Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra-oxa-7,16-diaza-cyclo-octa-deca-ne)barium(II)platinum(II)] hemihydrate].

The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the (01) set of crystal planes. In the crystal structure, disordered water mol-ecules (half occupancy) connect the sheets into a three-dimensional network via inter-molecular O-H⋯O hydrogen bonds. An N-H⋯N inter-action is also present. The shortest Pt⋯Pt contacts are 7.5969 (4) Å by an inversion relationship and 7.6781 (4) Å by translation along the a axis.

Related literature

For [BaPt(CN)4]·4H2O, see: Bergsoe et al. (1962 ▶); Williams et al. (1982 ▶). For the structure of a related salt, see: Olmstead et al. (2005 ▶).

Experimental

Crystal data

[BaPt(CN)4(C12H26N2O4)]·0.5H2O

M = 707.87

Monoclinic,

a = 7.6781 (4) Å

b = 14.8881 (9) Å

c = 20.2325 (12) Å

β = 93.254 (2)°

V = 2309.1 (2) Å3

Z = 4

Mo Kα radiation

μ = 7.78 mm−1

T = 93 K

0.18 × 0.10 × 0.06 mm

Data collection

Bruker SMART APEXII diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.469, T max = 0.676 (expected range = 0.435–0.627)

30095 measured reflections

5292 independent reflections

5066 reflections with I > 2σ(I)

R int = 0.027

Refinement

R[F 2 > 2σ(F 2)] = 0.013

wR(F 2) = 0.032

S = 1.03

5292 reflections

276 parameters

3 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.72 e Å−3

Δρmin = −0.42 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶), PovChem (Thiessen, 2000 ▶) and POV-RAY (Cason et al., 2004 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809008915/lh2782sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809008915/lh2782Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[BaPt(CN)4(C12H26N2O4)]·0.5H2O	F(000) = 1340
Mr = 707.87	Dx = 2.036 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 7683 reflections
a = 7.6781 (4) Å	θ = 2.4–33.6°
b = 14.8881 (9) Å	µ = 7.78 mm−1
c = 20.2325 (12) Å	T = 93 K
β = 93.254 (2)°	Prism, colorless
V = 2309.1 (2) Å3	0.18 × 0.10 × 0.06 mm
Z = 4

Bruker SMART APEXII diffractometer	5292 independent reflections
Radiation source: fine-focus sealed tube	5066 reflections with I > 2σ(I)
graphite	Rint = 0.027
Detector resolution: 8.3 pixels mm-1	θmax = 27.5°, θmin = 1.7°
ω scans	h = −9→9
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	k = −19→19
Tmin = 0.469, Tmax = 0.676	l = −26→26
30095 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.013	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.032	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ2(Fo2) + (0.0143P)2 + 1.2267P] where P = (Fo2 + 2Fc2)/3
5292 reflections	(Δ/σ)max = 0.003
276 parameters	Δρmax = 0.72 e Å−3
3 restraints	Δρmin = −0.42 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ba1	0.208165 (16)	0.303438 (8)	0.122058 (6)	0.01394 (3)
Pt1	0.519371 (10)	0.670691 (5)	0.139759 (4)	0.01325 (3)
O1	0.4491 (2)	0.29360 (10)	0.22989 (7)	0.0214 (3)
O2	0.4371 (2)	0.15673 (10)	0.13466 (8)	0.0215 (3)
O3	−0.0794 (2)	0.28946 (11)	0.02904 (8)	0.0238 (3)
O4	−0.0661 (2)	0.42719 (11)	0.12179 (8)	0.0243 (3)
O5	0.9018 (6)	1.0164 (3)	0.1191 (2)	0.0460 (10)	0.50
H5C	0.809 (6)	0.985 (4)	0.142 (3)	0.069*	0.50
H5D	0.944 (8)	1.063 (3)	0.151 (2)	0.069*	0.50
N1	0.6016 (3)	0.66373 (15)	−0.00967 (11)	0.0382 (6)
N2	0.6503 (3)	0.87107 (13)	0.13625 (10)	0.0296 (5)
N3	0.4574 (3)	0.67833 (12)	0.29213 (9)	0.0225 (4)
N4	0.3748 (3)	0.47391 (13)	0.13041 (9)	0.0249 (4)
N5	0.1327 (3)	0.39373 (13)	0.24229 (9)	0.0208 (4)
H5	0.067 (4)	0.361 (2)	0.2607 (14)	0.033 (8)*
N6	0.1924 (3)	0.15917 (12)	0.02347 (10)	0.0215 (4)
H6	0.251 (4)	0.1801 (17)	−0.0055 (15)	0.031 (8)*
C1	0.5688 (3)	0.66477 (15)	0.04481 (12)	0.0240 (5)
C2	0.6033 (3)	0.79805 (15)	0.13932 (10)	0.0200 (4)
C3	0.4780 (3)	0.67493 (13)	0.23617 (11)	0.0170 (4)
C4	0.4298 (3)	0.54565 (14)	0.13458 (10)	0.0175 (4)
C5	0.5553 (3)	0.21485 (16)	0.23661 (12)	0.0287 (5)
H5A	0.4929	0.1678	0.2605	0.034*
H5B	0.6649	0.2291	0.2626	0.034*
C6	0.5967 (3)	0.18077 (16)	0.16941 (13)	0.0265 (5)
H6A	0.6568	0.2280	0.1448	0.032*
H6B	0.6745	0.1278	0.1739	0.032*
C7	0.4592 (3)	0.09987 (15)	0.07817 (11)	0.0251 (5)
H7A	0.5213	0.0441	0.0921	0.030*
H7B	0.5289	0.1313	0.0456	0.030*
C8	0.2811 (3)	0.07755 (15)	0.04759 (11)	0.0262 (5)
H8A	0.2926	0.0352	0.0104	0.031*
H8B	0.2109	0.0480	0.0809	0.031*
C9	0.0142 (3)	0.14452 (17)	−0.00443 (13)	0.0305 (5)
H9A	−0.0576	0.1176	0.0295	0.037*
H9B	0.0161	0.1023	−0.0422	0.037*
C10	−0.0645 (3)	0.23237 (17)	−0.02739 (12)	0.0305 (5)
H10A	0.0104	0.2612	−0.0595	0.037*
H10B	−0.1811	0.2220	−0.0495	0.037*
C11	−0.1347 (3)	0.37872 (16)	0.01136 (12)	0.0268 (5)
H11A	−0.2267	0.3764	−0.0249	0.032*
H11B	−0.0351	0.4136	−0.0041	0.032*
C12	−0.2041 (3)	0.42288 (17)	0.07133 (12)	0.0284 (5)
H12A	−0.2463	0.4841	0.0600	0.034*
H12B	−0.3029	0.3877	0.0872	0.034*
C13	−0.1241 (3)	0.46060 (16)	0.18350 (12)	0.0271 (5)
H13A	−0.2026	0.4164	0.2030	0.033*
H13B	−0.1893	0.5174	0.1760	0.033*
C14	0.0335 (3)	0.47660 (15)	0.23000 (11)	0.0257 (5)
H14A	0.1096	0.5221	0.2106	0.031*
H14B	−0.0047	0.5004	0.2725	0.031*
C15	0.2917 (3)	0.40898 (16)	0.28449 (11)	0.0261 (5)
H15A	0.2594	0.4311	0.3283	0.031*
H15B	0.3630	0.4559	0.2643	0.031*
C16	0.3982 (3)	0.32446 (15)	0.29356 (11)	0.0258 (5)
H16A	0.5034	0.3366	0.3228	0.031*
H16B	0.3286	0.2775	0.3146	0.031*

	U11	U22	U33	U12	U13	U23
Ba1	0.01958 (6)	0.01186 (6)	0.01060 (6)	−0.00094 (4)	0.00280 (4)	0.00008 (4)
Pt1	0.01580 (4)	0.01269 (4)	0.01157 (4)	−0.00147 (3)	0.00343 (3)	−0.00084 (3)
O1	0.0295 (9)	0.0185 (8)	0.0160 (7)	0.0012 (6)	−0.0015 (6)	−0.0014 (6)
O2	0.0250 (8)	0.0182 (8)	0.0213 (8)	0.0018 (6)	0.0009 (6)	−0.0040 (6)
O3	0.0294 (9)	0.0220 (8)	0.0196 (8)	0.0003 (7)	−0.0030 (7)	0.0013 (6)
O4	0.0240 (8)	0.0266 (9)	0.0224 (8)	0.0054 (7)	0.0017 (6)	−0.0021 (7)
O5	0.050 (2)	0.040 (2)	0.048 (2)	−0.0111 (19)	0.008 (2)	−0.0052 (19)
N1	0.0621 (16)	0.0335 (12)	0.0210 (11)	−0.0269 (11)	0.0185 (11)	−0.0095 (9)
N2	0.0400 (12)	0.0207 (10)	0.0293 (11)	−0.0052 (9)	0.0132 (9)	−0.0031 (8)
N3	0.0286 (11)	0.0216 (10)	0.0176 (10)	0.0007 (8)	0.0046 (8)	−0.0011 (7)
N4	0.0339 (11)	0.0202 (10)	0.0215 (10)	−0.0049 (8)	0.0087 (8)	−0.0026 (8)
N5	0.0300 (10)	0.0161 (9)	0.0170 (9)	0.0001 (8)	0.0068 (8)	−0.0001 (7)
N6	0.0315 (11)	0.0162 (9)	0.0171 (9)	−0.0034 (8)	0.0029 (8)	−0.0001 (7)
C1	0.0327 (13)	0.0184 (11)	0.0215 (12)	−0.0098 (9)	0.0072 (10)	−0.0035 (8)
C2	0.0231 (11)	0.0212 (11)	0.0162 (10)	−0.0025 (9)	0.0067 (8)	−0.0024 (8)
C3	0.0190 (10)	0.0131 (10)	0.0189 (11)	−0.0016 (8)	0.0016 (8)	−0.0003 (8)
C4	0.0202 (10)	0.0205 (11)	0.0124 (9)	−0.0008 (8)	0.0057 (8)	−0.0016 (8)
C5	0.0322 (13)	0.0233 (12)	0.0295 (13)	0.0052 (10)	−0.0076 (10)	−0.0015 (10)
C6	0.0243 (12)	0.0212 (12)	0.0338 (14)	0.0004 (9)	−0.0005 (10)	−0.0029 (10)
C7	0.0347 (13)	0.0181 (11)	0.0231 (11)	0.0055 (9)	0.0069 (10)	−0.0046 (9)
C8	0.0403 (14)	0.0146 (11)	0.0234 (11)	0.0002 (10)	0.0014 (10)	−0.0055 (9)
C9	0.0391 (14)	0.0240 (12)	0.0275 (13)	−0.0070 (11)	−0.0062 (11)	−0.0067 (10)
C10	0.0369 (14)	0.0306 (13)	0.0229 (12)	−0.0044 (11)	−0.0086 (10)	−0.0040 (10)
C11	0.0267 (12)	0.0284 (13)	0.0251 (12)	0.0018 (10)	−0.0015 (9)	0.0053 (10)
C12	0.0268 (12)	0.0293 (13)	0.0289 (12)	0.0051 (10)	0.0009 (10)	0.0056 (10)
C13	0.0304 (12)	0.0226 (12)	0.0294 (12)	0.0074 (10)	0.0107 (10)	−0.0013 (10)
C14	0.0368 (13)	0.0188 (11)	0.0224 (11)	0.0043 (10)	0.0098 (10)	−0.0034 (9)
C15	0.0419 (14)	0.0229 (12)	0.0137 (10)	−0.0020 (10)	0.0021 (9)	−0.0047 (9)
C16	0.0376 (14)	0.0245 (12)	0.0148 (11)	−0.0031 (10)	−0.0035 (10)	−0.0031 (9)

Ba1—O1	2.7831 (15)	N6—C9	1.466 (3)
Ba1—O2	2.8062 (15)	N6—H6	0.82 (3)
Ba1—O3	2.8261 (16)	C5—C6	1.502 (3)
Ba1—O4	2.7980 (15)	C5—H5A	0.9900
Ba1—N1i	2.814 (2)	C5—H5B	0.9900
Ba1—N3ii	2.8896 (19)	C6—H6A	0.9900
Ba1—N4	2.8431 (19)	C6—H6B	0.9900
Ba1—N5	2.8671 (18)	C7—C8	1.506 (3)
Ba1—N6	2.9291 (19)	C7—H7A	0.9900
Pt1—Pt1i	7.5969 (4)	C7—H7B	0.9900
Pt1—Pt1iii	7.6781 (4)	C8—H8A	0.9900
Pt1—C1	1.981 (2)	C8—H8B	0.9900
Pt1—C2	2.003 (2)	C9—C10	1.503 (4)
Pt1—C3	1.995 (2)	C9—H9A	0.9900
Pt1—C4	1.985 (2)	C9—H9B	0.9900
O1—C5	1.430 (3)	C10—H10A	0.9900
O1—C16	1.442 (3)	C10—H10B	0.9900
O2—C6	1.424 (3)	C11—C12	1.504 (3)
O2—C7	1.440 (3)	C11—H11A	0.9900
O3—C10	1.433 (3)	C11—H11B	0.9900
O3—C11	1.434 (3)	C12—H12A	0.9900
O4—C12	1.431 (3)	C12—H12B	0.9900
O4—C13	1.438 (3)	C13—C14	1.509 (3)
O5—H5C	0.990 (10)	C13—H13A	0.9900
O5—H5D	0.989 (10)	C13—H13B	0.9900
N1—C1	1.145 (3)	C14—H14A	0.9900
N2—C2	1.148 (3)	C14—H14B	0.9900
N3—C3	1.153 (3)	C15—C16	1.506 (3)
N4—C4	1.150 (3)	C15—H15A	0.9900
N5—C14	1.464 (3)	C15—H15B	0.9900
N5—C15	1.467 (3)	C16—H16A	0.9900
N5—H5	0.81 (3)	C16—H16B	0.9900
N6—C8	1.463 (3)
O1—Ba1—O4	120.20 (4)	N4—C4—Pt1	178.3 (2)
O1—Ba1—O2	60.18 (4)	O1—C5—C6	109.86 (19)
O4—Ba1—O2	168.59 (5)	O1—C5—H5A	109.7
O1—Ba1—N1i	106.86 (6)	C6—C5—H5A	109.7
O4—Ba1—N1i	108.01 (6)	O1—C5—H5B	109.7
O2—Ba1—N1i	81.80 (6)	C6—C5—H5B	109.7
O1—Ba1—O3	167.83 (5)	H5A—C5—H5B	108.2
O4—Ba1—O3	59.19 (5)	O2—C6—C5	108.1 (2)
O2—Ba1—O3	117.70 (5)	O2—C6—H6A	110.1
N1i—Ba1—O3	84.06 (6)	C5—C6—H6A	110.1
O1—Ba1—N4	73.94 (5)	O2—C6—H6B	110.1
O4—Ba1—N4	75.43 (5)	C5—C6—H6B	110.1
O2—Ba1—N4	114.32 (5)	H6A—C6—H6B	108.4
N1i—Ba1—N4	68.93 (6)	O2—C7—C8	108.08 (18)
O3—Ba1—N4	115.93 (5)	O2—C7—H7A	110.1
O1—Ba1—N5	61.12 (5)	C8—C7—H7A	110.1
O4—Ba1—N5	60.30 (5)	O2—C7—H7B	110.1
O2—Ba1—N5	116.33 (5)	C8—C7—H7B	110.1
N1i—Ba1—N5	138.01 (6)	H7A—C7—H7B	108.4
O3—Ba1—N5	114.31 (5)	N6—C8—C7	110.40 (19)
N4—Ba1—N5	69.08 (5)	N6—C8—H8A	109.6
O1—Ba1—N3ii	77.91 (5)	C7—C8—H8A	109.6
O4—Ba1—N3ii	93.95 (5)	N6—C8—H8B	109.6
O2—Ba1—N3ii	74.83 (5)	C7—C8—H8B	109.6
N1i—Ba1—N3ii	149.73 (6)	H8A—C8—H8B	108.1
O3—Ba1—N3ii	89.94 (5)	N6—C9—C10	109.8 (2)
N4—Ba1—N3ii	138.73 (5)	N6—C9—H9A	109.7
N5—Ba1—N3ii	71.06 (5)	C10—C9—H9A	109.7
O1—Ba1—N6	119.68 (5)	N6—C9—H9B	109.7
O4—Ba1—N6	118.65 (5)	C10—C9—H9B	109.7
O2—Ba1—N6	59.51 (5)	H9A—C9—H9B	108.2
N1i—Ba1—N6	65.19 (6)	O3—C10—C9	108.59 (19)
O3—Ba1—N6	59.47 (5)	O3—C10—H10A	110.0
N4—Ba1—N6	134.12 (5)	C9—C10—H10A	110.0
N5—Ba1—N6	156.79 (6)	O3—C10—H10B	110.0
N3ii—Ba1—N6	86.21 (5)	C9—C10—H10B	110.0
C1—Pt1—C2	87.61 (9)	H10A—C10—H10B	108.4
C1—Pt1—C3	177.97 (10)	O3—C11—C12	108.50 (19)
C1—Pt1—C4	89.54 (8)	O3—C11—H11A	110.0
C3—Pt1—C2	92.50 (8)	C12—C11—H11A	110.0
C4—Pt1—C2	176.47 (9)	O3—C11—H11B	110.0
C4—Pt1—C3	90.42 (8)	C12—C11—H11B	110.0
C5—O1—C16	110.98 (17)	H11A—C11—H11B	108.4
C5—O1—Ba1	117.88 (12)	O4—C12—C11	108.26 (19)
C16—O1—Ba1	118.79 (13)	O4—C12—H12A	110.0
C6—O2—C7	113.74 (17)	C11—C12—H12A	110.0
C6—O2—Ba1	111.50 (12)	O4—C12—H12B	110.0
C7—O2—Ba1	119.14 (13)	C11—C12—H12B	110.0
C10—O3—C11	112.75 (17)	H12A—C12—H12B	108.4
C10—O3—Ba1	118.66 (13)	O4—C13—C14	108.62 (18)
C11—O3—Ba1	107.88 (13)	O4—C13—H13A	110.0
C12—O4—C13	112.47 (17)	C14—C13—H13A	110.0
C12—O4—Ba1	119.92 (13)	O4—C13—H13B	110.0
C13—O4—Ba1	119.74 (13)	C14—C13—H13B	110.0
H5C—O5—H5D	104 (3)	H13A—C13—H13B	108.3
C1—N1—Ba1i	158.2 (2)	N5—C14—C13	111.34 (19)
C3—N3—Ba1iv	135.06 (16)	N5—C14—H14A	109.4
C4—N4—Ba1	174.69 (17)	C13—C14—H14A	109.4
C14—N5—C15	112.09 (18)	N5—C14—H14B	109.4
C14—N5—Ba1	112.29 (13)	C13—C14—H14B	109.4
C15—N5—Ba1	111.39 (13)	H14A—C14—H14B	108.0
C14—N5—H5	105 (2)	N5—C15—C16	111.70 (18)
C15—N5—H5	110 (2)	N5—C15—H15A	109.3
Ba1—N5—H5	106 (2)	C16—C15—H15A	109.3
C8—N6—C9	114.29 (18)	N5—C15—H15B	109.3
C8—N6—Ba1	112.42 (13)	C16—C15—H15B	109.3
C9—N6—Ba1	111.89 (14)	H15A—C15—H15B	107.9
C8—N6—H6	107 (2)	O1—C16—C15	109.27 (18)
C9—N6—H6	109 (2)	O1—C16—H16A	109.8
Ba1—N6—H6	101.8 (19)	C15—C16—H16A	109.8
N1—C1—Pt1	177.6 (2)	O1—C16—H16B	109.8
N2—C2—Pt1	177.15 (19)	C15—C16—H16B	109.8
N3—C3—Pt1	178.6 (2)	H16A—C16—H16B	108.3
O4—Ba1—O1—C5	162.79 (15)	N6—Ba1—O4—C13	142.47 (15)
O2—Ba1—O1—C5	−4.04 (14)	O1—Ba1—N5—C14	146.68 (17)
N1i—Ba1—O1—C5	−73.83 (16)	O4—Ba1—N5—C14	−20.73 (14)
O3—Ba1—O1—C5	79.3 (3)	O2—Ba1—N5—C14	171.63 (14)
N4—Ba1—O1—C5	−135.26 (16)	N1i—Ba1—N5—C14	63.44 (19)
N5—Ba1—O1—C5	150.13 (17)	O3—Ba1—N5—C14	−45.94 (16)
N3ii—Ba1—O1—C5	75.26 (15)	N4—Ba1—N5—C14	64.00 (15)
N6—Ba1—O1—C5	−3.21 (17)	N3ii—Ba1—N5—C14	−126.96 (16)
O4—Ba1—O1—C16	23.94 (15)	N6—Ba1—N5—C14	−114.77 (18)
O2—Ba1—O1—C16	−142.89 (15)	O1—Ba1—N5—C15	20.02 (13)
N1i—Ba1—O1—C16	147.32 (14)	O4—Ba1—N5—C15	−147.39 (16)
O3—Ba1—O1—C16	−59.6 (3)	O2—Ba1—N5—C15	44.97 (15)
N4—Ba1—O1—C16	85.89 (14)	N1i—Ba1—N5—C15	−63.22 (18)
N5—Ba1—O1—C16	11.28 (14)	O3—Ba1—N5—C15	−172.60 (13)
N3ii—Ba1—O1—C16	−63.59 (14)	N4—Ba1—N5—C15	−62.66 (14)
N6—Ba1—O1—C16	−142.06 (14)	N3ii—Ba1—N5—C15	106.38 (15)
O1—Ba1—O2—C6	−28.85 (14)	N6—Ba1—N5—C15	118.57 (17)
O4—Ba1—O2—C6	−124.0 (2)	O1—Ba1—N6—C8	16.47 (17)
N1i—Ba1—O2—C6	86.00 (15)	O4—Ba1—N6—C8	−149.75 (14)
O3—Ba1—O2—C6	164.83 (14)	O2—Ba1—N6—C8	17.30 (14)
N4—Ba1—O2—C6	23.63 (15)	N1i—Ba1—N6—C8	112.45 (17)
N5—Ba1—O2—C6	−54.05 (15)	O3—Ba1—N6—C8	−149.49 (17)
N3ii—Ba1—O2—C6	−113.42 (15)	N4—Ba1—N6—C8	112.74 (15)
N6—Ba1—O2—C6	151.98 (16)	N5—Ba1—N6—C8	−68.9 (2)
O1—Ba1—O2—C7	−164.49 (16)	N3ii—Ba1—N6—C8	−57.32 (15)
O4—Ba1—O2—C7	100.3 (3)	O1—Ba1—N6—C9	146.66 (14)
N1i—Ba1—O2—C7	−49.64 (15)	O4—Ba1—N6—C9	−19.55 (17)
O3—Ba1—O2—C7	29.19 (16)	O2—Ba1—N6—C9	147.49 (17)
N4—Ba1—O2—C7	−112.01 (15)	N1i—Ba1—N6—C9	−117.35 (17)
N5—Ba1—O2—C7	170.31 (14)	O3—Ba1—N6—C9	−19.29 (14)
N3ii—Ba1—O2—C7	110.94 (15)	N4—Ba1—N6—C9	−117.06 (16)
N6—Ba1—O2—C7	16.34 (14)	N5—Ba1—N6—C9	61.3 (2)
O1—Ba1—O3—C10	−104.1 (2)	N3ii—Ba1—N6—C9	72.88 (15)
O4—Ba1—O3—C10	165.23 (17)	C16—O1—C5—C6	176.36 (19)
O2—Ba1—O3—C10	−27.36 (16)	Ba1—O1—C5—C6	34.5 (2)
N1i—Ba1—O3—C10	50.13 (16)	C7—O2—C6—C5	−163.08 (18)
N4—Ba1—O3—C10	113.22 (15)	Ba1—O2—C6—C5	58.8 (2)
N5—Ba1—O3—C10	−169.25 (15)	O1—C5—C6—O2	−62.2 (2)
N3ii—Ba1—O3—C10	−100.14 (16)	C6—O2—C7—C8	178.29 (19)
N6—Ba1—O3—C10	−14.51 (15)	Ba1—O2—C7—C8	−47.0 (2)
O1—Ba1—O3—C11	126.2 (2)	C9—N6—C8—C7	−177.3 (2)
O4—Ba1—O3—C11	35.48 (12)	Ba1—N6—C8—C7	−48.3 (2)
O2—Ba1—O3—C11	−157.11 (12)	O2—C7—C8—N6	62.9 (2)
N1i—Ba1—O3—C11	−79.61 (13)	C8—N6—C9—C10	179.8 (2)
N4—Ba1—O3—C11	−16.52 (14)	Ba1—N6—C9—C10	50.6 (2)
N5—Ba1—O3—C11	61.00 (14)	C11—O3—C10—C9	173.3 (2)
N3ii—Ba1—O3—C11	130.11 (13)	Ba1—O3—C10—C9	45.8 (2)
N6—Ba1—O3—C11	−144.25 (14)	N6—C9—C10—O3	−64.2 (3)
O1—Ba1—O4—C12	−170.45 (14)	C10—O3—C11—C12	161.05 (19)
O2—Ba1—O4—C12	−81.9 (3)	Ba1—O3—C11—C12	−65.97 (19)
N1i—Ba1—O4—C12	66.73 (16)	C13—O4—C12—C11	−174.38 (19)
O3—Ba1—O4—C12	−4.57 (14)	Ba1—O4—C12—C11	−25.4 (2)
N4—Ba1—O4—C12	128.36 (16)	O3—C11—C12—O4	61.3 (2)
N5—Ba1—O4—C12	−157.69 (17)	C12—O4—C13—C14	−171.16 (19)
N3ii—Ba1—O4—C12	−92.14 (15)	Ba1—O4—C13—C14	39.8 (2)
N6—Ba1—O4—C12	−4.31 (17)	C15—N5—C14—C13	176.85 (18)
O1—Ba1—O4—C13	−23.67 (17)	Ba1—N5—C14—C13	50.6 (2)
O2—Ba1—O4—C13	64.9 (3)	O4—C13—C14—N5	−59.8 (2)
N1i—Ba1—O4—C13	−146.49 (15)	C14—N5—C15—C16	−176.63 (19)
O3—Ba1—O4—C13	142.21 (16)	Ba1—N5—C15—C16	−49.9 (2)
N4—Ba1—O4—C13	−84.86 (15)	C5—O1—C16—C15	178.20 (19)
N5—Ba1—O4—C13	−10.91 (15)	Ba1—O1—C16—C15	−40.3 (2)
N3ii—Ba1—O4—C13	54.64 (16)	N5—C15—C16—O1	60.5 (2)

D—H···A	D—H	H···A	D···A	D—H···A
O5—H5C···N2	0.99 (1)	2.09 (4)	2.934 (5)	142 (5)
O5—H5D···N3v	0.99 (1)	2.18 (1)	3.159 (4)	171 (5)
N6—H6···N1i	0.82 (3)	2.60 (3)	3.096 (3)	121 (2)

Ba1—O1	2.7831 (15)
Ba1—O2	2.8062 (15)
Ba1—O3	2.8261 (16)
Ba1—O4	2.7980 (15)
Ba1—N1i	2.814 (2)
Ba1—N3ii	2.8896 (19)
Ba1—N4	2.8431 (19)
Ba1—N5	2.8671 (18)
Ba1—N6	2.9291 (19)
Pt1—C1	1.981 (2)
Pt1—C2	2.003 (2)
Pt1—C3	1.995 (2)
Pt1—C4	1.985 (2)

C1—Pt1—C2	87.61 (9)
C1—Pt1—C3	177.97 (10)
C1—Pt1—C4	89.54 (8)
C3—Pt1—C2	92.50 (8)
C4—Pt1—C2	176.47 (9)
C4—Pt1—C3	90.42 (8)

Symmetry codes: (i) ; (ii) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O5—H5C⋯N2	0.990 (10)	2.09 (4)	2.934 (5)	142 (5)
O5—H5D⋯N3iv	0.989 (10)	2.179 (14)	3.159 (4)	171 (5)
N6—H6⋯N1i	0.82 (3)	2.60 (3)	3.096 (3)	121 (2)

Symmetry codes: (i) ; (iv) .