catena-Poly[[[[N'-(4-cyano-benzyl-idene)nicotinohydrazide]silver(I)]-μ-[N'-4-cyano-benzyl-idene)nicotinohydrazide]] hexa-fluoridoarsenate].

In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]AsF(6)}(n), the Ag(I) ion is coordinated by two N atoms from two different pyridyl rings and one N atom from one carbonitrile group of three different N'-(4-cyano-benzyl-idene)nicotinohydrazide ligands in a distorted T-shaped geometry. The Ag-N(carbonitrile) bond distance is significant longer than those of Ag-N(pyrid-yl). The bond angles around the Ag(I) atom are also not in line with those in an ideal T-shaped geometry. One type of ligand acts as the bridge that connects Ag(I) atoms into chains along [01]. These chains are linked to each other via N-H⋯O hydrogen bonds and Ag⋯O inter-actions with an Ag⋯O separation of 2.869 (2) Å. In addition, the [AsF(6)](-) counter-anions are linked to the hydrazone groups through N-H⋯F hydrogen bonds. Four of the F atoms of the [AsF(6)](-) anion are disordered over two sets of sites with occupancies of 0.732 (9) and 0.268 (9).

Related literature

For background to silver coordination polymers, see: Dong et al. (2004 ▶); Niu et al. (2007 ▶, 2008 ▶); Sumby & Hardie (2005 ▶); Vatsadze et al. (2004 ▶); Zheng et al. (2003 ▶).

Experimental

Crystal data

[Ag(C14H10N4O)2]AsF6

M = 797.31

Monoclinic,

a = 22.3785 (15) Å

b = 13.7662 (9) Å

c = 19.8482 (14) Å

β = 99.948 (1)°

V = 6022.6 (7) Å3

Z = 8

Mo Kα radiation

μ = 1.84 mm−1

T = 173 K

0.52 × 0.12 × 0.11 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.448, T max = 0.823

19207 measured reflections

6896 independent reflections

5017 reflections with I > 2σ(I)

R int = 0.028

Refinement

R[F 2 > 2σ(F 2)] = 0.038

wR(F 2) = 0.105

S = 1.02

6896 reflections

460 parameters

96 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.63 e Å−3

Δρmin = −0.47 e Å−3

Data collection: SMART (Siemens, 1996 ▶); cell refinement: SAINT (Siemens, 1996 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶) and DIAMOND (Brandenburg, 2005 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809026907/jh2084sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809026907/jh2084Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C14H10N4O)2]AsF6	F(000) = 3152
Mr = 797.31	Dx = 1.759 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 5377 reflections
a = 22.3785 (15) Å	θ = 2.1–27.5°
b = 13.7662 (9) Å	µ = 1.84 mm−1
c = 19.8482 (14) Å	T = 173 K
β = 99.948 (1)°	Prism, colourless
V = 6022.6 (7) Å3	0.52 × 0.12 × 0.11 mm
Z = 8

Bruker APEXII CCD area-detector diffractometer	6896 independent reflections
Radiation source: fine-focus sealed tube	5017 reflections with I > 2σ(I)
graphite	Rint = 0.028
φ and ω scans	θmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −29→18
Tmin = 0.448, Tmax = 0.823	k = −17→17
19207 measured reflections	l = −25→25

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.105	H atoms treated by a mixture of independent and constrained refinement
S = 1.02	w = 1/[σ2(Fo2) + (0.0526P)2 + 5.7237P] where P = (Fo2 + 2Fc2)/3
6896 reflections	(Δ/σ)max = 0.001
460 parameters	Δρmax = 0.63 e Å−3
96 restraints	Δρmin = −0.46 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.183850 (14)	0.187891 (18)	0.197856 (15)	0.05547 (11)
N1	0.20655 (13)	0.32823 (17)	0.15519 (13)	0.0404 (6)
N2	0.33194 (14)	0.3474 (2)	0.02005 (14)	0.0471 (7)
N3	0.37007 (13)	0.3480 (2)	−0.02752 (14)	0.0480 (7)
N4	0.61376 (15)	0.2368 (3)	−0.23488 (16)	0.0667 (9)
N5	0.17227 (13)	0.03059 (19)	0.20139 (13)	0.0435 (6)
N6	0.26690 (13)	−0.16253 (19)	0.09119 (14)	0.0440 (6)
N7	0.30676 (13)	−0.2188 (2)	0.06251 (14)	0.0452 (6)
N8	0.5343 (2)	−0.4267 (3)	−0.1374 (2)	0.0990 (15)
O1	0.29409 (11)	0.49652 (17)	−0.01123 (12)	0.0540 (6)
O2	0.25137 (12)	−0.28036 (16)	0.16611 (13)	0.0569 (6)
C1	0.19143 (15)	0.4121 (2)	0.18267 (16)	0.0426 (7)
H1	0.1669	0.4098	0.2172	0.051*
C2	0.21021 (17)	0.5008 (2)	0.16271 (17)	0.0478 (8)
H2	0.1992	0.5585	0.1838	0.057*
C3	0.24503 (16)	0.5056 (2)	0.11201 (16)	0.0448 (8)
H3	0.2582	0.5665	0.0975	0.054*
C4	0.26041 (14)	0.4200 (2)	0.08263 (15)	0.0365 (7)
C5	0.24032 (15)	0.3332 (2)	0.10548 (16)	0.0389 (7)
H5	0.2508	0.2745	0.0852	0.047*
C6	0.29680 (15)	0.4257 (2)	0.02645 (15)	0.0400 (7)
C7	0.40093 (16)	0.2709 (3)	−0.02952 (17)	0.0513 (8)
H7	0.3955	0.2179	−0.0005	0.062*
C8	0.44496 (15)	0.2627 (3)	−0.07618 (16)	0.0461 (8)
C9	0.46234 (17)	0.3429 (3)	−0.11026 (18)	0.0499 (8)
H9	0.4440	0.4042	−0.1055	0.060*
C10	0.50556 (18)	0.3345 (3)	−0.15064 (18)	0.0528 (9)
H10	0.5178	0.3901	−0.1732	0.063*
C11	0.53175 (15)	0.2446 (3)	−0.15883 (16)	0.0476 (8)
C12	0.51410 (18)	0.1635 (3)	−0.1266 (2)	0.0594 (10)
H12	0.5312	0.1018	−0.1330	0.071*
C13	0.47112 (18)	0.1734 (3)	−0.0847 (2)	0.0588 (10)
H13	0.4594	0.1181	−0.0615	0.071*
C14	0.57804 (17)	0.2385 (3)	−0.20097 (18)	0.0527 (9)
C15	0.13563 (17)	−0.0091 (2)	0.24079 (17)	0.0491 (8)
H15	0.1117	0.0327	0.2633	0.059*
C16	0.13129 (18)	−0.1077 (3)	0.24988 (19)	0.0538 (9)
H16	0.1051	−0.1333	0.2784	0.065*
C17	0.16547 (17)	−0.1682 (2)	0.21708 (18)	0.0473 (8)
H17	0.1633	−0.2366	0.2228	0.057*
C18	0.20314 (14)	−0.1297 (2)	0.17564 (15)	0.0370 (7)
C19	0.20477 (15)	−0.0293 (2)	0.16906 (15)	0.0397 (7)
H19	0.2301	−0.0021	0.1402	0.048*
C20	0.24264 (15)	−0.1984 (2)	0.14389 (16)	0.0398 (7)
C21	0.33262 (17)	−0.1765 (2)	0.01809 (18)	0.0488 (8)
H21	0.3241	−0.1102	0.0072	0.059*
C22	0.37552 (16)	−0.2300 (3)	−0.01634 (17)	0.0473 (8)
C23	0.38639 (17)	−0.3282 (3)	−0.00388 (19)	0.0507 (8)
H23	0.3654	−0.3614	0.0269	0.061*
C24	0.42693 (18)	−0.3782 (3)	−0.03525 (19)	0.0552 (9)
H24	0.4341	−0.4453	−0.0260	0.066*
C25	0.45761 (17)	−0.3300 (3)	−0.0808 (2)	0.0556 (9)
C26	0.44726 (19)	−0.2317 (3)	−0.0942 (2)	0.0625 (10)
H26	0.4682	−0.1987	−0.1251	0.075*
C27	0.40629 (19)	−0.1822 (3)	−0.0622 (2)	0.0587 (10)
H27	0.3990	−0.1152	−0.0715	0.070*
C28	0.5002 (2)	−0.3825 (3)	−0.1133 (2)	0.0700 (12)
As1	0.377276 (19)	0.09939 (3)	0.14799 (2)	0.05697 (13)
F5	0.38907 (15)	0.21973 (18)	0.13618 (16)	0.1020 (9)
F6	0.36110 (16)	−0.01902 (19)	0.1542 (2)	0.1292 (13)
H28	0.3375 (17)	0.306 (2)	0.0537 (14)	0.056 (11)*
H29	0.2555 (17)	−0.1086 (19)	0.0702 (18)	0.061 (12)*
F1	0.3247 (3)	0.1084 (5)	0.0751 (3)	0.142 (3)	0.732 (9)
F2	0.3208 (3)	0.1242 (3)	0.1925 (3)	0.111 (2)	0.732 (9)
F3	0.4252 (4)	0.0990 (7)	0.2174 (5)	0.203 (4)	0.732 (9)
F4	0.4308 (3)	0.0776 (4)	0.1007 (5)	0.135 (3)	0.732 (9)
F1'	0.3034 (4)	0.1259 (9)	0.1417 (10)	0.111 (5)	0.268 (9)
F2'	0.3871 (8)	0.1196 (8)	0.2320 (4)	0.095 (5)	0.268 (9)
F3'	0.4516 (4)	0.0732 (7)	0.1563 (8)	0.084 (4)	0.268 (9)
F4'	0.3710 (9)	0.0775 (9)	0.0641 (5)	0.116 (5)	0.268 (9)

	U11	U22	U33	U12	U13	U23
Ag1	0.0725 (2)	0.03016 (14)	0.0723 (2)	0.00011 (12)	0.03658 (16)	0.00469 (11)
N1	0.0519 (16)	0.0292 (13)	0.0455 (15)	−0.0014 (11)	0.0234 (13)	0.0001 (10)
N2	0.0587 (18)	0.0446 (15)	0.0450 (16)	0.0072 (14)	0.0290 (14)	0.0084 (13)
N3	0.0510 (17)	0.0533 (17)	0.0455 (15)	0.0038 (14)	0.0248 (13)	0.0021 (13)
N4	0.063 (2)	0.081 (2)	0.066 (2)	0.0065 (18)	0.0362 (18)	0.0071 (18)
N5	0.0556 (17)	0.0335 (14)	0.0455 (15)	0.0012 (12)	0.0209 (13)	0.0030 (11)
N6	0.0540 (17)	0.0341 (14)	0.0469 (16)	0.0066 (12)	0.0175 (14)	0.0016 (12)
N7	0.0505 (17)	0.0408 (14)	0.0466 (15)	0.0024 (13)	0.0150 (13)	−0.0058 (12)
N8	0.104 (3)	0.080 (3)	0.134 (4)	−0.010 (2)	0.081 (3)	−0.022 (3)
O1	0.0690 (17)	0.0442 (13)	0.0556 (14)	0.0016 (12)	0.0298 (13)	0.0130 (11)
O2	0.0758 (18)	0.0302 (11)	0.0705 (16)	0.0041 (11)	0.0285 (14)	0.0048 (11)
C1	0.0487 (19)	0.0373 (17)	0.0474 (18)	0.0036 (14)	0.0241 (15)	0.0002 (13)
C2	0.066 (2)	0.0305 (15)	0.0521 (19)	0.0043 (15)	0.0249 (17)	−0.0060 (14)
C3	0.058 (2)	0.0293 (15)	0.0505 (19)	−0.0016 (14)	0.0196 (16)	0.0020 (13)
C4	0.0427 (17)	0.0330 (15)	0.0356 (15)	−0.0004 (13)	0.0119 (13)	0.0004 (12)
C5	0.0505 (19)	0.0277 (14)	0.0429 (17)	−0.0005 (13)	0.0202 (15)	−0.0033 (12)
C6	0.0471 (19)	0.0370 (16)	0.0393 (16)	−0.0033 (14)	0.0169 (14)	−0.0004 (13)
C7	0.054 (2)	0.055 (2)	0.050 (2)	0.0019 (17)	0.0259 (17)	0.0060 (16)
C8	0.0439 (19)	0.056 (2)	0.0419 (17)	0.0036 (16)	0.0161 (15)	0.0004 (15)
C9	0.057 (2)	0.0452 (18)	0.053 (2)	0.0041 (16)	0.0240 (17)	−0.0017 (15)
C10	0.062 (2)	0.050 (2)	0.052 (2)	−0.0039 (17)	0.0267 (18)	0.0020 (16)
C11	0.0433 (19)	0.059 (2)	0.0446 (18)	0.0019 (16)	0.0179 (15)	−0.0010 (15)
C12	0.060 (2)	0.055 (2)	0.070 (2)	0.0133 (18)	0.031 (2)	0.0047 (18)
C13	0.062 (2)	0.053 (2)	0.070 (2)	0.0099 (18)	0.034 (2)	0.0157 (18)
C14	0.052 (2)	0.060 (2)	0.050 (2)	0.0052 (17)	0.0173 (17)	0.0032 (17)
C15	0.059 (2)	0.0436 (18)	0.0493 (19)	0.0054 (16)	0.0234 (17)	0.0022 (15)
C16	0.060 (2)	0.048 (2)	0.062 (2)	−0.0014 (17)	0.0319 (19)	0.0104 (16)
C17	0.056 (2)	0.0322 (16)	0.057 (2)	−0.0058 (14)	0.0179 (17)	0.0073 (14)
C18	0.0437 (18)	0.0300 (14)	0.0378 (16)	−0.0026 (13)	0.0086 (14)	0.0019 (12)
C19	0.0498 (19)	0.0324 (15)	0.0399 (16)	−0.0027 (13)	0.0164 (14)	0.0021 (12)
C20	0.0467 (19)	0.0278 (15)	0.0457 (17)	−0.0014 (13)	0.0099 (15)	−0.0021 (12)
C21	0.055 (2)	0.0429 (18)	0.0496 (19)	0.0016 (16)	0.0121 (17)	−0.0012 (15)
C22	0.0473 (19)	0.0509 (19)	0.0449 (18)	−0.0051 (16)	0.0113 (15)	−0.0066 (15)
C23	0.051 (2)	0.052 (2)	0.052 (2)	−0.0068 (16)	0.0190 (17)	−0.0040 (16)
C24	0.057 (2)	0.051 (2)	0.062 (2)	−0.0013 (17)	0.0216 (18)	−0.0078 (17)
C25	0.048 (2)	0.063 (2)	0.060 (2)	−0.0091 (18)	0.0211 (18)	−0.0159 (18)
C26	0.067 (3)	0.067 (3)	0.060 (2)	−0.013 (2)	0.029 (2)	−0.0030 (19)
C27	0.065 (3)	0.051 (2)	0.064 (2)	−0.0047 (18)	0.022 (2)	−0.0003 (17)
C28	0.066 (3)	0.068 (3)	0.084 (3)	−0.014 (2)	0.037 (2)	−0.014 (2)
As1	0.0619 (3)	0.03366 (19)	0.0799 (3)	−0.00267 (16)	0.0248 (2)	0.00097 (16)
F5	0.140 (3)	0.0476 (14)	0.123 (2)	−0.0164 (15)	0.034 (2)	0.0104 (14)
F6	0.139 (3)	0.0433 (14)	0.224 (4)	−0.0122 (16)	0.086 (3)	−0.0032 (19)
F1	0.126 (5)	0.177 (6)	0.109 (4)	−0.018 (4)	−0.025 (3)	−0.016 (4)
F2	0.147 (5)	0.084 (3)	0.127 (4)	−0.013 (3)	0.092 (4)	−0.024 (3)
F3	0.152 (6)	0.254 (8)	0.177 (7)	−0.023 (6)	−0.046 (5)	0.065 (6)
F4	0.125 (5)	0.092 (3)	0.219 (7)	0.009 (3)	0.115 (5)	0.000 (4)
F1'	0.075 (6)	0.096 (7)	0.162 (11)	0.008 (6)	0.021 (7)	0.017 (8)
F2'	0.161 (10)	0.079 (6)	0.054 (5)	0.020 (6)	0.043 (6)	−0.004 (4)
F3'	0.055 (5)	0.066 (6)	0.132 (9)	0.006 (4)	0.021 (6)	0.000 (6)
F4'	0.161 (11)	0.093 (7)	0.085 (7)	−0.017 (7)	−0.003 (7)	−0.018 (6)

Ag1—N5	2.183 (3)	C11—C12	1.378 (5)
Ag1—N1	2.204 (2)	C11—C14	1.442 (4)
Ag1—N4i	2.458 (3)	C12—C13	1.382 (5)
N1—C5	1.344 (4)	C12—H12	0.9500
N1—C1	1.345 (4)	C13—H13	0.9500
N2—C6	1.353 (4)	C15—C16	1.374 (5)
N2—N3	1.378 (3)	C15—H15	0.9500
N2—H28	0.868 (19)	C16—C17	1.370 (5)
N3—C7	1.271 (5)	C16—H16	0.9500
N4—C14	1.131 (4)	C17—C18	1.382 (4)
N4—Ag1ii	2.458 (3)	C17—H17	0.9500
N5—C19	1.335 (4)	C18—C19	1.389 (4)
N5—C15	1.343 (4)	C18—C20	1.506 (4)
N6—C20	1.353 (4)	C19—H19	0.9500
N6—N7	1.376 (4)	C21—C22	1.468 (5)
N6—H29	0.868 (19)	C21—H21	0.9500
N7—C21	1.275 (4)	C22—C23	1.389 (5)
N8—C28	1.144 (5)	C22—C27	1.397 (5)
O1—C6	1.224 (4)	C23—C24	1.371 (5)
O2—C20	1.214 (4)	C23—H23	0.9500
C1—C2	1.372 (4)	C24—C25	1.394 (5)
C1—H1	0.9500	C24—H24	0.9500
C2—C3	1.377 (4)	C25—C26	1.391 (6)
C2—H2	0.9500	C25—C28	1.436 (5)
C3—C4	1.384 (4)	C26—C27	1.381 (5)
C3—H3	0.9500	C26—H26	0.9500
C4—C5	1.381 (4)	C27—H27	0.9500
C4—C6	1.492 (4)	As1—F3	1.593 (6)
C5—H5	0.9500	As1—F2'	1.667 (8)
C7—C8	1.468 (4)	As1—F4	1.671 (4)
C7—H7	0.9500	As1—F4'	1.674 (9)
C8—C13	1.384 (5)	As1—F1'	1.675 (10)
C8—C9	1.386 (5)	As1—F6	1.679 (3)
C9—C10	1.363 (5)	As1—F3'	1.682 (8)
C9—H9	0.9500	As1—F2	1.696 (4)
C10—C11	1.392 (5)	As1—F5	1.700 (2)
C10—H10	0.9500	As1—F1	1.704 (5)
N5—Ag1—N1	156.68 (9)	N5—C19—C18	123.0 (3)
N5—Ag1—N4i	108.09 (11)	N5—C19—H19	118.5
N1—Ag1—N4i	92.87 (11)	C18—C19—H19	118.5
C5—N1—C1	117.8 (3)	O2—C20—N6	124.0 (3)
C5—N1—Ag1	121.53 (19)	O2—C20—C18	120.1 (3)
C1—N1—Ag1	120.4 (2)	N6—C20—C18	115.9 (3)
C6—N2—N3	119.9 (3)	N7—C21—C22	120.3 (3)
C6—N2—H28	117 (2)	N7—C21—H21	119.8
N3—N2—H28	120 (3)	C22—C21—H21	119.8
C7—N3—N2	114.9 (3)	C23—C22—C27	118.9 (3)
C14—N4—Ag1ii	153.9 (3)	C23—C22—C21	120.9 (3)
C19—N5—C15	117.8 (3)	C27—C22—C21	120.2 (3)
C19—N5—Ag1	121.3 (2)	C24—C23—C22	121.2 (3)
C15—N5—Ag1	120.7 (2)	C24—C23—H23	119.4
C20—N6—N7	119.3 (3)	C22—C23—H23	119.4
C20—N6—H29	124 (3)	C23—C24—C25	119.6 (4)
N7—N6—H29	116 (3)	C23—C24—H24	120.2
C21—N7—N6	115.7 (3)	C25—C24—H24	120.2
N1—C1—C2	122.4 (3)	C26—C25—C24	120.2 (3)
N1—C1—H1	118.8	C26—C25—C28	120.3 (4)
C2—C1—H1	118.8	C24—C25—C28	119.5 (4)
C1—C2—C3	119.6 (3)	C27—C26—C25	119.6 (4)
C1—C2—H2	120.2	C27—C26—H26	120.2
C3—C2—H2	120.2	C25—C26—H26	120.2
C2—C3—C4	118.7 (3)	C26—C27—C22	120.6 (4)
C2—C3—H3	120.7	C26—C27—H27	119.7
C4—C3—H3	120.7	C22—C27—H27	119.7
C5—C4—C3	118.7 (3)	N8—C28—C25	177.5 (5)
C5—C4—C6	122.8 (3)	F3—As1—F4	92.5 (4)
C3—C4—C6	118.5 (3)	F2'—As1—F4	127.4 (6)
N1—C5—C4	122.8 (3)	F3—As1—F4'	142.0 (7)
N1—C5—H5	118.6	F2'—As1—F4'	177.2 (7)
C4—C5—H5	118.6	F4—As1—F4'	49.8 (6)
O1—C6—N2	123.1 (3)	F3—As1—F1'	125.0 (7)
O1—C6—C4	121.5 (3)	F2'—As1—F1'	89.8 (6)
N2—C6—C4	115.4 (3)	F4—As1—F1'	142.2 (6)
N3—C7—C8	120.7 (3)	F4'—As1—F1'	93.0 (7)
N3—C7—H7	119.6	F3—As1—F6	93.1 (3)
C8—C7—H7	119.6	F2'—As1—F6	94.7 (4)
C13—C8—C9	119.2 (3)	F4—As1—F6	92.9 (2)
C13—C8—C7	119.3 (3)	F4'—As1—F6	85.2 (4)
C9—C8—C7	121.5 (3)	F1'—As1—F6	89.7 (4)
C10—C9—C8	120.5 (3)	F3—As1—F3'	53.7 (5)
C10—C9—H9	119.8	F2'—As1—F3'	88.9 (6)
C8—C9—H9	119.8	F4'—As1—F3'	88.3 (6)
C9—C10—C11	120.0 (3)	F1'—As1—F3'	178.7 (7)
C9—C10—H10	120.0	F6—As1—F3'	90.4 (4)
C11—C10—H10	120.0	F3—As1—F2	90.1 (4)
C12—C11—C10	120.4 (3)	F2'—As1—F2	55.1 (5)
C12—C11—C14	121.0 (3)	F4—As1—F2	177.1 (3)
C10—C11—C14	118.6 (3)	F4'—As1—F2	127.7 (6)
C11—C12—C13	119.0 (3)	F6—As1—F2	88.16 (19)
C11—C12—H12	120.5	F3'—As1—F2	143.6 (5)
C13—C12—H12	120.5	F3—As1—F5	91.5 (3)
C12—C13—C8	120.9 (3)	F2'—As1—F5	88.8 (4)
C12—C13—H13	119.5	F4—As1—F5	87.4 (2)
C8—C13—H13	119.5	F4'—As1—F5	91.5 (4)
N4—C14—C11	177.6 (4)	F1'—As1—F5	87.3 (4)
N5—C15—C16	122.9 (3)	F6—As1—F5	175.38 (19)
N5—C15—H15	118.6	F3'—As1—F5	92.8 (4)
C16—C15—H15	118.6	F2—As1—F5	91.32 (19)
C17—C16—C15	118.7 (3)	F3—As1—F1	175.8 (4)
C17—C16—H16	120.6	F2'—As1—F1	142.2 (5)
C15—C16—H16	120.6	F4—As1—F1	89.6 (3)
C16—C17—C18	119.8 (3)	F1'—As1—F1	52.7 (6)
C16—C17—H17	120.1	F6—As1—F1	90.4 (3)
C18—C17—H17	120.1	F3'—As1—F1	128.6 (5)
C17—C18—C19	117.8 (3)	F2—As1—F1	87.7 (3)
C17—C18—C20	118.0 (3)	F5—As1—F1	85.0 (2)
C19—C18—C20	124.0 (3)
N5—Ag1—N1—C5	−17.9 (4)	C10—C11—C12—C13	−1.6 (6)
N4i—Ag1—N1—C5	−172.2 (3)	C14—C11—C12—C13	177.7 (4)
N5—Ag1—N1—C1	168.2 (3)	C11—C12—C13—C8	1.4 (6)
N4i—Ag1—N1—C1	13.8 (3)	C9—C8—C13—C12	0.0 (6)
C6—N2—N3—C7	−179.8 (3)	C7—C8—C13—C12	−178.0 (4)
N1—Ag1—N5—C19	27.0 (4)	C19—N5—C15—C16	1.2 (5)
N4i—Ag1—N5—C19	180.0 (2)	Ag1—N5—C15—C16	−173.6 (3)
N1—Ag1—N5—C15	−158.4 (3)	N5—C15—C16—C17	−0.4 (6)
N4i—Ag1—N5—C15	−5.4 (3)	C15—C16—C17—C18	−0.3 (6)
C20—N6—N7—C21	−172.9 (3)	C16—C17—C18—C19	0.1 (5)
C5—N1—C1—C2	−1.3 (5)	C16—C17—C18—C20	176.5 (3)
Ag1—N1—C1—C2	172.9 (3)	C15—N5—C19—C18	−1.4 (5)
N1—C1—C2—C3	1.1 (6)	Ag1—N5—C19—C18	173.4 (2)
C1—C2—C3—C4	−0.3 (5)	C17—C18—C19—N5	0.7 (5)
C2—C3—C4—C5	−0.1 (5)	C20—C18—C19—N5	−175.4 (3)
C2—C3—C4—C6	178.4 (3)	N7—N6—C20—O2	−3.8 (5)
C1—N1—C5—C4	0.9 (5)	N7—N6—C20—C18	175.7 (3)
Ag1—N1—C5—C4	−173.2 (2)	C17—C18—C20—O2	−16.5 (5)
C3—C4—C5—N1	−0.2 (5)	C19—C18—C20—O2	159.6 (3)
C6—C4—C5—N1	−178.7 (3)	C17—C18—C20—N6	164.0 (3)
N3—N2—C6—O1	4.6 (5)	C19—C18—C20—N6	−19.9 (5)
N3—N2—C6—C4	−176.0 (3)	N6—N7—C21—C22	−179.3 (3)
C5—C4—C6—O1	150.3 (3)	N7—C21—C22—C23	3.3 (5)
C3—C4—C6—O1	−28.2 (5)	N7—C21—C22—C27	−176.5 (3)
C5—C4—C6—N2	−29.0 (5)	C27—C22—C23—C24	0.6 (6)
C3—C4—C6—N2	152.4 (3)	C21—C22—C23—C24	−179.2 (3)
N2—N3—C7—C8	−177.9 (3)	C22—C23—C24—C25	−0.4 (6)
N3—C7—C8—C13	−170.4 (4)	C23—C24—C25—C26	0.2 (6)
N3—C7—C8—C9	11.7 (6)	C23—C24—C25—C28	179.8 (4)
C13—C8—C9—C10	−1.3 (6)	C24—C25—C26—C27	−0.2 (6)
C7—C8—C9—C10	176.7 (4)	C28—C25—C26—C27	−179.7 (4)
C8—C9—C10—C11	1.2 (6)	C25—C26—C27—C22	0.4 (6)
C9—C10—C11—C12	0.3 (6)	C23—C22—C27—C26	−0.6 (6)
C9—C10—C11—C14	−179.0 (4)	C21—C22—C27—C26	179.2 (4)

D—H···A	D—H	H···A	D···A	D—H···A
N6—H29···O1iii	0.87 (2)	2.13 (2)	2.976 (4)	165 (4)
N2—H28···F5	0.87 (2)	2.19 (2)	3.003 (4)	157 (3)

Ag1—N5	2.183 (3)
Ag1—N1	2.204 (2)
Ag1—N4i	2.458 (3)

N5—Ag1—N1	156.68 (9)
N5—Ag1—N4i	108.09 (11)
N1—Ag1—N4i	92.87 (11)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N6—H29⋯O1ii	0.868 (19)	2.13 (2)	2.976 (4)	165 (4)
N2—H28⋯F5	0.868 (19)	2.19 (2)	3.003 (4)	157 (3)

Symmetry code: (ii) .