Literature DB >> 21581821

Bis{2-formyl-4-methyl-6-[(tri-2-pyridyl-meth-yl)imino-meth-yl]phenolato}nickel(II).

Yan-Qiu Dang, Hong-Jun Yang, Lai-Jin Tian.   

Abstract

The title compound, [Ni(C(25)H(19)N(4)O(2))(2)], which was obtained by the reaction of nickel(II) perchlorate with 2,6-diformyl-4-methyl-phenol and (tri-2-pyridylmeth-yl)amine in methanol solution, is a discrete monometallic complex. The Ni(II) atom is six-coordinated by the phenolate O, imine N and pyridine N atoms from two tridentate Schiff base ligands in a distorted NiN(4)O(2) octa-hedral geometry. The dihedral angles between the noncoordinated pyridyl rings of each ligand are 72.95 (8) and 69.59 (7)°.

Entities:  

Year:  2009        PMID: 21581821      PMCID: PMC2968412          DOI: 10.1107/S160053680900244X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  3 in total

1.  Metal-free methods in the synthesis of macrocyclic schiff bases.

Authors:  Nataliya E Borisova; Marina D Reshetova; Yuri A Ustynyuk
Journal:  Chem Rev       Date:  2007-01       Impact factor: 60.622

2.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

3.  2-pyrrolylthiones as monoanionic bidentate N,S-chelators: synthesis and molecular structure of 2-pyrrolylthionato complexes of nickel(II), cobalt(III), and mercury(II).

Authors:  C Brückner; S J Rettig; D Dolphin
Journal:  Inorg Chem       Date:  2000-12-25       Impact factor: 5.165

  3 in total
  1 in total

1.  cis-Bis{(E)-2-[(2-fluoro-phen-yl)imino-meth-yl]phenolato-κ(2) N,O}bis-(pyridine-κN)nickel(II).

Authors:  Marcela C G Souza; Leonardo da C Ferreira; Nadia M Comerlato; Glaucio B Ferreira; Lorenzo do Canto Visentin
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-10
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.