Bis[4-(dimethyl-amino)pyridinium] tetra-bromidobis(3,4-dichloro-phen-yl)stannate(IV)-1-bromo-3,4-dichloro-benzene (1/1).

The Sn atom in the title substituted pyridinium stannate bromo-3,4-dichloro-benzene solvate, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(3)Cl(2))(2)]·C(6)H(3)BrCl(2), lies on a twofold axis within an octa-hedral C(2)Br(4) donor set. Each cation forms an N-H⋯Br hydrogen bond to one of the Br atoms of the anion. The solvent mol-ecule is disordered about the twofold rotation axis with equal occupancy. The crystal under investigation was non-merohedrally twinned, with a twin component ratio of 0.76:0.24.

Related literature

For bis­(4-dimethyl­amino­pyridinium) tetra­halido­diorgano­stan­nates, see: Lo & Ng (2008a ▶,b ▶); Yap et al. (2008 ▶). For deconvolution of the diffraction data, see: Spek (2009 ▶).

Experimental

Crystal data

(C7H11N2)2[SnBr4(C6H3Cl2)2]·C6H3BrCl2

M = 1202.55

Monoclinic,

a = 19.2308 (2) Å

b = 13.8983 (2) Å

c = 15.4961 (2) Å

β = 107.491 (1)°

V = 3950.23 (9) Å3

Z = 4

Mo Kα radiation

μ = 6.14 mm−1

T = 100 K

0.25 × 0.20 × 0.15 mm

Data collection

Bruker SMART APEX diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.309, T max = 0.459 (expected range = 0.268–0.398)

17636 measured reflections

4495 independent reflections

4061 reflections with I > 2σ(I)

R int = 0.030

Refinement

R[F 2 > 2σ(F 2)] = 0.050

wR(F 2) = 0.243

S = 1.47

4495 reflections

225 parameters

39 restraints

H-atom parameters constrained

Δρmax = 2.01 e Å−3

Δρmin = −1.80 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: X-SEED (Barbour, 2001 ▶); software used to prepare material for publication: publCIF (Westrip, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809017590/tk2446sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809017590/tk2446Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

(C7H11N2)2[SnBr4(C6H3Cl2)2]·C6H3BrCl2	F(000) = 2312
Mr = 1202.55	Dx = 2.022 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 9914 reflections
a = 19.2308 (2) Å	θ = 2.2–28.4°
b = 13.8983 (2) Å	µ = 6.14 mm−1
c = 15.4961 (2) Å	T = 100 K
β = 107.491 (1)°	Block, colorless
V = 3950.23 (9) Å3	0.25 × 0.20 × 0.15 mm
Z = 4

Bruker SMART APEX diffractometer	4495 independent reflections
Radiation source: fine-focus sealed tube	4061 reflections with I > 2σ(I)
graphite	Rint = 0.030
ω scans	θmax = 27.5°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −24→24
Tmin = 0.309, Tmax = 0.459	k = −18→18
17636 measured reflections	l = −20→20

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.050	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.243	H-atom parameters constrained
S = 1.47	w = 1/[σ2(Fo2) + (0.15P)2] where P = (Fo2 + 2Fc2)/3
4495 reflections	(Δ/σ)max = 0.001
225 parameters	Δρmax = 2.01 e Å−3
39 restraints	Δρmin = −1.80 e Å−3

	x	y	z	Uiso*/Ueq	Occ. (<1)
Sn1	0.5000	0.61725 (3)	0.7500	0.0092 (2)
Br2	0.44267 (3)	0.48127 (5)	0.62311 (4)	0.0174 (2)
Br1	0.44630 (3)	0.75638 (5)	0.62507 (4)	0.0186 (2)
Cl1	0.81264 (8)	0.62573 (10)	0.85386 (12)	0.0179 (4)
Cl2	0.81408 (10)	0.62116 (11)	0.65044 (13)	0.0243 (4)
N2	0.2115 (3)	0.6236 (4)	0.1836 (4)	0.0196 (12)
C1	0.60066 (16)	0.6174 (2)	0.7153 (3)	0.0102 (11)
C2	0.6660 (2)	0.6216 (2)	0.7850 (2)	0.0102 (11)
H2	0.6657	0.6238	0.8461	0.012*
C3	0.73187 (16)	0.6224 (2)	0.7651 (2)	0.0138 (12)
C4	0.73233 (17)	0.6191 (3)	0.6756 (3)	0.0155 (13)
C5	0.6670 (2)	0.6150 (3)	0.6060 (2)	0.0151 (13)
H5	0.6673	0.6128	0.5449	0.018*
C6	0.60113 (17)	0.6142 (2)	0.6259 (2)	0.0175 (13)
H6	0.5564	0.6113	0.5783	0.021*
N1	0.3539 (2)	0.6345 (3)	0.4428 (2)	0.0293 (14)
H1	0.3842	0.6371	0.4981	0.035*
C7	0.38080 (17)	0.6245 (3)	0.3695 (3)	0.0244 (16)
H7	0.4319	0.6205	0.3790	0.029*
C8	0.3330 (2)	0.6204 (3)	0.2822 (3)	0.0185 (14)
H8	0.3514	0.6135	0.2320	0.022*
C9	0.2582 (2)	0.6262 (3)	0.2682 (2)	0.0144 (12)
C10	0.23132 (17)	0.6362 (3)	0.3415 (3)	0.0185 (13)
H10	0.1802	0.6401	0.3320	0.022*
C11	0.2791 (2)	0.6403 (3)	0.4288 (2)	0.0239 (14)
H11	0.2608	0.6471	0.4790	0.029*
C12	0.2386 (5)	0.6177 (5)	0.1057 (5)	0.0273 (17)
H12A	0.2695	0.6737	0.1050	0.041*
H12B	0.1974	0.6168	0.0501	0.041*
H12C	0.2672	0.5587	0.1095	0.041*
C13	0.1323 (4)	0.6238 (5)	0.1685 (6)	0.0268 (17)
H13A	0.1196	0.5727	0.2047	0.040*
H13B	0.1071	0.6126	0.1043	0.040*
H13C	0.1175	0.6862	0.1866	0.040*
Br3	0.5258 (5)	0.7963 (5)	0.4343 (4)	0.0355 (11)	0.50
Cl3	0.4624 (2)	0.9970 (3)	0.0505 (2)	0.0351 (9)	0.50
Cl4	0.4620 (14)	0.7751 (14)	0.0633 (11)	0.038 (3)	0.50
C14	0.5139 (16)	0.8551 (8)	0.3234 (8)	0.027 (4)	0.50
C15	0.501 (2)	0.7983 (4)	0.2464 (11)	0.027 (3)	0.50
H15	0.5033	0.7302	0.2517	0.032*	0.50
C16	0.4852 (16)	0.8411 (7)	0.1616 (9)	0.025 (4)	0.50
C17	0.4820 (8)	0.9408 (8)	0.1538 (4)	0.023 (4)	0.50
C18	0.4948 (9)	0.9976 (4)	0.2309 (6)	0.023 (4)	0.50
H18	0.4926	1.0657	0.2255	0.028*	0.50
C19	0.5107 (8)	0.9548 (8)	0.3156 (4)	0.021 (3)	0.50
H19	0.5194	0.9936	0.3683	0.025*	0.50

	U11	U22	U33	U12	U13	U23
Sn1	0.0068 (4)	0.0113 (4)	0.0099 (3)	0.000	0.0031 (2)	0.000
Br2	0.0141 (4)	0.0186 (4)	0.0195 (4)	−0.0016 (2)	0.0048 (3)	−0.0054 (2)
Br1	0.0175 (4)	0.0215 (4)	0.0169 (4)	0.0013 (2)	0.0050 (3)	0.0030 (2)
Cl1	0.0082 (7)	0.0195 (8)	0.0236 (8)	0.0003 (5)	0.0010 (6)	−0.0001 (5)
Cl2	0.0133 (8)	0.0351 (10)	0.0291 (9)	−0.0020 (5)	0.0132 (7)	−0.0020 (6)
N2	0.019 (3)	0.019 (3)	0.018 (3)	0.0001 (18)	0.001 (2)	0.0001 (19)
C1	0.011 (3)	0.009 (3)	0.011 (3)	0.0016 (17)	0.003 (2)	0.0001 (17)
C2	0.007 (3)	0.014 (3)	0.010 (3)	0.0001 (17)	0.003 (2)	−0.0007 (18)
C3	0.008 (3)	0.014 (3)	0.019 (3)	−0.0021 (18)	0.004 (2)	−0.001 (2)
C4	0.008 (3)	0.015 (3)	0.026 (4)	−0.0011 (18)	0.008 (3)	0.000 (2)
C5	0.016 (3)	0.017 (3)	0.014 (3)	−0.003 (2)	0.007 (2)	−0.002 (2)
C6	0.018 (3)	0.019 (3)	0.016 (3)	−0.002 (2)	0.006 (3)	−0.002 (2)
N1	0.027 (4)	0.033 (3)	0.018 (3)	0.008 (2)	−0.007 (3)	−0.007 (2)
C7	0.016 (3)	0.018 (3)	0.033 (4)	0.003 (2)	−0.002 (3)	−0.006 (3)
C8	0.016 (3)	0.016 (3)	0.023 (3)	0.001 (2)	0.007 (3)	−0.002 (2)
C9	0.017 (3)	0.012 (3)	0.014 (3)	−0.002 (2)	0.003 (2)	−0.0018 (19)
C10	0.015 (3)	0.013 (3)	0.027 (3)	0.000 (2)	0.006 (3)	0.001 (2)
C11	0.033 (4)	0.026 (3)	0.012 (3)	0.008 (3)	0.007 (3)	−0.002 (3)
C12	0.036 (5)	0.031 (4)	0.011 (3)	0.001 (3)	0.001 (3)	0.001 (2)
C13	0.013 (4)	0.032 (4)	0.030 (4)	0.001 (2)	−0.002 (3)	−0.004 (3)
Br3	0.050 (3)	0.036 (3)	0.0186 (11)	−0.0140 (19)	0.0077 (13)	−0.0007 (11)
Cl3	0.049 (2)	0.0289 (19)	0.0208 (16)	−0.0123 (16)	−0.0002 (15)	0.0031 (14)
Cl4	0.047 (7)	0.039 (8)	0.026 (3)	0.008 (4)	0.009 (3)	−0.003 (3)
C14	0.030 (8)	0.036 (7)	0.017 (6)	−0.012 (7)	0.012 (6)	0.003 (6)
C15	0.028 (5)	0.024 (5)	0.032 (5)	0.003 (9)	0.014 (4)	−0.008 (9)
C16	0.018 (7)	0.039 (8)	0.027 (6)	0.014 (6)	0.018 (6)	0.001 (6)
C17	0.024 (6)	0.028 (7)	0.020 (7)	−0.007 (5)	0.012 (5)	−0.009 (6)
C18	0.026 (6)	0.025 (5)	0.019 (9)	0.003 (5)	0.007 (7)	0.000 (4)
C19	0.022 (6)	0.022 (6)	0.023 (7)	−0.007 (5)	0.015 (6)	0.000 (6)

Sn1—C1i	2.159 (3)	C8—C9	1.3900
Sn1—C1	2.159 (3)	C8—H8	0.9500
Sn1—Br2	2.7111 (7)	C9—C10	1.3900
Sn1—Br2i	2.7111 (7)	C10—C11	1.3900
Sn1—Br1i	2.7114 (7)	C10—H10	0.9500
Sn1—Br1	2.7114 (7)	C11—H11	0.9500
Cl1—C3	1.739 (3)	C12—H12A	0.9800
Cl2—C4	1.730 (3)	C12—H12B	0.9800
N2—C9	1.349 (7)	C12—H12C	0.9800
N2—C12	1.454 (10)	C13—H13A	0.9800
N2—C13	1.468 (10)	C13—H13B	0.9800
C1—C2	1.3900	C13—H13C	0.9800
C1—C6	1.3900	Br3—C14	1.855 (6)
C2—C3	1.3900	Cl3—C17	1.719 (7)
C2—H2	0.9500	Cl4—C16	1.718 (9)
C3—C4	1.3900	C14—C15	1.3900
C4—C5	1.3900	C14—C19	1.3900
C5—C6	1.3900	C15—C16	1.3900
C5—H5	0.9500	C15—H15	0.9500
C6—H6	0.9500	C16—C17	1.3900
N1—C7	1.3900	C17—C18	1.3900
N1—C11	1.3900	C18—C19	1.3900
N1—H1	0.8800	C18—H18	0.9500
C7—C8	1.3900	C19—H19	0.9500
C7—H7	0.9500
C1i—Sn1—C1	179.87 (18)	C7—C8—C9	120.0
C1i—Sn1—Br2	88.95 (10)	C7—C8—H8	120.0
C1—Sn1—Br2	91.15 (10)	C9—C8—H8	120.0
C1i—Sn1—Br2i	91.15 (10)	N2—C9—C8	120.4 (4)
C1—Sn1—Br2i	88.95 (10)	N2—C9—C10	119.6 (4)
Br2—Sn1—Br2i	91.62 (3)	C8—C9—C10	120.0
C1i—Sn1—Br1i	89.95 (10)	C11—C10—C9	120.0
C1—Sn1—Br1i	89.95 (10)	C11—C10—H10	120.0
Br2—Sn1—Br1i	178.301 (19)	C9—C10—H10	120.0
Br2i—Sn1—Br1i	89.70 (2)	C10—C11—N1	120.0
C1i—Sn1—Br1	89.95 (10)	C10—C11—H11	120.0
C1—Sn1—Br1	89.95 (10)	N1—C11—H11	120.0
Br2—Sn1—Br1	89.70 (2)	N2—C12—H12A	109.5
Br2i—Sn1—Br1	178.301 (19)	N2—C12—H12B	109.5
Br1i—Sn1—Br1	89.01 (3)	H12A—C12—H12B	109.5
C9—N2—C12	120.5 (6)	N2—C12—H12C	109.5
C9—N2—C13	120.7 (6)	H12A—C12—H12C	109.5
C12—N2—C13	118.8 (6)	H12B—C12—H12C	109.5
C2—C1—C6	120.0	N2—C13—H13A	109.5
C2—C1—Sn1	118.5 (2)	N2—C13—H13B	109.5
C6—C1—Sn1	121.5 (2)	H13A—C13—H13B	109.5
C3—C2—C1	120.0	N2—C13—H13C	109.5
C3—C2—H2	120.0	H13A—C13—H13C	109.5
C1—C2—H2	120.0	H13B—C13—H13C	109.5
C2—C3—C4	120.0	C15—C14—C19	120.0
C2—C3—Cl1	118.8 (2)	C15—C14—Br3	119.1 (9)
C4—C3—Cl1	121.2 (2)	C19—C14—Br3	120.6 (9)
C5—C4—C3	120.0	C16—C15—C14	120.0
C5—C4—Cl2	119.8 (2)	C16—C15—H15	120.0
C3—C4—Cl2	120.2 (2)	C14—C15—H15	120.0
C4—C5—C6	120.0	C15—C16—C17	120.0
C4—C5—H5	120.0	C15—C16—Cl4	122.3 (11)
C6—C5—H5	120.0	C17—C16—Cl4	117.6 (11)
C5—C6—C1	120.0	C18—C17—C16	120.0
C5—C6—H6	120.0	C18—C17—Cl3	118.3 (8)
C1—C6—H6	120.0	C16—C17—Cl3	121.7 (8)
C7—N1—C11	120.0	C17—C18—C19	120.0
C7—N1—H1	120.0	C17—C18—H18	120.0
C11—N1—H1	120.0	C19—C18—H18	120.0
C8—C7—N1	120.0	C18—C19—C14	120.0
C8—C7—H7	120.0	C18—C19—H19	120.0
N1—C7—H7	120.0	C14—C19—H19	120.0
Br2—Sn1—C1—C2	−138.45 (15)	C12—N2—C9—C8	−1.9 (6)
Br2i—Sn1—C1—C2	−46.86 (16)	C13—N2—C9—C8	176.2 (4)
Br1i—Sn1—C1—C2	42.84 (16)	C12—N2—C9—C10	177.2 (4)
Br1—Sn1—C1—C2	131.85 (16)	C13—N2—C9—C10	−4.7 (6)
Br2—Sn1—C1—C6	41.96 (17)	C7—C8—C9—N2	179.0 (4)
Br2i—Sn1—C1—C6	133.56 (17)	C7—C8—C9—C10	0.0
Br1i—Sn1—C1—C6	−136.74 (17)	N2—C9—C10—C11	−179.0 (4)
Br1—Sn1—C1—C6	−47.73 (17)	C8—C9—C10—C11	0.0
C6—C1—C2—C3	0.0	C9—C10—C11—N1	0.0
Sn1—C1—C2—C3	−179.6 (2)	C7—N1—C11—C10	0.0
C1—C2—C3—C4	0.0	C19—C14—C15—C16	0.0
C1—C2—C3—Cl1	−179.0 (2)	Br3—C14—C15—C16	173.9 (18)
C2—C3—C4—C5	0.0	C14—C15—C16—C17	0.0
Cl1—C3—C4—C5	179.0 (3)	C14—C15—C16—Cl4	−175 (2)
C2—C3—C4—Cl2	179.5 (3)	C15—C16—C17—C18	0.0
Cl1—C3—C4—Cl2	−1.5 (3)	Cl4—C16—C17—C18	175.1 (19)
C3—C4—C5—C6	0.0	C15—C16—C17—Cl3	−179.9 (11)
Cl2—C4—C5—C6	−179.5 (3)	Cl4—C16—C17—Cl3	−5(2)
C4—C5—C6—C1	0.0	C16—C17—C18—C19	0.0
C2—C1—C6—C5	0.0	Cl3—C17—C18—C19	179.9 (10)
Sn1—C1—C6—C5	179.6 (2)	C17—C18—C19—C14	0.0
C11—N1—C7—C8	0.0	C15—C14—C19—C18	0.0
N1—C7—C8—C9	0.0	Br3—C14—C19—C18	−173.8 (18)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1···Br1	0.88	2.58	3.315 (3)	142

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1⋯Br1	0.88	2.58	3.315 (3)	142