Bis(triphenyl-phosphine-κP)(tropolonato-κO,O')silver(I) dichloro-methane solvate.

The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.

Related literature

For general background, see: Crous et al. (2005 ▶); Dewar (1945 ▶). For structurally related oxalate derivatives, see: Dean et al. (2001 ▶). For related diketonate complexes, see: Hill & Steyl (2008 ▶); Steyl (2006 ▶).

Experimental

Crystal data

[Ag(C7H5O2)(C18H15P)2]·CH2Cl2

M = 838.45

Triclinic,

a = 12.0175 (3) Å

b = 12.9925 (4) Å

c = 13.8394 (7) Å

α = 100.487 (2)°

β = 93.760 (2)°

γ = 116.809 (1)°

V = 1869.33 (12) Å3

Z = 2

Mo Kα radiation

μ = 0.81 mm−1

T = 100 (2) K

0.19 × 0.11 × 0.08 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T min = 0.862, T max = 0.938

33544 measured reflections

8178 independent reflections

6931 reflections with I > 2σ(I)

R int = 0.046

Refinement

R[F 2 > 2σ(F 2)] = 0.030

wR(F 2) = 0.070

S = 1.05

8178 reflections

460 parameters

H-atom parameters constrained

Δρmax = 0.51 e Å−3

Δρmin = −0.41 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT-Plus (Bruker, 2007 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg & Putz, 1999 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809002785/hy2179sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809002785/hy2179Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C7H5O2)(C18H15P)2]·CH2Cl2	Z = 2
Mr = 838.45	F(000) = 856
Triclinic, P1	Dx = 1.490 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 12.0175 (3) Å	Cell parameters from 9106 reflections
b = 12.9925 (4) Å	θ = 2.3–28.3°
c = 13.8394 (7) Å	µ = 0.81 mm−1
α = 100.487 (2)°	T = 100 K
β = 93.760 (2)°	Cuboid, yellow
γ = 116.809 (1)°	0.19 × 0.11 × 0.08 mm
V = 1869.33 (12) Å3

Bruker APEXII CCD diffractometer	8178 independent reflections
Radiation source: fine-focus sealed tube	6931 reflections with I > 2σ(I)
graphite	Rint = 0.046
φ and ω scans	θmax = 27.0°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Bruker, 2001)	h = −13→15
Tmin = 0.862, Tmax = 0.938	k = −16→16
33544 measured reflections	l = −17→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.070	H-atom parameters constrained
S = 1.05	w = 1/[σ2(Fo2) + (0.0283P)2 + 0.6452P] where P = (Fo2 + 2Fc2)/3
8178 reflections	(Δ/σ)max = 0.002
460 parameters	Δρmax = 0.51 e Å−3
0 restraints	Δρmin = −0.41 e Å−3

	x	y	z	Uiso*/Ueq
Ag	0.743570 (16)	0.720243 (14)	0.744274 (12)	0.01303 (5)
P2	0.86325 (5)	0.62927 (5)	0.65456 (4)	0.01241 (12)
P1	0.71316 (5)	0.87540 (5)	0.69503 (4)	0.01207 (12)
O1	0.79674 (15)	0.70564 (14)	0.90673 (11)	0.0184 (4)
C236	0.6628 (2)	0.49295 (19)	0.49875 (17)	0.0156 (5)
H236	0.6130	0.4770	0.5501	0.019*
O2	0.57859 (15)	0.56103 (15)	0.78664 (12)	0.0223 (4)
C115	1.0246 (2)	1.1352 (2)	0.61838 (19)	0.0231 (6)
H115	1.0505	1.1622	0.5603	0.028*
C211	0.8758 (2)	0.50995 (19)	0.69797 (16)	0.0132 (5)
C131	0.6271 (2)	0.93724 (19)	0.76747 (16)	0.0134 (5)
C116	0.9035 (2)	1.0442 (2)	0.61294 (17)	0.0174 (5)
H116	0.8465	1.0099	0.5514	0.021*
C111	0.8651 (2)	1.00316 (19)	0.69726 (16)	0.0131 (5)
C132	0.6443 (2)	1.0510 (2)	0.77170 (16)	0.0160 (5)
H132	0.7057	1.1010	0.7383	0.019*
C231	0.7939 (2)	0.56327 (18)	0.52340 (16)	0.0119 (4)
C233	0.8062 (2)	0.5380 (2)	0.34768 (17)	0.0164 (5)
H233	0.8555	0.5529	0.2960	0.020*
C232	0.8649 (2)	0.58525 (19)	0.44675 (16)	0.0145 (5)
H232	0.9542	0.6329	0.4624	0.017*
C122	0.6516 (2)	0.7563 (2)	0.49517 (16)	0.0165 (5)
H122	0.7103	0.7299	0.5131	0.020*
C2	0.6043 (2)	0.5279 (2)	0.86135 (16)	0.0163 (5)
C121	0.6314 (2)	0.83422 (19)	0.56701 (16)	0.0130 (4)
C216	0.8462 (2)	0.40129 (19)	0.63496 (17)	0.0149 (5)
H216	0.8168	0.3862	0.5659	0.018*
C221	1.0266 (2)	0.73307 (19)	0.65092 (15)	0.0124 (4)
C133	0.5721 (2)	1.0925 (2)	0.82465 (17)	0.0211 (5)
H133	0.5848	1.1708	0.8280	0.025*
C235	0.6052 (2)	0.4466 (2)	0.40016 (18)	0.0187 (5)
H235	0.5160	0.3985	0.3842	0.022*
C123	0.5874 (2)	0.7175 (2)	0.39882 (17)	0.0188 (5)
H123	0.6026	0.6652	0.3507	0.023*
C226	1.0571 (2)	0.8503 (2)	0.65170 (16)	0.0155 (5)
H226	0.9939	0.8749	0.6565	0.019*
C124	0.5006 (2)	0.7547 (2)	0.37165 (17)	0.0200 (5)
H124	0.4555	0.7270	0.3054	0.024*
C136	0.5374 (2)	0.8647 (2)	0.81740 (16)	0.0170 (5)
H136	0.5262	0.7873	0.8164	0.020*
C222	1.1212 (2)	0.6993 (2)	0.64488 (17)	0.0182 (5)
H222	1.1019	0.6200	0.6452	0.022*
C215	0.8596 (2)	0.3150 (2)	0.67277 (18)	0.0191 (5)
H215	0.8393	0.2410	0.6294	0.023*
C126	0.5451 (2)	0.8718 (2)	0.53879 (17)	0.0169 (5)
H126	0.5305	0.9250	0.5864	0.020*
C114	1.1078 (2)	1.1868 (2)	0.7076 (2)	0.0233 (6)
H114	1.1902	1.2499	0.7111	0.028*
C224	1.2722 (2)	0.8965 (2)	0.63878 (18)	0.0203 (5)
H224	1.3557	0.9522	0.6344	0.024*
C112	0.9504 (2)	1.0542 (2)	0.78683 (17)	0.0183 (5)
H112	0.9258	1.0258	0.8446	0.022*
C113	1.0710 (2)	1.1464 (2)	0.79192 (19)	0.0227 (5)
H113	1.1282	1.1818	0.8533	0.027*
C223	1.2432 (2)	0.7803 (2)	0.63844 (18)	0.0203 (5)
H223	1.3068	0.7561	0.6338	0.024*
C1	0.7289 (2)	0.6063 (2)	0.92667 (16)	0.0152 (5)
C134	0.4822 (2)	1.0193 (2)	0.87219 (17)	0.0227 (6)
H134	0.4322	1.0470	0.9077	0.027*
C125	0.4804 (2)	0.8322 (2)	0.44196 (18)	0.0198 (5)
H125	0.4218	0.8585	0.4236	0.024*
C234	0.6762 (2)	0.4693 (2)	0.32393 (17)	0.0178 (5)
H234	0.6358	0.4381	0.2562	0.021*
C3	0.5113 (2)	0.4195 (2)	0.87918 (17)	0.0200 (5)
H3	0.4331	0.3847	0.8350	0.024*
C7	0.7775 (2)	0.5754 (2)	1.00616 (17)	0.0207 (5)
H7	0.8607	0.6334	1.0379	0.025*
C213	0.9307 (2)	0.4435 (2)	0.83629 (18)	0.0224 (5)
H213	0.9596	0.4579	0.9054	0.027*
C225	1.1789 (2)	0.9311 (2)	0.64553 (17)	0.0191 (5)
H225	1.1987	1.0107	0.6459	0.023*
C135	0.4643 (2)	0.9060 (2)	0.86865 (18)	0.0239 (6)
H135	0.4018	0.8560	0.9014	0.029*
C214	0.9023 (2)	0.3358 (2)	0.77313 (18)	0.0208 (5)
H214	0.9122	0.2767	0.7987	0.025*
C212	0.9173 (2)	0.5296 (2)	0.79969 (17)	0.0192 (5)
H212	0.9363	0.6028	0.8437	0.023*
C6	0.7276 (3)	0.4775 (2)	1.04662 (18)	0.0258 (6)
H6	0.7831	0.4780	1.0991	0.031*
C4	0.5130 (3)	0.3559 (2)	0.94783 (18)	0.0244 (6)
H4	0.4364	0.2854	0.9435	0.029*
C5	0.6098 (3)	0.3790 (2)	1.02256 (19)	0.0281 (6)
H5	0.5933	0.3215	1.0608	0.034*
Cl1	0.82465 (6)	0.96237 (6)	0.01672 (5)	0.03396 (16)
C01	0.9005 (3)	1.1161 (3)	0.0739 (2)	0.0347 (7)
H01A	0.8877	1.1276	0.1442	0.042*
H01B	0.9926	1.1495	0.0736	0.042*
Cl2	0.84113 (7)	1.19298 (7)	0.01169 (5)	0.03632 (17)

	U11	U22	U33	U12	U13	U23
Ag	0.01416 (9)	0.01288 (9)	0.01448 (9)	0.00751 (7)	0.00373 (7)	0.00533 (6)
P2	0.0128 (3)	0.0121 (3)	0.0143 (3)	0.0071 (2)	0.0035 (2)	0.0041 (2)
P1	0.0126 (3)	0.0120 (3)	0.0140 (3)	0.0069 (2)	0.0042 (2)	0.0046 (2)
O1	0.0174 (9)	0.0154 (8)	0.0183 (8)	0.0046 (7)	0.0003 (7)	0.0043 (7)
C236	0.0139 (12)	0.0145 (12)	0.0195 (12)	0.0066 (10)	0.0044 (9)	0.0067 (9)
O2	0.0160 (9)	0.0265 (10)	0.0211 (9)	0.0052 (8)	0.0008 (7)	0.0123 (7)
C115	0.0213 (14)	0.0205 (13)	0.0322 (14)	0.0099 (11)	0.0124 (11)	0.0135 (11)
C211	0.0109 (11)	0.0157 (12)	0.0168 (11)	0.0077 (10)	0.0054 (9)	0.0081 (9)
C131	0.0132 (11)	0.0142 (11)	0.0121 (11)	0.0068 (10)	0.0015 (9)	0.0014 (9)
C116	0.0196 (13)	0.0154 (12)	0.0200 (12)	0.0096 (10)	0.0049 (10)	0.0070 (10)
C111	0.0123 (11)	0.0113 (11)	0.0192 (11)	0.0083 (9)	0.0043 (9)	0.0039 (9)
C132	0.0171 (12)	0.0176 (12)	0.0141 (11)	0.0085 (10)	0.0021 (9)	0.0045 (9)
C231	0.0153 (11)	0.0078 (10)	0.0147 (11)	0.0072 (9)	0.0017 (9)	0.0027 (8)
C233	0.0185 (12)	0.0166 (12)	0.0179 (11)	0.0104 (10)	0.0049 (9)	0.0063 (9)
C232	0.0120 (11)	0.0120 (11)	0.0210 (12)	0.0062 (10)	0.0030 (9)	0.0056 (9)
C122	0.0170 (12)	0.0182 (12)	0.0180 (12)	0.0099 (10)	0.0054 (9)	0.0077 (9)
C2	0.0186 (12)	0.0181 (12)	0.0149 (11)	0.0102 (10)	0.0066 (9)	0.0049 (9)
C121	0.0111 (11)	0.0124 (11)	0.0145 (11)	0.0038 (9)	0.0025 (9)	0.0057 (9)
C216	0.0141 (12)	0.0159 (12)	0.0167 (11)	0.0073 (10)	0.0039 (9)	0.0071 (9)
C221	0.0128 (11)	0.0117 (11)	0.0117 (10)	0.0056 (9)	0.0012 (9)	0.0012 (8)
C133	0.0264 (14)	0.0221 (13)	0.0207 (12)	0.0179 (12)	0.0012 (10)	0.0018 (10)
C235	0.0118 (12)	0.0137 (12)	0.0262 (13)	0.0028 (10)	−0.0008 (10)	0.0048 (10)
C123	0.0219 (13)	0.0179 (12)	0.0177 (12)	0.0093 (11)	0.0072 (10)	0.0056 (10)
C226	0.0162 (12)	0.0159 (12)	0.0184 (11)	0.0105 (10)	0.0041 (9)	0.0049 (9)
C124	0.0206 (13)	0.0200 (13)	0.0155 (12)	0.0063 (11)	−0.0003 (10)	0.0054 (10)
C136	0.0189 (12)	0.0171 (12)	0.0175 (11)	0.0091 (10)	0.0067 (10)	0.0068 (9)
C222	0.0179 (12)	0.0139 (12)	0.0236 (12)	0.0088 (10)	0.0027 (10)	0.0034 (10)
C215	0.0166 (12)	0.0131 (12)	0.0274 (13)	0.0068 (10)	0.0053 (10)	0.0042 (10)
C126	0.0161 (12)	0.0144 (12)	0.0211 (12)	0.0081 (10)	0.0037 (10)	0.0036 (9)
C114	0.0138 (13)	0.0137 (12)	0.0420 (16)	0.0049 (10)	0.0077 (11)	0.0092 (11)
C224	0.0138 (12)	0.0197 (13)	0.0233 (13)	0.0045 (10)	0.0028 (10)	0.0051 (10)
C112	0.0179 (12)	0.0173 (12)	0.0216 (12)	0.0095 (11)	0.0053 (10)	0.0050 (10)
C113	0.0193 (13)	0.0171 (13)	0.0306 (14)	0.0102 (11)	−0.0020 (11)	0.0008 (10)
C223	0.0152 (12)	0.0211 (13)	0.0278 (13)	0.0113 (11)	0.0031 (10)	0.0056 (10)
C1	0.0202 (12)	0.0164 (12)	0.0128 (11)	0.0118 (10)	0.0055 (9)	0.0026 (9)
C134	0.0240 (14)	0.0336 (15)	0.0175 (12)	0.0202 (12)	0.0061 (10)	0.0033 (11)
C125	0.0161 (12)	0.0200 (13)	0.0241 (13)	0.0092 (11)	−0.0009 (10)	0.0065 (10)
C234	0.0209 (13)	0.0132 (12)	0.0178 (12)	0.0085 (10)	−0.0028 (10)	0.0008 (9)
C3	0.0211 (13)	0.0193 (13)	0.0161 (12)	0.0071 (11)	0.0045 (10)	0.0025 (10)
C7	0.0210 (13)	0.0271 (14)	0.0165 (12)	0.0131 (11)	0.0029 (10)	0.0063 (10)
C213	0.0232 (14)	0.0280 (14)	0.0205 (12)	0.0142 (12)	0.0031 (10)	0.0100 (11)
C225	0.0223 (13)	0.0136 (12)	0.0224 (12)	0.0087 (11)	0.0055 (10)	0.0052 (10)
C135	0.0216 (14)	0.0314 (15)	0.0218 (13)	0.0133 (12)	0.0095 (11)	0.0092 (11)
C214	0.0173 (13)	0.0207 (13)	0.0306 (14)	0.0107 (11)	0.0069 (11)	0.0146 (11)
C212	0.0222 (13)	0.0202 (13)	0.0182 (12)	0.0130 (11)	0.0039 (10)	0.0034 (10)
C6	0.0353 (16)	0.0388 (16)	0.0164 (12)	0.0257 (14)	0.0078 (11)	0.0134 (11)
C4	0.0320 (15)	0.0166 (13)	0.0232 (13)	0.0085 (12)	0.0139 (12)	0.0065 (10)
C5	0.0455 (18)	0.0265 (15)	0.0265 (14)	0.0234 (14)	0.0185 (13)	0.0173 (12)
Cl1	0.0284 (4)	0.0349 (4)	0.0261 (3)	0.0032 (3)	0.0014 (3)	0.0117 (3)
C01	0.0299 (16)	0.0410 (17)	0.0203 (14)	0.0081 (14)	−0.0073 (11)	0.0050 (12)
Cl2	0.0302 (4)	0.0453 (4)	0.0321 (4)	0.0184 (3)	0.0015 (3)	0.0057 (3)

Ag—O1	2.3612 (16)	C123—H123	0.9500
Ag—O2	2.3342 (16)	C226—C225	1.384 (3)
Ag—P1	2.4070 (6)	C226—H226	0.9500
Ag—P2	2.4981 (5)	C124—C125	1.384 (3)
P2—C231	1.821 (2)	C124—H124	0.9500
P2—C221	1.823 (2)	C136—C135	1.389 (3)
P2—C211	1.824 (2)	C136—H136	0.9500
P1—C131	1.820 (2)	C222—C223	1.387 (3)
P1—C111	1.825 (2)	C222—H222	0.9500
P1—C121	1.829 (2)	C215—C214	1.382 (3)
O1—C1	1.271 (3)	C215—H215	0.9500
C236—C235	1.380 (3)	C126—C125	1.385 (3)
C236—C231	1.397 (3)	C126—H126	0.9500
C236—H236	0.9500	C114—C113	1.383 (3)
O2—C2	1.261 (3)	C114—H114	0.9500
C115—C114	1.381 (4)	C224—C225	1.385 (3)
C115—C116	1.386 (3)	C224—C223	1.388 (3)
C115—H115	0.9500	C224—H224	0.9500
C211—C216	1.392 (3)	C112—C113	1.390 (3)
C211—C212	1.399 (3)	C112—H112	0.9500
C131—C132	1.386 (3)	C113—H113	0.9500
C131—C136	1.395 (3)	C223—H223	0.9500
C116—C111	1.391 (3)	C1—C7	1.414 (3)
C116—H116	0.9500	C134—C135	1.379 (3)
C111—C112	1.395 (3)	C134—H134	0.9500
C132—C133	1.393 (3)	C125—H125	0.9500
C132—H132	0.9500	C234—H234	0.9500
C231—C232	1.395 (3)	C3—C4	1.373 (3)
C233—C234	1.383 (3)	C3—H3	0.9500
C233—C232	1.390 (3)	C7—C6	1.382 (3)
C233—H233	0.9500	C7—H7	0.9500
C232—H232	0.9500	C213—C212	1.376 (3)
C122—C123	1.377 (3)	C213—C214	1.387 (3)
C122—C121	1.400 (3)	C213—H213	0.9500
C122—H122	0.9500	C225—H225	0.9500
C2—C3	1.427 (3)	C135—H135	0.9500
C2—C1	1.486 (3)	C214—H214	0.9500
C121—C126	1.391 (3)	C212—H212	0.9500
C216—C215	1.387 (3)	C6—C5	1.379 (4)
C216—H216	0.9500	C6—H6	0.9500
C221—C222	1.393 (3)	C4—C5	1.388 (4)
C221—C226	1.394 (3)	C4—H4	0.9500
C133—C134	1.378 (3)	C5—H5	0.9500
C133—H133	0.9500	Cl1—C01	1.770 (3)
C235—C234	1.390 (3)	C01—Cl2	1.768 (3)
C235—H235	0.9500	C01—H01A	0.9900
C123—C124	1.390 (3)	C01—H01B	0.9900
O2—Ag—O1	68.67 (6)	C125—C124—H124	120.3
O2—Ag—P1	121.43 (4)	C123—C124—H124	120.3
O1—Ag—P1	128.35 (4)	C135—C136—C131	119.8 (2)
O2—Ag—P2	103.97 (4)	C135—C136—H136	120.1
O1—Ag—P2	98.81 (4)	C131—C136—H136	120.1
P1—Ag—P2	122.391 (19)	C223—C222—C221	120.7 (2)
C231—P2—C221	103.35 (10)	C223—C222—H222	119.6
C231—P2—C211	103.57 (10)	C221—C222—H222	119.6
C221—P2—C211	103.62 (10)	C214—C215—C216	120.5 (2)
C231—P2—Ag	111.93 (7)	C214—C215—H215	119.8
C221—P2—Ag	114.95 (7)	C216—C215—H215	119.8
C211—P2—Ag	117.80 (7)	C125—C126—C121	120.6 (2)
C131—P1—C111	104.60 (10)	C125—C126—H126	119.7
C131—P1—C121	103.57 (10)	C121—C126—H126	119.7
C111—P1—C121	104.03 (10)	C115—C114—C113	119.9 (2)
C131—P1—Ag	118.60 (7)	C115—C114—H114	120.1
C111—P1—Ag	110.63 (7)	C113—C114—H114	120.1
C121—P1—Ag	114.02 (7)	C225—C224—C223	119.7 (2)
C1—O1—Ag	115.51 (14)	C225—C224—H224	120.1
C235—C236—C231	120.3 (2)	C223—C224—H224	120.1
C235—C236—H236	119.8	C113—C112—C111	120.3 (2)
C231—C236—H236	119.8	C113—C112—H112	119.8
C2—O2—Ag	117.18 (14)	C111—C112—H112	119.8
C114—C115—C116	120.4 (2)	C114—C113—C112	120.0 (2)
C114—C115—H115	119.8	C114—C113—H113	120.0
C116—C115—H115	119.8	C112—C113—H113	120.0
C216—C211—C212	119.0 (2)	C222—C223—C224	119.9 (2)
C216—C211—P2	123.18 (17)	C222—C223—H223	120.0
C212—C211—P2	117.83 (17)	C224—C223—H223	120.0
C132—C131—C136	119.41 (19)	O1—C1—C7	118.7 (2)
C132—C131—P1	122.58 (16)	O1—C1—C2	117.0 (2)
C136—C131—P1	117.97 (16)	C7—C1—C2	124.2 (2)
C115—C116—C111	120.2 (2)	C133—C134—C135	120.5 (2)
C115—C116—H116	119.9	C133—C134—H134	119.7
C111—C116—H116	119.9	C135—C134—H134	119.7
C116—C111—C112	119.1 (2)	C124—C125—C126	120.4 (2)
C116—C111—P1	123.35 (18)	C124—C125—H125	119.8
C112—C111—P1	117.30 (17)	C126—C125—H125	119.8
C131—C132—C133	120.4 (2)	C233—C234—C235	119.3 (2)
C131—C132—H132	119.8	C233—C234—H234	120.3
C133—C132—H132	119.8	C235—C234—H234	120.3
C232—C231—C236	118.8 (2)	C4—C3—C2	132.4 (2)
C232—C231—P2	122.87 (17)	C4—C3—H3	113.8
C236—C231—P2	118.21 (16)	C2—C3—H3	113.8
C234—C233—C232	120.3 (2)	C6—C7—C1	132.6 (2)
C234—C233—H233	119.8	C6—C7—H7	113.7
C232—C233—H233	119.8	C1—C7—H7	113.7
C233—C232—C231	120.5 (2)	C212—C213—C214	120.5 (2)
C233—C232—H232	119.8	C212—C213—H213	119.7
C231—C232—H232	119.8	C214—C213—H213	119.7
C123—C122—C121	120.7 (2)	C226—C225—C224	120.4 (2)
C123—C122—H122	119.6	C226—C225—H225	119.8
C121—C122—H122	119.6	C224—C225—H225	119.8
O2—C2—C3	118.2 (2)	C134—C135—C136	120.2 (2)
O2—C2—C1	117.6 (2)	C134—C135—H135	119.9
C3—C2—C1	124.2 (2)	C136—C135—H135	119.9
C126—C121—C122	118.5 (2)	C215—C214—C213	119.5 (2)
C126—C121—P1	123.10 (16)	C215—C214—H214	120.2
C122—C121—P1	118.31 (17)	C213—C214—H214	120.2
C215—C216—C211	120.2 (2)	C213—C212—C211	120.3 (2)
C215—C216—H216	119.9	C213—C212—H212	119.8
C211—C216—H216	119.9	C211—C212—H212	119.8
C222—C221—C226	118.8 (2)	C5—C6—C7	130.0 (3)
C222—C221—P2	122.69 (17)	C5—C6—H6	115.0
C226—C221—P2	118.54 (16)	C7—C6—H6	115.0
C134—C133—C132	119.6 (2)	C3—C4—C5	129.8 (2)
C134—C133—H133	120.2	C3—C4—H4	115.1
C132—C133—H133	120.2	C5—C4—H4	115.1
C236—C235—C234	120.8 (2)	C6—C5—C4	126.3 (2)
C236—C235—H235	119.6	C6—C5—H5	116.9
C234—C235—H235	119.6	C4—C5—H5	116.9
C122—C123—C124	120.3 (2)	Cl2—C01—Cl1	111.60 (15)
C122—C123—H123	119.8	Cl2—C01—H01A	109.3
C124—C123—H123	119.8	Cl1—C01—H01A	109.3
C225—C226—C221	120.5 (2)	Cl2—C01—H01B	109.3
C225—C226—H226	119.7	Cl1—C01—H01B	109.3
C221—C226—H226	119.7	H01A—C01—H01B	108.0
C125—C124—C123	119.4 (2)
O2—Ag—P2—C231	83.92 (9)	C131—P1—C121—C126	13.0 (2)
O1—Ag—P2—C231	153.99 (8)	C111—P1—C121—C126	−96.14 (19)
P1—Ag—P2—C231	−58.66 (8)	Ag—P1—C121—C126	143.27 (17)
O2—Ag—P2—C221	−158.57 (9)	C131—P1—C121—C122	−163.60 (17)
O1—Ag—P2—C221	−88.49 (9)	C111—P1—C121—C122	87.28 (18)
P1—Ag—P2—C221	58.85 (8)	Ag—P1—C121—C122	−33.31 (19)
O2—Ag—P2—C211	−35.96 (10)	C212—C211—C216—C215	−0.9 (3)
O1—Ag—P2—C211	34.11 (10)	P2—C211—C216—C215	179.11 (16)
P1—Ag—P2—C211	−178.54 (9)	C231—P2—C221—C222	−86.0 (2)
O2—Ag—P1—C131	44.96 (10)	C211—P2—C221—C222	21.8 (2)
O1—Ag—P1—C131	−41.59 (10)	Ag—P2—C221—C222	151.70 (16)
P2—Ag—P1—C131	−178.76 (8)	C231—P2—C221—C226	92.32 (18)
O2—Ag—P1—C111	165.75 (9)	C211—P2—C221—C226	−159.88 (17)
O1—Ag—P1—C111	79.20 (9)	Ag—P2—C221—C226	−29.94 (19)
P2—Ag—P1—C111	−57.97 (8)	C131—C132—C133—C134	−0.7 (4)
O2—Ag—P1—C121	−77.42 (9)	C231—C236—C235—C234	−0.3 (3)
O1—Ag—P1—C121	−163.97 (8)	C121—C122—C123—C124	−0.5 (3)
P2—Ag—P1—C121	58.86 (8)	C222—C221—C226—C225	0.7 (3)
O2—Ag—O1—C1	17.65 (14)	P2—C221—C226—C225	−177.75 (17)
P1—Ag—O1—C1	131.53 (13)	C122—C123—C124—C125	0.9 (3)
P2—Ag—O1—C1	−83.99 (14)	C132—C131—C136—C135	1.5 (3)
O1—Ag—O2—C2	−15.03 (15)	P1—C131—C136—C135	−176.21 (19)
P1—Ag—O2—C2	−137.85 (14)	C226—C221—C222—C223	−0.8 (3)
P2—Ag—O2—C2	79.12 (15)	P2—C221—C222—C223	177.51 (18)
C231—P2—C211—C216	5.0 (2)	C211—C216—C215—C214	0.0 (3)
C221—P2—C211—C216	−102.68 (19)	C122—C121—C126—C125	0.4 (3)
Ag—P2—C211—C216	129.12 (16)	P1—C121—C126—C125	−176.20 (18)
C231—P2—C211—C212	−175.02 (17)	C116—C115—C114—C113	1.0 (4)
C221—P2—C211—C212	77.34 (18)	C116—C111—C112—C113	1.3 (3)
Ag—P2—C211—C212	−50.86 (19)	P1—C111—C112—C113	175.55 (17)
C111—P1—C131—C132	30.9 (2)	C115—C114—C113—C112	−0.1 (3)
C121—P1—C131—C132	−77.8 (2)	C111—C112—C113—C114	−1.1 (3)
Ag—P1—C131—C132	154.70 (17)	C221—C222—C223—C224	0.5 (4)
C111—P1—C131—C136	−151.45 (18)	C225—C224—C223—C222	0.0 (4)
C121—P1—C131—C136	99.85 (19)	Ag—O1—C1—C7	158.97 (15)
Ag—P1—C131—C136	−27.6 (2)	Ag—O1—C1—C2	−18.7 (2)
C114—C115—C116—C111	−0.7 (3)	O2—C2—C1—O1	5.2 (3)
C115—C116—C111—C112	−0.4 (3)	C3—C2—C1—O1	−173.26 (19)
C115—C116—C111—P1	−174.29 (17)	O2—C2—C1—C7	−172.4 (2)
C131—P1—C111—C116	−113.66 (19)	C3—C2—C1—C7	9.2 (3)
C121—P1—C111—C116	−5.3 (2)	C132—C133—C134—C135	0.8 (4)
Ag—P1—C111—C116	117.54 (17)	C123—C124—C125—C126	−0.6 (4)
C131—P1—C111—C112	72.36 (18)	C121—C126—C125—C124	0.0 (4)
C121—P1—C111—C112	−179.28 (16)	C232—C233—C234—C235	−1.0 (3)
Ag—P1—C111—C112	−56.44 (17)	C236—C235—C234—C233	0.9 (3)
C136—C131—C132—C133	−0.5 (3)	O2—C2—C3—C4	174.6 (2)
P1—C131—C132—C133	177.16 (18)	C1—C2—C3—C4	−7.0 (4)
C235—C236—C231—C232	−0.2 (3)	O1—C1—C7—C6	178.7 (2)
C235—C236—C231—P2	176.33 (17)	C2—C1—C7—C6	−3.8 (4)
C221—P2—C231—C232	6.6 (2)	C221—C226—C225—C224	−0.2 (3)
C211—P2—C231—C232	−101.18 (19)	C223—C224—C225—C226	−0.1 (4)
Ag—P2—C231—C232	130.91 (16)	C133—C134—C135—C136	0.3 (4)
C221—P2—C231—C236	−169.69 (17)	C131—C136—C135—C134	−1.5 (4)
C211—P2—C231—C236	82.48 (18)	C216—C215—C214—C213	0.6 (3)
Ag—P2—C231—C236	−45.43 (19)	C212—C213—C214—C215	−0.4 (3)
C234—C233—C232—C231	0.6 (3)	C214—C213—C212—C211	−0.5 (3)
C236—C231—C232—C233	0.0 (3)	C216—C211—C212—C213	1.2 (3)
P2—C231—C232—C233	−176.29 (17)	P2—C211—C212—C213	−178.86 (17)
Ag—O2—C2—C3	−169.93 (14)	C1—C7—C6—C5	−2.5 (4)
Ag—O2—C2—C1	11.5 (2)	C2—C3—C4—C5	−0.4 (4)
C123—C122—C121—C126	−0.1 (3)	C7—C6—C5—C4	1.3 (4)
C123—C122—C121—P1	176.62 (17)	C3—C4—C5—C6	2.8 (4)

Ag—O1	2.3612 (16)
Ag—O2	2.3342 (16)
Ag—P1	2.4070 (6)
Ag—P2	2.4981 (5)

O2—Ag—O1	68.67 (6)
O2—Ag—P1	121.43 (4)
O1—Ag—P1	128.35 (4)
O2—Ag—P2	103.97 (4)
O1—Ag—P2	98.81 (4)
P1—Ag—P2	122.391 (19)