Literature DB >> 21582390

Bis(2,2':6',2''-terpyridine)cobalt(II) bis-(tricyano-methanide).

Jun Luo, Xin-Rong Zhang, Li-Juan Qiu, Bao-Shu Liu, Zhi-Yan Zhang.   

Abstract

The title complex, [Co(C(15)H(11)N(3))(2)](n class="Chemical">C(4)N(3))(2), is built up from discrete [Co(terpy)(2)](2+) cations (terpy is 2,2':6',2''-terpyridine) and [C(CN)(3)](-) anions. In the cation, the Co(II) atom is coordinated by two terpy mol-ecules, giving a distorted octa-hedral geometry. The tricyano-methanide anions are not directly coordinated to the Co(II) atom, but some weak C-H⋯N hydrogen bonds involving the terminal N atoms of the tricyaomethanide ions and the terpyridine H atoms link anions and cations building a three-dimensional network.

Entities:  

Year:  2009        PMID： 21582390      PMCID： PMC2968836          DOI： 10.1107/S160053680901071X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For the structural characteristics and magnetic properties of tricyano­methanide coordination polymers, see: Batten et al. (1998 ▶, 2000 ▶); Batten & Murray (2003 ▶); Miller & Manson (2001 ▶); Manson et al. (1998 ▶, 2000 ▶); Manson & Schlueter (2004 ▶); Feyerherm et al. (2003 ▶, 2004 ▶); Abrahams et al. (2003 ▶); Hoshino et al. (1999 ▶); Yuste et al. (2008 ▶); Luo et al. (2008 ▶). For Co—N(n class="Chemical">terpy) distances in other cobalt–terpyridine complexes, see: Indumathy et al. (2007 ▶). For bond distances and bond angles in other tricyano­methanide complexes, see: Hoshino et al. (1999 ▶); Batten et al. (1999 ▶). For weak C—H⋯N inter­actions, see: Nardelli (1995 ▶).

Experimental

Crystal data

[Co(C15H11N3)2](C4N3)2 M = 705.61 Monoclinic, a = 9.042 (3) Å b = 9.167 (3) Å c = 40.340 (14) Å β = 91.163 (6)° V = 3343 (2) Å3 Z = 4 Mo Kα radiation μ = 0.56 mm−1 T = 293 K 0.20 × 0.15 × 0.10 mm

Data collection

Bruker SMART APEX CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.896, T max = 0.946 13582 measured reflections 5880 independent reflections 3009 reflections with I > 2σ(I) R int = 0.093

Refinement

R[F 2 > 2σ(F 2)] = 0.061 wR(F 2) = 0.106 S = 0.96 5880 reflections 460 parameters H-atom parameters constrained Δρmax = 0.27 e Å−3 Δρmin = −0.20 e Å−3 Data collection: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: PLATON (Spek, 2009 ▶); software used to prepare material for publication: SHELXL97 Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053680901071X/dn2438sup1.cif Structure factors: contains datablocks I. DOI: 10.1107/S160053680901071X/dn2438Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report
[Co(C15H11N3)2](C4N3)2F(000) = 1444
Mr = 705.61Dx = 1.402 Mg m−3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 925 reflections
a = 9.042 (3) Åθ = 2.3–17.9°
b = 9.167 (3) ŵ = 0.56 mm−1
c = 40.340 (14) ÅT = 293 K
β = 91.163 (6)°Block, dark-brown
V = 3343 (2) Å30.20 × 0.15 × 0.10 mm
Z = 4
Bruker SMART APEX CCD area-detector diffractometer5880 independent reflections
Radiation source: fine-focus sealed tube3009 reflections with I > 2σ(I)
graphiteRint = 0.093
φ and ω scansθmax = 25.0°, θmin = 1.0°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)h = −10→10
Tmin = 0.896, Tmax = 0.946k = −10→7
13582 measured reflectionsl = −41→47
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.061Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.106H-atom parameters constrained
S = 0.96w = 1/[σ2(Fo2) + (0.0281P)2] where P = (Fo2 + 2Fc2)/3
5880 reflections(Δ/σ)max = 0.001
460 parametersΔρmax = 0.27 e Å−3
0 restraintsΔρmin = −0.20 e Å−3
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/Ueq
Co10.50103 (6)0.82076 (6)0.873406 (12)0.04411 (18)
N10.5876 (3)1.0222 (4)0.87728 (8)0.0463 (9)
N20.4973 (3)0.8719 (4)0.82884 (7)0.0448 (9)
N30.4127 (3)0.6366 (3)0.85446 (8)0.0442 (9)
N40.2901 (4)0.9020 (3)0.88713 (8)0.0481 (9)
N50.4994 (4)0.7677 (3)0.91878 (7)0.0390 (8)
N60.7138 (3)0.7206 (3)0.87885 (8)0.0463 (9)
N70.7089 (6)1.5090 (7)0.78492 (11)0.125 (2)
N80.5165 (6)1.6925 (6)0.69117 (11)0.1123 (18)
N90.4373 (7)1.2455 (7)0.71648 (15)0.143 (2)
N10−0.1268 (5)0.3628 (5)0.98032 (11)0.0990 (16)
N110.3099 (6)0.3292 (7)0.93731 (12)0.134 (2)
N120.1971 (5)0.0363 (5)1.01956 (9)0.0799 (13)
C10.6312 (5)1.0933 (5)0.90478 (11)0.0591 (12)
H10.62091.04780.92520.071*
C20.6907 (5)1.2314 (6)0.90391 (13)0.0734 (15)
H20.72001.27830.92340.088*
C30.7061 (5)1.2981 (5)0.87393 (15)0.0823 (16)
H30.74641.39130.87280.099*
C40.6618 (5)1.2270 (5)0.84551 (12)0.0665 (14)
H40.67211.27130.82490.080*
C50.6023 (4)1.0899 (5)0.84780 (11)0.0495 (11)
C60.5480 (4)1.0029 (5)0.81958 (10)0.0502 (11)
C70.5449 (5)1.0430 (5)0.78661 (11)0.0687 (14)
H70.58231.13270.78010.082*
C80.4850 (5)0.9473 (6)0.76338 (11)0.0746 (15)
H80.48130.97300.74110.090*
C90.4313 (5)0.8148 (6)0.77329 (10)0.0677 (13)
H90.38990.75050.75790.081*
C100.4397 (4)0.7784 (5)0.80649 (10)0.0506 (12)
C110.3901 (4)0.6421 (5)0.82150 (10)0.0483 (11)
C120.3275 (5)0.5262 (5)0.80430 (11)0.0651 (13)
H120.31310.53160.78140.078*
C130.2866 (5)0.4027 (5)0.82127 (13)0.0782 (15)
H130.24440.32400.81000.094*
C140.3089 (5)0.3974 (5)0.85490 (13)0.0686 (14)
H140.28150.31570.86700.082*
C150.3725 (4)0.5155 (5)0.87038 (11)0.0553 (12)
H150.38870.51110.89320.066*
C160.1884 (5)0.9738 (5)0.86914 (10)0.0570 (12)
H160.20670.99200.84690.068*
C170.0580 (5)1.0218 (5)0.88197 (11)0.0650 (13)
H17−0.00961.07340.86880.078*
C180.0289 (5)0.9927 (5)0.91433 (12)0.0665 (14)
H18−0.05971.02260.92350.080*
C190.1318 (5)0.9189 (5)0.93328 (10)0.0569 (12)
H190.11400.89880.95540.068*
C200.2617 (5)0.8748 (4)0.91917 (10)0.0447 (11)
C210.3810 (5)0.7973 (4)0.93730 (10)0.0441 (10)
C220.3758 (5)0.7565 (5)0.97017 (10)0.0575 (12)
H220.29490.78050.98290.069*
C230.4929 (6)0.6797 (5)0.98366 (10)0.0651 (13)
H230.49130.65131.00580.078*
C240.6118 (5)0.6446 (4)0.96480 (10)0.0521 (12)
H240.68890.58840.97350.063*
C250.6151 (4)0.6943 (4)0.93254 (10)0.0436 (10)
C260.7392 (4)0.6738 (4)0.91018 (10)0.0434 (10)
C270.8725 (5)0.6127 (4)0.91970 (11)0.0582 (12)
H270.88940.58400.94160.070*
C280.9802 (5)0.5945 (5)0.89658 (13)0.0671 (14)
H281.07000.55160.90260.081*
C290.9545 (5)0.6399 (5)0.86442 (12)0.0709 (14)
H291.02570.62820.84830.085*
C300.8198 (5)0.7032 (5)0.85694 (10)0.0578 (12)
H300.80220.73550.83540.069*
C310.6441 (6)1.4961 (6)0.76014 (16)0.0919 (18)
C320.5614 (6)1.4782 (7)0.73069 (14)0.0798 (16)
C330.5377 (6)1.5952 (8)0.70963 (15)0.0877 (18)
C340.4954 (7)1.3530 (9)0.72316 (15)0.095 (2)
C35−0.0143 (7)0.3069 (6)0.98015 (11)0.0685 (14)
C360.1248 (6)0.2411 (5)0.97914 (11)0.0605 (13)
C370.2264 (7)0.2885 (6)0.95613 (13)0.0851 (17)
C380.1641 (5)0.1271 (6)1.00156 (12)0.0623 (14)
U11U22U33U12U13U23
Co10.0432 (4)0.0457 (3)0.0434 (3)0.0000 (3)0.0007 (2)0.0009 (3)
N10.043 (2)0.051 (2)0.044 (2)0.0019 (18)−0.0023 (17)0.0019 (19)
N20.043 (2)0.049 (2)0.043 (2)−0.0044 (18)−0.0004 (17)−0.0033 (18)
N30.040 (2)0.049 (2)0.044 (2)−0.0012 (17)0.0030 (17)−0.0019 (18)
N40.047 (2)0.052 (2)0.045 (2)0.0024 (18)0.0013 (18)−0.0024 (18)
N50.038 (2)0.038 (2)0.041 (2)−0.0004 (17)0.0005 (17)0.0006 (16)
N60.043 (2)0.047 (2)0.049 (2)−0.0055 (17)0.0023 (18)0.0000 (18)
N70.109 (5)0.181 (6)0.084 (4)0.013 (4)−0.007 (3)0.006 (4)
N80.137 (5)0.114 (5)0.087 (4)0.011 (4)0.004 (3)−0.002 (3)
N90.137 (6)0.116 (5)0.176 (6)−0.024 (4)−0.028 (4)0.016 (4)
N100.082 (4)0.086 (4)0.129 (4)0.016 (3)0.010 (3)0.036 (3)
N110.106 (4)0.194 (6)0.104 (4)−0.018 (4)0.023 (3)0.068 (4)
N120.090 (4)0.076 (3)0.073 (3)0.004 (3)0.001 (2)0.013 (2)
C10.054 (3)0.063 (3)0.060 (3)0.004 (3)−0.008 (2)0.003 (3)
C20.062 (4)0.062 (4)0.097 (4)−0.002 (3)−0.010 (3)−0.019 (3)
C30.073 (4)0.050 (3)0.123 (5)−0.010 (3)−0.008 (3)−0.008 (4)
C40.062 (4)0.053 (3)0.084 (4)−0.003 (3)−0.003 (3)0.009 (3)
C50.036 (3)0.043 (3)0.069 (3)−0.001 (2)0.000 (2)0.011 (3)
C60.048 (3)0.056 (3)0.046 (3)0.002 (2)0.000 (2)0.003 (3)
C70.076 (4)0.071 (4)0.059 (3)−0.006 (3)0.004 (3)0.019 (3)
C80.076 (4)0.096 (4)0.053 (3)−0.001 (3)0.002 (3)0.015 (3)
C90.075 (4)0.082 (4)0.046 (3)−0.008 (3)−0.003 (2)0.002 (3)
C100.052 (3)0.063 (3)0.037 (3)0.001 (2)0.001 (2)0.002 (2)
C110.042 (3)0.055 (3)0.047 (3)0.004 (2)0.002 (2)−0.007 (2)
C120.069 (4)0.071 (4)0.055 (3)−0.009 (3)−0.002 (3)−0.018 (3)
C130.078 (4)0.068 (4)0.089 (4)−0.020 (3)−0.003 (3)−0.014 (3)
C140.070 (4)0.053 (3)0.082 (4)−0.015 (3)0.001 (3)0.002 (3)
C150.048 (3)0.058 (3)0.060 (3)−0.005 (3)0.007 (2)0.004 (3)
C160.059 (4)0.065 (3)0.047 (3)0.010 (3)0.002 (3)0.003 (2)
C170.055 (4)0.077 (4)0.063 (3)0.015 (3)−0.011 (3)0.002 (3)
C180.048 (3)0.085 (4)0.066 (3)0.013 (3)0.003 (3)−0.012 (3)
C190.050 (3)0.071 (3)0.050 (3)0.005 (3)0.000 (3)−0.015 (2)
C200.043 (3)0.045 (3)0.047 (3)0.003 (2)0.002 (2)−0.005 (2)
C210.049 (3)0.040 (3)0.043 (3)−0.004 (2)0.003 (2)0.000 (2)
C220.061 (3)0.059 (3)0.053 (3)0.001 (3)0.013 (2)0.004 (2)
C230.072 (4)0.074 (3)0.050 (3)0.003 (3)0.004 (3)0.014 (3)
C240.059 (3)0.044 (3)0.053 (3)0.002 (2)−0.005 (2)0.007 (2)
C250.044 (3)0.038 (2)0.048 (3)−0.006 (2)0.000 (2)−0.002 (2)
C260.041 (3)0.036 (2)0.053 (3)0.001 (2)−0.006 (2)−0.002 (2)
C270.048 (3)0.060 (3)0.066 (3)0.002 (3)−0.003 (3)0.003 (2)
C280.044 (3)0.059 (3)0.098 (4)0.006 (2)−0.001 (3)0.000 (3)
C290.056 (4)0.071 (4)0.085 (4)0.003 (3)0.017 (3)0.001 (3)
C300.061 (3)0.055 (3)0.058 (3)−0.005 (3)0.009 (3)−0.001 (2)
C310.078 (5)0.112 (5)0.086 (5)0.005 (4)0.013 (4)−0.001 (4)
C320.072 (4)0.095 (5)0.072 (4)0.001 (4)0.000 (3)0.008 (4)
C330.088 (5)0.107 (6)0.068 (4)0.001 (4)0.002 (4)−0.021 (4)
C340.075 (5)0.114 (7)0.096 (5)−0.006 (4)−0.007 (4)0.008 (5)
C350.082 (4)0.056 (4)0.068 (3)−0.003 (3)0.002 (3)0.014 (3)
C360.069 (4)0.060 (3)0.053 (3)−0.006 (3)−0.001 (3)0.011 (3)
C370.081 (4)0.102 (5)0.072 (4)−0.003 (4)−0.011 (3)0.024 (3)
C380.065 (4)0.067 (4)0.056 (3)−0.009 (3)0.005 (3)−0.007 (3)
Co1—N21.858 (3)C10—C111.463 (5)
Co1—N51.894 (3)C11—C121.384 (5)
Co1—N12.011 (3)C12—C131.377 (6)
Co1—N32.012 (3)C12—H120.9300
Co1—N42.131 (3)C13—C141.368 (5)
Co1—N62.139 (3)C13—H130.9300
N1—C11.339 (5)C14—C151.370 (5)
N1—C51.350 (5)C14—H140.9300
N2—C61.341 (5)C15—H150.9300
N2—C101.342 (4)C16—C171.370 (5)
N3—C151.337 (5)C16—H160.9300
N3—C111.342 (4)C17—C181.363 (5)
N4—C161.334 (4)C17—H170.9300
N4—C201.346 (4)C18—C191.371 (5)
N5—C211.346 (4)C18—H180.9300
N5—C251.354 (4)C19—C201.376 (5)
N6—C301.326 (5)C19—H190.9300
N6—C261.350 (4)C20—C211.473 (5)
N7—C311.155 (6)C21—C221.379 (5)
N8—C331.176 (7)C22—C231.375 (5)
N9—C341.146 (7)C22—H220.9300
N10—C351.139 (6)C23—C241.368 (5)
N11—C371.144 (6)C23—H230.9300
N12—C381.141 (5)C24—C251.379 (5)
C1—C21.376 (6)C24—H240.9300
C1—H10.9300C25—C261.466 (5)
C2—C31.365 (6)C26—C271.377 (5)
C2—H20.9300C27—C281.372 (5)
C3—C41.371 (5)C27—H270.9300
C3—H30.9300C28—C291.378 (5)
C4—C51.371 (5)C28—H280.9300
C4—H40.9300C29—C301.377 (6)
C5—C61.466 (5)C29—H290.9300
C6—C71.380 (5)C30—H300.9300
C7—C81.385 (6)C31—C321.400 (7)
C7—H70.9300C32—C341.327 (8)
C8—C91.370 (6)C32—C331.382 (7)
C8—H80.9300C35—C361.396 (6)
C9—C101.381 (5)C36—C371.389 (7)
C9—H90.9300C36—C381.423 (6)
N2—Co1—N5178.48 (14)C11—C12—H12120.2
N2—Co1—N180.96 (14)C14—C13—C12119.1 (4)
N5—Co1—N199.85 (13)C14—C13—H13120.5
N2—Co1—N381.07 (14)C12—C13—H13120.5
N5—Co1—N398.11 (13)C13—C14—C15118.4 (4)
N1—Co1—N3162.03 (14)C13—C14—H14120.8
N2—Co1—N499.46 (14)C15—C14—H14120.8
N5—Co1—N479.28 (14)N3—C15—C14123.6 (4)
N1—Co1—N490.45 (12)N3—C15—H15118.2
N3—Co1—N492.38 (12)C14—C15—H15118.2
N2—Co1—N6101.91 (13)N4—C16—C17122.8 (4)
N5—Co1—N679.36 (13)N4—C16—H16118.6
N1—Co1—N692.19 (12)C17—C16—H16118.6
N3—Co1—N691.61 (12)C18—C17—C16118.9 (4)
N4—Co1—N6158.61 (13)C18—C17—H17120.6
C1—N1—C5118.3 (4)C16—C17—H17120.6
C1—N1—Co1128.3 (3)C17—C18—C19119.3 (4)
C5—N1—Co1113.5 (3)C17—C18—H18120.4
C6—N2—C10121.0 (3)C19—C18—H18120.4
C6—N2—Co1119.7 (3)C18—C19—C20119.3 (4)
C10—N2—Co1119.2 (3)C18—C19—H19120.4
C15—N3—C11118.0 (3)C20—C19—H19120.4
C15—N3—Co1128.6 (3)N4—C20—C19121.6 (4)
C11—N3—Co1113.4 (3)N4—C20—C21114.4 (4)
C16—N4—C20118.1 (4)C19—C20—C21123.9 (4)
C16—N4—Co1129.9 (3)N5—C21—C22121.5 (4)
C20—N4—Co1112.0 (3)N5—C21—C20113.8 (4)
C21—N5—C25119.3 (3)C22—C21—C20124.7 (4)
C21—N5—Co1120.5 (3)C23—C22—C21118.6 (4)
C25—N5—Co1120.2 (3)C23—C22—H22120.7
C30—N6—C26118.3 (4)C21—C22—H22120.7
C30—N6—Co1130.1 (3)C24—C23—C22120.5 (4)
C26—N6—Co1111.6 (3)C24—C23—H23119.7
N1—C1—C2122.4 (4)C22—C23—H23119.7
N1—C1—H1118.8C23—C24—C25118.6 (4)
C2—C1—H1118.8C23—C24—H24120.7
C3—C2—C1118.8 (5)C25—C24—H24120.7
C3—C2—H2120.6N5—C25—C24121.3 (4)
C1—C2—H2120.6N5—C25—C26114.0 (4)
C2—C3—C4119.6 (5)C24—C25—C26124.7 (4)
C2—C3—H3120.2N6—C26—C27121.5 (4)
C4—C3—H3120.2N6—C26—C25114.7 (4)
C5—C4—C3119.2 (5)C27—C26—C25123.8 (4)
C5—C4—H4120.4C28—C27—C26119.3 (4)
C3—C4—H4120.4C28—C27—H27120.4
N1—C5—C4121.7 (4)C26—C27—H27120.4
N1—C5—C6113.4 (4)C27—C28—C29119.7 (4)
C4—C5—C6124.9 (4)C27—C28—H28120.1
N2—C6—C7120.4 (4)C29—C28—H28120.1
N2—C6—C5112.4 (4)C30—C29—C28117.7 (4)
C7—C6—C5127.1 (4)C30—C29—H29121.2
C6—C7—C8118.9 (4)C28—C29—H29121.2
C6—C7—H7120.5N6—C30—C29123.5 (4)
C8—C7—H7120.5N6—C30—H30118.2
C9—C8—C7120.0 (4)C29—C30—H30118.2
C9—C8—H8120.0N7—C31—C32178.0 (7)
C7—C8—H8120.0C34—C32—C33117.9 (6)
C8—C9—C10119.0 (4)C34—C32—C31121.7 (6)
C8—C9—H9120.5C33—C32—C31120.3 (6)
C10—C9—H9120.5N8—C33—C32178.5 (7)
N2—C10—C9120.7 (4)N9—C34—C32179.3 (8)
N2—C10—C11112.7 (4)N10—C35—C36178.2 (6)
C9—C10—C11126.6 (4)C37—C36—C35119.5 (4)
N3—C11—C12121.4 (4)C37—C36—C38119.6 (5)
N3—C11—C10113.6 (4)C35—C36—C38120.8 (4)
C12—C11—C10125.0 (4)N11—C37—C36179.2 (8)
C13—C12—C11119.5 (4)N12—C38—C36179.2 (6)
C13—C12—H12120.2
D—H···AD—HH···AD···AD—H···A
C4—H4···N70.932.743.589 (7)153
C8—H8···N90.932.713.347 (8)126
C15—H15···N110.932.553.254 (6)133
C1—H1···N12i0.932.853.598 (6)138
C23—H23···N11i0.932.893.622 (6)136
C2—H2···N10ii0.932.773.670 (7)164
C29—H29···N9iii0.932.853.560 (8)134
C17—H17···N8iv0.932.653.395 (7)137
C13—H13···N8v0.932.653.379 (7)136
C18—H18···N12vi0.932.693.403 (6)134
C22—H22···N10vi0.932.513.231 (6)134
C19—H19···N12vii0.932.963.679 (6)135
C22—H22···N12vii0.932.923.645 (6)136
C24—H24···N10viii0.932.673.548 (6)158
C27—H27···N10viii0.932.573.350 (6)142
Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯AD—HH⋯AD⋯AD—H⋯A
C4—H4⋯N70.932.743.589 (7)153
C8—H8⋯N90.932.713.347 (8)126
C15—H15⋯N110.932.553.254 (6)133
C1—H1⋯N12i0.932.853.598 (6)138
C23—H23⋯N11i0.932.893.622 (6)136
C2—H2⋯N10ii0.932.773.670 (7)164
C29—H29⋯N9iii0.932.853.560 (8)134
C17—H17⋯N8iv0.932.653.395 (7)137
C13—H13⋯N8v0.932.653.379 (7)136
C18—H18⋯N12vi0.932.693.403 (6)134
C22—H22⋯N10vi0.932.513.231 (6)134
C19—H19⋯N12vii0.932.963.679 (6)135
C22—H22⋯N12vii0.932.923.645 (6)136
C24—H24⋯N10viii0.932.673.548 (6)158
C27—H27⋯N10viii0.932.573.350 (6)142

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) ; (vii) ; (viii) .

  10 in total

1.  Spin frustration in MII[C(CN)3]2 (M = V, Cr). A magnetism and neutron diffraction study.

Authors:  J L Manson; E Ressouche; J S Miller
Journal:  Inorg Chem       Date:  2000-03-20       Impact factor: 5.165

2.  AgC(CN)3-based coordination polymers.

Authors:  Brendan F Abrahams; Stuart R Batten; Bernard F Hoskins; Richard Robson
Journal:  Inorg Chem       Date:  2003-04-21       Impact factor: 5.165

3.  Magnetic ordering in iron tricyanomethanide.

Authors:  Ralf Feyerherm; Anja Loose; Sven Landsgesell; Jamie L Manson
Journal:  Inorg Chem       Date:  2004-10-18       Impact factor: 5.165

4.  Cobalt complexes of terpyridine ligand: crystal structure and photocleavage of DNA.

Authors:  Ramasamy Indumathy; Srinivasan Radhika; Mookandi Kanthimathi; T Weyhermuller; Balachandran Unni Nair
Journal:  J Inorg Biochem       Date:  2006-11-15       Impact factor: 4.155

5.  Synthesis, crystal structures and magnetic properties of tricyanomethanide-containing copper(II) complexes.

Authors:  C Yuste; D Armentano; N Marino; L Cañadillas-Delgado; F S Delgado; C Ruiz-Pérez; D P Rillema; F Lloret; M Julve
Journal:  Dalton Trans       Date:  2008-02-26       Impact factor: 4.390

6.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

7.  Interdigitation, interpenetration and intercalation in layered cuprous tricyanomethanide derivatives

Authors: 
Journal:  Chemistry       Date:  2000-01       Impact factor: 5.236

8.  Designer magnets containing cyanides and nitriles.

Authors:  J S Miller; J L Manson
Journal:  Acc Chem Res       Date:  2001-07       Impact factor: 22.384

9.  catena-Poly[[(2,2':6',2''-terpyridine-κN,N',N'')(tricyano-methanido-κN)nickel(II)]-μ-tricyano-methanido].

Authors:  Jun Luo; Xin-Rong Zhang; Wei-Quan Dai; Li-Li Cui; Bao-Shu Liu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-27

10.  Structure validation in chemical crystallography.

Authors:  Anthony L Spek
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2009-01-20
  10 in total
  1 in total

1.  Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N')iron(II) bis-(tricyano-methanide).

Authors:  Lucia Váhovská; Ivan Potočňák
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-24
  1 in total

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