Di-μ-chromato-κO:O'-bis-[bis-(phenan-throline-κN,N')cadmium(II)] dihydrate.

In the title compound, [Cd(2)Cr(2)O(8)(C(12)H(8)N(2))(4)]·2H(2)O, which was obtained by hydro-thermal reaction of CdCO(3) and phenanthroline with K(2)CrO(4) at 393 K, two distorted Cd(N(4)O(2)) octa-hedra are linked through μ(2)-bridging chromate anions, forming a centrosymmetric tetra-nuclear eight-membered ring complex. The water mol-ecules link the chromate O atoms via inter-molecular O-H⋯O hydrogen bonds. These aggregates pack to a three-dimensional network through weak inter-molecular C-H⋯O and C-H⋯π hydrogen-bonding contacts.

Related literature

For the properties of multimetallic complexes, see: Costisor et al. (2001 ▶). For the structures of heterometallic macrocyclic rings, see: Larsen et al. (2003 ▶); Timco et al. (2005 ▶). For related structures, see: Dai et al. (2002 ▶); Chaudhuri et al. (1988 ▶); Yoshikawa et al. (2002 ▶).

Experimental

Crystal data

[Cd2Cr2O8(C12H8N2)4]·2H2O

M = 1213.65

Monoclinic,

a = 11.2303 (13) Å

b = 13.6892 (16) Å

c = 14.5352 (19) Å

β = 91.928 (1)°

V = 2233.3 (5) Å3

Z = 2

Mo Kα radiation

μ = 1.48 mm−1

T = 298 K

0.13 × 0.08 × 0.05 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 1997 ▶) T min = 0.830, T max = 0.930

11590 measured reflections

3922 independent reflections

2145 reflections with I > 2σ(I)

R int = 0.096

Refinement

R[F 2 > 2σ(F 2)] = 0.045

wR(F 2) = 0.065

S = 0.86

3922 reflections

316 parameters

H-atom parameters constrained

Δρmax = 0.50 e Å−3

Δρmin = −0.52 e Å−3

Data collection: SMART (Bruker, 1997 ▶); cell refinement: SAINT (Bruker, 1997 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053680900823X/si2157sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053680900823X/si2157Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cd2Cr2O8(C12H8N2)4]·2H2O	F(000) = 1208
Mr = 1213.65	Dx = 1.805 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 11.2303 (13) Å	Cell parameters from 1518 reflections
b = 13.6892 (16) Å	θ = 2.3–25.0°
c = 14.5352 (19) Å	µ = 1.48 mm−1
β = 91.928 (1)°	T = 298 K
V = 2233.3 (5) Å3	Prism, yellow
Z = 2	0.13 × 0.08 × 0.05 mm

Bruker SMART CCD area-detector diffractometer	3922 independent reflections
Radiation source: fine-focus sealed tube	2145 reflections with I > 2σ(I)
graphite	Rint = 0.096
φ and ω scans	θmax = 25.0°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 1997)	h = −13→9
Tmin = 0.830, Tmax = 0.930	k = −16→14
11590 measured reflections	l = −17→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.045	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.065	H-atom parameters constrained
S = 0.86	w = 1/[σ2(Fo2) + (0.0001P)2] where P = (Fo2 + 2Fc2)/3
3922 reflections	(Δ/σ)max = 0.001
316 parameters	Δρmax = 0.50 e Å−3
0 restraints	Δρmin = −0.52 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cd1	0.54305 (4)	0.67292 (3)	0.58619 (3)	0.03350 (14)
N1	0.5517 (4)	0.7535 (3)	0.7310 (3)	0.0336 (13)
N2	0.7407 (4)	0.6723 (3)	0.6487 (3)	0.0345 (12)
N3	0.6012 (5)	0.8015 (3)	0.4851 (4)	0.0439 (15)
N4	0.3768 (4)	0.7747 (3)	0.5434 (3)	0.0359 (13)
O1	0.6078 (4)	0.5715 (3)	0.4790 (3)	0.0484 (13)
O2	0.4197 (3)	0.5701 (3)	0.6521 (3)	0.0407 (12)
O3	0.7995 (3)	0.4755 (3)	0.4225 (3)	0.0453 (12)
O4	0.6869 (3)	0.5992 (3)	0.3082 (3)	0.0482 (12)
O5	0.9994 (4)	1.0021 (3)	1.3274 (3)	0.0759 (16)
H5A	0.9990	0.9605	1.2840	0.091*
H5B	0.9505	1.0471	1.3117	0.091*
Cr1	0.66961 (8)	0.51967 (7)	0.38910 (7)	0.0325 (3)
C1	0.4611 (5)	0.7872 (4)	0.7770 (4)	0.0391 (17)
H1	0.3848	0.7689	0.7570	0.047*
C2	0.4718 (6)	0.8482 (4)	0.8532 (4)	0.0436 (18)
H2	0.4043	0.8706	0.8819	0.052*
C3	0.5821 (6)	0.8746 (4)	0.8852 (4)	0.0431 (18)
H3	0.5907	0.9143	0.9368	0.052*
C4	0.6834 (5)	0.8415 (4)	0.8399 (4)	0.0341 (15)
C5	0.6630 (5)	0.7787 (4)	0.7641 (4)	0.0276 (15)
C6	0.7639 (5)	0.7354 (4)	0.7186 (4)	0.0276 (15)
C7	0.8814 (6)	0.7601 (4)	0.7509 (4)	0.0346 (16)
C8	0.9753 (6)	0.7126 (4)	0.7098 (4)	0.0429 (18)
H8	1.0533	0.7264	0.7289	0.051*
C9	0.9533 (6)	0.6458 (4)	0.6413 (5)	0.049 (2)
H9	1.0154	0.6119	0.6152	0.059*
C10	0.8346 (6)	0.6298 (4)	0.6116 (4)	0.0391 (17)
H10	0.8206	0.5869	0.5629	0.047*
C11	0.8043 (6)	0.8687 (4)	0.8675 (4)	0.0435 (18)
H11	0.8177	0.9134	0.9149	0.052*
C12	0.8964 (5)	0.8294 (5)	0.8249 (4)	0.0423 (16)
H12	0.9732	0.8475	0.8437	0.051*
C13	0.7115 (6)	0.8143 (5)	0.4542 (4)	0.053 (2)
H13	0.7723	0.7738	0.4766	0.063*
C14	0.7391 (7)	0.8865 (5)	0.3892 (5)	0.060 (2)
H14	0.8168	0.8932	0.3700	0.072*
C15	0.6527 (6)	0.9458 (5)	0.3549 (5)	0.052 (2)
H15	0.6705	0.9934	0.3119	0.063*
C16	0.5359 (6)	0.9354 (5)	0.3845 (4)	0.0423 (18)
C17	0.5154 (6)	0.8613 (4)	0.4499 (4)	0.0380 (17)
C18	0.3954 (5)	0.8468 (4)	0.4803 (4)	0.0306 (15)
C19	0.3029 (6)	0.9051 (4)	0.4452 (4)	0.0396 (18)
C20	0.1869 (6)	0.8889 (5)	0.4757 (4)	0.050 (2)
H20	0.1234	0.9270	0.4540	0.060*
C21	0.1692 (5)	0.8152 (5)	0.5387 (5)	0.0480 (18)
H21	0.0935	0.8025	0.5598	0.058*
C22	0.2666 (6)	0.7604 (5)	0.5700 (4)	0.0460 (19)
H22	0.2535	0.7107	0.6122	0.055*
C23	0.4397 (7)	0.9928 (5)	0.3503 (5)	0.054 (2)
H23	0.4540	1.0412	0.3071	0.065*
C24	0.3285 (6)	0.9795 (5)	0.3783 (4)	0.053 (2)
H24	0.2671	1.0185	0.3544	0.064*

	U11	U22	U33	U12	U13	U23
Cd1	0.0289 (2)	0.0347 (3)	0.0369 (3)	0.0001 (3)	0.0019 (2)	−0.0027 (3)
N1	0.021 (3)	0.046 (3)	0.034 (3)	0.003 (3)	0.003 (3)	−0.002 (3)
N2	0.037 (3)	0.032 (3)	0.034 (3)	0.011 (3)	0.002 (3)	−0.008 (3)
N3	0.039 (3)	0.041 (4)	0.053 (4)	0.005 (3)	0.011 (3)	−0.003 (3)
N4	0.035 (3)	0.034 (3)	0.039 (4)	0.002 (3)	0.000 (3)	0.008 (3)
O1	0.044 (3)	0.051 (3)	0.050 (3)	−0.002 (2)	0.007 (2)	−0.018 (2)
O2	0.043 (3)	0.037 (3)	0.043 (3)	−0.015 (2)	0.003 (2)	−0.005 (2)
O3	0.027 (3)	0.052 (3)	0.057 (3)	0.010 (2)	0.003 (2)	0.004 (2)
O4	0.042 (3)	0.049 (3)	0.054 (3)	−0.004 (2)	0.003 (2)	0.019 (2)
O5	0.079 (4)	0.088 (4)	0.059 (4)	0.000 (3)	−0.019 (3)	0.011 (3)
Cr1	0.0274 (6)	0.0340 (6)	0.0361 (7)	−0.0011 (5)	0.0021 (5)	0.0003 (5)
C1	0.030 (4)	0.039 (4)	0.048 (5)	0.000 (3)	0.005 (4)	0.005 (3)
C2	0.044 (4)	0.042 (5)	0.046 (5)	0.009 (4)	0.006 (4)	−0.008 (3)
C3	0.059 (5)	0.037 (4)	0.033 (4)	0.008 (4)	0.001 (4)	−0.012 (3)
C4	0.044 (4)	0.025 (4)	0.033 (4)	0.002 (3)	−0.001 (3)	0.002 (3)
C5	0.034 (4)	0.021 (3)	0.028 (4)	0.002 (3)	−0.002 (3)	0.002 (3)
C6	0.026 (4)	0.030 (4)	0.027 (4)	−0.008 (3)	0.002 (3)	−0.004 (3)
C7	0.032 (4)	0.039 (4)	0.033 (4)	0.001 (3)	−0.002 (3)	0.002 (3)
C8	0.029 (4)	0.053 (5)	0.047 (5)	−0.005 (4)	−0.001 (4)	0.012 (4)
C9	0.035 (4)	0.052 (5)	0.061 (5)	0.007 (4)	0.017 (4)	0.009 (4)
C10	0.041 (4)	0.044 (4)	0.033 (4)	−0.001 (4)	0.009 (4)	−0.001 (3)
C11	0.050 (5)	0.043 (4)	0.037 (4)	−0.017 (4)	−0.009 (4)	−0.008 (3)
C12	0.033 (4)	0.051 (4)	0.042 (4)	−0.008 (4)	−0.010 (3)	0.011 (4)
C13	0.048 (5)	0.045 (5)	0.067 (5)	0.003 (4)	0.017 (4)	−0.004 (4)
C14	0.051 (5)	0.064 (6)	0.067 (6)	−0.017 (5)	0.023 (5)	0.009 (4)
C15	0.063 (5)	0.039 (5)	0.055 (5)	0.003 (4)	0.014 (5)	0.004 (4)
C16	0.057 (5)	0.038 (4)	0.033 (4)	−0.008 (4)	0.009 (4)	0.001 (3)
C17	0.038 (4)	0.036 (4)	0.039 (4)	0.003 (4)	0.005 (4)	−0.006 (3)
C18	0.037 (4)	0.022 (4)	0.033 (4)	−0.004 (3)	0.001 (3)	−0.003 (3)
C19	0.048 (5)	0.032 (4)	0.039 (5)	−0.003 (4)	0.000 (4)	−0.001 (3)
C20	0.048 (5)	0.049 (5)	0.053 (5)	0.018 (4)	−0.004 (4)	−0.005 (4)
C21	0.032 (4)	0.049 (5)	0.063 (5)	0.002 (4)	−0.005 (4)	0.007 (4)
C22	0.046 (5)	0.052 (5)	0.040 (5)	−0.004 (4)	0.008 (4)	0.003 (4)
C23	0.075 (6)	0.040 (5)	0.049 (5)	−0.005 (5)	0.008 (5)	0.015 (4)
C24	0.060 (5)	0.050 (5)	0.048 (5)	0.004 (4)	−0.006 (4)	0.009 (4)

Cd1—O2	2.215 (4)	C7—C8	1.390 (7)
Cd1—O1	2.226 (4)	C7—C12	1.440 (8)
Cd1—N2	2.370 (5)	C8—C9	1.367 (8)
Cd1—N1	2.376 (5)	C8—H8	0.9300
Cd1—N4	2.394 (5)	C9—C10	1.405 (8)
Cd1—N3	2.397 (5)	C9—H9	0.9300
N1—C1	1.319 (6)	C10—H10	0.9300
N1—C5	1.369 (7)	C11—C12	1.336 (7)
N2—C10	1.334 (6)	C11—H11	0.9300
N2—C6	1.353 (6)	C12—H12	0.9300
N3—C13	1.344 (7)	C13—C14	1.408 (8)
N3—C17	1.352 (7)	C13—H13	0.9300
N4—C22	1.324 (7)	C14—C15	1.348 (8)
N4—C18	1.369 (6)	C14—H14	0.9300
O1—Cr1	1.660 (4)	C15—C16	1.401 (8)
O2—Cr1i	1.683 (4)	C15—H15	0.9300
O3—Cr1	1.638 (4)	C16—C23	1.412 (9)
O4—Cr1	1.619 (4)	C16—C17	1.415 (8)
O5—H5A	0.8501	C17—C18	1.445 (7)
O5—H5B	0.8500	C18—C19	1.394 (8)
Cr1—O2i	1.683 (4)	C19—C20	1.408 (8)
C1—C2	1.388 (7)	C19—C24	1.442 (8)
C1—H1	0.9300	C20—C21	1.381 (7)
C2—C3	1.357 (8)	C20—H20	0.9300
C2—H2	0.9300	C21—C22	1.390 (8)
C3—C4	1.408 (7)	C21—H21	0.9300
C3—H3	0.9300	C22—H22	0.9300
C4—C5	1.410 (7)	C23—C24	1.339 (8)
C4—C11	1.452 (8)	C23—H23	0.9300
C5—C6	1.456 (7)	C24—H24	0.9300
C6—C7	1.426 (8)
O2—Cd1—O1	97.47 (13)	C8—C7—C6	117.1 (6)
O2—Cd1—N2	115.01 (15)	C8—C7—C12	123.9 (6)
O1—Cd1—N2	86.70 (15)	C6—C7—C12	119.0 (5)
O2—Cd1—N1	85.37 (15)	C9—C8—C7	120.3 (6)
O1—Cd1—N1	154.79 (16)	C9—C8—H8	119.9
N2—Cd1—N1	69.64 (15)	C7—C8—H8	119.9
O2—Cd1—N4	89.34 (15)	C8—C9—C10	118.3 (6)
O1—Cd1—N4	116.81 (16)	C8—C9—H9	120.9
N2—Cd1—N4	144.46 (17)	C10—C9—H9	120.9
N1—Cd1—N4	88.19 (16)	N2—C10—C9	124.3 (6)
O2—Cd1—N3	156.75 (17)	N2—C10—H10	117.9
O1—Cd1—N3	85.81 (15)	C9—C10—H10	117.9
N2—Cd1—N3	88.10 (17)	C12—C11—C4	120.0 (6)
N1—Cd1—N3	101.44 (17)	C12—C11—H11	120.0
N4—Cd1—N3	68.90 (17)	C4—C11—H11	120.0
C1—N1—C5	116.4 (5)	C11—C12—C7	122.6 (6)
C1—N1—Cd1	127.0 (4)	C11—C12—H12	118.7
C5—N1—Cd1	116.0 (4)	C7—C12—H12	118.7
C10—N2—C6	116.6 (5)	N3—C13—C14	122.8 (6)
C10—N2—Cd1	126.1 (4)	N3—C13—H13	118.6
C6—N2—Cd1	116.1 (4)	C14—C13—H13	118.6
C13—N3—C17	116.6 (5)	C15—C14—C13	119.9 (7)
C13—N3—Cd1	125.1 (5)	C15—C14—H14	120.0
C17—N3—Cd1	118.1 (4)	C13—C14—H14	120.0
C22—N4—C18	117.9 (5)	C14—C15—C16	119.7 (7)
C22—N4—Cd1	124.5 (4)	C14—C15—H15	120.2
C18—N4—Cd1	117.3 (4)	C16—C15—H15	120.2
Cr1—O1—Cd1	166.5 (2)	C15—C16—C23	123.3 (6)
Cr1i—O2—Cd1	133.1 (2)	C15—C16—C17	117.0 (7)
H5A—O5—H5B	107.4	C23—C16—C17	119.7 (6)
O4—Cr1—O3	109.6 (2)	N3—C17—C16	124.0 (6)
O4—Cr1—O1	110.4 (2)	N3—C17—C18	117.5 (6)
O3—Cr1—O1	108.4 (2)	C16—C17—C18	118.5 (6)
O4—Cr1—O2i	108.5 (2)	N4—C18—C19	122.0 (5)
O3—Cr1—O2i	110.5 (2)	N4—C18—C17	117.9 (6)
O1—Cr1—O2i	109.40 (18)	C19—C18—C17	120.1 (6)
N1—C1—C2	124.5 (6)	C18—C19—C20	118.7 (6)
N1—C1—H1	117.7	C18—C19—C24	119.2 (6)
C2—C1—H1	117.7	C20—C19—C24	122.1 (7)
C3—C2—C1	119.1 (6)	C21—C20—C19	118.6 (6)
C3—C2—H2	120.4	C21—C20—H20	120.7
C1—C2—H2	120.4	C19—C20—H20	120.7
C2—C3—C4	119.7 (6)	C20—C21—C22	118.9 (6)
C2—C3—H3	120.1	C20—C21—H21	120.6
C4—C3—H3	120.1	C22—C21—H21	120.6
C3—C4—C5	116.7 (6)	N4—C22—C21	123.9 (6)
C3—C4—C11	123.4 (6)	N4—C22—H22	118.1
C5—C4—C11	119.9 (5)	C21—C22—H22	118.1
N1—C5—C4	123.4 (5)	C24—C23—C16	121.8 (6)
N1—C5—C6	117.0 (5)	C24—C23—H23	119.1
C4—C5—C6	119.6 (6)	C16—C23—H23	119.1
N2—C6—C7	123.4 (5)	C23—C24—C19	120.7 (7)
N2—C6—C5	117.9 (5)	C23—C24—H24	119.7
C7—C6—C5	118.7 (5)	C19—C24—H24	119.7
O2—Cd1—N1—C1	−55.4 (5)	C11—C4—C5—N1	−176.7 (5)
O1—Cd1—N1—C1	−153.1 (4)	C3—C4—C5—C6	−175.1 (5)
N2—Cd1—N1—C1	−174.2 (5)	C11—C4—C5—C6	4.8 (9)
N4—Cd1—N1—C1	34.1 (5)	C10—N2—C6—C7	2.1 (8)
N3—Cd1—N1—C1	102.1 (5)	Cd1—N2—C6—C7	−166.0 (5)
O2—Cd1—N1—C5	133.8 (4)	C10—N2—C6—C5	−176.5 (5)
O1—Cd1—N1—C5	36.1 (6)	Cd1—N2—C6—C5	15.3 (6)
N2—Cd1—N1—C5	15.0 (4)	N1—C5—C6—N2	−1.5 (8)
N4—Cd1—N1—C5	−136.7 (4)	C4—C5—C6—N2	177.2 (5)
N3—Cd1—N1—C5	−68.6 (4)	N1—C5—C6—C7	179.8 (5)
O2—Cd1—N2—C10	102.9 (4)	C4—C5—C6—C7	−1.5 (8)
O1—Cd1—N2—C10	6.2 (5)	N2—C6—C7—C8	−2.7 (9)
N1—Cd1—N2—C10	177.3 (5)	C5—C6—C7—C8	175.9 (5)
N4—Cd1—N2—C10	−127.9 (4)	N2—C6—C7—C12	179.1 (5)
N3—Cd1—N2—C10	−79.7 (5)	C5—C6—C7—C12	−2.3 (9)
O2—Cd1—N2—C6	−90.2 (4)	C6—C7—C8—C9	0.2 (9)
O1—Cd1—N2—C6	173.1 (4)	C12—C7—C8—C9	178.3 (6)
N1—Cd1—N2—C6	−15.8 (4)	C7—C8—C9—C10	2.6 (9)
N4—Cd1—N2—C6	38.9 (5)	C6—N2—C10—C9	0.9 (9)
N3—Cd1—N2—C6	87.2 (4)	Cd1—N2—C10—C9	167.7 (5)
O2—Cd1—N3—C13	−156.8 (4)	C8—C9—C10—N2	−3.3 (10)
O1—Cd1—N3—C13	−57.6 (5)	C3—C4—C11—C12	175.7 (6)
N2—Cd1—N3—C13	29.2 (5)	C5—C4—C11—C12	−4.2 (9)
N1—Cd1—N3—C13	98.0 (5)	C4—C11—C12—C7	0.3 (10)
N4—Cd1—N3—C13	−178.5 (5)	C8—C7—C12—C11	−175.1 (6)
O2—Cd1—N3—C17	17.3 (7)	C6—C7—C12—C11	3.0 (10)
O1—Cd1—N3—C17	116.5 (5)	C17—N3—C13—C14	0.7 (10)
N2—Cd1—N3—C17	−156.7 (5)	Cd1—N3—C13—C14	174.9 (5)
N1—Cd1—N3—C17	−87.9 (5)	N3—C13—C14—C15	−0.5 (11)
N4—Cd1—N3—C17	−4.4 (4)	C13—C14—C15—C16	0.2 (11)
O2—Cd1—N4—C22	6.7 (5)	C14—C15—C16—C23	−178.3 (7)
O1—Cd1—N4—C22	104.8 (5)	C14—C15—C16—C17	−0.2 (10)
N2—Cd1—N4—C22	−128.6 (5)	C13—N3—C17—C16	−0.7 (9)
N1—Cd1—N4—C22	−78.7 (5)	Cd1—N3—C17—C16	−175.3 (5)
N3—Cd1—N4—C22	178.3 (5)	C13—N3—C17—C18	178.2 (5)
O2—Cd1—N4—C18	−166.9 (4)	Cd1—N3—C17—C18	3.6 (7)
O1—Cd1—N4—C18	−68.8 (4)	C15—C16—C17—N3	0.4 (10)
N2—Cd1—N4—C18	57.8 (5)	C23—C16—C17—N3	178.6 (6)
N1—Cd1—N4—C18	107.8 (4)	C15—C16—C17—C18	−178.5 (6)
N3—Cd1—N4—C18	4.8 (4)	C23—C16—C17—C18	−0.3 (9)
O2—Cd1—O1—Cr1	168.8 (11)	C22—N4—C18—C19	0.9 (9)
N2—Cd1—O1—Cr1	−76.4 (11)	Cd1—N4—C18—C19	174.9 (4)
N1—Cd1—O1—Cr1	−96.2 (12)	C22—N4—C18—C17	−178.9 (5)
N4—Cd1—O1—Cr1	75.7 (11)	Cd1—N4—C18—C17	−4.9 (7)
N3—Cd1—O1—Cr1	11.9 (11)	N3—C17—C18—N4	0.8 (8)
O1—Cd1—O2—Cr1i	−35.6 (3)	C16—C17—C18—N4	179.8 (5)
N2—Cd1—O2—Cr1i	−125.5 (3)	N3—C17—C18—C19	−178.9 (6)
N1—Cd1—O2—Cr1i	169.6 (3)	C16—C17—C18—C19	0.1 (9)
N4—Cd1—O2—Cr1i	81.3 (3)	N4—C18—C19—C20	−0.1 (9)
N3—Cd1—O2—Cr1i	61.2 (5)	C17—C18—C19—C20	179.7 (5)
Cd1—O1—Cr1—O4	−24.0 (12)	N4—C18—C19—C24	−179.6 (5)
Cd1—O1—Cr1—O3	96.1 (11)	C17—C18—C19—C24	0.2 (9)
Cd1—O1—Cr1—O2i	−143.3 (11)	C18—C19—C20—C21	−0.6 (9)
C5—N1—C1—C2	2.4 (9)	C24—C19—C20—C21	178.9 (6)
Cd1—N1—C1—C2	−168.3 (4)	C19—C20—C21—C22	0.4 (10)
N1—C1—C2—C3	−1.4 (10)	C18—N4—C22—C21	−1.0 (10)
C1—C2—C3—C4	1.2 (10)	Cd1—N4—C22—C21	−174.6 (5)
C2—C3—C4—C5	−2.2 (9)	C20—C21—C22—N4	0.4 (11)
C2—C3—C4—C11	177.9 (6)	C15—C16—C23—C24	178.3 (7)
C1—N1—C5—C4	−3.5 (8)	C17—C16—C23—C24	0.2 (11)
Cd1—N1—C5—C4	168.3 (4)	C16—C23—C24—C19	0.0 (11)
C1—N1—C5—C6	175.1 (5)	C18—C19—C24—C23	−0.2 (10)
Cd1—N1—C5—C6	−13.1 (6)	C20—C19—C24—C23	−179.7 (6)
C3—C4—C5—N1	3.4 (9)

D—H···A	D—H	H···A	D···A	D—H···A
O5—H5A···O2ii	0.85	2.13	2.849 (6)	142
O5—H5B···O4iii	0.85	2.40	3.122 (6)	144
C2—H2···O3iv	0.93	2.49	3.274 (7)	142
C3—H3···O3iii	0.93	2.50	3.352 (8)	153
C9—H9···O3v	0.93	2.48	3.391 (7)	168
C10—H10···O3	0.93	2.55	3.478 (7)	175
C12—H12···O4ii	0.93	2.58	3.423 (7)	151
C20—H20···O5vi	0.93	2.49	3.344 (8)	152
C8—H8···Cg2ii	0.93	3.07	3.638 (7)	113
C12—H12···Cg3ii	0.93	3.03	3.277 (7)	95
C23—H23···Cg1vii	0.93	2.61	3.509 (7)	164

Table 1

Selected geometric parameters (Å, °)

Cd1—O2	2.215 (4)
Cd1—O1	2.226 (4)
Cd1—N2	2.370 (5)
Cd1—N1	2.376 (5)
Cd1—N4	2.394 (5)
Cd1—N3	2.397 (5)
O1—Cr1	1.660 (4)
O2—Cr1i	1.683 (4)
O3—Cr1	1.638 (4)
O4—Cr1	1.619 (4)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O5—H5A⋯O2ii	0.85	2.13	2.849 (6)	142
O5—H5B⋯O4iii	0.85	2.40	3.122 (6)	144
C2—H2⋯O3iv	0.93	2.49	3.274 (7)	142
C3—H3⋯O3iii	0.93	2.50	3.352 (8)	153
C9—H9⋯O3v	0.93	2.48	3.391 (7)	168
C10—H10⋯O3	0.93	2.55	3.478 (7)	175
C12—H12⋯O4ii	0.93	2.58	3.423 (7)	151
C20—H20⋯O5vi	0.93	2.49	3.344 (8)	152
C23—H23⋯Cg1vii	0.93	2.61	3.509 (7)	164

Symmetry codes: (ii) ; (iii) ; (iv) ; (v) ; (vi) ; (vii) . Cg1 is the centroid of atoms N1,C1–C5.