70—C71	1.392 (6)
C14—C15	1.399 (6)	C70—C75	1.390 (6)
C15—C16	1.381 (7)	C71—C72	1.388 (6)
C15—H15	0.9500	C71—H71	0.9500
C16—C17	1.376 (7)	C72—C73	1.378 (7)
C16—H16	0.9500	C72—H72	0.9500
C17—C18	1.394 (7)	C73—C74	1.394 (7)
C17—H17	0.9500	C73—H73	0.9500
C18—C19	1.390 (7)	C74—C75	1.385 (6)
C18—H18	0.9500	C74—H74	0.9500
C19—H19	0.9500	C75—H75	0.9500
C20—C21	1.398 (6)	O1—C76	1.224 (6)
C20—C25	1.396 (6)	N1—C76	1.333 (6)
C21—C22	1.397 (6)	N1—C77	1.452 (6)
C21—H21	0.9500	N1—C78	1.465 (7)
C22—C23	1.384 (8)	C76—H76	0.9500
C22—H22	0.9500	C77—H77A	0.9800
C23—C24	1.376 (8)	C77—H77B	0.9800
C23—H23	0.9500	C77—H77C	0.9800
C24—C25	1.398 (7)	C78—H78A	0.9800
C24—H24	0.9500	C78—H78B	0.9800
C25—H25	0.9500	C78—H78C	0.9800
C26—C27	1.387 (6)	O2—C79	1.237 (7)
C26—C31	1.399 (6)	N2—C79	1.300 (7)
C27—C28	1.383 (7)	N2—C81	1.427 (7)
C27—H27	0.9500	N2—C80	1.481 (7)
C28—C29	1.392 (7)	C79—H79	0.9500
C28—H28	0.9500	C80—H80A	0.9800
C29—C30	1.401 (7)	C80—H80B	0.9800
C29—H29	0.9500	C80—H80C	0.9800
C30—C31	1.376 (7)	C81—H81A	0.9800
C30—H30	0.9500	C81—H81B	0.9800
C31—H31	0.9500	C81—H81C	0.9800
S4—W1—S1	107.81 (4)	C25—C24—H24	119.8
S4—W1—S3	108.47 (4)	C20—C25—C24	120.0 (5)
S1—W1—S3	109.03 (4)	C20—C25—H25	120.0
S4—W1—S2	108.04 (4)	C24—C25—H25	120.0
S1—W1—S2	111.20 (4)	C27—C26—C31	118.3 (4)
S3—W1—S2	112.14 (4)	C27—C26—P5	118.7 (3)
S4—W1—Ag2	131.67 (3)	C31—C26—P5	123.0 (3)
S1—W1—Ag2	120.49 (3)	C28—C27—C26	121.5 (5)
S3—W1—Ag2	55.67 (3)	C28—C27—H27	119.2
S2—W1—Ag2	57.14 (3)	C26—C27—H27	119.2
S4—W1—Ag1	136.25 (3)	C27—C28—C29	119.8 (5)
S1—W1—Ag1	56.40 (3)	C27—C28—H28	120.1
S3—W1—Ag1	115.24 (3)	C29—C28—H28	120.1
S2—W1—Ag1	56.88 (3)	C28—C29—C30	119.2 (5)
Ag2—W1—Ag1	78.214 (10)	C28—C29—H29	120.4
S8—W2—S6	110.73 (6)	C30—C29—H29	120.4
S8—W2—S7	109.18 (5)	C31—C30—C29	120.2 (4)
S6—W2—S7	109.38 (5)	C31—C30—H30	119.9
S8—W2—S5	108.25 (5)	C29—C30—H30	119.9
S6—W2—S5	110.66 (4)	C30—C31—C26	120.9 (4)
S7—W2—S5	108.61 (4)	C30—C31—H31	119.5
S8—W2—Ag4	148.67 (5)	C26—C31—H31	119.5
S6—W2—Ag4	100.53 (4)	C33—C32—C37	119.0 (4)
S7—W2—Ag4	60.14 (3)	C33—C32—P5	118.1 (3)
S5—W2—Ag4	56.25 (3)	C37—C32—P5	122.8 (3)
S8—W2—Ag3	112.82 (4)	C32—C33—C34	120.8 (4)
S6—W2—Ag3	58.26 (3)	C32—C33—H33	119.6
S7—W2—Ag3	137.85 (3)	C34—C33—H33	119.6
S5—W2—Ag3	54.42 (3)	C33—C34—C35	119.6 (4)
Ag4—W2—Ag3	81.533 (11)	C33—C34—H34	120.2
P1—Ag1—S1	125.90 (4)	C35—C34—H34	120.2
P1—Ag1—S2	125.34 (4)	C36—C35—C34	120.2 (4)
S1—Ag1—S2	92.36 (4)	C36—C35—H35	119.9
P1—Ag1—S5	112.32 (4)	C34—C35—H35	119.9
S1—Ag1—S5	103.87 (4)	C35—C36—C37	119.7 (4)
S2—Ag1—S5	89.89 (3)	C35—C36—H36	120.2
P1—Ag1—W1	156.66 (3)	C37—C36—H36	120.2
S1—Ag1—W1	46.40 (3)	C32—C37—C36	120.6 (4)
S2—Ag1—W1	47.43 (2)	C32—C37—H37	119.7
S5—Ag1—W1	90.70 (2)	C36—C37—H37	119.7
P2—Ag2—S3	134.21 (4)	P5—C38—P4	114.5 (2)
P2—Ag2—S2	118.94 (4)	P5—C38—H38A	108.6
S3—Ag2—S2	93.86 (4)	P4—C38—H38A	108.6
P2—Ag2—S5	112.41 (4)	P5—C38—H38B	108.6
S3—Ag2—S5	98.39 (4)	P4—C38—H38B	108.6
S2—Ag2—S5	88.61 (3)	H38A—C38—H38B	107.6
P2—Ag2—W1	155.06 (3)	C40—C39—C44	119.8 (4)
S3—Ag2—W1	46.95 (3)	C40—C39—P4	119.9 (3)
S2—Ag2—W1	47.38 (2)	C44—C39—P4	120.1 (3)
S5—Ag2—W1	89.76 (2)	C41—C40—C39	119.5 (4)
P4—Ag3—P3	130.09 (4)	C41—C40—H40	120.3
P4—Ag3—S5	105.22 (4)	C39—C40—H40	120.3
P3—Ag3—S5	123.65 (4)	C42—C41—C40	120.6 (5)
P4—Ag3—S6	102.12 (4)	C42—C41—H41	119.7
P3—Ag3—S6	90.68 (4)	C40—C41—H41	119.7
S5—Ag3—S6	87.08 (4)	C41—C42—C43	120.5 (5)
P4—Ag3—W2	117.46 (3)	C41—C42—H42	119.8
P3—Ag3—W2	104.71 (3)	C43—C42—H42	119.8
S5—Ag3—W2	45.48 (2)	C42—C43—C44	119.6 (4)
S6—Ag3—W2	42.93 (3)	C42—C43—H43	120.2
P6—Ag4—P5	122.24 (4)	C44—C43—H43	120.2
P6—Ag4—S5	117.74 (4)	C39—C44—C43	120.0 (4)
P5—Ag4—S5	115.87 (4)	C39—C44—H44	120.0
P6—Ag4—S7	91.08 (4)	C43—C44—H44	120.0
P5—Ag4—S7	112.28 (4)	C46—C45—C50	119.2 (4)
S5—Ag4—S7	86.36 (4)	C46—C45—P4	120.1 (3)
P6—Ag4—W2	124.47 (3)	C50—C45—P4	120.5 (4)
P5—Ag4—W2	107.12 (3)	C45—C46—C47	119.9 (5)
S5—Ag4—W2	47.06 (3)	C45—C46—H46	120.0
S7—Ag4—W2	44.41 (2)	C47—C46—H46	120.0
W1—S1—Ag1	77.20 (4)	C48—C47—C46	119.9 (5)
W1—S2—Ag1	75.69 (3)	C48—C47—H47	120.0
W1—S2—Ag2	75.48 (3)	C46—C47—H47	120.0
Ag1—S2—Ag2	93.50 (4)	C49—C48—C47	120.2 (5)
W1—S3—Ag2	77.39 (3)	C49—C48—H48	119.9
W2—S5—Ag4	76.69 (3)	C47—C48—H48	119.9
W2—S5—Ag3	80.10 (3)	C48—C49—C50	120.7 (5)
Ag4—S5—Ag3	102.12 (4)	C48—C49—H49	119.7
W2—S5—Ag1	128.34 (4)	C50—C49—H49	119.7
Ag4—S5—Ag1	92.22 (4)	C49—C50—C45	120.0 (5)
Ag3—S5—Ag1	150.82 (5)	C49—C50—H50	120.0
W2—S5—Ag2	114.86 (4)	C45—C50—H50	120.0
Ag4—S5—Ag2	167.86 (5)	C56—C51—C52	119.1 (5)
Ag3—S5—Ag2	77.31 (3)	C56—C51—P3	123.5 (4)
Ag1—S5—Ag2	83.40 (3)	C52—C51—P3	117.4 (4)
W2—S6—Ag3	78.81 (4)	C51—C52—C53	120.6 (6)
W2—S7—Ag4	75.45 (3)	C51—C52—H52	119.7
C1—P1—C7	106.7 (2)	C53—C52—H52	119.7
C1—P1—C13	101.0 (2)	C54—C53—C52	119.9 (5)
C7—P1—C13	104.3 (2)	C54—C53—H53	120.0
C1—P1—Ag1	111.83 (16)	C52—C53—H53	120.0
C7—P1—Ag1	112.73 (15)	C53—C54—C55	120.3 (5)
C13—P1—Ag1	119.05 (14)	C53—C54—H54	119.8
C70—P2—C64	102.5 (2)	C55—C54—H54	119.8
C70—P2—C63	104.0 (2)	C56—C55—C54	119.7 (6)
C64—P2—C63	106.9 (2)	C56—C55—H55	120.1
C70—P2—Ag2	113.57 (15)	C54—C55—H55	120.1
C64—P2—Ag2	111.52 (15)	C51—C56—C55	120.4 (5)
C63—P2—Ag2	116.97 (15)	C51—C56—H56	119.8
C57—P3—C51	103.1 (2)	C55—C56—H56	119.8
C57—P3—C63	103.1 (2)	C62—C57—C58	119.2 (4)
C51—P3—C63	103.4 (2)	C62—C57—P3	120.5 (3)
C57—P3—Ag3	122.93 (15)	C58—C57—P3	120.2 (3)
C51—P3—Ag3	109.79 (15)	C59—C58—C57	120.2 (4)
C63—P3—Ag3	112.48 (15)	C59—C58—H58	119.9
C39—P4—C45	104.2 (2)	C57—C58—H58	119.9
C39—P4—C38	102.7 (2)	C58—C59—C60	120.2 (5)
C45—P4—C38	101.0 (2)	C58—C59—H59	119.9
C39—P4—Ag3	124.25 (15)	C60—C59—H59	119.9
C45—P4—Ag3	110.63 (15)	C61—C60—C59	120.5 (4)
C38—P4—Ag3	111.39 (15)	C61—C60—H60	119.7
C32—P5—C26	103.6 (2)	C59—C60—H60	119.7
C32—P5—C38	100.7 (2)	C60—C61—C62	120.1 (4)
C26—P5—C38	105.3 (2)	C60—C61—H61	120.0
C32—P5—Ag4	112.51 (15)	C62—C61—H61	120.0
C26—P5—Ag4	109.23 (15)	C57—C62—C61	119.8 (4)
C38—P5—Ag4	123.52 (15)	C57—C62—H62	120.1
C14—P6—C20	103.7 (2)	C61—C62—H62	120.1
C14—P6—C13	107.2 (2)	P2—C63—P3	112.0 (2)
C20—P6—C13	103.2 (2)	P2—C63—H63A	109.2
C14—P6—Ag4	121.93 (15)	P3—C63—H63A	109.2
C20—P6—Ag4	108.08 (14)	P2—C63—H63B	109.2
C13—P6—Ag4	110.97 (15)	P3—C63—H63B	109.2
C6—C1—C2	119.4 (5)	H63A—C63—H63B	107.9
C6—C1—P1	123.9 (4)	C69—C64—C65	118.7 (4)
C2—C1—P1	116.7 (4)	C69—C64—P2	118.9 (4)
C3—C2—C1	119.9 (6)	C65—C64—P2	122.4 (4)
C3—C2—H2	120.1	C64—C65—C66	120.7 (5)
C1—C2—H2	120.1	C64—C65—H65	119.6
C2—C3—C4	119.8 (6)	C66—C65—H65	119.6
C2—C3—H3	120.1	C67—C66—C65	120.0 (5)
C4—C3—H3	120.1	C67—C66—H66	120.0
C5—C4—C3	120.6 (6)	C65—C66—H66	120.0
C5—C4—H4	119.7	C66—C67—C68	120.3 (5)
C3—C4—H4	119.7	C66—C67—H67	119.9
C4—C5—C6	120.1 (6)	C68—C67—H67	119.9
C4—C5—H5	120.0	C67—C68—C69	119.6 (5)
C6—C5—H5	120.0	C67—C68—H68	120.2
C1—C6—C5	120.2 (6)	C69—C68—H68	120.2
C1—C6—H6	119.9	C64—C69—C68	120.7 (5)
C5—C6—H6	119.9	C64—C69—H69	119.7
C12—C7—C8	119.3 (4)	C68—C69—H69	119.7
C12—C7—P1	123.2 (4)	C71—C70—C75	119.5 (4)
C8—C7—P1	117.6 (4)	C71—C70—P2	123.7 (4)
C9—C8—C7	120.7 (5)	C75—C70—P2	116.8 (3)
C9—C8—H8	119.6	C70—C71—C72	120.0 (4)
C7—C8—H8	119.6	C70—C71—H71	120.0
C8—C9—C10	119.4 (5)	C72—C71—H71	120.0
C8—C9—H9	120.3	C73—C72—C71	120.2 (4)
C10—C9—H9	120.3	C73—C72—H72	119.9
C9—C10—C11	120.8 (5)	C71—C72—H72	119.9
C9—C10—H10	119.6	C72—C73—C74	120.2 (4)
C11—C10—H10	119.6	C72—C73—H73	119.9
C12—C11—C10	120.2 (5)	C74—C73—H73	119.9
C12—C11—H11	119.9	C75—C74—C73	119.6 (5)
C10—C11—H11	119.9	C75—C74—H74	120.2
C11—C12—C7	119.7 (5)	C73—C74—H74	120.2
C11—C12—H12	120.2	C74—C75—C70	120.4 (5)
C7—C12—H12	120.2	C74—C75—H75	119.8
P1—C13—P6	114.1 (2)	C70—C75—H75	119.8
P1—C13—H13A	108.7	C76—N1—C77	121.0 (5)
P6—C13—H13A	108.7	C76—N1—C78	121.9 (4)
P1—C13—H13B	108.7	C77—N1—C78	117.1 (4)
P6—C13—H13B	108.7	O1—C76—N1	125.7 (5)
H13A—C13—H13B	107.6	O1—C76—H76	117.1
C19—C14—C15	118.8 (4)	N1—C76—H76	117.1
C19—C14—P6	122.1 (3)	N1—C77—H77A	109.5
C15—C14—P6	119.1 (4)	N1—C77—H77B	109.5
C16—C15—C14	120.5 (4)	H77A—C77—H77B	109.5
C16—C15—H15	119.7	N1—C77—H77C	109.5
C14—C15—H15	119.7	H77A—C77—H77C	109.5
C17—C16—C15	120.6 (5)	H77B—C77—H77C	109.5
C17—C16—H16	119.7	N1—C78—H78A	109.5
C15—C16—H16	119.7	N1—C78—H78B	109.5
C16—C17—C18	119.7 (5)	H78A—C78—H78B	109.5
C16—C17—H17	120.2	N1—C78—H78C	109.5
C18—C17—H17	120.2	H78A—C78—H78C	109.5
C19—C18—C17	120.0 (5)	H78B—C78—H78C	109.5
C19—C18—H18	120.0	C79—N2—C81	125.7 (5)
C17—C18—H18	120.0	C79—N2—C80	120.2 (5)
C14—C19—C18	120.4 (4)	C81—N2—C80	114.1 (5)
C14—C19—H19	119.8	O2—C79—N2	125.1 (6)
C18—C19—H19	119.8	O2—C79—H79	117.4
C21—C20—C25	118.8 (4)	N2—C79—H79	117.4
C21—C20—P6	123.1 (4)	N2—C80—H80A	109.5
C25—C20—P6	117.8 (4)	N2—C80—H80B	109.5
C22—C21—C20	120.7 (5)	H80A—C80—H80B	109.5
C22—C21—H21	119.7	N2—C80—H80C	109.5
C20—C21—H21	119.7	H80A—C80—H80C	109.5
C23—C22—C21	119.7 (5)	H80B—C80—H80C	109.5
C23—C22—H22	120.2	N2—C81—H81A	109.5
C21—C22—H22	120.2	N2—C81—H81B	109.5
C24—C23—C22	120.3 (5)	H81A—C81—H81B	109.5
C24—C23—H23	119.9	N2—C81—H81C	109.5
C22—C23—H23	119.9	H81A—C81—H81C	109.5
C23—C24—C25	120.5 (5)	H81B—C81—H81C	109.5
C23—C24—H24	119.8