catena-Poly[hemi{bis-[4'-(3-pyrid-yl)-2,2':6',2''-terpyridine-κN,N,N]copper(II)} [cuprate(I)-di-μ(2)-thio-cyanato-κN:S;κS:N]].

The title compound, {[Cu(C(20)H(14)N(4))(2)][Cu(2)(NCS)(4)]}(n), was obtained by reacting copper acetate hydrate, ammonium thio-cyanate and 4'-(3-pyrid-yl)-2,2':6',2''-terpyridine (3-pytpy) under solvothermal conditions. The polymeric complex is isostructural with the 4'-phenyl-2,2':6',2''-terpyridine (phtpy) analogue. All intramolecular distances and angles are very similar for the two structures. Substitution of a phenyl group with a pyridyl group has no significant effect on the crystal packing which is accomplished by C-H⋯N and C-H⋯S hydrogen-bonding interactions.

Related literature

For background to 2,2′:6′,2′′-terpyridine derivatives and their complexes, see: Andres & Schubert (2004 ▶); Constable (1986 ▶); Hofmeier & Schubert (2004 ▶). For the isostructural 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) analogue, see: Shi (2009 ▶).

Experimental

Crystal data

[Cu(C20H14N4)2][Cu2(NCS)4]

M = 1043.64

Triclinic,

a = 10.0031 (6) Å

b = 10.2202 (6) Å

c = 21.2612 (12) Å

α = 82.607 (1)°

β = 87.732 (1)°

γ = 80.132 (1)°

V = 2123.3 (2) Å3

Z = 2

Mo Kα radiation

μ = 1.74 mm−1

T = 295 K

0.16 × 0.13 × 0.11 mm

Data collection

Bruker SMART APEX area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.769, T max = 0.832

16747 measured reflections

8252 independent reflections

6751 reflections with I > 2σ(I)

R int = 0.022

Refinement

R[F 2 > 2σ(F 2)] = 0.044

wR(F 2) = 0.103

S = 1.03

8252 reflections

568 parameters

H-atom parameters constrained

Δρmax = 0.69 e Å−3

Δρmin = −0.50 e Å−3

Data collection: SMART (Bruker, 2002 ▶); cell refinement: SAINT (Bruker, 2002 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809023356/zl2221sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809023356/zl2221Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu(C20H14N4)2][Cu2(NCS)4]	Z = 2
Mr = 1043.64	F(000) = 1054
Triclinic, P1	Dx = 1.632 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.0031 (6) Å	Cell parameters from 4926 reflections
b = 10.2202 (6) Å	θ = 2.4–25.2°
c = 21.2612 (12) Å	µ = 1.74 mm−1
α = 82.607 (1)°	T = 295 K
β = 87.732 (1)°	Block, black
γ = 80.132 (1)°	0.16 × 0.13 × 0.11 mm
V = 2123.3 (2) Å3

Bruker SMART APEX area-detector diffractometer	8252 independent reflections
Radiation source: fine-focus sealed tube	6751 reflections with I > 2σ(I)
graphite	Rint = 0.022
φ and ω scans	θmax = 26.0°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −12→12
Tmin = 0.769, Tmax = 0.832	k = −12→12
16747 measured reflections	l = −26→26

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.044	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.103	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0476P)2 + 1.2038P] where P = (Fo2 + 2Fc2)/3
8252 reflections	(Δ/σ)max = 0.001
568 parameters	Δρmax = 0.69 e Å−3
0 restraints	Δρmin = −0.50 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cu1	0.47293 (4)	0.80579 (4)	0.251577 (17)	0.03901 (11)
Cu2	1.01294 (4)	0.24421 (4)	0.02065 (2)	0.04908 (13)
Cu3	−0.01615 (5)	0.25397 (4)	0.48921 (2)	0.05715 (14)
N1	0.6206 (3)	0.6156 (3)	0.28018 (11)	0.0387 (6)
N2	0.4788 (2)	0.7971 (2)	0.34566 (10)	0.0327 (5)
N3	0.3369 (3)	0.9916 (3)	0.27154 (12)	0.0465 (7)
N4	0.4223 (3)	0.8771 (3)	0.64121 (12)	0.0518 (7)
N5	0.2940 (3)	0.7189 (3)	0.24240 (11)	0.0437 (6)
N6	0.4761 (2)	0.7898 (2)	0.16064 (10)	0.0321 (5)
N7	0.6464 (3)	0.8943 (3)	0.21930 (11)	0.0381 (6)
N8	0.6683 (3)	0.6192 (3)	−0.11272 (13)	0.0522 (7)
N9	0.9311 (3)	0.6200 (3)	0.04686 (12)	0.0467 (7)
N10	1.1099 (3)	−0.1402 (3)	0.01414 (14)	0.0470 (7)
N11	0.0763 (3)	−0.1208 (3)	0.55590 (14)	0.0511 (7)
N12	−0.0855 (3)	0.6058 (3)	0.55087 (16)	0.0623 (9)
C1	0.6908 (4)	0.5291 (3)	0.24430 (15)	0.0472 (8)
H1	0.6739	0.5408	0.2011	0.057*
C2	0.7870 (4)	0.4236 (4)	0.26798 (17)	0.0572 (10)
H2	0.8322	0.3635	0.2417	0.069*
C3	0.8147 (4)	0.4092 (4)	0.33145 (18)	0.0645 (11)
H3	0.8793	0.3388	0.3489	0.077*
C4	0.7461 (3)	0.4997 (4)	0.36902 (15)	0.0548 (10)
H4	0.7652	0.4922	0.4119	0.066*
C5	0.6487 (3)	0.6016 (3)	0.34224 (13)	0.0368 (7)
C6	0.5626 (3)	0.6988 (3)	0.37951 (13)	0.0339 (6)
C7	0.5660 (3)	0.6887 (3)	0.44499 (13)	0.0354 (7)
H7	0.6278	0.6222	0.4673	0.042*
C8	0.4769 (3)	0.7781 (3)	0.47749 (13)	0.0325 (6)
C9	0.3883 (3)	0.8766 (3)	0.44160 (13)	0.0348 (6)
H9	0.3249	0.9360	0.4616	0.042*
C10	0.3944 (3)	0.8864 (3)	0.37578 (13)	0.0338 (6)
C11	0.3129 (3)	0.9965 (3)	0.33412 (14)	0.0388 (7)
C12	0.2258 (3)	1.1015 (4)	0.35601 (17)	0.0586 (10)
H12	0.2097	1.1030	0.3993	0.070*
C13	0.1628 (4)	1.2041 (5)	0.3131 (2)	0.0748 (13)
H13	0.1053	1.2764	0.3272	0.090*
C14	0.1857 (4)	1.1985 (5)	0.24968 (19)	0.0760 (13)
H14	0.1433	1.2659	0.2199	0.091*
C15	0.2728 (4)	1.0909 (5)	0.23085 (17)	0.0650 (11)
H15	0.2878	1.0870	0.1876	0.078*
C16	0.4781 (3)	0.7684 (3)	0.54771 (13)	0.0333 (6)
C17	0.5365 (3)	0.6531 (3)	0.58521 (14)	0.0449 (8)
H17	0.5751	0.5774	0.5668	0.054*
C18	0.5366 (4)	0.6524 (4)	0.64972 (16)	0.0528 (9)
H18	0.5758	0.5761	0.6755	0.063*
C19	0.4787 (4)	0.7644 (4)	0.67586 (15)	0.0521 (9)
H19	0.4787	0.7621	0.7197	0.063*
C20	0.4238 (3)	0.8768 (3)	0.57879 (14)	0.0412 (7)
H20	0.3855	0.9552	0.5542	0.049*
C21	0.1992 (4)	0.6952 (4)	0.28617 (16)	0.0595 (10)
H21	0.2133	0.7078	0.3278	0.071*
C22	0.0817 (4)	0.6531 (5)	0.27245 (18)	0.0662 (11)
H22	0.0180	0.6368	0.3043	0.079*
C23	0.0595 (4)	0.6354 (5)	0.21107 (19)	0.0643 (11)
H23	−0.0191	0.6064	0.2007	0.077*
C24	0.1557 (3)	0.6613 (4)	0.16508 (16)	0.0478 (8)
H24	0.1421	0.6515	0.1230	0.057*
C25	0.2718 (3)	0.7017 (3)	0.18210 (13)	0.0344 (6)
C26	0.3818 (3)	0.7318 (3)	0.13663 (13)	0.0312 (6)
C27	0.3933 (3)	0.7013 (3)	0.07485 (13)	0.0339 (6)
H27	0.3275	0.6613	0.0587	0.041*
C28	0.5031 (3)	0.7306 (3)	0.03723 (13)	0.0353 (7)
C29	0.5989 (3)	0.7911 (3)	0.06305 (13)	0.0386 (7)
H29	0.6735	0.8120	0.0387	0.046*
C30	0.5832 (3)	0.8204 (3)	0.12494 (13)	0.0336 (6)
C31	0.6784 (3)	0.8833 (3)	0.15784 (13)	0.0352 (7)
C32	0.7917 (3)	0.9271 (4)	0.12923 (15)	0.0494 (8)
H32	0.8125	0.9182	0.0868	0.059*
C33	0.8734 (4)	0.9842 (4)	0.16454 (18)	0.0600 (10)
H33	0.9493	1.0159	0.1460	0.072*
C34	0.8420 (4)	0.9938 (4)	0.22712 (18)	0.0588 (10)
H34	0.8969	1.0308	0.2518	0.071*
C35	0.7277 (4)	0.9480 (4)	0.25305 (16)	0.0506 (9)
H35	0.7065	0.9547	0.2956	0.061*
C36	0.5201 (3)	0.6971 (3)	−0.02901 (13)	0.0369 (7)
C37	0.4111 (4)	0.7106 (4)	−0.06815 (16)	0.0576 (10)
H37	0.3239	0.7406	−0.0534	0.069*
C38	0.4316 (4)	0.6796 (4)	−0.12910 (16)	0.0629 (11)
H38	0.3589	0.6894	−0.1563	0.075*
C39	0.5585 (4)	0.6349 (4)	−0.14877 (15)	0.0538 (9)
H39	0.5709	0.6135	−0.1900	0.065*
C40	0.6475 (3)	0.6510 (3)	−0.05347 (14)	0.0416 (7)
H40	0.7221	0.6416	−0.0275	0.050*
C41	0.9319 (3)	0.5134 (3)	0.07233 (14)	0.0372 (7)
C42	1.1444 (3)	−0.0539 (3)	0.03533 (14)	0.0360 (7)
C43	0.0940 (3)	−0.0174 (4)	0.56498 (16)	0.0481 (8)
C44	−0.1332 (3)	0.5119 (3)	0.54818 (15)	0.0424 (7)
S1	0.93354 (10)	0.35967 (9)	0.10770 (4)	0.0526 (2)
S2	1.19304 (8)	0.07079 (8)	0.06543 (4)	0.04238 (19)
S3	0.12114 (14)	0.13226 (10)	0.57617 (7)	0.0930 (5)
S4	−0.20423 (8)	0.38015 (8)	0.54243 (4)	0.0432 (2)

	U11	U22	U33	U12	U13	U23
Cu1	0.0398 (2)	0.0517 (2)	0.0291 (2)	−0.01341 (18)	0.00678 (15)	−0.01289 (16)
Cu2	0.0598 (3)	0.0413 (2)	0.0492 (3)	−0.0138 (2)	−0.0012 (2)	−0.01005 (19)
Cu3	0.0643 (3)	0.0389 (2)	0.0721 (3)	−0.0152 (2)	−0.0013 (2)	−0.0129 (2)
N1	0.0449 (15)	0.0456 (15)	0.0255 (12)	−0.0068 (12)	0.0033 (11)	−0.0066 (11)
N2	0.0296 (12)	0.0454 (15)	0.0251 (12)	−0.0077 (11)	0.0023 (10)	−0.0105 (10)
N3	0.0477 (16)	0.0646 (19)	0.0276 (13)	−0.0092 (14)	−0.0033 (12)	−0.0070 (13)
N4	0.0620 (19)	0.0620 (19)	0.0304 (14)	0.0020 (15)	−0.0043 (13)	−0.0172 (13)
N5	0.0398 (15)	0.0644 (18)	0.0284 (13)	−0.0121 (13)	0.0027 (11)	−0.0082 (12)
N6	0.0341 (13)	0.0393 (14)	0.0231 (12)	−0.0071 (11)	0.0005 (10)	−0.0036 (10)
N7	0.0422 (14)	0.0476 (15)	0.0273 (12)	−0.0108 (12)	0.0052 (11)	−0.0128 (11)
N8	0.0590 (18)	0.0608 (19)	0.0391 (16)	−0.0101 (15)	0.0085 (14)	−0.0171 (14)
N9	0.0602 (18)	0.0456 (17)	0.0354 (15)	−0.0108 (14)	0.0009 (13)	−0.0079 (13)
N10	0.0471 (16)	0.0381 (15)	0.0561 (18)	−0.0028 (13)	−0.0121 (13)	−0.0085 (13)
N11	0.0586 (18)	0.0425 (17)	0.0542 (18)	−0.0103 (14)	−0.0072 (14)	−0.0089 (14)
N12	0.061 (2)	0.0516 (19)	0.081 (2)	−0.0240 (16)	0.0248 (17)	−0.0224 (17)
C1	0.060 (2)	0.054 (2)	0.0272 (16)	−0.0068 (17)	0.0052 (15)	−0.0116 (15)
C2	0.063 (2)	0.061 (2)	0.042 (2)	0.0087 (19)	0.0159 (17)	−0.0168 (17)
C3	0.054 (2)	0.078 (3)	0.048 (2)	0.023 (2)	0.0072 (17)	−0.0057 (19)
C4	0.047 (2)	0.082 (3)	0.0281 (16)	0.0123 (19)	0.0019 (14)	−0.0086 (17)
C5	0.0351 (16)	0.0483 (18)	0.0268 (15)	−0.0039 (14)	0.0038 (12)	−0.0087 (13)
C6	0.0292 (15)	0.0465 (18)	0.0283 (15)	−0.0093 (13)	0.0024 (12)	−0.0105 (13)
C7	0.0356 (16)	0.0430 (17)	0.0268 (14)	−0.0033 (13)	0.0009 (12)	−0.0064 (13)
C8	0.0345 (15)	0.0404 (16)	0.0255 (14)	−0.0135 (13)	0.0044 (12)	−0.0072 (12)
C9	0.0363 (16)	0.0402 (16)	0.0290 (15)	−0.0070 (13)	0.0064 (12)	−0.0092 (13)
C10	0.0301 (15)	0.0438 (17)	0.0292 (15)	−0.0087 (13)	0.0000 (12)	−0.0071 (13)
C11	0.0330 (16)	0.055 (2)	0.0283 (15)	−0.0072 (14)	0.0004 (12)	−0.0051 (14)
C12	0.044 (2)	0.080 (3)	0.0402 (19)	0.0129 (19)	0.0069 (15)	−0.0007 (18)
C13	0.055 (2)	0.092 (3)	0.061 (3)	0.024 (2)	0.001 (2)	0.008 (2)
C14	0.059 (2)	0.103 (4)	0.050 (2)	0.015 (2)	−0.0102 (19)	0.016 (2)
C15	0.064 (3)	0.096 (3)	0.0342 (19)	−0.014 (2)	−0.0097 (17)	0.000 (2)
C16	0.0346 (16)	0.0427 (17)	0.0242 (14)	−0.0102 (13)	0.0035 (12)	−0.0061 (12)
C17	0.053 (2)	0.0462 (19)	0.0344 (17)	−0.0043 (16)	0.0068 (14)	−0.0074 (14)
C18	0.061 (2)	0.058 (2)	0.0348 (18)	−0.0044 (18)	−0.0021 (16)	0.0047 (16)
C19	0.057 (2)	0.075 (3)	0.0257 (16)	−0.0123 (19)	−0.0019 (15)	−0.0062 (17)
C20	0.0469 (18)	0.0463 (18)	0.0289 (15)	−0.0011 (15)	−0.0035 (13)	−0.0070 (13)
C21	0.055 (2)	0.098 (3)	0.0286 (17)	−0.022 (2)	0.0074 (15)	−0.0111 (18)
C22	0.059 (2)	0.099 (3)	0.045 (2)	−0.029 (2)	0.0206 (18)	−0.009 (2)
C23	0.045 (2)	0.097 (3)	0.060 (2)	−0.032 (2)	0.0101 (18)	−0.020 (2)
C24	0.0423 (18)	0.068 (2)	0.0371 (17)	−0.0172 (17)	0.0024 (14)	−0.0133 (16)
C25	0.0338 (15)	0.0404 (17)	0.0282 (15)	−0.0036 (13)	0.0000 (12)	−0.0053 (12)
C26	0.0297 (14)	0.0363 (16)	0.0261 (14)	−0.0032 (12)	−0.0029 (11)	−0.0015 (12)
C27	0.0355 (16)	0.0396 (16)	0.0273 (14)	−0.0066 (13)	−0.0033 (12)	−0.0055 (12)
C28	0.0386 (16)	0.0414 (17)	0.0254 (14)	−0.0047 (13)	−0.0023 (12)	−0.0046 (12)
C29	0.0408 (17)	0.0500 (19)	0.0274 (15)	−0.0151 (15)	0.0058 (13)	−0.0057 (13)
C30	0.0377 (16)	0.0385 (16)	0.0247 (14)	−0.0092 (13)	0.0016 (12)	−0.0010 (12)
C31	0.0395 (16)	0.0406 (17)	0.0270 (14)	−0.0097 (13)	0.0029 (12)	−0.0069 (12)
C32	0.053 (2)	0.068 (2)	0.0335 (17)	−0.0271 (18)	0.0107 (15)	−0.0125 (16)
C33	0.056 (2)	0.080 (3)	0.056 (2)	−0.037 (2)	0.0086 (18)	−0.019 (2)
C34	0.061 (2)	0.073 (3)	0.054 (2)	−0.027 (2)	−0.0038 (18)	−0.0269 (19)
C35	0.057 (2)	0.064 (2)	0.0358 (18)	−0.0140 (18)	0.0024 (15)	−0.0226 (16)
C36	0.0420 (17)	0.0445 (18)	0.0249 (14)	−0.0087 (14)	0.0001 (12)	−0.0056 (13)
C37	0.045 (2)	0.088 (3)	0.0385 (19)	−0.0023 (19)	−0.0017 (15)	−0.0151 (18)
C38	0.055 (2)	0.104 (3)	0.0302 (18)	−0.007 (2)	−0.0104 (16)	−0.0191 (19)
C39	0.069 (3)	0.066 (2)	0.0287 (17)	−0.012 (2)	0.0001 (16)	−0.0155 (16)
C40	0.0486 (19)	0.0453 (18)	0.0334 (16)	−0.0105 (15)	0.0000 (14)	−0.0104 (14)
C41	0.0356 (16)	0.050 (2)	0.0283 (15)	−0.0066 (14)	−0.0003 (12)	−0.0138 (14)
C42	0.0324 (16)	0.0390 (17)	0.0332 (16)	0.0005 (13)	−0.0025 (12)	0.0003 (13)
C43	0.0436 (19)	0.047 (2)	0.053 (2)	0.0014 (16)	−0.0157 (16)	−0.0117 (16)
C44	0.0419 (18)	0.0455 (19)	0.0380 (17)	−0.0054 (15)	0.0085 (14)	−0.0040 (14)
S1	0.0757 (6)	0.0453 (5)	0.0377 (5)	−0.0136 (4)	0.0099 (4)	−0.0066 (4)
S2	0.0480 (5)	0.0433 (4)	0.0378 (4)	−0.0120 (4)	−0.0076 (3)	−0.0045 (3)
S3	0.1096 (10)	0.0421 (6)	0.1313 (11)	0.0040 (6)	−0.0765 (9)	−0.0253 (6)
S4	0.0447 (5)	0.0419 (4)	0.0439 (5)	−0.0118 (4)	0.0051 (4)	−0.0041 (4)

Cu1—N6	1.960 (2)	C10—C11	1.484 (4)
Cu1—N2	1.994 (2)	C11—C12	1.380 (5)
Cu1—N7	2.141 (3)	C12—C13	1.379 (5)
Cu1—N5	2.156 (3)	C12—H12	0.9300
Cu1—N3	2.217 (3)	C13—C14	1.366 (6)
Cu1—N1	2.261 (3)	C13—H13	0.9300
Cu2—N10i	1.977 (3)	C14—C15	1.373 (6)
Cu2—N9ii	1.997 (3)	C14—H14	0.9300
Cu2—S1	2.3607 (10)	C15—H15	0.9300
Cu2—S2	2.4291 (9)	C16—C20	1.383 (4)
Cu3—N11iii	1.948 (3)	C16—C17	1.387 (4)
Cu3—N12iv	1.983 (3)	C17—C18	1.371 (4)
Cu3—S4	2.4204 (10)	C17—H17	0.9300
Cu3—S3	2.4239 (12)	C18—C19	1.366 (5)
N1—C1	1.333 (4)	C18—H18	0.9300
N1—C5	1.345 (4)	C19—H19	0.9300
N2—C10	1.341 (4)	C20—H20	0.9300
N2—C6	1.343 (4)	C21—C22	1.373 (5)
N3—C15	1.336 (5)	C21—H21	0.9300
N3—C11	1.348 (4)	C22—C23	1.372 (5)
N4—C20	1.327 (4)	C22—H22	0.9300
N4—C19	1.334 (5)	C23—C24	1.378 (5)
N5—C21	1.332 (4)	C23—H23	0.9300
N5—C25	1.348 (4)	C24—C25	1.374 (4)
N6—C26	1.345 (3)	C24—H24	0.9300
N6—C30	1.345 (4)	C25—C26	1.482 (4)
N7—C35	1.334 (4)	C26—C27	1.385 (4)
N7—C31	1.347 (3)	C27—C28	1.385 (4)
N8—C39	1.340 (4)	C27—H27	0.9300
N8—C40	1.341 (4)	C28—C29	1.391 (4)
N9—C41	1.152 (4)	C28—C36	1.488 (4)
N9—Cu2ii	1.997 (3)	C29—C30	1.383 (4)
N10—C42	1.149 (4)	C29—H29	0.9300
N10—Cu2i	1.977 (3)	C30—C31	1.480 (4)
N11—C43	1.142 (4)	C31—C32	1.379 (4)
N11—Cu3iii	1.948 (3)	C32—C33	1.378 (5)
N12—C44	1.151 (4)	C32—H32	0.9300
N12—Cu3iv	1.983 (3)	C33—C34	1.367 (5)
C1—C2	1.373 (5)	C33—H33	0.9300
C1—H1	0.9300	C34—C35	1.377 (5)
C2—C3	1.373 (5)	C34—H34	0.9300
C2—H2	0.9300	C35—H35	0.9300
C3—C4	1.376 (5)	C36—C37	1.375 (4)
C3—H3	0.9300	C36—C40	1.386 (4)
C4—C5	1.379 (4)	C37—C38	1.372 (5)
C4—H4	0.9300	C37—H37	0.9300
C5—C6	1.487 (4)	C38—C39	1.343 (5)
C6—C7	1.384 (4)	C38—H38	0.9300
C7—C8	1.393 (4)	C39—H39	0.9300
C7—H7	0.9300	C40—H40	0.9300
C8—C9	1.389 (4)	C41—S1	1.650 (4)
C8—C16	1.484 (4)	C42—S2	1.648 (3)
C9—C10	1.390 (4)	C43—S3	1.647 (4)
C9—H9	0.9300	C44—S4	1.647 (4)
N6—Cu1—N2	172.70 (10)	C13—C14—C15	118.5 (4)
N6—Cu1—N7	78.36 (9)	C13—C14—H14	120.7
N2—Cu1—N7	103.42 (9)	C15—C14—H14	120.7
N6—Cu1—N5	78.09 (9)	N3—C15—C14	123.2 (4)
N2—Cu1—N5	100.30 (9)	N3—C15—H15	118.4
N7—Cu1—N5	156.29 (9)	C14—C15—H15	118.4
N6—Cu1—N3	110.24 (10)	C20—C16—C17	116.8 (3)
N2—Cu1—N3	76.69 (10)	C20—C16—C8	120.9 (3)
N7—Cu1—N3	97.67 (10)	C17—C16—C8	122.3 (3)
N5—Cu1—N3	87.92 (10)	C18—C17—C16	119.1 (3)
N6—Cu1—N1	96.53 (9)	C18—C17—H17	120.4
N2—Cu1—N1	76.60 (9)	C16—C17—H17	120.4
N7—Cu1—N1	86.65 (10)	C19—C18—C17	119.6 (3)
N5—Cu1—N1	98.71 (10)	C19—C18—H18	120.2
N3—Cu1—N1	153.21 (9)	C17—C18—H18	120.2
N10i—Cu2—N9ii	110.41 (11)	N4—C19—C18	122.9 (3)
N10i—Cu2—S1	117.89 (9)	N4—C19—H19	118.6
N9ii—Cu2—S1	106.52 (8)	C18—C19—H19	118.6
N10i—Cu2—S2	102.63 (8)	N4—C20—C16	124.7 (3)
N9ii—Cu2—S2	116.21 (9)	N4—C20—H20	117.6
S1—Cu2—S2	103.41 (3)	C16—C20—H20	117.6
N11iii—Cu3—N12iv	124.29 (13)	N5—C21—C22	122.8 (3)
N11iii—Cu3—S4	111.33 (9)	N5—C21—H21	118.6
N12iv—Cu3—S4	103.13 (9)	C22—C21—H21	118.6
N11iii—Cu3—S3	106.80 (9)	C23—C22—C21	119.0 (3)
N12iv—Cu3—S3	106.13 (11)	C23—C22—H22	120.5
S4—Cu3—S3	103.22 (5)	C21—C22—H22	120.5
C1—N1—C5	118.3 (3)	C22—C23—C24	118.9 (3)
C1—N1—Cu1	129.8 (2)	C22—C23—H23	120.6
C5—N1—Cu1	111.40 (19)	C24—C23—H23	120.6
C10—N2—C6	119.6 (2)	C25—C24—C23	119.2 (3)
C10—N2—Cu1	119.94 (19)	C25—C24—H24	120.4
C6—N2—Cu1	120.44 (19)	C23—C24—H24	120.4
C15—N3—C11	118.2 (3)	N5—C25—C24	122.1 (3)
C15—N3—Cu1	129.1 (2)	N5—C25—C26	114.2 (3)
C11—N3—Cu1	112.6 (2)	C24—C25—C26	123.7 (3)
C20—N4—C19	116.9 (3)	N6—C26—C27	120.8 (3)
C21—N5—C25	118.0 (3)	N6—C26—C25	114.3 (2)
C21—N5—Cu1	128.6 (2)	C27—C26—C25	124.9 (3)
C25—N5—Cu1	112.98 (19)	C26—C27—C28	119.8 (3)
C26—N6—C30	120.7 (2)	C26—C27—H27	120.1
C26—N6—Cu1	119.71 (18)	C28—C27—H27	120.1
C30—N6—Cu1	119.00 (19)	C27—C28—C29	118.4 (3)
C35—N7—C31	118.6 (3)	C27—C28—C36	121.3 (3)
C35—N7—Cu1	128.2 (2)	C29—C28—C36	120.4 (3)
C31—N7—Cu1	112.99 (19)	C30—C29—C28	120.0 (3)
C39—N8—C40	116.7 (3)	C30—C29—H29	120.0
C41—N9—Cu2ii	154.6 (3)	C28—C29—H29	120.0
C42—N10—Cu2i	159.1 (3)	N6—C30—C29	120.5 (3)
C43—N11—Cu3iii	157.5 (3)	N6—C30—C31	114.5 (2)
C44—N12—Cu3iv	150.6 (3)	C29—C30—C31	125.0 (3)
N1—C1—C2	123.3 (3)	N7—C31—C32	121.7 (3)
N1—C1—H1	118.4	N7—C31—C30	114.4 (2)
C2—C1—H1	118.4	C32—C31—C30	123.9 (3)
C3—C2—C1	118.1 (3)	C33—C32—C31	118.9 (3)
C3—C2—H2	120.9	C33—C32—H32	120.5
C1—C2—H2	120.9	C31—C32—H32	120.5
C2—C3—C4	119.5 (3)	C34—C33—C32	119.4 (3)
C2—C3—H3	120.2	C34—C33—H33	120.3
C4—C3—H3	120.2	C32—C33—H33	120.3
C3—C4—C5	119.1 (3)	C33—C34—C35	119.0 (3)
C3—C4—H4	120.4	C33—C34—H34	120.5
C5—C4—H4	120.4	C35—C34—H34	120.5
N1—C5—C4	121.6 (3)	N7—C35—C34	122.4 (3)
N1—C5—C6	115.1 (3)	N7—C35—H35	118.8
C4—C5—C6	123.3 (3)	C34—C35—H35	118.8
N2—C6—C7	121.5 (3)	C37—C36—C40	117.6 (3)
N2—C6—C5	115.8 (2)	C37—C36—C28	121.7 (3)
C7—C6—C5	122.7 (3)	C40—C36—C28	120.8 (3)
C6—C7—C8	120.0 (3)	C38—C37—C36	119.7 (3)
C6—C7—H7	120.0	C38—C37—H37	120.1
C8—C7—H7	120.0	C36—C37—H37	120.1
C9—C8—C7	117.4 (3)	C39—C38—C37	118.7 (3)
C9—C8—C16	121.6 (3)	C39—C38—H38	120.6
C7—C8—C16	120.9 (3)	C37—C38—H38	120.6
C8—C9—C10	120.0 (3)	N8—C39—C38	124.2 (3)
C8—C9—H9	120.0	N8—C39—H39	117.9
C10—C9—H9	120.0	C38—C39—H39	117.9
N2—C10—C9	121.3 (3)	N8—C40—C36	123.1 (3)
N2—C10—C11	115.5 (2)	N8—C40—H40	118.4
C9—C10—C11	123.2 (3)	C36—C40—H40	118.4
N3—C11—C12	121.3 (3)	N9—C41—S1	179.0 (3)
N3—C11—C10	114.4 (3)	N10—C42—S2	179.6 (3)
C12—C11—C10	124.1 (3)	N11—C43—S3	178.5 (4)
C13—C12—C11	119.4 (3)	N12—C44—S4	178.2 (3)
C13—C12—H12	120.3	C41—S1—Cu2	97.99 (10)
C11—C12—H12	120.3	C42—S2—Cu2	96.50 (10)
C14—C13—C12	119.3 (4)	C43—S3—Cu3	96.18 (12)
C14—C13—H13	120.3	C44—S4—Cu3	97.22 (11)
C12—C13—H13	120.3
N6—Cu1—N1—C1	3.8 (3)	C9—C10—C11—N3	177.4 (3)
N2—Cu1—N1—C1	−178.7 (3)	N2—C10—C11—C12	−176.5 (3)
N7—Cu1—N1—C1	−74.1 (3)	C9—C10—C11—C12	1.7 (5)
N5—Cu1—N1—C1	82.7 (3)	N3—C11—C12—C13	−0.5 (6)
N3—Cu1—N1—C1	−174.5 (3)	C10—C11—C12—C13	175.0 (4)
N6—Cu1—N1—C5	175.5 (2)	C11—C12—C13—C14	1.3 (7)
N2—Cu1—N1—C5	−7.0 (2)	C12—C13—C14—C15	−0.9 (7)
N7—Cu1—N1—C5	97.7 (2)	C11—N3—C15—C14	1.2 (6)
N5—Cu1—N1—C5	−105.6 (2)	Cu1—N3—C15—C14	176.9 (3)
N3—Cu1—N1—C5	−2.7 (3)	C13—C14—C15—N3	−0.4 (7)
N7—Cu1—N2—C10	103.0 (2)	C9—C8—C16—C20	−20.1 (4)
N5—Cu1—N2—C10	−77.2 (2)	C7—C8—C16—C20	159.5 (3)
N3—Cu1—N2—C10	8.2 (2)	C9—C8—C16—C17	161.9 (3)
N1—Cu1—N2—C10	−173.8 (2)	C7—C8—C16—C17	−18.5 (4)
N7—Cu1—N2—C6	−80.0 (2)	C20—C16—C17—C18	0.4 (5)
N5—Cu1—N2—C6	99.8 (2)	C8—C16—C17—C18	178.5 (3)
N3—Cu1—N2—C6	−174.8 (2)	C16—C17—C18—C19	0.4 (5)
N1—Cu1—N2—C6	3.2 (2)	C20—N4—C19—C18	0.2 (5)
N6—Cu1—N3—C15	−6.4 (3)	C17—C18—C19—N4	−0.7 (6)
N2—Cu1—N3—C15	176.0 (3)	C19—N4—C20—C16	0.7 (5)
N7—Cu1—N3—C15	73.9 (3)	C17—C16—C20—N4	−1.0 (5)
N5—Cu1—N3—C15	−82.9 (3)	C8—C16—C20—N4	−179.1 (3)
N1—Cu1—N3—C15	171.8 (3)	C25—N5—C21—C22	0.7 (6)
N6—Cu1—N3—C11	169.5 (2)	Cu1—N5—C21—C22	172.4 (3)
N2—Cu1—N3—C11	−8.1 (2)	N5—C21—C22—C23	−0.6 (7)
N7—Cu1—N3—C11	−110.2 (2)	C21—C22—C23—C24	−0.4 (7)
N5—Cu1—N3—C11	93.0 (2)	C22—C23—C24—C25	1.1 (6)
N1—Cu1—N3—C11	−12.3 (4)	C21—N5—C25—C24	0.1 (5)
N6—Cu1—N5—C21	−174.0 (3)	Cu1—N5—C25—C24	−172.9 (3)
N2—Cu1—N5—C21	13.3 (3)	C21—N5—C25—C26	179.3 (3)
N7—Cu1—N5—C21	−167.2 (3)	Cu1—N5—C25—C26	6.3 (3)
N3—Cu1—N5—C21	−62.8 (3)	C23—C24—C25—N5	−1.0 (5)
N1—Cu1—N5—C21	91.1 (3)	C23—C24—C25—C26	179.9 (3)
N6—Cu1—N5—C25	−1.9 (2)	C30—N6—C26—C27	0.6 (4)
N2—Cu1—N5—C25	−174.7 (2)	Cu1—N6—C26—C27	−170.3 (2)
N7—Cu1—N5—C25	4.8 (4)	C30—N6—C26—C25	178.7 (3)
N3—Cu1—N5—C25	109.3 (2)	Cu1—N6—C26—C25	7.9 (3)
N1—Cu1—N5—C25	−96.8 (2)	N5—C25—C26—N6	−9.2 (4)
N7—Cu1—N6—C26	179.3 (2)	C24—C25—C26—N6	170.0 (3)
N5—Cu1—N6—C26	−3.5 (2)	N5—C25—C26—C27	168.9 (3)
N3—Cu1—N6—C26	−86.7 (2)	C24—C25—C26—C27	−11.9 (5)
N1—Cu1—N6—C26	94.1 (2)	N6—C26—C27—C28	0.0 (4)
N7—Cu1—N6—C30	8.3 (2)	C25—C26—C27—C28	−178.0 (3)
N5—Cu1—N6—C30	−174.5 (2)	C26—C27—C28—C29	−0.3 (4)
N3—Cu1—N6—C30	102.3 (2)	C26—C27—C28—C36	178.9 (3)
N1—Cu1—N6—C30	−76.9 (2)	C27—C28—C29—C30	0.1 (5)
N6—Cu1—N7—C35	178.8 (3)	C36—C28—C29—C30	−179.2 (3)
N2—Cu1—N7—C35	−8.4 (3)	C26—N6—C30—C29	−0.8 (4)
N5—Cu1—N7—C35	172.0 (3)	Cu1—N6—C30—C29	170.1 (2)
N3—Cu1—N7—C35	69.6 (3)	C26—N6—C30—C31	−179.8 (2)
N1—Cu1—N7—C35	−83.8 (3)	Cu1—N6—C30—C31	−8.9 (3)
N6—Cu1—N7—C31	−6.2 (2)	C28—C29—C30—N6	0.5 (5)
N2—Cu1—N7—C31	166.6 (2)	C28—C29—C30—C31	179.4 (3)
N5—Cu1—N7—C31	−12.9 (4)	C35—N7—C31—C32	−0.6 (5)
N3—Cu1—N7—C31	−115.4 (2)	Cu1—N7—C31—C32	−176.1 (3)
N1—Cu1—N7—C31	91.2 (2)	C35—N7—C31—C30	179.0 (3)
C5—N1—C1—C2	2.4 (5)	Cu1—N7—C31—C30	3.5 (3)
Cu1—N1—C1—C2	173.7 (3)	N6—C30—C31—N7	3.0 (4)
N1—C1—C2—C3	−2.0 (6)	C29—C30—C31—N7	−176.0 (3)
C1—C2—C3—C4	0.0 (6)	N6—C30—C31—C32	−177.4 (3)
C2—C3—C4—C5	1.3 (6)	C29—C30—C31—C32	3.6 (5)
C1—N1—C5—C4	−0.9 (5)	N7—C31—C32—C33	−0.4 (5)
Cu1—N1—C5—C4	−173.7 (3)	C30—C31—C32—C33	−180.0 (3)
C1—N1—C5—C6	−177.9 (3)	C31—C32—C33—C34	1.2 (6)
Cu1—N1—C5—C6	9.3 (3)	C32—C33—C34—C35	−1.1 (6)
C3—C4—C5—N1	−0.9 (6)	C31—N7—C35—C34	0.8 (5)
C3—C4—C5—C6	175.7 (3)	Cu1—N7—C35—C34	175.5 (3)
C10—N2—C6—C7	−1.3 (4)	C33—C34—C35—N7	0.1 (6)
Cu1—N2—C6—C7	−178.3 (2)	C27—C28—C36—C37	38.3 (5)
C10—N2—C6—C5	177.8 (3)	C29—C28—C36—C37	−142.4 (3)
Cu1—N2—C6—C5	0.8 (3)	C27—C28—C36—C40	−141.7 (3)
N1—C5—C6—N2	−7.3 (4)	C29—C28—C36—C40	37.5 (4)
C4—C5—C6—N2	175.8 (3)	C40—C36—C37—C38	−0.5 (6)
N1—C5—C6—C7	171.8 (3)	C28—C36—C37—C38	179.4 (3)
C4—C5—C6—C7	−5.1 (5)	C36—C37—C38—C39	0.9 (6)
N2—C6—C7—C8	2.9 (4)	C40—N8—C39—C38	−0.1 (6)
C5—C6—C7—C8	−176.1 (3)	C37—C38—C39—N8	−0.6 (7)
C6—C7—C8—C9	−0.9 (4)	C39—N8—C40—C36	0.5 (5)
C6—C7—C8—C16	179.5 (3)	C37—C36—C40—N8	−0.2 (5)
C7—C8—C9—C10	−2.5 (4)	C28—C36—C40—N8	179.9 (3)
C16—C8—C9—C10	177.0 (3)	N10i—Cu2—S1—C41	−115.26 (14)
C6—N2—C10—C9	−2.3 (4)	N9ii—Cu2—S1—C41	9.39 (14)
Cu1—N2—C10—C9	174.7 (2)	S2—Cu2—S1—C41	132.37 (11)
C6—N2—C10—C11	175.9 (3)	N10i—Cu2—S2—C42	9.39 (14)
Cu1—N2—C10—C11	−7.0 (3)	N9ii—Cu2—S2—C42	−111.19 (14)
C8—C9—C10—N2	4.3 (4)	S1—Cu2—S2—C42	132.50 (11)
C8—C9—C10—C11	−173.8 (3)	N11iii—Cu3—S3—C43	−5.28 (17)
C15—N3—C11—C12	−0.7 (5)	N12iv—Cu3—S3—C43	−139.71 (17)
Cu1—N3—C11—C12	−177.1 (3)	S4—Cu3—S3—C43	112.18 (14)
C15—N3—C11—C10	−176.6 (3)	N11iii—Cu3—S4—C44	−158.24 (15)
Cu1—N3—C11—C10	7.0 (3)	N12iv—Cu3—S4—C44	−22.83 (16)
N2—C10—C11—N3	−0.8 (4)	S3—Cu3—S4—C44	87.53 (12)

D—H···A	D—H	H···A	D···A	D—H···A
C4—H4···S4v	0.93	2.87	3.756 (3)	160
C15—H15···S2vi	0.93	2.83	3.676 (4)	151
C17—H17···S4v	0.93	2.80	3.650 (3)	152
C21—H21···S4iv	0.93	2.79	3.627 (3)	150
C29—H29···S2ii	0.93	2.78	3.654 (3)	156
C35—H35···N4vii	0.93	2.47	3.217 (4)	137

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C4—H4⋯S4i	0.93	2.87	3.756 (3)	160
C15—H15⋯S2ii	0.93	2.83	3.676 (4)	151
C17—H17⋯S4i	0.93	2.80	3.650 (3)	152
C21—H21⋯S4iii	0.93	2.79	3.627 (3)	150
C29—H29⋯S2iv	0.93	2.78	3.654 (3)	156
C35—H35⋯N4v	0.93	2.47	3.217 (4)	137

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .