Aqua-bis(triphenyl-phosphine-κP)copper(I) tetra-fluoridoborate.

In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl-phosphine ligands and one water mol-ecule in a distorted trigonal geometry. In the BF(4) (-) anion, three F atoms are disordered over two sites around the B-F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu⋯F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter-action. O-H⋯F and weak C-H⋯F hydrogen bonding is present in the crystal structure.

Related literature

For the applications of CuI complexes, see: Kirchhoff et al. (1985 ▶); Zhang et al. (2004 ▶); Moudam et al. (2007 ▶). For the tetra­hedral coordination geometry of CuI complexes, see: Engelhardt et al. (1985 ▶); Barron et al. (1987 ▶). For the weak Cu⋯F inter­action, see: Mao et al. (2003 ▶); Fu et al. (2004 ▶). For Cu—P and Cu—O bond distances, see: Meng et al. (2006 ▶).

Experimental

Crystal data

[Cu(C18H15P)2(H2O)]BF4

M = 692.91

Monoclinic,

a = 13.9737 (14) Å

b = 12.4258 (11) Å

c = 19.4276 (18) Å

β = 94.521 (1)°

V = 3362.8 (5) Å3

Z = 4

Mo Kα radiation

μ = 0.79 mm−1

T = 298 K

0.48 × 0.19 × 0.16 mm

Data collection

Bruker SMART APEXII area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.702, T max = 0.883

17192 measured reflections

5914 independent reflections

3008 reflections with I > 2σ(I)

R int = 0.078

Refinement

R[F 2 > 2σ(F 2)] = 0.061

wR(F 2) = 0.202

S = 1.04

5914 reflections

434 parameters

1 restraint

H-atom parameters constrained

Δρmax = 0.93 e Å−3

Δρmin = −0.36 e Å−3

Data collection: APEX2 (Bruker, 2008 ▶); cell refinement: SAINT (Bruker, 2008 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809029559/xu2555sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809029559/xu2555Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu(C18H15P)2(H2O)]BF4	F(000) = 1424
Mr = 692.91	Dx = 1.369 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 2641 reflections
a = 13.9737 (14) Å	θ = 2.2–21.6°
b = 12.4258 (11) Å	µ = 0.79 mm−1
c = 19.4276 (18) Å	T = 298 K
β = 94.521 (1)°	Block, yellow
V = 3362.8 (5) Å3	0.48 × 0.19 × 0.16 mm
Z = 4

Bruker SMART APEXII area-detector diffractometer	5914 independent reflections
Radiation source: fine-focus sealed tube	3008 reflections with I > 2σ(I)
graphite	Rint = 0.078
φ and ω scans	θmax = 25.0°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −16→15
Tmin = 0.702, Tmax = 0.883	k = −14→14
17192 measured reflections	l = −23→22

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.061	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.202	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0646P)2 + 7.3064P] where P = (Fo2 + 2Fc2)/3
5914 reflections	(Δ/σ)max = 0.001
434 parameters	Δρmax = 0.93 e Å−3
1 restraint	Δρmin = −0.36 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cu1	0.36105 (6)	0.80395 (7)	0.13634 (4)	0.0517 (3)
O1	0.2503 (4)	0.7985 (4)	0.2037 (2)	0.0875 (17)
H1C	0.2344	0.8634	0.2107	0.105*
H1D	0.2314	0.7597	0.2361	0.105*
P1	0.50924 (12)	0.81613 (14)	0.18770 (8)	0.0460 (4)
P2	0.29834 (12)	0.72605 (14)	0.03854 (8)	0.0464 (4)
C1	0.6043 (4)	0.8457 (5)	0.1314 (3)	0.0463 (15)
C2	0.5854 (5)	0.9201 (6)	0.0780 (3)	0.0606 (19)
H2	0.5247	0.9510	0.0715	0.073*
C3	0.6543 (6)	0.9483 (6)	0.0352 (4)	0.069 (2)
H3	0.6399	0.9972	−0.0003	0.082*
C4	0.7436 (6)	0.9051 (6)	0.0442 (4)	0.067 (2)
H4	0.7902	0.9242	0.0149	0.081*
C5	0.7649 (5)	0.8330 (6)	0.0971 (4)	0.068 (2)
H5	0.8265	0.8044	0.1038	0.082*
C6	0.6956 (5)	0.8025 (6)	0.1404 (3)	0.0583 (18)
H6	0.7105	0.7530	0.1756	0.070*
C7	0.5344 (5)	0.9112 (5)	0.2578 (3)	0.0512 (17)
C8	0.6274 (5)	0.9386 (6)	0.2829 (3)	0.0610 (19)
H8	0.6793	0.9041	0.2652	0.073*
C9	0.6440 (6)	1.0154 (6)	0.3332 (4)	0.070 (2)
H9	0.7066	1.0337	0.3487	0.084*
C10	0.5692 (7)	1.0643 (7)	0.3602 (4)	0.077 (2)
H10	0.5807	1.1151	0.3950	0.092*
C11	0.4772 (6)	1.0403 (7)	0.3370 (4)	0.083 (3)
H11	0.4262	1.0753	0.3554	0.100*
C12	0.4599 (5)	0.9630 (6)	0.2857 (3)	0.067 (2)
H12	0.3970	0.9462	0.2702	0.080*
C13	0.5397 (5)	0.6851 (5)	0.2224 (3)	0.0527 (17)
C14	0.5584 (6)	0.6645 (6)	0.2916 (4)	0.077 (2)
H14	0.5589	0.7206	0.3234	0.092*
C15	0.5764 (7)	0.5595 (8)	0.3144 (5)	0.105 (3)
H15	0.5880	0.5459	0.3614	0.126*
C16	0.5774 (8)	0.4772 (8)	0.2688 (5)	0.106 (3)
H16	0.5910	0.4078	0.2845	0.127*
C17	0.5585 (7)	0.4957 (7)	0.2005 (5)	0.094 (3)
H17	0.5586	0.4392	0.1691	0.113*
C18	0.5394 (6)	0.5986 (6)	0.1781 (4)	0.075 (2)
H18	0.5257	0.6105	0.1311	0.090*
C19	0.3094 (4)	0.5817 (5)	0.0445 (3)	0.0479 (16)
C20	0.2846 (5)	0.5319 (6)	0.1046 (4)	0.067 (2)
H20	0.2710	0.5738	0.1422	0.080*
C21	0.2797 (6)	0.4224 (7)	0.1093 (4)	0.077 (2)
H21	0.2616	0.3908	0.1496	0.092*
C22	0.3010 (6)	0.3593 (7)	0.0560 (4)	0.077 (2)
H22	0.2961	0.2849	0.0593	0.092*
C23	0.3296 (6)	0.4054 (7)	−0.0029 (4)	0.081 (2)
H23	0.3467	0.3624	−0.0392	0.097*
C24	0.3332 (5)	0.5159 (6)	−0.0084 (4)	0.066 (2)
H24	0.3521	0.5466	−0.0488	0.080*
C25	0.1693 (5)	0.7425 (6)	0.0208 (3)	0.0487 (16)
C26	0.1270 (5)	0.8370 (6)	0.0406 (4)	0.070 (2)
H26	0.1638	0.8891	0.0645	0.084*
C27	0.0280 (6)	0.8544 (8)	0.0245 (4)	0.083 (3)
H27	−0.0007	0.9177	0.0380	0.099*
C28	−0.0256 (6)	0.7771 (8)	−0.0113 (4)	0.079 (2)
H28	−0.0904	0.7894	−0.0235	0.095*
C29	0.0150 (5)	0.6832 (7)	−0.0291 (4)	0.073 (2)
H29	−0.0223	0.6302	−0.0520	0.088*
C30	0.1115 (5)	0.6663 (6)	−0.0133 (3)	0.0610 (19)
H30	0.1386	0.6016	−0.0259	0.073*
C31	0.3468 (5)	0.7605 (5)	−0.0425 (3)	0.0512 (17)
C32	0.4439 (5)	0.7700 (6)	−0.0454 (4)	0.065 (2)
H32	0.4840	0.7570	−0.0057	0.078*
C33	0.4846 (6)	0.7984 (6)	−0.1059 (4)	0.074 (2)
H33	0.5509	0.8030	−0.1069	0.089*
C34	0.4255 (6)	0.8195 (7)	−0.1639 (4)	0.076 (2)
H34	0.4519	0.8389	−0.2046	0.091*
C35	0.3292 (6)	0.8125 (7)	−0.1625 (4)	0.080 (2)
H35	0.2896	0.8278	−0.2021	0.096*
C36	0.2894 (5)	0.7826 (6)	−0.1026 (3)	0.067 (2)
H36	0.2231	0.7771	−0.1023	0.080*
B1	0.2480 (10)	1.0703 (10)	0.1638 (6)	0.086 (3)
F1	0.3118 (4)	1.0059 (4)	0.1338 (2)	0.0998 (15)
F2	0.206 (2)	1.010 (2)	0.2129 (18)	0.108 (7)	0.67 (6)
F3	0.3076 (17)	1.150 (2)	0.1979 (18)	0.134 (9)	0.67 (6)
F4	0.188 (2)	1.115 (3)	0.1190 (10)	0.134 (10)	0.67 (6)
F2'	0.258 (5)	1.174 (2)	0.162 (3)	0.138 (17)	0.33 (6)
F3'	0.155 (3)	1.054 (5)	0.123 (3)	0.125 (15)	0.33 (6)
F4'	0.232 (5)	1.050 (6)	0.228 (2)	0.110 (15)	0.33 (6)

	U11	U22	U33	U12	U13	U23
Cu1	0.0530 (5)	0.0605 (6)	0.0401 (5)	0.0008 (4)	−0.0054 (3)	−0.0045 (4)
O1	0.121 (4)	0.076 (4)	0.069 (3)	−0.003 (3)	0.034 (3)	0.015 (3)
P1	0.0515 (10)	0.0508 (11)	0.0342 (9)	0.0055 (9)	−0.0063 (7)	−0.0053 (8)
P2	0.0489 (10)	0.0510 (11)	0.0378 (9)	0.0044 (8)	−0.0063 (7)	−0.0019 (8)
C1	0.053 (4)	0.044 (4)	0.040 (4)	−0.001 (3)	−0.005 (3)	−0.009 (3)
C2	0.068 (5)	0.055 (5)	0.058 (4)	0.013 (4)	−0.003 (4)	0.000 (4)
C3	0.085 (6)	0.058 (5)	0.062 (5)	−0.002 (5)	0.004 (4)	0.008 (4)
C4	0.082 (6)	0.059 (5)	0.063 (5)	−0.002 (4)	0.016 (4)	−0.004 (4)
C5	0.062 (5)	0.075 (6)	0.069 (5)	0.012 (4)	0.009 (4)	−0.012 (4)
C6	0.066 (5)	0.059 (5)	0.050 (4)	0.010 (4)	0.000 (4)	0.003 (3)
C7	0.063 (4)	0.052 (4)	0.037 (4)	0.004 (4)	−0.005 (3)	−0.007 (3)
C8	0.067 (5)	0.067 (5)	0.048 (4)	0.001 (4)	−0.008 (3)	−0.011 (4)
C9	0.080 (5)	0.072 (6)	0.056 (5)	−0.007 (5)	−0.010 (4)	−0.012 (4)
C10	0.110 (7)	0.069 (6)	0.050 (5)	−0.006 (5)	0.002 (5)	−0.019 (4)
C11	0.089 (6)	0.089 (7)	0.074 (6)	0.004 (5)	0.022 (5)	−0.032 (5)
C12	0.070 (5)	0.075 (5)	0.055 (4)	0.002 (4)	0.002 (4)	−0.020 (4)
C13	0.059 (4)	0.055 (5)	0.042 (4)	−0.001 (4)	−0.006 (3)	−0.002 (3)
C14	0.108 (6)	0.060 (5)	0.058 (5)	−0.002 (5)	−0.016 (4)	0.003 (4)
C15	0.161 (10)	0.080 (7)	0.068 (6)	0.000 (7)	−0.028 (6)	0.024 (5)
C16	0.153 (9)	0.062 (6)	0.097 (8)	0.014 (6)	−0.023 (7)	0.016 (6)
C17	0.136 (8)	0.060 (6)	0.085 (7)	0.013 (6)	−0.007 (6)	−0.004 (5)
C18	0.105 (6)	0.059 (5)	0.059 (5)	0.016 (5)	−0.004 (4)	0.002 (4)
C19	0.050 (4)	0.053 (4)	0.040 (4)	0.006 (3)	−0.001 (3)	0.000 (3)
C20	0.088 (6)	0.057 (5)	0.057 (5)	0.009 (4)	0.014 (4)	0.000 (4)
C21	0.099 (6)	0.064 (6)	0.069 (5)	0.007 (5)	0.016 (5)	0.011 (4)
C22	0.096 (6)	0.054 (5)	0.080 (6)	0.010 (5)	0.002 (5)	0.004 (5)
C23	0.107 (7)	0.062 (6)	0.073 (6)	0.014 (5)	0.013 (5)	−0.010 (4)
C24	0.084 (5)	0.060 (5)	0.056 (5)	0.011 (4)	0.009 (4)	0.001 (4)
C25	0.052 (4)	0.054 (4)	0.040 (4)	0.013 (3)	0.002 (3)	0.004 (3)
C26	0.070 (5)	0.066 (5)	0.072 (5)	0.013 (4)	−0.001 (4)	0.000 (4)
C27	0.077 (6)	0.082 (6)	0.091 (6)	0.035 (5)	0.014 (5)	0.012 (5)
C28	0.060 (5)	0.106 (8)	0.071 (6)	0.017 (5)	−0.004 (4)	0.009 (5)
C29	0.052 (4)	0.102 (7)	0.063 (5)	0.002 (5)	−0.007 (4)	−0.007 (5)
C30	0.054 (4)	0.074 (5)	0.053 (4)	0.009 (4)	−0.006 (3)	−0.007 (4)
C31	0.057 (4)	0.054 (4)	0.042 (4)	0.000 (3)	−0.002 (3)	0.002 (3)
C32	0.063 (5)	0.075 (5)	0.056 (5)	0.003 (4)	0.002 (4)	0.009 (4)
C33	0.067 (5)	0.081 (6)	0.075 (5)	0.004 (4)	0.019 (4)	0.013 (5)
C34	0.091 (6)	0.081 (6)	0.058 (5)	−0.002 (5)	0.018 (5)	0.008 (4)
C35	0.088 (6)	0.099 (7)	0.051 (5)	−0.011 (5)	−0.005 (4)	0.018 (4)
C36	0.063 (5)	0.086 (6)	0.050 (4)	−0.009 (4)	−0.001 (4)	0.012 (4)
B1	0.123 (10)	0.058 (8)	0.075 (8)	0.007 (8)	0.003 (8)	0.002 (6)
F1	0.111 (4)	0.107 (4)	0.085 (3)	0.013 (3)	0.026 (3)	0.007 (3)
F2	0.131 (14)	0.094 (13)	0.108 (16)	0.015 (9)	0.058 (12)	0.023 (9)
F3	0.134 (12)	0.113 (11)	0.151 (18)	−0.001 (10)	−0.009 (11)	−0.046 (11)
F4	0.139 (14)	0.14 (2)	0.119 (9)	0.048 (15)	−0.014 (9)	0.047 (13)
F2'	0.18 (4)	0.097 (19)	0.14 (3)	−0.014 (19)	−0.01 (3)	0.015 (17)
F3'	0.14 (2)	0.10 (3)	0.13 (2)	0.02 (2)	−0.016 (18)	−0.024 (19)
F4'	0.15 (3)	0.12 (4)	0.060 (15)	0.02 (3)	0.013 (16)	0.013 (18)

Cu1—O1	2.105 (5)	C17—H17	0.9300
Cu1—P1	2.2318 (18)	C18—H18	0.9300
Cu1—P2	2.2478 (18)	C19—C24	1.375 (9)
O1—H1C	0.8500	C19—C20	1.389 (9)
O1—H1D	0.8500	C20—C21	1.366 (10)
P1—C13	1.800 (7)	C20—H20	0.9300
P1—C7	1.816 (6)	C21—C22	1.349 (10)
P1—C1	1.823 (6)	C21—H21	0.9300
P2—C19	1.803 (7)	C22—C23	1.368 (10)
P2—C31	1.814 (6)	C22—H22	0.9300
P2—C25	1.820 (6)	C23—C24	1.377 (10)
C1—C6	1.383 (8)	C23—H23	0.9300
C1—C2	1.400 (9)	C24—H24	0.9300
C2—C3	1.366 (9)	C25—C30	1.380 (9)
C2—H2	0.9300	C25—C26	1.382 (9)
C3—C4	1.357 (10)	C26—C27	1.410 (10)
C3—H3	0.9300	C26—H26	0.9300
C4—C5	1.378 (10)	C27—C28	1.373 (11)
C4—H4	0.9300	C27—H27	0.9300
C5—C6	1.385 (9)	C28—C29	1.355 (11)
C5—H5	0.9300	C28—H28	0.9300
C6—H6	0.9300	C29—C30	1.375 (9)
C7—C12	1.373 (9)	C29—H29	0.9300
C7—C8	1.394 (9)	C30—H30	0.9300
C8—C9	1.374 (9)	C31—C32	1.367 (9)
C8—H8	0.9300	C31—C36	1.390 (9)
C9—C10	1.350 (10)	C32—C33	1.391 (9)
C9—H9	0.9300	C32—H32	0.9300
C10—C11	1.362 (10)	C33—C34	1.369 (10)
C10—H10	0.9300	C33—H33	0.9300
C11—C12	1.391 (10)	C34—C35	1.351 (10)
C11—H11	0.9300	C34—H34	0.9300
C12—H12	0.9300	C35—C36	1.381 (9)
C13—C14	1.374 (9)	C35—H35	0.9300
C13—C18	1.377 (9)	C36—H36	0.9300
C14—C15	1.393 (11)	B1—F4	1.285 (19)
C14—H14	0.9300	B1—F2'	1.30 (3)
C15—C16	1.354 (12)	B1—F4'	1.31 (5)
C15—H15	0.9300	B1—F1	1.363 (12)
C16—C17	1.352 (11)	B1—F2	1.38 (3)
C16—H16	0.9300	B1—F3	1.42 (2)
C17—C18	1.370 (10)	B1—F3'	1.48 (4)
O1—Cu1—P1	115.18 (16)	C17—C18—C13	122.6 (7)
O1—Cu1—P2	104.80 (16)	C17—C18—H18	118.7
P1—Cu1—P2	133.89 (7)	C13—C18—H18	118.7
Cu1—O1—H1C	106.5	C24—C19—C20	117.0 (7)
Cu1—O1—H1D	139.8	C24—C19—P2	124.6 (5)
H1C—O1—H1D	108.6	C20—C19—P2	118.1 (5)
C13—P1—C7	106.4 (3)	C21—C20—C19	121.1 (7)
C13—P1—C1	104.2 (3)	C21—C20—H20	119.4
C7—P1—C1	102.2 (3)	C19—C20—H20	119.4
C13—P1—Cu1	106.8 (2)	C22—C21—C20	120.8 (8)
C7—P1—Cu1	119.8 (2)	C22—C21—H21	119.6
C1—P1—Cu1	116.1 (2)	C20—C21—H21	119.6
C19—P2—C31	104.8 (3)	C21—C22—C23	119.7 (8)
C19—P2—C25	101.7 (3)	C21—C22—H22	120.2
C31—P2—C25	103.9 (3)	C23—C22—H22	120.2
C19—P2—Cu1	110.4 (2)	C22—C23—C24	119.8 (8)
C31—P2—Cu1	119.0 (2)	C22—C23—H23	120.1
C25—P2—Cu1	115.2 (2)	C24—C23—H23	120.1
C6—C1—C2	118.0 (6)	C19—C24—C23	121.5 (7)
C6—C1—P1	123.7 (5)	C19—C24—H24	119.2
C2—C1—P1	118.3 (5)	C23—C24—H24	119.2
C3—C2—C1	121.3 (7)	C30—C25—C26	118.0 (6)
C3—C2—H2	119.4	C30—C25—P2	123.2 (5)
C1—C2—H2	119.4	C26—C25—P2	118.8 (6)
C4—C3—C2	120.3 (7)	C25—C26—C27	120.2 (8)
C4—C3—H3	119.8	C25—C26—H26	119.9
C2—C3—H3	119.8	C27—C26—H26	119.9
C3—C4—C5	119.8 (7)	C28—C27—C26	119.4 (8)
C3—C4—H4	120.1	C28—C27—H27	120.3
C5—C4—H4	120.1	C26—C27—H27	120.3
C4—C5—C6	120.7 (7)	C29—C28—C27	120.6 (8)
C4—C5—H5	119.7	C29—C28—H28	119.7
C6—C5—H5	119.7	C27—C28—H28	119.7
C1—C6—C5	119.9 (6)	C28—C29—C30	119.8 (8)
C1—C6—H6	120.0	C28—C29—H29	120.1
C5—C6—H6	120.0	C30—C29—H29	120.1
C12—C7—C8	117.6 (6)	C29—C30—C25	121.9 (7)
C12—C7—P1	119.6 (5)	C29—C30—H30	119.0
C8—C7—P1	122.8 (5)	C25—C30—H30	119.0
C9—C8—C7	121.3 (7)	C32—C31—C36	117.2 (6)
C9—C8—H8	119.4	C32—C31—P2	119.7 (5)
C7—C8—H8	119.4	C36—C31—P2	123.0 (5)
C10—C9—C8	119.8 (7)	C31—C32—C33	122.0 (7)
C10—C9—H9	120.1	C31—C32—H32	119.0
C8—C9—H9	120.1	C33—C32—H32	119.0
C9—C10—C11	120.9 (7)	C34—C33—C32	118.9 (7)
C9—C10—H10	119.6	C34—C33—H33	120.5
C11—C10—H10	119.6	C32—C33—H33	120.5
C10—C11—C12	119.6 (7)	C35—C34—C33	120.6 (7)
C10—C11—H11	120.2	C35—C34—H34	119.7
C12—C11—H11	120.2	C33—C34—H34	119.7
C7—C12—C11	120.8 (7)	C34—C35—C36	120.1 (7)
C7—C12—H12	119.6	C34—C35—H35	120.0
C11—C12—H12	119.6	C36—C35—H35	120.0
C14—C13—C18	117.2 (7)	C35—C36—C31	121.2 (7)
C14—C13—P1	123.8 (6)	C35—C36—H36	119.4
C18—C13—P1	118.9 (5)	C31—C36—H36	119.4
C13—C14—C15	120.0 (8)	F4—B1—F1	112.3 (13)
C13—C14—H14	120.0	F4—B1—F2	114.1 (18)
C15—C14—H14	120.0	F1—B1—F2	107.7 (14)
C16—C15—C14	120.7 (8)	F4—B1—F3	110.3 (14)
C16—C15—H15	119.6	F1—B1—F3	103.1 (12)
C14—C15—H15	119.6	F2—B1—F3	108.8 (13)
C17—C16—C15	120.2 (9)	F2'—B1—F4'	104 (3)
C17—C16—H16	119.9	F2'—B1—F3'	103 (2)
C15—C16—H16	119.9	F4'—B1—F3'	106 (3)
C16—C17—C18	119.2 (8)	F1—B1—F3'	105.6 (16)
C16—C17—H17	120.4	F2'—B1—F1	120 (2)
C18—C17—H17	120.4	F4'—B1—F1	117 (3)
O1—Cu1—P1—C13	75.2 (3)	C13—C14—C15—C16	1.1 (15)
P2—Cu1—P1—C13	−72.4 (2)	C14—C15—C16—C17	−1.5 (17)
O1—Cu1—P1—C7	−45.7 (3)	C15—C16—C17—C18	0.6 (17)
P2—Cu1—P1—C7	166.8 (2)	C16—C17—C18—C13	0.8 (15)
O1—Cu1—P1—C1	−169.2 (3)	C14—C13—C18—C17	−1.3 (12)
P2—Cu1—P1—C1	43.3 (3)	P1—C13—C18—C17	−177.8 (7)
O1—Cu1—P2—C19	−83.8 (3)	C31—P2—C19—C24	−10.6 (7)
P1—Cu1—P2—C19	66.0 (2)	C25—P2—C19—C24	97.4 (6)
O1—Cu1—P2—C31	155.1 (3)	Cu1—P2—C19—C24	−139.8 (5)
P1—Cu1—P2—C31	−55.1 (3)	C31—P2—C19—C20	175.1 (5)
O1—Cu1—P2—C25	30.6 (3)	C25—P2—C19—C20	−76.9 (6)
P1—Cu1—P2—C25	−179.5 (2)	Cu1—P2—C19—C20	45.8 (6)
C13—P1—C1—C6	−26.4 (6)	C24—C19—C20—C21	−3.0 (11)
C7—P1—C1—C6	84.2 (6)	P2—C19—C20—C21	171.7 (6)
Cu1—P1—C1—C6	−143.5 (5)	C19—C20—C21—C22	1.4 (13)
C13—P1—C1—C2	156.7 (5)	C20—C21—C22—C23	1.4 (13)
C7—P1—C1—C2	−92.7 (5)	C21—C22—C23—C24	−2.4 (13)
Cu1—P1—C1—C2	39.6 (6)	C20—C19—C24—C23	2.0 (11)
C6—C1—C2—C3	1.0 (10)	P2—C19—C24—C23	−172.4 (6)
P1—C1—C2—C3	178.1 (6)	C22—C23—C24—C19	0.7 (12)
C1—C2—C3—C4	−0.8 (11)	C19—P2—C25—C30	−28.7 (6)
C2—C3—C4—C5	−0.3 (12)	C31—P2—C25—C30	80.0 (6)
C3—C4—C5—C6	1.1 (11)	Cu1—P2—C25—C30	−148.0 (5)
C2—C1—C6—C5	−0.2 (10)	C19—P2—C25—C26	153.1 (5)
P1—C1—C6—C5	−177.1 (5)	C31—P2—C25—C26	−98.3 (6)
C4—C5—C6—C1	−0.8 (11)	Cu1—P2—C25—C26	33.7 (6)
C13—P1—C7—C12	−111.1 (6)	C30—C25—C26—C27	−1.5 (10)
C1—P1—C7—C12	139.9 (6)	P2—C25—C26—C27	176.8 (6)
Cu1—P1—C7—C12	10.0 (7)	C25—C26—C27—C28	−0.4 (12)
C13—P1—C7—C8	72.0 (6)	C26—C27—C28—C29	2.3 (13)
C1—P1—C7—C8	−37.0 (6)	C27—C28—C29—C30	−2.2 (12)
Cu1—P1—C7—C8	−166.9 (5)	C28—C29—C30—C25	0.2 (11)
C12—C7—C8—C9	−0.7 (10)	C26—C25—C30—C29	1.6 (10)
P1—C7—C8—C9	176.2 (6)	P2—C25—C30—C29	−176.6 (5)
C7—C8—C9—C10	1.3 (11)	C19—P2—C31—C32	−81.9 (6)
C8—C9—C10—C11	−1.5 (13)	C25—P2—C31—C32	171.8 (6)
C9—C10—C11—C12	1.1 (13)	Cu1—P2—C31—C32	42.0 (7)
C8—C7—C12—C11	0.3 (11)	C19—P2—C31—C36	100.8 (6)
P1—C7—C12—C11	−176.7 (6)	C25—P2—C31—C36	−5.5 (7)
C10—C11—C12—C7	−0.5 (13)	Cu1—P2—C31—C36	−135.3 (6)
C7—P1—C13—C14	12.0 (7)	C36—C31—C32—C33	−1.2 (11)
C1—P1—C13—C14	119.6 (6)	P2—C31—C32—C33	−178.7 (6)
Cu1—P1—C13—C14	−117.1 (6)	C31—C32—C33—C34	1.3 (12)
C7—P1—C13—C18	−171.7 (6)	C32—C33—C34—C35	−0.3 (13)
C1—P1—C13—C18	−64.2 (6)	C33—C34—C35—C36	−0.7 (13)
Cu1—P1—C13—C18	59.2 (6)	C34—C35—C36—C31	0.8 (13)
C18—C13—C14—C15	0.3 (12)	C32—C31—C36—C35	0.1 (11)
P1—C13—C14—C15	176.6 (7)	P2—C31—C36—C35	177.5 (6)

D—H···A	D—H	H···A	D···A	D—H···A
O1—H1C···F2	0.85	1.87	2.71 (3)	171
O1—H1D···F3i	0.85	1.98	2.82 (3)	171
C28—H28···F4ii	0.93	2.51	3.25 (3)	137

Table 1

Selected bond lengths (Å)

Cu1—O1	2.105 (5)
Cu1—P1	2.2318 (18)
Cu1—P2	2.2478 (18)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1—H1C⋯F2	0.85	1.87	2.71 (3)	171
O1—H1D⋯F3i	0.85	1.98	2.82 (3)	171
C28—H28⋯F4ii	0.93	2.51	3.25 (3)	137

Symmetry codes: (i) ; (ii) .