Literature DB >> 21584291

Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents--a dramatic stabilisation of the low-spin state in water.

Simon A Barrett1, Colin A Kilner, Malcolm A Halcrow.   

Abstract

The temperature of spin-crossover in [Fe(3-bpp)(2)][BF(4)](2) (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) tends to increase in associating solvents. In particular, T(½) shifts to 60-70 K higher temperature in water compared to organic solvents.

Entities:  

Year:  2011        PMID： 21584291     DOI： 10.1039/c1dt10620a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  A Unified Treatment of the Relationship Between Ligand Substituents and Spin State in a Family of Iron(II) Complexes.

Authors:  Laurence J Kershaw Cook; Rafal Kulmaczewski; Rufeida Mohammed; Stephen Dudley; Simon A Barrett; Marc A Little; Robert J Deeth; Malcolm A Halcrow
Journal:  Angew Chem Int Ed Engl       Date:  2016-03-01       Impact factor: 15.336

2.  Water Soluble Iron-Based Coordination Trimers as Synergistic Adjuvants for Pancreatic Cancer.

Authors:  Marco Cordani; Esther Resines-Urien; Arturo Gamonal; Paula Milán-Rois; Lionel Salmon; Azzedine Bousseksou; Jose Sanchez Costa; Álvaro Somoza
Journal:  Antioxidants (Basel)       Date:  2021-01-07

3.  Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with N,N'-Disubstituted Bis(pyrazol-3-yl)pyridines.

Authors:  Dmitry Yu Aleshin; Igor Nikovskiy; Valentin V Novikov; Alexander V Polezhaev; Elizaveta K Melnikova; Yulia V Nelyubina
Journal:  ACS Omega       Date:  2021-11-22

4.  Interplay between spin crossover and proton migration along short strong hydrogen bonds.

Authors:  Verónica Jornet-Mollá; Carlos Giménez-Saiz; Laura Cañadillas-Delgado; Dmitry S Yufit; Judith A K Howard; Francisco M Romero
Journal:  Chem Sci       Date:  2020-11-16       Impact factor: 9.825
  4 in total

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