{6,6'-Dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}cobalt(II) dichloro-methane disolvate.

The title compound, [Co(C(22)H(18)N(2)O(4))]·2CH(2)Cl(2), was isolated from the reaction of N,N'(o-phenyl-ene)bis-(vanillalimine) (H(2)L) with Co(SCN)(2). The crystal structure contains a Co(II) ion surrounded by the L(2-) ligand in a slightly distorted square-planar fashion. Inter-molecular C-H⋯O hydrogen-bonding contacts between the dichloro-methane solvent mol-ecules and the meth-oxy or carboxyl-ate O atoms are observed in the crystal structure. The planar complex mol-ecules stack through inversion related π-π inter-actions between the six-membered rings of the vanillalimine half ligands. The distance between centroids is 3.498 (2) Å and the perpendicular distance is 3.345 Å. A partial stacking is observed with a centroid-centroid distance of 3.830 (2) Å, a perpendicular distance of 3.350 Å and a slippage of 1.856 Å.

Related literature

For general background, see: Cotton et al. (1999 ▶); Liu et al. (2007 ▶); Sharghi & Al Nasseri (2003 ▶). For related structures, see: Pahor et al. (1976 ▶). For related properties, see: Bella et al. (1995 ▶).

Experimental

Crystal data

[Co(C22H18N2O4)]·2CH2Cl2

M = 603.19

Monoclinic,

a = 13.309 (6) Å

b = 14.088 (6) Å

c = 14.101 (6) Å

β = 109.676 (6)°

V = 2489.4 (19) Å3

Z = 4

Mo Kα radiation

μ = 1.15 mm−1

T = 150 (1) K

0.50 × 0.30 × 0.10 mm

Data collection

Rigaku Mercury diffractometer

Absorption correction: multi-scan (REQAB; Jacobson, 1998 ▶) T min = 0.764, T max = 0.891

28457 measured reflections

5677 independent reflections

5100 reflections with F 2 > 2σ(F 2)

R int = 0.040

Refinement

R[F 2 > 2σ(F 2)] = 0.046

wR(F 2) = 0.089

S = 1.15

5677 reflections

317 parameters

H-atom parameters constrained

Δρmax = 0.53 e Å−3

Δρmin = −0.66 e Å−3

Data collection: CrystalClear (Rigaku/MSC, 2007 ▶); cell refinement: CrystalClear; data reduction: CrystalStructure (Rigaku/MSC, 2007 ▶); program(s) used to solve structure: SIR97 (Altomare et al., 1999 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEPII (Johnson, 1976 ▶); software used to prepare material for publication: CrystalStructure.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053680900083X/si2147sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053680900083X/si2147Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Co(C22H18N2O4)]·2CH2Cl2	F(000) = 1228.00
Mr = 603.19	Dx = 1.609 Mg m−3
Monoclinic, P21/a	Mo Kα radiation, λ = 0.71070 Å
Hall symbol: -P 2yab	Cell parameters from 6959 reflections
a = 13.309 (6) Å	θ = 3.1–27.5°
b = 14.088 (6) Å	µ = 1.15 mm−1
c = 14.101 (6) Å	T = 150 K
β = 109.676 (6)°	Block, brown
V = 2489.4 (19) Å3	0.50 × 0.30 × 0.10 mm
Z = 4

Rigaku Mercury diffractometer	5100 reflections with F2 > 2σ(F2)
Detector resolution: 7.31 pixels mm-1	Rint = 0.040
ω scans	θmax = 27.5°
Absorption correction: multi-scan (REQAB; Jacobson, 1998)	h = −17→17
Tmin = 0.764, Tmax = 0.891	k = −18→17
28457 measured reflections	l = −18→18
5677 independent reflections

Refinement on F2	H-atom parameters constrained
R[F2 > 2σ(F2)] = 0.046	w = 1/[σ2(Fo2) + (0.0308P)2 + 1.9552P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.089	(Δ/σ)max < 0.001
S = 1.15	Δρmax = 0.53 e Å−3
5677 reflections	Δρmin = −0.66 e Å−3
317 parameters

Geometry. The planar CoII complex has non-crystallographic mm2 symmetry.

Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).

	x	y	z	Uiso*/Ueq
Co1	0.13131 (2)	0.19517 (2)	0.52772 (2)	0.01696 (7)
Cl1	0.44427 (5)	0.14026 (5)	0.68960 (5)	0.03951 (16)
Cl2	0.47220 (7)	0.09420 (8)	0.89664 (6)	0.0672 (2)
Cl3	0.21820 (7)	0.13146 (7)	0.96127 (7)	0.0621 (2)
Cl4	−0.00594 (6)	0.12289 (5)	0.83886 (6)	0.04414 (17)
O1	0.17603 (12)	0.26802 (11)	0.64445 (11)	0.0208 (3)
O2	0.16176 (12)	0.08953 (10)	0.61189 (11)	0.0208 (3)
O3	0.24984 (13)	0.33830 (12)	0.82700 (11)	0.0269 (3)
O4	0.21621 (14)	−0.03363 (12)	0.75913 (12)	0.0310 (3)
N1	0.09468 (14)	0.30090 (13)	0.44144 (13)	0.0186 (3)
N2	0.09571 (14)	0.12300 (13)	0.40921 (13)	0.0186 (3)
C1	0.05949 (17)	0.27635 (16)	0.33749 (16)	0.0202 (4)
C2	0.06502 (17)	0.17945 (16)	0.32009 (16)	0.0207 (4)
C3	0.04319 (19)	0.14651 (18)	0.22208 (17)	0.0277 (5)
C4	0.0107 (2)	0.2098 (2)	0.14228 (18)	0.0329 (5)
C5	−0.00149 (19)	0.3053 (2)	0.15966 (18)	0.0315 (5)
C6	0.02351 (19)	0.33956 (18)	0.25698 (18)	0.0273 (5)
C7	0.10471 (17)	0.39009 (16)	0.46840 (17)	0.0218 (4)
C8	0.14351 (17)	0.42339 (16)	0.56916 (17)	0.0210 (4)
C9	0.14867 (19)	0.52326 (16)	0.58418 (19)	0.0271 (5)
C10	0.1866 (2)	0.56020 (17)	0.6785 (2)	0.0301 (5)
C11	0.22151 (19)	0.49922 (17)	0.76248 (19)	0.0279 (5)
C12	0.21817 (17)	0.40256 (16)	0.74993 (17)	0.0215 (4)
C13	0.17848 (17)	0.36031 (15)	0.65197 (16)	0.0187 (4)
C14	0.2753 (2)	0.3763 (2)	0.92607 (18)	0.0356 (6)
C15	0.09237 (17)	0.03043 (17)	0.40283 (17)	0.0226 (4)
C16	0.12100 (17)	−0.03338 (16)	0.48546 (17)	0.0206 (4)
C17	0.11515 (19)	−0.13206 (16)	0.46470 (19)	0.0261 (5)
C18	0.14356 (19)	−0.19674 (17)	0.5414 (2)	0.0293 (5)
C19	0.17852 (19)	−0.16544 (17)	0.64144 (19)	0.0270 (5)
C20	0.18411 (18)	−0.07012 (16)	0.66371 (17)	0.0227 (4)
C21	0.15525 (17)	0.00007 (15)	0.58599 (16)	0.0193 (4)
C22	0.2476 (2)	−0.09938 (19)	0.84100 (19)	0.0353 (6)
C23	0.38345 (19)	0.14048 (19)	0.78310 (18)	0.0298 (5)
C24	0.1234 (2)	0.1508 (2)	0.8408 (2)	0.0408 (6)
H3	0.0505	0.0810	0.2100	0.033*
H4	−0.0033	0.1877	0.0754	0.039*
H5	−0.0272	0.3476	0.1043	0.038*
H6	0.0162	0.4052	0.2687	0.033*
H7	0.0844	0.4363	0.4164	0.026*
H9	0.1254	0.5646	0.5277	0.033*
H10	0.1896	0.6271	0.6879	0.036*
H11	0.2476	0.5253	0.8284	0.034*
H14A	0.2969	0.3247	0.9754	0.043*
H14B	0.2125	0.4084	0.9323	0.043*
H14C	0.3339	0.4219	0.9385	0.043*
H15	0.0687	0.0036	0.3372	0.027*
H17	0.0912	−0.1534	0.3968	0.031*
H18	0.1396	−0.2628	0.5268	0.035*
H19	0.1986	−0.2106	0.6946	0.032*
H22A	0.2687	−0.0645	0.9049	0.042*
H22B	0.3081	−0.1372	0.8375	0.042*
H22C	0.1877	−0.1415	0.8368	0.042*
H23A	0.3633	0.2061	0.7942	0.036*
H23B	0.3177	0.1015	0.7605	0.036*
H24A	0.1258	0.2182	0.8216	0.049*
H24B	0.1414	0.1111	0.7908	0.049*

	U11	U22	U33	U12	U13	U23
Co1	0.02030 (15)	0.01570 (15)	0.01475 (14)	0.00061 (12)	0.00574 (11)	0.00093 (11)
Cl1	0.0392 (3)	0.0514 (4)	0.0337 (3)	0.0015 (3)	0.0199 (2)	0.0022 (3)
Cl2	0.0516 (4)	0.1169 (8)	0.0295 (3)	0.0179 (5)	0.0088 (3)	0.0173 (4)
Cl3	0.0503 (4)	0.0594 (5)	0.0615 (5)	0.0012 (4)	−0.0009 (3)	0.0198 (4)
Cl4	0.0392 (3)	0.0473 (4)	0.0512 (4)	−0.0109 (3)	0.0223 (3)	−0.0102 (3)
O1	0.0281 (8)	0.0165 (7)	0.0177 (7)	0.0011 (6)	0.0075 (6)	0.0001 (6)
O2	0.0258 (8)	0.0177 (7)	0.0178 (7)	−0.0001 (6)	0.0062 (6)	0.0002 (6)
O3	0.0367 (9)	0.0249 (8)	0.0172 (7)	0.0024 (7)	0.0066 (6)	−0.0028 (6)
O4	0.0449 (10)	0.0263 (9)	0.0203 (8)	0.0014 (7)	0.0089 (7)	0.0072 (6)
N1	0.0183 (8)	0.0200 (9)	0.0176 (8)	0.0018 (7)	0.0064 (7)	0.0030 (7)
N2	0.0185 (8)	0.0214 (9)	0.0160 (8)	0.0001 (7)	0.0059 (6)	0.0011 (7)
C1	0.0170 (10)	0.0269 (11)	0.0164 (10)	−0.0008 (8)	0.0050 (8)	0.0029 (8)
C2	0.0172 (10)	0.0277 (12)	0.0168 (10)	−0.0018 (8)	0.0051 (8)	0.0024 (8)
C3	0.0299 (12)	0.0314 (13)	0.0199 (11)	−0.0034 (10)	0.0061 (9)	−0.0020 (9)
C4	0.0300 (13)	0.0490 (16)	0.0174 (11)	−0.0070 (11)	0.0049 (9)	0.0015 (10)
C5	0.0289 (12)	0.0431 (15)	0.0197 (11)	−0.0016 (11)	0.0046 (9)	0.0106 (10)
C6	0.0264 (12)	0.0315 (12)	0.0236 (11)	0.0013 (10)	0.0077 (9)	0.0068 (10)
C7	0.0212 (10)	0.0225 (11)	0.0223 (11)	0.0021 (9)	0.0082 (8)	0.0062 (8)
C8	0.0193 (10)	0.0189 (11)	0.0269 (11)	0.0006 (8)	0.0104 (9)	0.0006 (9)
C9	0.0289 (12)	0.0197 (11)	0.0326 (13)	0.0016 (9)	0.0103 (10)	0.0029 (9)
C10	0.0347 (13)	0.0162 (11)	0.0401 (14)	−0.0005 (10)	0.0135 (11)	−0.0049 (10)
C11	0.0282 (12)	0.0244 (12)	0.0312 (12)	−0.0008 (10)	0.0099 (10)	−0.0094 (10)
C12	0.0205 (10)	0.0224 (11)	0.0230 (10)	0.0011 (9)	0.0090 (8)	−0.0016 (9)
C13	0.0168 (10)	0.0188 (11)	0.0220 (10)	0.0008 (8)	0.0084 (8)	−0.0006 (8)
C14	0.0459 (15)	0.0377 (14)	0.0208 (11)	0.0024 (12)	0.0078 (11)	−0.0074 (10)
C15	0.0211 (11)	0.0250 (11)	0.0224 (11)	−0.0022 (9)	0.0083 (8)	−0.0042 (9)
C16	0.0183 (10)	0.0208 (11)	0.0236 (10)	−0.0014 (8)	0.0084 (8)	−0.0010 (9)
C17	0.0270 (12)	0.0207 (11)	0.0321 (12)	−0.0029 (9)	0.0119 (10)	−0.0066 (9)
C18	0.0299 (13)	0.0179 (11)	0.0429 (14)	−0.0014 (10)	0.0162 (11)	−0.0013 (10)
C19	0.0283 (12)	0.0192 (11)	0.0361 (13)	0.0025 (9)	0.0141 (10)	0.0089 (9)
C20	0.0205 (11)	0.0223 (11)	0.0267 (11)	0.0007 (9)	0.0099 (9)	0.0044 (9)
C21	0.0167 (10)	0.0169 (10)	0.0252 (11)	0.0004 (8)	0.0084 (8)	0.0011 (8)
C22	0.0393 (14)	0.0388 (15)	0.0277 (12)	0.0043 (12)	0.0109 (11)	0.0156 (11)
C23	0.0251 (12)	0.0379 (14)	0.0265 (12)	−0.0005 (10)	0.0090 (9)	−0.0011 (10)
C24	0.0342 (14)	0.0486 (17)	0.0425 (15)	0.0010 (13)	0.0169 (12)	0.0072 (13)

Co1—O1	1.8593 (15)	C12—C13	1.432 (3)
Co1—O2	1.8611 (14)	C15—C16	1.418 (3)
Co1—N1	1.8807 (17)	C16—C17	1.417 (3)
Co1—N2	1.8755 (18)	C16—C21	1.416 (3)
Cl1—C23	1.764 (3)	C17—C18	1.366 (3)
Cl2—C23	1.764 (2)	C18—C19	1.400 (3)
Cl3—C24	1.764 (2)	C19—C20	1.375 (3)
Cl4—C24	1.757 (3)	C20—C21	1.429 (3)
O1—C13	1.304 (2)	C3—H3	0.950
O2—C21	1.307 (2)	C4—H4	0.950
O3—C12	1.367 (2)	C5—H5	0.950
O3—C14	1.426 (2)	C6—H6	0.950
O4—C20	1.367 (2)	C7—H7	0.950
O4—C22	1.428 (3)	C9—H9	0.950
N1—C1	1.423 (2)	C10—H10	0.950
N1—C7	1.306 (2)	C11—H11	0.950
N2—C2	1.426 (2)	C14—H14A	0.980
N2—C15	1.307 (3)	C14—H14B	0.980
C1—C2	1.393 (3)	C14—H14C	0.980
C1—C6	1.395 (3)	C15—H15	0.950
C2—C3	1.393 (3)	C17—H17	0.950
C3—C4	1.386 (3)	C18—H18	0.950
C4—C5	1.386 (3)	C19—H19	0.950
C5—C6	1.386 (3)	C22—H22A	0.980
C7—C8	1.418 (3)	C22—H22B	0.980
C8—C9	1.421 (3)	C22—H22C	0.980
C8—C13	1.416 (3)	C23—H23A	0.990
C9—C10	1.358 (3)	C23—H23B	0.990
C10—C11	1.409 (3)	C24—H24A	0.990
C11—C12	1.372 (3)	C24—H24B	0.990
O1—Co1—O2	86.60 (6)	O2—C21—C20	118.52 (19)
O1—Co1—N1	94.10 (7)	C16—C21—C20	116.76 (19)
O1—Co1—N2	175.97 (8)	Cl1—C23—Cl2	110.01 (14)
O2—Co1—N1	177.70 (7)	Cl3—C24—Cl4	111.07 (18)
O2—Co1—N2	94.02 (7)	C2—C3—H3	120.2
N1—Co1—N2	85.43 (7)	C4—C3—H3	120.2
Co1—O1—C13	127.89 (13)	C3—C4—H4	119.9
Co1—O2—C21	127.82 (13)	C5—C4—H4	119.9
C12—O3—C14	115.96 (18)	C4—C5—H5	119.7
C20—O4—C22	117.44 (18)	C6—C5—H5	119.7
Co1—N1—C1	113.43 (14)	C1—C6—H6	120.5
Co1—N1—C7	126.48 (14)	C5—C6—H6	120.5
C1—N1—C7	119.96 (18)	N1—C7—H7	117.4
Co1—N2—C2	113.23 (14)	C8—C7—H7	117.4
Co1—N2—C15	126.50 (15)	C8—C9—H9	119.7
C2—N2—C15	120.19 (18)	C10—C9—H9	119.7
N1—C1—C2	113.64 (18)	C9—C10—H10	120.1
N1—C1—C6	125.9 (2)	C11—C10—H10	120.1
C2—C1—C6	120.4 (2)	C10—C11—H11	119.7
N2—C2—C1	114.06 (19)	C12—C11—H11	119.7
N2—C2—C3	126.2 (2)	O3—C14—H14A	109.5
C1—C2—C3	119.7 (2)	O3—C14—H14B	109.5
C2—C3—C4	119.7 (2)	O3—C14—H14C	109.5
C3—C4—C5	120.3 (2)	H14A—C14—H14B	109.5
C4—C5—C6	120.7 (2)	H14A—C14—H14C	109.5
C1—C6—C5	119.1 (2)	H14B—C14—H14C	109.5
N1—C7—C8	125.2 (2)	N2—C15—H15	117.2
C7—C8—C9	117.4 (2)	C16—C15—H15	117.2
C7—C8—C13	121.8 (2)	C16—C17—H17	119.7
C9—C8—C13	120.8 (2)	C18—C17—H17	119.7
C8—C9—C10	120.6 (2)	C17—C18—H18	120.1
C9—C10—C11	119.9 (2)	C19—C18—H18	120.1
C10—C11—C12	120.6 (2)	C18—C19—H19	119.6
O3—C12—C11	124.5 (2)	C20—C19—H19	119.6
O3—C12—C13	113.98 (18)	O4—C22—H22A	109.5
C11—C12—C13	121.5 (2)	O4—C22—H22B	109.5
O1—C13—C8	124.51 (19)	O4—C22—H22C	109.5
O1—C13—C12	118.94 (18)	H22A—C22—H22B	109.5
C8—C13—C12	116.54 (19)	H22A—C22—H22C	109.5
N2—C15—C16	125.6 (2)	H22B—C22—H22C	109.5
C15—C16—C17	118.1 (2)	Cl1—C23—H23A	109.7
C15—C16—C21	121.2 (2)	Cl1—C23—H23B	109.7
C17—C16—C21	120.7 (2)	Cl2—C23—H23A	109.7
C16—C17—C18	120.6 (2)	Cl2—C23—H23B	109.7
C17—C18—C19	119.8 (2)	H23A—C23—H23B	108.2
C18—C19—C20	120.8 (2)	Cl3—C24—H24A	109.4
O4—C20—C19	124.5 (2)	Cl3—C24—H24B	109.4
O4—C20—C21	114.12 (19)	Cl4—C24—H24A	109.4
C19—C20—C21	121.4 (2)	Cl4—C24—H24B	109.4
O2—C21—C16	124.72 (19)	H24A—C24—H24B	108.0
O1—Co1—O2—C21	−176.86 (19)	N2—C2—C3—C4	177.9 (2)
O2—Co1—O1—C13	−178.94 (19)	C1—C2—C3—C4	−3.4 (3)
O1—Co1—N1—C1	176.77 (15)	C2—C3—C4—C5	−0.9 (3)
O1—Co1—N1—C7	1.0 (2)	C3—C4—C5—C6	3.2 (4)
N1—Co1—O1—C13	−1.1 (2)	C4—C5—C6—C1	−1.1 (3)
O2—Co1—N2—C2	179.84 (15)	N1—C7—C8—C9	−179.9 (2)
O2—Co1—N2—C15	3.2 (2)	N1—C7—C8—C13	1.7 (3)
N2—Co1—O2—C21	−0.85 (19)	C7—C8—C9—C10	−178.9 (2)
N1—Co1—N2—C2	2.08 (15)	C7—C8—C13—O1	−1.9 (3)
N1—Co1—N2—C15	−174.6 (2)	C7—C8—C13—C12	178.6 (2)
N2—Co1—N1—C1	0.78 (16)	C9—C8—C13—O1	179.8 (2)
N2—Co1—N1—C7	−175.0 (2)	C9—C8—C13—C12	0.3 (3)
Co1—O1—C13—C8	1.8 (3)	C13—C8—C9—C10	−0.5 (3)
Co1—O1—C13—C12	−178.74 (16)	C8—C9—C10—C11	0.2 (3)
Co1—O2—C21—C16	−1.1 (3)	C9—C10—C11—C12	0.4 (4)
Co1—O2—C21—C20	179.16 (16)	C10—C11—C12—O3	−179.6 (2)
C14—O3—C12—C11	7.9 (3)	C10—C11—C12—C13	−0.6 (3)
C14—O3—C12—C13	−171.2 (2)	O3—C12—C13—O1	−0.1 (2)
C22—O4—C20—C19	1.1 (3)	O3—C12—C13—C8	179.4 (2)
C22—O4—C20—C21	−179.3 (2)	C11—C12—C13—O1	−179.3 (2)
Co1—N1—C1—C2	−3.6 (2)	C11—C12—C13—C8	0.3 (3)
Co1—N1—C1—C6	177.4 (2)	N2—C15—C16—C17	−178.4 (2)
Co1—N1—C7—C8	−1.4 (3)	N2—C15—C16—C21	1.2 (3)
C1—N1—C7—C8	−177.0 (2)	C15—C16—C17—C18	178.8 (2)
C7—N1—C1—C2	172.6 (2)	C15—C16—C21—O2	1.3 (3)
C7—N1—C1—C6	−6.5 (3)	C15—C16—C21—C20	−178.9 (2)
Co1—N2—C2—C1	−4.6 (2)	C17—C16—C21—O2	−179.1 (2)
Co1—N2—C2—C3	174.2 (2)	C17—C16—C21—C20	0.7 (3)
Co1—N2—C15—C16	−3.7 (3)	C21—C16—C17—C18	−0.7 (3)
C2—N2—C15—C16	179.8 (2)	C16—C17—C18—C19	0.2 (3)
C15—N2—C2—C1	172.3 (2)	C17—C18—C19—C20	0.4 (4)
C15—N2—C2—C3	−8.9 (3)	C18—C19—C20—O4	179.3 (2)
N1—C1—C2—N2	5.3 (2)	C18—C19—C20—C21	−0.4 (3)
N1—C1—C2—C3	−173.6 (2)	O4—C20—C21—O2	−0.0 (2)
N1—C1—C6—C5	175.8 (2)	O4—C20—C21—C16	−179.8 (2)
C2—C1—C6—C5	−3.2 (3)	C19—C20—C21—O2	179.7 (2)
C6—C1—C2—N2	−175.6 (2)	C19—C20—C21—C16	−0.1 (2)
C6—C1—C2—C3	5.5 (3)

D—H···A	D—H	H···A	D···A	D—H···A
C23—H23A···O3	0.99	2.54	3.472 (4)	158
C23—H23B···O4	0.99	2.33	3.252 (4)	154
C23—H23B···O2	0.99	2.41	3.202 (3)	137
C24—H24A···O3	0.99	2.35	3.173 (4)	140
C24—H24B···O4	0.99	2.38	3.250 (4)	147

Table 1

Selected bond lengths (Å)

Co1—O1	1.8593 (15)
Co1—O2	1.8611 (14)
Co1—N1	1.8807 (17)
Co1—N2	1.8755 (18)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C23—H23A⋯O3	0.99	2.54	3.472 (4)	158
C23—H23B⋯O4	0.99	2.33	3.252 (4)	154
C23—H23B⋯O2	0.99	2.41	3.202 (3)	137
C24—H24A⋯O3	0.99	2.35	3.173 (4)	140
C24—H24B⋯O4	0.99	2.38	3.250 (4)	147