trans-Di-μ-carbonyl-bis-{carbon-yl[η-2,3,4,5-tetra-methyl-1-(5-methyl-2-fur-yl)cyclo-penta-dien-yl]ruthenium(I)}(Ru-Ru).

In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo-penta-dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered rings which are located on centres of inversion. The Ru-Ru distance of 2.7483 (11) Å corresponds to a single bond. The two carbonyl groups in these binuclear complexes are trans-oriented.

Related literature

For the crystal structures of related ruthenium complexes, see: Schumann et al. (2002 ▶); Bailey et al. (1978 ▶); Möhring & Coville (2006 ▶); King (1976 ▶); Arndt (2002 ▶).

Experimental

Crystal data

[Ru2(C14H17O)2(CO)4]

M = 716.73

Monoclinic,

a = 8.504 (3) Å

b = 16.978 (7) Å

c = 10.223 (4) Å

β = 102.220 (6)°

V = 1442.5 (10) Å3

Z = 2

Mo Kα radiation

μ = 1.09 mm−1

T = 273 K

0.15 × 0.11 × 0.08 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 1998 ▶) T min = 0.854, T max = 0.918

7123 measured reflections

2552 independent reflections

2448 reflections with I > 2σ(I)

R int = 0.028

Refinement

R[F 2 > 2σ(F 2)] = 0.036

wR(F 2) = 0.088

S = 1.28

2552 reflections

181 parameters

H-atom parameters constrained

Δρmax = 0.72 e Å−3

Δρmin = −0.74 e Å−3

Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT (Bruker, 1998 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809026075/nc2148sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809026075/nc2148Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ru2(C14H17O)2(CO)4]	F(000) = 724
Mr = 716.73	Dx = 1.650 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 1828 reflections
a = 8.504 (3) Å	θ = 5.5–24.8°
b = 16.978 (7) Å	µ = 1.09 mm−1
c = 10.223 (4) Å	T = 273 K
β = 102.220 (6)°	Prism, red
V = 1442.5 (10) Å3	0.15 × 0.11 × 0.08 mm
Z = 2

Bruker SMART CCD area-detector diffractometer	2552 independent reflections
Radiation source: fine-focus sealed tube	2448 reflections with I > 2σ(I)
graphite	Rint = 0.028
φ and ω scans	θmax = 25.1°, θmin = 2.4°
Absorption correction: multi-scan (SADABS; Bruker, 1998)	h = −10→9
Tmin = 0.854, Tmax = 0.918	k = −19→20
7123 measured reflections	l = −9→12

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.036	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.088	H-atom parameters constrained
S = 1.28	w = 1/[σ2(Fo2) + (0.0263P)2 + 2.646P] where P = (Fo2 + 2Fc2)/3
2552 reflections	(Δ/σ)max = 0.001
181 parameters	Δρmax = 0.72 e Å−3
0 restraints	Δρmin = −0.74 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Ru1	0.51265 (3)	0.030918 (17)	0.12603 (3)	0.02286 (12)
O1	0.1922 (3)	0.0424 (2)	−0.0644 (3)	0.0433 (8)
O2	0.6179 (5)	0.1919 (2)	0.0632 (4)	0.0637 (11)
O3	0.2618 (4)	0.15332 (18)	0.3848 (3)	0.0422 (7)
C1	0.3276 (5)	0.0237 (2)	−0.0361 (4)	0.0285 (8)
C2	0.5750 (5)	0.1294 (3)	0.0811 (4)	0.0353 (9)
C3	0.3747 (5)	0.0432 (2)	0.2912 (4)	0.0286 (8)
C4	0.5421 (5)	0.0615 (2)	0.3412 (4)	0.0280 (8)
C5	0.6327 (5)	−0.0087 (2)	0.3353 (4)	0.0286 (8)
C6	0.5228 (5)	−0.0684 (2)	0.2787 (4)	0.0288 (8)
C7	0.3654 (5)	−0.0376 (2)	0.2524 (4)	0.0299 (8)
C8	0.2398 (5)	0.0956 (2)	0.2882 (4)	0.0330 (9)
C9	0.0903 (5)	0.1014 (3)	0.2136 (5)	0.0506 (12)
H9	0.0443	0.0695	0.1417	0.061*
C10	0.0163 (6)	0.1652 (3)	0.2653 (6)	0.0559 (14)
H10	−0.0879	0.1832	0.2327	0.067*
C11	0.1194 (6)	0.1946 (3)	0.3670 (5)	0.0486 (12)
C12	0.1170 (9)	0.2592 (4)	0.4635 (7)	0.082 (2)
H12A	0.0222	0.2906	0.4342	0.122*
H12B	0.2108	0.2915	0.4688	0.122*
H12C	0.1165	0.2374	0.5501	0.122*
C13	0.6112 (6)	0.1365 (3)	0.4048 (4)	0.0416 (10)
H13A	0.5533	0.1803	0.3585	0.062*
H13B	0.7225	0.1401	0.4000	0.062*
H13C	0.6021	0.1373	0.4968	0.062*
C14	0.8093 (5)	−0.0180 (3)	0.3875 (5)	0.0416 (10)
H14A	0.8298	−0.0277	0.4822	0.062*
H14B	0.8637	0.0292	0.3705	0.062*
H14C	0.8480	−0.0617	0.3436	0.062*
C15	0.5671 (6)	−0.1531 (3)	0.2627 (5)	0.0451 (11)
H15A	0.5814	−0.1794	0.3475	0.068*
H15B	0.6654	−0.1555	0.2309	0.068*
H15C	0.4827	−0.1785	0.1994	0.068*
C16	0.2141 (6)	−0.0843 (3)	0.2052 (5)	0.0474 (11)
H16A	0.1693	−0.0718	0.1132	0.071*
H16B	0.1377	−0.0715	0.2588	0.071*
H16C	0.2385	−0.1395	0.2132	0.071*

	U11	U22	U33	U12	U13	U23
Ru1	0.02253 (18)	0.02590 (19)	0.02035 (18)	−0.00050 (11)	0.00502 (12)	−0.00010 (11)
O1	0.0261 (16)	0.065 (2)	0.0381 (17)	0.0129 (14)	0.0044 (13)	−0.0035 (15)
O2	0.091 (3)	0.0361 (19)	0.060 (2)	−0.0199 (19)	0.007 (2)	0.0109 (16)
O3	0.0409 (17)	0.0434 (17)	0.0429 (18)	0.0105 (14)	0.0103 (14)	−0.0034 (14)
C1	0.031 (2)	0.032 (2)	0.0239 (19)	0.0003 (16)	0.0086 (16)	0.0000 (15)
C2	0.040 (2)	0.037 (2)	0.026 (2)	−0.0032 (18)	0.0023 (17)	0.0005 (17)
C3	0.029 (2)	0.035 (2)	0.0244 (19)	0.0005 (16)	0.0114 (15)	0.0021 (16)
C4	0.0233 (18)	0.039 (2)	0.0216 (19)	−0.0025 (16)	0.0054 (15)	0.0040 (16)
C5	0.030 (2)	0.035 (2)	0.0228 (19)	0.0011 (16)	0.0091 (15)	0.0037 (15)
C6	0.034 (2)	0.031 (2)	0.0224 (19)	0.0012 (16)	0.0085 (16)	0.0035 (15)
C7	0.031 (2)	0.035 (2)	0.0239 (19)	−0.0062 (16)	0.0073 (16)	0.0026 (16)
C8	0.031 (2)	0.042 (2)	0.030 (2)	0.0006 (18)	0.0151 (17)	0.0002 (18)
C9	0.031 (2)	0.076 (4)	0.046 (3)	0.006 (2)	0.008 (2)	−0.009 (2)
C10	0.039 (3)	0.074 (4)	0.059 (3)	0.021 (3)	0.021 (2)	0.013 (3)
C11	0.048 (3)	0.050 (3)	0.053 (3)	0.020 (2)	0.024 (2)	0.009 (2)
C12	0.087 (5)	0.065 (4)	0.097 (5)	0.034 (3)	0.029 (4)	−0.013 (4)
C13	0.046 (3)	0.043 (3)	0.035 (2)	−0.011 (2)	0.0085 (19)	−0.0113 (19)
C14	0.028 (2)	0.058 (3)	0.036 (2)	0.0045 (19)	0.0018 (18)	0.008 (2)
C15	0.060 (3)	0.033 (2)	0.042 (3)	0.006 (2)	0.009 (2)	0.0045 (19)
C16	0.039 (3)	0.048 (3)	0.053 (3)	−0.019 (2)	0.006 (2)	0.001 (2)

Ru1—C2	1.842 (4)	C7—C16	1.502 (6)
Ru1—C1i	2.020 (4)	C8—C9	1.341 (6)
Ru1—C1	2.033 (4)	C9—C10	1.410 (7)
Ru1—C4	2.222 (4)	C9—H9	0.9300
Ru1—C3	2.260 (4)	C10—C11	1.310 (8)
Ru1—C5	2.268 (4)	C10—H10	0.9300
Ru1—C6	2.286 (4)	C11—C12	1.477 (8)
Ru1—C7	2.297 (4)	C12—H12A	0.9600
Ru1—Ru1i	2.7483 (11)	C12—H12B	0.9600
O1—C1	1.170 (5)	C12—H12C	0.9600
O2—C2	1.149 (5)	C13—H13A	0.9600
O3—C8	1.376 (5)	C13—H13B	0.9600
O3—C11	1.378 (5)	C13—H13C	0.9600
C1—Ru1i	2.020 (4)	C14—H14A	0.9600
C3—C7	1.425 (5)	C14—H14B	0.9600
C3—C4	1.441 (5)	C14—H14C	0.9600
C3—C8	1.447 (6)	C15—H15A	0.9600
C4—C5	1.427 (6)	C15—H15B	0.9600
C4—C13	1.492 (6)	C15—H15C	0.9600
C5—C6	1.416 (6)	C16—H16A	0.9600
C5—C14	1.493 (6)	C16—H16B	0.9600
C6—C7	1.409 (6)	C16—H16C	0.9600
C6—C15	1.506 (6)
C2—Ru1—C1i	92.69 (17)	C4—C5—Ru1	69.7 (2)
C2—Ru1—C1	93.75 (17)	C14—C5—Ru1	125.9 (3)
C1i—Ru1—C1	94.61 (16)	C7—C6—C5	109.3 (3)
C2—Ru1—C4	93.23 (16)	C7—C6—C15	125.7 (4)
C1i—Ru1—C4	127.74 (15)	C5—C6—C15	124.7 (4)
C1—Ru1—C4	136.60 (15)	C7—C6—Ru1	72.5 (2)
C2—Ru1—C3	108.97 (17)	C5—C6—Ru1	71.2 (2)
C1i—Ru1—C3	152.57 (15)	C15—C6—Ru1	127.2 (3)
C1—Ru1—C3	100.37 (15)	C6—C7—C3	108.0 (3)
C4—Ru1—C3	37.50 (14)	C6—C7—C16	125.5 (4)
C2—Ru1—C5	114.09 (16)	C3—C7—C16	126.2 (4)
C1i—Ru1—C5	94.66 (15)	C6—C7—Ru1	71.7 (2)
C1—Ru1—C5	150.13 (15)	C3—C7—Ru1	70.4 (2)
C4—Ru1—C5	37.04 (14)	C16—C7—Ru1	128.2 (3)
C3—Ru1—C5	61.57 (14)	C9—C8—O3	108.9 (4)
C2—Ru1—C6	150.26 (16)	C9—C8—C3	135.1 (4)
C1i—Ru1—C6	92.30 (15)	O3—C8—C3	115.9 (4)
C1—Ru1—C6	115.03 (15)	C8—C9—C10	106.7 (5)
C4—Ru1—C6	61.08 (14)	C8—C9—H9	126.6
C3—Ru1—C6	60.55 (14)	C10—C9—H9	126.6
C5—Ru1—C6	36.24 (14)	C11—C10—C9	108.3 (4)
C2—Ru1—C7	145.09 (17)	C11—C10—H10	125.8
C1i—Ru1—C7	121.50 (15)	C9—C10—H10	125.8
C1—Ru1—C7	90.47 (15)	C10—C11—O3	109.4 (4)
C4—Ru1—C7	61.45 (14)	C10—C11—C12	135.4 (5)
C3—Ru1—C7	36.42 (14)	O3—C11—C12	115.2 (5)
C5—Ru1—C7	60.63 (14)	C11—C12—H12A	109.5
C6—Ru1—C7	35.80 (14)	C11—C12—H12B	109.5
C2—Ru1—Ru1i	94.75 (13)	H12A—C12—H12B	109.5
C1i—Ru1—Ru1i	47.51 (11)	C11—C12—H12C	109.5
C1—Ru1—Ru1i	47.10 (11)	H12A—C12—H12C	109.5
C4—Ru1—Ru1i	170.90 (11)	H12B—C12—H12C	109.5
C3—Ru1—Ru1i	141.76 (10)	C4—C13—H13A	109.5
C5—Ru1—Ru1i	134.53 (10)	C4—C13—H13B	109.5
C6—Ru1—Ru1i	110.03 (10)	H13A—C13—H13B	109.5
C7—Ru1—Ru1i	112.96 (10)	C4—C13—H13C	109.5
C8—O3—C11	106.6 (4)	H13A—C13—H13C	109.5
O1—C1—Ru1i	137.2 (3)	H13B—C13—H13C	109.5
O1—C1—Ru1	137.4 (3)	C5—C14—H14A	109.5
Ru1i—C1—Ru1	85.39 (16)	C5—C14—H14B	109.5
O2—C2—Ru1	174.9 (4)	H14A—C14—H14B	109.5
C7—C3—C4	107.4 (3)	C5—C14—H14C	109.5
C7—C3—C8	126.1 (4)	H14A—C14—H14C	109.5
C4—C3—C8	126.4 (4)	H14B—C14—H14C	109.5
C7—C3—Ru1	73.2 (2)	C6—C15—H15A	109.5
C4—C3—Ru1	69.8 (2)	C6—C15—H15B	109.5
C8—C3—Ru1	125.1 (3)	H15A—C15—H15B	109.5
C5—C4—C3	107.8 (3)	C6—C15—H15C	109.5
C5—C4—C13	124.4 (4)	H15A—C15—H15C	109.5
C3—C4—C13	127.4 (4)	H15B—C15—H15C	109.5
C5—C4—Ru1	73.2 (2)	C7—C16—H16A	109.5
C3—C4—Ru1	72.7 (2)	C7—C16—H16B	109.5
C13—C4—Ru1	125.6 (3)	H16A—C16—H16B	109.5
C6—C5—C4	107.4 (3)	C7—C16—H16C	109.5
C6—C5—C14	126.7 (4)	H16A—C16—H16C	109.5
C4—C5—C14	125.8 (4)	H16B—C16—H16C	109.5
C6—C5—Ru1	72.6 (2)
C2—Ru1—C1—O1	−87.0 (5)	C6—Ru1—C5—C4	−116.8 (3)
C1i—Ru1—C1—O1	180.0 (6)	C7—Ru1—C5—C4	−80.5 (2)
C4—Ru1—C1—O1	11.7 (6)	Ru1i—Ru1—C5—C4	−174.79 (17)
C3—Ru1—C1—O1	23.0 (5)	C2—Ru1—C5—C14	−59.5 (4)
C5—Ru1—C1—O1	72.3 (6)	C1i—Ru1—C5—C14	35.5 (4)
C6—Ru1—C1—O1	85.3 (5)	C1—Ru1—C5—C14	143.2 (4)
C7—Ru1—C1—O1	58.3 (5)	C4—Ru1—C5—C14	−120.2 (5)
Ru1i—Ru1—C1—O1	180.0 (6)	C3—Ru1—C5—C14	−158.9 (4)
C2—Ru1—C1—Ru1i	93.01 (17)	C6—Ru1—C5—C14	123.1 (5)
C1i—Ru1—C1—Ru1i	0.0	C7—Ru1—C5—C14	159.3 (4)
C4—Ru1—C1—Ru1i	−168.28 (16)	Ru1i—Ru1—C5—C14	65.0 (4)
C3—Ru1—C1—Ru1i	−156.93 (13)	C4—C5—C6—C7	−1.5 (4)
C5—Ru1—C1—Ru1i	−107.7 (3)	C14—C5—C6—C7	174.9 (4)
C6—Ru1—C1—Ru1i	−94.71 (15)	Ru1—C5—C6—C7	−62.9 (3)
C7—Ru1—C1—Ru1i	−121.66 (14)	C4—C5—C6—C15	−175.8 (4)
C1i—Ru1—C2—O2	−115 (5)	C14—C5—C6—C15	0.5 (6)
C1—Ru1—C2—O2	150 (5)	Ru1—C5—C6—C15	122.8 (4)
C4—Ru1—C2—O2	13 (5)	C4—C5—C6—Ru1	61.4 (2)
C3—Ru1—C2—O2	48 (5)	C14—C5—C6—Ru1	−122.2 (4)
C5—Ru1—C2—O2	−19 (5)	C2—Ru1—C6—C7	113.5 (4)
C6—Ru1—C2—O2	−16 (5)	C1i—Ru1—C6—C7	−147.0 (2)
C7—Ru1—C2—O2	54 (5)	C1—Ru1—C6—C7	−50.8 (3)
Ru1i—Ru1—C2—O2	−163 (5)	C4—Ru1—C6—C7	80.4 (2)
C2—Ru1—C3—C7	174.1 (2)	C3—Ru1—C6—C7	37.2 (2)
C1i—Ru1—C3—C7	−45.5 (4)	C5—Ru1—C6—C7	118.3 (3)
C1—Ru1—C3—C7	76.5 (2)	Ru1i—Ru1—C6—C7	−101.8 (2)
C4—Ru1—C3—C7	−116.4 (3)	C2—Ru1—C6—C5	−4.8 (4)
C5—Ru1—C3—C7	−78.1 (2)	C1i—Ru1—C6—C5	94.7 (2)
C6—Ru1—C3—C7	−36.5 (2)	C1—Ru1—C6—C5	−169.1 (2)
Ru1i—Ru1—C3—C7	48.8 (3)	C4—Ru1—C6—C5	−37.9 (2)
C2—Ru1—C3—C4	−69.5 (3)	C3—Ru1—C6—C5	−81.1 (2)
C1i—Ru1—C3—C4	70.8 (4)	C7—Ru1—C6—C5	−118.3 (3)
C1—Ru1—C3—C4	−167.2 (2)	Ru1i—Ru1—C6—C5	139.9 (2)
C5—Ru1—C3—C4	38.2 (2)	C2—Ru1—C6—C15	−124.6 (4)
C6—Ru1—C3—C4	79.8 (2)	C1i—Ru1—C6—C15	−25.1 (4)
C7—Ru1—C3—C4	116.4 (3)	C1—Ru1—C6—C15	71.1 (4)
Ru1i—Ru1—C3—C4	165.20 (18)	C4—Ru1—C6—C15	−157.7 (4)
C2—Ru1—C3—C8	51.4 (4)	C3—Ru1—C6—C15	159.1 (4)
C1i—Ru1—C3—C8	−168.2 (3)	C5—Ru1—C6—C15	−119.8 (5)
C1—Ru1—C3—C8	−46.2 (4)	C7—Ru1—C6—C15	121.9 (5)
C4—Ru1—C3—C8	121.0 (4)	Ru1i—Ru1—C6—C15	20.1 (4)
C5—Ru1—C3—C8	159.2 (4)	C5—C6—C7—C3	0.7 (4)
C6—Ru1—C3—C8	−159.2 (4)	C15—C6—C7—C3	175.0 (4)
C7—Ru1—C3—C8	−122.7 (5)	Ru1—C6—C7—C3	−61.4 (3)
Ru1i—Ru1—C3—C8	−73.8 (4)	C5—C6—C7—C16	−173.6 (4)
C7—C3—C4—C5	−1.3 (4)	C15—C6—C7—C16	0.7 (7)
C8—C3—C4—C5	175.3 (4)	Ru1—C6—C7—C16	124.3 (4)
Ru1—C3—C4—C5	−65.3 (3)	C5—C6—C7—Ru1	62.1 (3)
C7—C3—C4—C13	−174.0 (4)	C15—C6—C7—Ru1	−123.7 (4)
C8—C3—C4—C13	2.6 (6)	C4—C3—C7—C6	0.4 (4)
Ru1—C3—C4—C13	121.9 (4)	C8—C3—C7—C6	−176.3 (4)
C7—C3—C4—Ru1	64.0 (3)	Ru1—C3—C7—C6	62.2 (3)
C8—C3—C4—Ru1	−119.4 (4)	C4—C3—C7—C16	174.6 (4)
C2—Ru1—C4—C5	−127.1 (3)	C8—C3—C7—C16	−2.0 (7)
C1i—Ru1—C4—C5	−31.2 (3)	Ru1—C3—C7—C16	−123.6 (4)
C1—Ru1—C4—C5	133.9 (2)	C4—C3—C7—Ru1	−61.8 (2)
C3—Ru1—C4—C5	115.4 (3)	C8—C3—C7—Ru1	121.6 (4)
C6—Ru1—C4—C5	37.1 (2)	C2—Ru1—C7—C6	−127.4 (3)
C7—Ru1—C4—C5	78.1 (2)	C1i—Ru1—C7—C6	39.7 (3)
Ru1i—Ru1—C4—C5	24.2 (7)	C1—Ru1—C7—C6	135.4 (2)
C2—Ru1—C4—C3	117.5 (3)	C4—Ru1—C7—C6	−79.2 (2)
C1i—Ru1—C4—C3	−146.6 (2)	C3—Ru1—C7—C6	−117.6 (3)
C1—Ru1—C4—C3	18.5 (3)	C5—Ru1—C7—C6	−36.7 (2)
C5—Ru1—C4—C3	−115.4 (3)	Ru1i—Ru1—C7—C6	92.8 (2)
C6—Ru1—C4—C3	−78.3 (2)	C2—Ru1—C7—C3	−9.7 (4)
C7—Ru1—C4—C3	−37.3 (2)	C1i—Ru1—C7—C3	157.3 (2)
Ru1i—Ru1—C4—C3	−91.2 (6)	C1—Ru1—C7—C3	−107.0 (2)
C2—Ru1—C4—C13	−6.5 (4)	C4—Ru1—C7—C3	38.4 (2)
C1i—Ru1—C4—C13	89.4 (4)	C5—Ru1—C7—C3	80.9 (2)
C1—Ru1—C4—C13	−105.4 (4)	C6—Ru1—C7—C3	117.6 (3)
C3—Ru1—C4—C13	−124.0 (5)	Ru1i—Ru1—C7—C3	−149.6 (2)
C5—Ru1—C4—C13	120.6 (4)	C2—Ru1—C7—C16	111.5 (4)
C6—Ru1—C4—C13	157.7 (4)	C1i—Ru1—C7—C16	−81.5 (4)
C7—Ru1—C4—C13	−161.3 (4)	C1—Ru1—C7—C16	14.2 (4)
Ru1i—Ru1—C4—C13	144.8 (5)	C4—Ru1—C7—C16	159.6 (4)
C3—C4—C5—C6	1.7 (4)	C3—Ru1—C7—C16	121.2 (5)
C13—C4—C5—C6	174.7 (4)	C5—Ru1—C7—C16	−157.8 (4)
Ru1—C4—C5—C6	−63.2 (3)	C6—Ru1—C7—C16	−121.2 (5)
C3—C4—C5—C14	−174.7 (4)	Ru1i—Ru1—C7—C16	−28.4 (4)
C13—C4—C5—C14	−1.7 (6)	C11—O3—C8—C9	0.3 (5)
Ru1—C4—C5—C14	120.3 (4)	C11—O3—C8—C3	−178.2 (4)
C3—C4—C5—Ru1	64.9 (3)	C7—C3—C8—C9	−29.6 (8)
C13—C4—C5—Ru1	−122.0 (4)	C4—C3—C8—C9	154.4 (5)
C2—Ru1—C5—C6	177.4 (2)	Ru1—C3—C8—C9	64.7 (7)
C1i—Ru1—C5—C6	−87.5 (2)	C7—C3—C8—O3	148.4 (4)
C1—Ru1—C5—C6	20.2 (4)	C4—C3—C8—O3	−27.6 (6)
C4—Ru1—C5—C6	116.8 (3)	Ru1—C3—C8—O3	−117.3 (3)
C3—Ru1—C5—C6	78.0 (2)	O3—C8—C9—C10	0.1 (5)
C7—Ru1—C5—C6	36.2 (2)	C3—C8—C9—C10	178.2 (5)
Ru1i—Ru1—C5—C6	−58.0 (3)	C8—C9—C10—C11	−0.6 (6)
C2—Ru1—C5—C4	60.7 (3)	C9—C10—C11—O3	0.7 (6)
C1i—Ru1—C5—C4	155.7 (2)	C9—C10—C11—C12	−178.8 (6)
C1—Ru1—C5—C4	−96.6 (3)	C8—O3—C11—C10	−0.6 (5)
C3—Ru1—C5—C4	−38.7 (2)	C8—O3—C11—C12	179.0 (5)