Poly[diethyl-enetriammonium [aquadi-μ(2)-sulfato-sulfatolanthanum(III)]].

In the title compound, {(C(4)H(16)N(3))[La(SO(4))(3)(H(2)O)]}(n), the La atom adopts an irregular LaO(9) coordination geometry, including one bonded water mol-ecule. The three sulfate groups adopt both monodentate and bidentate coordination to the metal ions. Two of the sulfate groups serve as bridges in the (100) and (010) directions, yielding infinite sheets, whereas the third is pendant to one La(3+) cation. The protonated organic species inter-acts with the layers by way of N-H⋯O hydrogen bonds, and O-H⋯O hydrogen bonds involving aqua ligands also occur.

Related literature

For related lanthanide sulfate structures, see: Bataille & Louër (2004 ▶); Dan et al. (2004 ▶); Liu et al. (2005 ▶); Rao et al. (2006 ▶); Wickleder (2002 ▶); Xing et al. (2003 ▶).

Experimental

Crystal data

(C4H16N3)[La(SO4)3(H2O)]

M = 551.33

Monoclinic,

a = 6.7128 (13) Å

b = 10.442 (2) Å

c = 11.103 (2) Å

β = 93.94 (3)°

V = 776.4 (3) Å3

Z = 2

Mo Kα radiation

μ = 3.23 mm−1

T = 293 K

0.45 × 0.31 × 0.06 mm

Data collection

Rigaku R-AXIS RAPID diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.317, T max = 0.830

7574 measured reflections

3429 independent reflections

3312 reflections with I > 2σ(I)

R int = 0.028

Refinement

R[F 2 > 2σ(F 2)] = 0.021

wR(F 2) = 0.049

S = 1.17

3429 reflections

225 parameters

4 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.35 e Å−3

Δρmin = −0.61 e Å−3

Absolute structure: Flack (1983 ▶), 1552 Friedel pairs

Flack parameter: −0.098 (11)

Data collection: PROCESS-AUTO (Rigaku, 1998 ▶); cell refinement: PROCESS-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 2000 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809022272/hb2997sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809022272/hb2997Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

(C4H16N3)[La(SO4)3(H2O)]	F(000) = 544
Mr = 551.33	Dx = 2.358 Mg m−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 2000 reflections
a = 6.7128 (13) Å	θ = 3.0–27.5°
b = 10.442 (2) Å	µ = 3.23 mm−1
c = 11.103 (2) Å	T = 293 K
β = 93.94 (3)°	Rod, colourless
V = 776.4 (3) Å3	0.45 × 0.31 × 0.06 mm
Z = 2

Rigaku R-AXIS RAPID diffractometer	3429 independent reflections
Radiation source: fine-focus sealed tube	3312 reflections with I > 2σ(I)
graphite	Rint = 0.028
Detector resolution: 10.00 pixels mm-1	θmax = 27.5°, θmin = 3.0°
ω scans	h = −8→7
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	k = −13→13
Tmin = 0.317, Tmax = 0.830	l = −14→14
7574 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.021	H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.049	w = 1/[σ2(Fo2) + (0.0089P)2] where P = (Fo2 + 2Fc2)/3
S = 1.17	(Δ/σ)max = 0.006
3429 reflections	Δρmax = 0.35 e Å−3
225 parameters	Δρmin = −0.60 e Å−3
4 restraints	Absolute structure: Flack (1983), 1552 Friedel pairs
Primary atom site location: structure-invariant direct methods	Flack parameter: −0.098 (11)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
La1	0.53138 (2)	0.36394 (2)	0.180431 (16)	0.00943 (6)
S1	−0.00721 (14)	0.31013 (9)	0.24266 (10)	0.0156 (2)
S2	0.42405 (15)	0.58541 (9)	0.36244 (10)	0.0176 (2)
S3	0.42773 (14)	0.02938 (9)	0.06143 (10)	0.0167 (2)
O1	0.4541 (4)	0.1705 (3)	0.0573 (3)	0.0236 (7)
O2	0.6123 (4)	−0.0363 (3)	0.0235 (3)	0.0234 (7)
O3	0.4904 (4)	0.4531 (3)	0.3940 (3)	0.0241 (7)
O4	0.3862 (5)	−0.0119 (3)	0.1833 (3)	0.0287 (7)
O5	−0.1328 (4)	0.4210 (3)	0.2793 (3)	0.0226 (6)
O6	0.4374 (4)	0.5935 (3)	0.2274 (3)	0.0220 (7)
O7	0.1623 (3)	0.3571 (4)	0.1758 (2)	0.0233 (6)
O8	−0.1464 (4)	0.2337 (3)	0.1610 (3)	0.0217 (7)
O9	0.2667 (4)	−0.0115 (3)	−0.0290 (3)	0.0226 (7)
O10	0.0654 (5)	0.2351 (3)	0.3473 (3)	0.0333 (8)
O11	0.5666 (5)	0.6790 (3)	0.4210 (3)	0.0285 (7)
O12	0.2219 (4)	0.6107 (3)	0.3958 (3)	0.0320 (8)
O1W	0.5151 (5)	0.1920 (3)	0.3288 (3)	0.0242 (7)
H1F	0.478 (6)	0.119 (3)	0.303 (4)	0.029*
H1G	0.554 (7)	0.188 (4)	0.403 (2)	0.029*
N1	1.0903 (5)	0.6434 (3)	0.0681 (4)	0.0267 (8)
H1A	1.1667	0.6620	0.0081	0.032*
H1B	0.9960	0.5881	0.0422	0.032*
H1C	1.1651	0.6089	0.1290	0.032*
N2	0.7510 (5)	0.8376 (3)	0.2587 (4)	0.0270 (10)
H2A	0.6714	0.8687	0.1970	0.032*
H2B	0.6714	0.8081	0.3145	0.032*
N3	1.0998 (5)	1.0100 (3)	0.4815 (4)	0.0265 (9)
H3A	1.1893	0.9822	0.5384	0.032*
H3B	0.9983	1.0464	0.5159	0.032*
H3C	1.1567	1.0671	0.4352	0.032*
C1	0.9941 (7)	0.7643 (4)	0.1105 (5)	0.0280 (10)
H1D	0.9115	0.8028	0.0451	0.034*
H1E	1.0952	0.8257	0.1387	0.034*
C2	0.8674 (6)	0.7262 (4)	0.2127 (4)	0.0221 (9)
H2C	0.7749	0.6595	0.1847	0.027*
H2D	0.9532	0.6915	0.2786	0.027*
C3	0.8728 (7)	0.9459 (4)	0.3132 (5)	0.0293 (11)
H3D	0.9384	0.9900	0.2500	0.035*
H3E	0.7849	1.0066	0.3492	0.035*
C4	1.0257 (7)	0.9011 (4)	0.4067 (5)	0.0339 (12)
H4A	0.9679	0.8373	0.4573	0.041*
H4B	1.1359	0.8618	0.3682	0.041*

	U11	U22	U33	U12	U13	U23
La1	0.00845 (8)	0.00909 (8)	0.01059 (9)	−0.00017 (11)	−0.00037 (6)	−0.00017 (12)
S1	0.0125 (4)	0.0176 (4)	0.0165 (5)	−0.0001 (4)	−0.0004 (4)	0.0015 (4)
S2	0.0180 (5)	0.0177 (5)	0.0169 (5)	−0.0002 (4)	0.0002 (4)	−0.0024 (4)
S3	0.0182 (5)	0.0156 (4)	0.0161 (5)	−0.0013 (4)	0.0002 (4)	−0.0022 (4)
O1	0.0310 (17)	0.0163 (14)	0.0238 (18)	−0.0007 (13)	0.0034 (14)	−0.0025 (12)
O2	0.0223 (16)	0.0224 (14)	0.0253 (18)	0.0088 (12)	0.0006 (13)	−0.0037 (13)
O3	0.0279 (17)	0.0219 (14)	0.0226 (18)	0.0050 (13)	0.0023 (14)	0.0011 (13)
O4	0.0431 (19)	0.0273 (16)	0.0161 (18)	−0.0080 (15)	0.0038 (14)	−0.0004 (13)
O5	0.0148 (14)	0.0283 (14)	0.0247 (17)	0.0027 (13)	0.0012 (13)	−0.0069 (13)
O6	0.0255 (16)	0.0225 (14)	0.0175 (17)	0.0009 (13)	−0.0028 (13)	−0.0019 (12)
O7	0.0146 (11)	0.0317 (14)	0.0243 (14)	0.0013 (18)	0.0053 (10)	0.010 (2)
O8	0.0191 (14)	0.0188 (14)	0.0268 (18)	−0.0017 (12)	−0.0004 (13)	−0.0053 (12)
O9	0.0210 (15)	0.0258 (15)	0.0204 (18)	0.0016 (13)	−0.0035 (12)	−0.0051 (13)
O10	0.0318 (18)	0.0370 (18)	0.030 (2)	0.0032 (16)	−0.0058 (15)	0.0145 (15)
O11	0.0305 (17)	0.0313 (16)	0.0228 (18)	−0.0111 (14)	−0.0037 (14)	−0.0056 (14)
O12	0.0224 (15)	0.0356 (17)	0.039 (2)	0.0066 (14)	0.0108 (15)	−0.0046 (16)
O1W	0.0368 (17)	0.0208 (15)	0.0153 (17)	−0.0009 (15)	0.0034 (14)	0.0021 (13)
N1	0.0235 (19)	0.033 (2)	0.024 (2)	−0.0013 (17)	0.0031 (16)	0.0009 (17)
N2	0.0222 (16)	0.027 (3)	0.031 (2)	0.0017 (15)	−0.0033 (15)	−0.0011 (16)
N3	0.030 (2)	0.0243 (18)	0.024 (2)	−0.0041 (17)	−0.0034 (17)	0.0005 (16)
C1	0.028 (2)	0.026 (2)	0.030 (3)	−0.0006 (19)	0.000 (2)	0.004 (2)
C2	0.023 (2)	0.020 (2)	0.024 (2)	0.0011 (17)	0.0016 (18)	0.0003 (18)
C3	0.035 (3)	0.0159 (19)	0.036 (3)	−0.0007 (19)	−0.008 (2)	−0.0034 (19)
C4	0.050 (3)	0.022 (2)	0.028 (3)	0.007 (2)	−0.011 (2)	−0.0010 (18)

La1—O1W	2.445 (3)	N1—C1	1.508 (6)
La1—O1	2.474 (3)	N1—H1A	0.8900
La1—O7	2.475 (2)	N1—H1B	0.8900
La1—O5i	2.510 (3)	N1—H1C	0.8900
La1—O6	2.542 (3)	N2—C3	1.498 (5)
La1—O8i	2.577 (3)	N2—C2	1.510 (5)
La1—O3	2.580 (3)	N2—H2A	0.9000
La1—O9ii	2.583 (3)	N2—H2B	0.9000
La1—O2ii	2.615 (3)	N3—C4	1.474 (5)
S1—O10	1.457 (3)	N3—H3A	0.8900
S1—O7	1.484 (3)	N3—H3B	0.8900
S1—O8	1.488 (3)	N3—H3C	0.8900
S1—O5	1.504 (3)	C1—C2	1.517 (6)
S2—O12	1.455 (3)	C1—H1D	0.9700
S2—O11	1.486 (3)	C1—H1E	0.9700
S2—O3	1.486 (3)	C2—H2C	0.9700
S2—O6	1.511 (3)	C2—H2D	0.9700
S3—O4	1.465 (3)	C3—C4	1.485 (6)
S3—O1	1.485 (3)	C3—H3D	0.9700
S3—O9	1.486 (3)	C3—H3E	0.9700
S3—O2	1.501 (3)	C4—H4A	0.9700
O1W—H1F	0.841 (19)	C4—H4B	0.9700
O1W—H1G	0.850 (18)
O1W—La1—O1	75.84 (11)	S3—O1—La1	144.5 (2)
O1W—La1—O7	84.36 (11)	S3—O2—La1iii	99.36 (14)
O1—La1—O7	78.07 (11)	S2—O3—La1	99.67 (16)
O1W—La1—O5i	87.70 (11)	S1—O5—La1iv	101.69 (14)
O1—La1—O5i	125.67 (9)	S2—O6—La1	100.57 (14)
O7—La1—O5i	152.06 (10)	S1—O7—La1	143.12 (17)
O1W—La1—O6	122.10 (10)	S1—O8—La1iv	99.29 (14)
O1—La1—O6	146.90 (10)	S3—O9—La1iii	101.23 (14)
O7—La1—O6	76.67 (11)	La1—O1W—H1F	117 (3)
O5i—La1—O6	85.11 (9)	La1—O1W—H1G	132 (3)
O1W—La1—O8i	75.26 (11)	H1F—O1W—H1G	110 (3)
O1—La1—O8i	70.62 (9)	C1—N1—H1A	109.5
O7—La1—O8i	145.87 (10)	C1—N1—H1B	109.5
O5i—La1—O8i	55.10 (9)	H1A—N1—H1B	109.5
O6—La1—O8i	137.43 (9)	C1—N1—H1C	109.5
O1W—La1—O3	68.48 (10)	H1A—N1—H1C	109.5
O1—La1—O3	140.45 (10)	H1B—N1—H1C	109.5
O7—La1—O3	81.93 (10)	C3—N2—C2	115.9 (3)
O5i—La1—O3	70.24 (10)	C3—N2—H2A	108.3
O6—La1—O3	55.07 (9)	C2—N2—H2A	108.3
O8i—La1—O3	114.26 (10)	C3—N2—H2B	108.3
O1W—La1—O9ii	149.15 (10)	C2—N2—H2B	108.3
O1—La1—O9ii	98.68 (10)	H2A—N2—H2B	107.4
O7—La1—O9ii	124.77 (10)	C4—N3—H3A	109.5
O5i—La1—O9ii	70.70 (10)	C4—N3—H3B	109.5
O6—La1—O9ii	78.89 (10)	H3A—N3—H3B	109.5
O8i—La1—O9ii	74.33 (10)	C4—N3—H3C	109.5
O3—La1—O9ii	120.71 (10)	H3A—N3—H3C	109.5
O1W—La1—O2ii	147.69 (10)	H3B—N3—H3C	109.5
O1—La1—O2ii	78.24 (10)	N1—C1—C2	106.8 (4)
O7—La1—O2ii	71.61 (9)	N1—C1—H1D	110.4
O5i—La1—O2ii	123.41 (9)	C2—C1—H1D	110.4
O6—La1—O2ii	73.73 (10)	N1—C1—H1E	110.4
O8i—La1—O2ii	113.54 (10)	C2—C1—H1E	110.4
O3—La1—O2ii	126.54 (10)	H1D—C1—H1E	108.6
O9ii—La1—O2ii	54.16 (9)	N2—C2—C1	112.4 (3)
O10—S1—O7	110.52 (18)	N2—C2—H2C	109.1
O10—S1—O8	111.06 (19)	C1—C2—H2C	109.1
O7—S1—O8	110.06 (18)	N2—C2—H2D	109.1
O10—S1—O5	111.2 (2)	C1—C2—H2D	109.1
O7—S1—O5	110.1 (2)	H2C—C2—H2D	107.9
O8—S1—O5	103.72 (16)	C4—C3—N2	112.1 (3)
O12—S2—O11	110.7 (2)	C4—C3—H3D	109.2
O12—S2—O3	112.23 (19)	N2—C3—H3D	109.2
O11—S2—O3	109.55 (19)	C4—C3—H3E	109.2
O12—S2—O6	111.26 (19)	N2—C3—H3E	109.2
O11—S2—O6	108.49 (18)	H3D—C3—H3E	107.9
O3—S2—O6	104.40 (17)	N3—C4—C3	109.9 (4)
O4—S3—O1	110.57 (18)	N3—C4—H4A	109.7
O4—S3—O9	111.30 (18)	C3—C4—H4A	109.7
O1—S3—O9	110.28 (18)	N3—C4—H4B	109.7
O4—S3—O2	109.77 (19)	C3—C4—H4B	109.7
O1—S3—O2	109.99 (18)	H4A—C4—H4B	108.2
O9—S3—O2	104.78 (17)
O4—S3—O1—La1	20.4 (4)	O11—S2—O6—La1	121.73 (16)
O4—S3—O1—La1	20.4 (4)	O3—S2—O6—La1	4.98 (17)
O9—S3—O1—La1	144.0 (3)	O1W—La1—O6—S2	11.55 (19)
O2—S3—O1—La1	−101.0 (3)	O1—La1—O6—S2	127.22 (17)
La1iii—S3—O1—La1	−159.2 (2)	O7—La1—O6—S2	86.02 (15)
O1W—La1—O1—S3	−4.8 (3)	O5i—La1—O6—S2	−72.65 (15)
O7—La1—O1—S3	−91.9 (3)	O8i—La1—O6—S2	−92.26 (18)
O5i—La1—O1—S3	71.8 (3)	O3—La1—O6—S2	−3.38 (12)
O6—La1—O1—S3	−132.8 (3)	O9ii—La1—O6—S2	−143.91 (15)
O8i—La1—O1—S3	74.3 (3)	O2ii—La1—O6—S2	160.44 (16)
O3—La1—O1—S3	−30.7 (4)	S1i—La1—O6—S2	−79.21 (14)
O9ii—La1—O1—S3	144.2 (3)	S3ii—La1—O6—S2	−170.95 (15)
O2ii—La1—O1—S3	−165.3 (3)	O10—S1—O7—La1	−4.0 (4)
S1i—La1—O1—S3	71.8 (3)	O8—S1—O7—La1	−127.0 (3)
S2—La1—O1—S3	−76.5 (4)	O5—S1—O7—La1	119.3 (4)
S3ii—La1—O1—S3	169.9 (3)	La1iv—S1—O7—La1	174.6 (2)
O4—S3—O2—La1iii	125.92 (15)	O1W—La1—O7—S1	16.6 (4)
O4—S3—O2—La1iii	125.92 (15)	O1—La1—O7—S1	93.2 (4)
O1—S3—O2—La1iii	−112.21 (16)	O5i—La1—O7—S1	−57.7 (5)
O9—S3—O2—La1iii	6.31 (17)	O6—La1—O7—S1	−108.3 (4)
O12—S2—O3—La1	115.73 (19)	O8i—La1—O7—S1	69.6 (4)
O11—S2—O3—La1	−120.90 (17)	O3—La1—O7—S1	−52.4 (4)
O11—S2—O3—La1	−120.90 (17)	O9ii—La1—O7—S1	−174.4 (3)
O6—S2—O3—La1	−4.89 (17)	O2ii—La1—O7—S1	174.7 (4)
O1W—La1—O3—S2	−163.00 (19)	S1i—La1—O7—S1	15.3 (6)
O1—La1—O3—S2	−135.94 (15)	S2—La1—O7—S1	−79.7 (4)
O7—La1—O3—S2	−75.91 (16)	S3ii—La1—O7—S1	−178.3 (4)
O5i—La1—O3—S2	101.50 (16)	O10—S1—O8—La1iv	115.43 (17)
O6—La1—O3—S2	3.43 (12)	O7—S1—O8—La1iv	−121.86 (17)
O8i—La1—O3—S2	135.54 (13)	O5—S1—O8—La1iv	−4.05 (18)
O9ii—La1—O3—S2	49.94 (18)	O4—S3—O9—La1iii	−125.00 (16)
O2ii—La1—O3—S2	−16.0 (2)	O4—S3—O9—La1iii	−125.00 (16)
S1i—La1—O3—S2	119.34 (14)	O1—S3—O9—La1iii	111.89 (16)
S3ii—La1—O3—S2	18.23 (18)	O2—S3—O9—La1iii	−6.43 (18)
O1—S3—O4—O4	0.00 (18)	O12—S2—O11—O11	0.0 (3)
O9—S3—O4—O4	0.00 (10)	O3—S2—O11—O11	0.0 (3)
O2—S3—O4—O4	0.00 (13)	O6—S2—O11—O11	0.0 (4)
La1iii—S3—O4—O4	0.00 (5)	La1—S2—O11—O11	0.0 (4)
O10—S1—O5—La1iv	−115.22 (18)	C3—N2—C2—C1	−62.8 (5)
O7—S1—O5—La1iv	121.94 (14)	N1—C1—C2—N2	−176.3 (3)
O8—S1—O5—La1iv	4.19 (18)	C2—N2—C3—C4	−51.4 (6)
O12—S2—O6—La1	−116.29 (17)	N2—C3—C4—N3	−163.4 (4)
O11—S2—O6—La1	121.73 (16)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1F···O4	0.84 (2)	1.98 (2)	2.775 (5)	157 (4)
O1W—H1G···O11v	0.85 (2)	2.17 (4)	2.872 (5)	140 (4)
N1—H1A···O8ii	0.89	2.02	2.762 (5)	141
N1—H1B···O9ii	0.89	2.04	2.900 (5)	161
N1—H1C···O6i	0.89	2.07	2.874 (5)	150
N2—H2B···O11	0.90	1.96	2.798 (5)	155
N2—H2A···O2vi	0.90	2.18	3.015 (5)	154
N2—H2A···O4vi	0.90	2.28	2.981 (5)	134
N3—H3A···O5vii	0.89	2.18	2.809 (5)	127
N3—H3A···O3viii	0.89	2.25	3.051 (5)	150
N3—H3B···O12vii	0.89	1.95	2.834 (5)	174
N3—H3C···O10ix	0.89	2.08	2.784 (5)	135

Table 1

Selected bond lengths (Å)

La1—O1W	2.445 (3)
La1—O1	2.474 (3)
La1—O7	2.475 (2)
La1—O5i	2.510 (3)
La1—O6	2.542 (3)
La1—O8i	2.577 (3)
La1—O3	2.580 (3)
La1—O9ii	2.583 (3)
La1—O2ii	2.615 (3)

Symmetry codes: (i) ; (ii) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1F⋯O4	0.841 (19)	1.98 (2)	2.775 (5)	157 (4)
O1W—H1G⋯O11iii	0.850 (18)	2.17 (4)	2.872 (5)	140 (4)
N1—H1A⋯O8ii	0.89	2.02	2.762 (5)	141
N1—H1B⋯O9ii	0.89	2.04	2.900 (5)	161
N1—H1C⋯O6i	0.89	2.07	2.874 (5)	150
N2—H2B⋯O11	0.90	1.96	2.798 (5)	155
N2—H2A⋯O2iv	0.90	2.18	3.015 (5)	154
N2—H2A⋯O4iv	0.90	2.28	2.981 (5)	134
N3—H3A⋯O5v	0.89	2.18	2.809 (5)	127
N3—H3A⋯O3vi	0.89	2.25	3.051 (5)	150
N3—H3B⋯O12v	0.89	1.95	2.834 (5)	174
N3—H3C⋯O10vii	0.89	2.08	2.784 (5)	135

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) ; (vii) .