| Literature DB >> 21584301 |
Lynton J Baird1, Cédric Colomban, Claire Turner, Paul H Teesdale-Spittle, Joanne E Harvey.
Abstract
Methyl 2-[(diethoxyphosphoryl)methyl]benzoate reacts with several aldehydes to produce an alkenylphosphonate as the major product, together with varying amounts of the expected Horner-Wadsworth-Emmons product, a 1,2-disubstituted E-alkene. Use of a bulky aldehyde or the tert-butyl ester favours the normal HWE product.Entities:
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Year: 2011 PMID： 21584301 DOI： 10.1039/c1ob05506b
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876