A novel zinc(II) complex with the ligand 2,2',2''-(1,4,7-triazanonane-1,4,7-triyl)triacetate (NOTA).

The zinc(II) complex with NOTA [2,2',2''-(1,4,7-triazanonane-1,4,7-triyl)triacetate] has previously been synthesized and studied in solution, but was not isolated. The corresponding title Zn(II) complex penta-sodium(I) bis-{[2,2',2''-(1,4,7-triazanonane-1,4,7-triyl)triacetato]zinc(II)} tris-(perchlorate) methanol solvate, Na(5)[Zn(C(12)H(18)N(3)O(6))](2)(ClO(4))(3)·CH(3)OH, was crystallized as a sodium perchlorate double salt in methano-l solution. The asymmetric unit contains two independent [Zn(NOTA)](-) complex anion entities, five sodium cations, three perchlorate anions and a methanol solvent mol-ecule. The two Zn(II) cations exhibit a distorted trigonal-prismatic N(3)O(3) coordination with a bifacial arrangement of the donor atoms. Neither the methanol solvent mol-ecule nor the perchlorate anions appear to be coordinated to the Zn centres. The crystal structure shows a layer arrangement parallel to (001) generated by inter-actions between the [Zn(NOTA)](-) units, the Na(+) cations, two ClO(4) (-) units and the methanole mol-ecule, leading to an overall layer composition of [Na(5)[Zn(C(12)H(18)N(3)O(6))](2)(ClO(4))(2) (.)CH(3)OH](+). The third ClO(4) anion is isolated and situated between the layers without any significant inter-actions.

Related literature

Details on the synthesis of NOTA are given by Desreux (1980 ▶). For NOTA complexes of Al, Cr, Fe, Co, Ni, Cu, Ga and In characterized by X-ray diffraction studies, see: Boeyens & Van der Merwe (1997 ▶); Bossek et al. (1995 ▶); Clarke & Martell (1991 ▶); Craig et al. (1989 ▶); Jyo et al. (1990 ▶); Van der Merwe et al. (1983 ▶, 1985 ▶); Moore et al. (1990 ▶); Wieghardt et al. (1982 ▶). For general background, see: Geraldes et al. (1985 ▶).

Experimental

Crystal data

Na5[Zn(C12H18N3O6)]2(ClO4)3·CH4O

M = 1176.67

Orthorhombic,

a = 16.8879 (5) Å

b = 9.4723 (3) Å

c = 26.4552 (9) Å

V = 4232.0 (2) Å3

Z = 4

Mo Kα radiation

μ = 1.47 mm−1

T = 100 (2) K

0.22 × 0.10 × 0.10 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.738, T max = 0.867

31309 measured reflections

9954 independent reflections

8605 reflections with I > 2σ(I)

R int = 0.036

Refinement

R[F 2 > 2σ(F 2)] = 0.039

wR(F 2) = 0.084

S = 1.07

9954 reflections

601 parameters

1 restraint

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.56 e Å−3

Δρmin = −0.58 e Å−3

Absolute structure: Flack (1983 ▶), 4585 Friedel pairs

Flack parameter: 0.383 (7)

Data collection: APEX2 (Bruker, 2005 ▶); cell refinement: APEX2; data reduction: SHELXTL (Sheldrick, 2008 ▶); program(s) used to solve structure: SIR92 (Altomare et al., 1993 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808041895/wm2202sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808041895/wm2202Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Na5[Zn(C12H18N3O6)]2(ClO4)3·CH4O	F(000) = 2392
Mr = 1176.67	Dx = 1.847 Mg m−3
Orthorhombic, Pna21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2c -2n	Cell parameters from 9827 reflections
a = 16.8879 (5) Å	θ = 2.4–27.7°
b = 9.4723 (3) Å	µ = 1.47 mm−1
c = 26.4552 (9) Å	T = 100 K
V = 4232.0 (2) Å3	Prism, colourless
Z = 4	0.22 × 0.10 × 0.10 mm

Bruker APEXII CCD diffractometer	9954 independent reflections
Radiation source: fine-focus sealed tube	8605 reflections with I > 2σ(I)
graphite	Rint = 0.036
ω and φ scans	θmax = 28.3°, θmin = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −21→22
Tmin = 0.738, Tmax = 0.867	k = −12→12
31309 measured reflections	l = −35→32

Refinement on F2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H atoms treated by a mixture of independent and constrained refinement
R[F2 > 2σ(F2)] = 0.039	w = 1/[σ2(Fo2) + (0.0392P)2 + 1.4688P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.084	(Δ/σ)max = 0.001
S = 1.07	Δρmax = 0.56 e Å−3
9954 reflections	Δρmin = −0.58 e Å−3
601 parameters	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
1 restraint	Extinction coefficient: 0.00024 (8)
Primary atom site location: structure-invariant direct methods	Absolute structure: Flack (1983), 4585 Friedel pairs
Secondary atom site location: difference Fourier map	Flack parameter: 0.383 (7)

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Zn1	1.07460 (2)	0.01616 (4)	0.917626 (16)	0.00860 (9)
N1	1.12568 (18)	−0.1518 (3)	0.96418 (12)	0.0120 (7)
N2	1.12185 (18)	0.1482 (3)	0.97696 (12)	0.0118 (7)
N3	0.97800 (19)	−0.0083 (3)	0.97112 (12)	0.0129 (7)
O1	1.16120 (14)	−0.0640 (3)	0.87080 (10)	0.0118 (5)
O2	1.21023 (15)	−0.2696 (3)	0.84582 (10)	0.0149 (6)
O3	1.08723 (14)	0.2045 (3)	0.87911 (10)	0.0109 (5)
O4	1.14849 (15)	0.4106 (3)	0.88043 (10)	0.0138 (6)
O5	0.98658 (14)	−0.0531 (3)	0.87180 (10)	0.0127 (6)
O6	0.85724 (14)	−0.0775 (3)	0.86305 (10)	0.0134 (6)
C1	1.1941 (2)	−0.0791 (4)	0.98715 (16)	0.0161 (8)
H1A	1.2341	−0.0596	0.9607	0.019*
H1B	1.2187	−0.1417	1.0127	0.019*
C2	1.1699 (2)	0.0601 (4)	1.01240 (15)	0.0174 (8)
H2A	1.1386	0.0398	1.0432	0.021*
H2B	1.2179	0.1128	1.0226	0.021*
C3	1.0484 (2)	0.2058 (4)	1.00086 (15)	0.0134 (8)
H3A	1.0233	0.2739	0.9774	0.016*
H3B	1.0629	0.2573	1.0321	0.016*
C4	0.9891 (2)	0.0898 (4)	1.01387 (15)	0.0169 (9)
H4A	1.0082	0.0367	1.0437	0.020*
H4B	0.9376	0.1332	1.0227	0.020*
C5	0.9838 (2)	−0.1590 (4)	0.98620 (15)	0.0157 (8)
H5A	0.9663	−0.2188	0.9576	0.019*
H5B	0.9474	−0.1764	1.0149	0.019*
C6	1.0663 (2)	−0.2020 (4)	1.00137 (14)	0.0156 (8)
H6A	1.0787	−0.1621	1.0350	0.019*
H6B	1.0692	−0.3061	1.0039	0.019*
C7	1.1508 (2)	−0.2609 (4)	0.92774 (14)	0.0152 (8)
H7A	1.1064	−0.3272	0.9217	0.018*
H7B	1.1955	−0.3151	0.9421	0.018*
C8	1.1760 (2)	−0.1946 (4)	0.87764 (14)	0.0095 (7)
C9	1.1674 (2)	0.2606 (4)	0.95153 (14)	0.0140 (8)
H9A	1.2228	0.2292	0.9470	0.017*
H9B	1.1678	0.3460	0.9731	0.017*
C10	1.1323 (2)	0.2972 (4)	0.90042 (14)	0.0107 (8)
C11	0.9056 (2)	0.0144 (4)	0.94157 (15)	0.0128 (8)
H11A	0.8936	0.1166	0.9399	0.015*
H11B	0.8605	−0.0336	0.9582	0.015*
C12	0.9163 (2)	−0.0434 (4)	0.88855 (15)	0.0120 (8)
Zn2	0.60272 (2)	0.05820 (4)	0.708125 (16)	0.00988 (9)
N21	0.53471 (18)	−0.0972 (3)	0.66409 (11)	0.0111 (7)
N22	0.68311 (18)	0.0323 (3)	0.64345 (12)	0.0137 (7)
N23	0.54514 (19)	0.2003 (3)	0.65352 (12)	0.0141 (7)
O21	0.52931 (15)	−0.0254 (3)	0.76249 (10)	0.0134 (6)
O22	0.45361 (15)	−0.2103 (3)	0.78197 (10)	0.0168 (6)
O23	0.70301 (16)	−0.0144 (3)	0.74292 (10)	0.0160 (6)
O24	0.83384 (17)	−0.0339 (3)	0.73661 (12)	0.0267 (7)
O25	0.60456 (15)	0.2484 (3)	0.74679 (10)	0.0142 (6)
O26	0.55583 (15)	0.4664 (3)	0.74935 (10)	0.0145 (6)
C21	0.5825 (2)	−0.1491 (4)	0.62115 (14)	0.0129 (8)
H21A	0.5636	−0.1044	0.5895	0.015*
H21B	0.5754	−0.2524	0.6178	0.015*
C22	0.6700 (2)	−0.1160 (4)	0.62845 (16)	0.0162 (8)
H22A	0.6920	−0.1791	0.6548	0.019*
H22B	0.6986	−0.1350	0.5965	0.019*
C23	0.6640 (2)	0.1362 (4)	0.60296 (15)	0.0161 (8)
H23A	0.6354	0.0882	0.5752	0.019*
H23B	0.7136	0.1761	0.5891	0.019*
C24	0.6130 (2)	0.2540 (4)	0.62434 (16)	0.0160 (8)
H24A	0.6460	0.3145	0.6465	0.019*
H24B	0.5933	0.3132	0.5962	0.019*
C25	0.4863 (2)	0.1230 (4)	0.62259 (15)	0.0151 (8)
H25A	0.5090	0.1028	0.5888	0.018*
H25B	0.4386	0.1823	0.6179	0.018*
C26	0.4633 (2)	−0.0149 (4)	0.64821 (15)	0.0132 (8)
H26A	0.4303	0.0058	0.6783	0.016*
H26B	0.4312	−0.0725	0.6246	0.016*
C27	0.5128 (2)	−0.2061 (4)	0.70054 (15)	0.0145 (8)
H27A	0.5563	−0.2757	0.7034	0.017*
H27B	0.4650	−0.2564	0.6884	0.017*
C28	0.4961 (2)	−0.1420 (4)	0.75278 (14)	0.0121 (8)
C29	0.7628 (2)	0.0498 (4)	0.66439 (15)	0.0175 (9)
H29A	0.7774	0.1510	0.6637	0.021*
H29B	0.8013	−0.0023	0.6432	0.021*
C30	0.7672 (2)	−0.0043 (4)	0.71825 (16)	0.0165 (9)
C31	0.5101 (2)	0.3140 (4)	0.68376 (14)	0.0140 (8)
H31A	0.4565	0.2856	0.6950	0.017*
H31B	0.5048	0.3998	0.6627	0.017*
C32	0.5604 (2)	0.3469 (4)	0.72938 (15)	0.0140 (8)
Cl1P	0.90733 (6)	0.49270 (10)	0.94241 (4)	0.0164 (2)
Cl2P	0.76010 (6)	0.50986 (10)	0.57365 (4)	0.0207 (2)
Cl3P	0.85405 (6)	0.29914 (10)	0.79612 (4)	0.0198 (2)
O1P	0.87409 (16)	0.4307 (3)	0.81979 (11)	0.0225 (7)
O2P	0.78137 (15)	0.2457 (3)	0.81750 (11)	0.0215 (7)
O3P	0.91798 (15)	0.2025 (3)	0.80605 (11)	0.0199 (6)
O4P	0.84347 (19)	0.3166 (3)	0.74240 (12)	0.0322 (8)
O5P	0.98116 (16)	0.4732 (3)	0.91612 (13)	0.0264 (7)
O6P	0.92441 (19)	0.5250 (3)	0.99436 (12)	0.0300 (8)
O7P	0.86528 (16)	0.6093 (3)	0.91977 (11)	0.0196 (6)
O8P	0.86005 (19)	0.3672 (3)	0.93927 (13)	0.0326 (8)
O9P	0.81100 (17)	0.6321 (3)	0.57245 (13)	0.0307 (7)
O10P	0.7577 (3)	0.4429 (4)	0.52517 (14)	0.0578 (12)
O11P	0.68191 (19)	0.5555 (3)	0.58564 (16)	0.0445 (10)
O12P	0.78848 (18)	0.4105 (3)	0.61010 (12)	0.0303 (8)
C1S	0.7491 (3)	0.6009 (5)	0.71492 (18)	0.0350 (12)
H1S1	0.7719	0.5133	0.7016	0.053*
H1S2	0.7837	0.6804	0.7064	0.053*
H1S3	0.6967	0.6160	0.6999	0.053*
O1S	0.74181 (18)	0.5907 (3)	0.76745 (11)	0.0238 (7)
H1S	0.708 (3)	0.650 (5)	0.7779 (19)	0.036*
Na1	0.94165 (8)	0.95334 (15)	0.78618 (6)	0.0129 (3)
Na2	0.84425 (8)	0.67402 (15)	0.83292 (6)	0.0180 (3)
Na3	0.52011 (8)	0.11140 (16)	0.83393 (6)	0.0175 (3)
Na4	0.66600 (9)	0.40410 (15)	0.80596 (6)	0.0146 (3)
Na5	0.74113 (8)	−0.00225 (14)	0.82877 (6)	0.0121 (3)

	U11	U22	U33	U12	U13	U23
Zn1	0.00958 (19)	0.00826 (19)	0.0080 (2)	−0.00044 (15)	−0.00002 (19)	−0.00020 (19)
N1	0.0161 (16)	0.0096 (15)	0.0102 (16)	−0.0003 (12)	−0.0014 (13)	−0.0001 (13)
N2	0.0135 (16)	0.0102 (16)	0.0117 (16)	−0.0013 (12)	−0.0008 (13)	−0.0011 (13)
N3	0.0172 (18)	0.0110 (16)	0.0106 (16)	−0.0007 (12)	0.0024 (14)	−0.0027 (13)
O1	0.0138 (13)	0.0109 (13)	0.0106 (13)	0.0039 (10)	0.0041 (11)	0.0003 (11)
O2	0.0156 (14)	0.0128 (14)	0.0164 (14)	0.0043 (10)	0.0033 (12)	−0.0003 (11)
O3	0.0119 (13)	0.0117 (13)	0.0092 (13)	−0.0018 (10)	−0.0016 (11)	0.0001 (11)
O4	0.0160 (14)	0.0092 (13)	0.0162 (14)	−0.0019 (10)	0.0031 (11)	0.0019 (11)
O5	0.0076 (13)	0.0175 (14)	0.0129 (14)	−0.0008 (10)	0.0012 (11)	−0.0014 (11)
O6	0.0137 (13)	0.0096 (13)	0.0169 (14)	−0.0006 (10)	−0.0021 (12)	0.0009 (11)
C1	0.011 (2)	0.021 (2)	0.016 (2)	0.0011 (15)	−0.0043 (16)	0.0070 (17)
C2	0.023 (2)	0.019 (2)	0.010 (2)	−0.0010 (17)	−0.0045 (17)	0.0019 (17)
C3	0.0168 (19)	0.0116 (18)	0.012 (2)	−0.0009 (15)	0.0002 (17)	−0.0036 (15)
C4	0.018 (2)	0.021 (2)	0.012 (2)	−0.0015 (16)	0.0039 (17)	−0.0072 (17)
C5	0.019 (2)	0.019 (2)	0.0092 (19)	−0.0068 (16)	0.0041 (16)	0.0022 (16)
C6	0.023 (2)	0.014 (2)	0.010 (2)	−0.0046 (16)	0.0002 (17)	0.0041 (15)
C7	0.020 (2)	0.0091 (18)	0.016 (2)	0.0005 (14)	0.0023 (17)	−0.0012 (15)
C8	0.0067 (17)	0.0114 (18)	0.0104 (19)	0.0003 (13)	−0.0034 (15)	−0.0009 (15)
C9	0.016 (2)	0.0124 (19)	0.014 (2)	−0.0023 (15)	−0.0031 (16)	−0.0035 (16)
C10	0.0114 (18)	0.0064 (17)	0.0142 (19)	0.0013 (13)	0.0013 (15)	−0.0013 (14)
C11	0.0127 (19)	0.0101 (18)	0.016 (2)	−0.0017 (14)	0.0032 (16)	−0.0029 (16)
C12	0.014 (2)	0.0089 (18)	0.013 (2)	0.0000 (14)	−0.0019 (16)	0.0032 (15)
Zn2	0.0111 (2)	0.0108 (2)	0.0077 (2)	0.00016 (16)	0.00000 (19)	−0.00050 (18)
N21	0.0112 (16)	0.0143 (17)	0.0078 (16)	0.0000 (12)	0.0030 (13)	−0.0013 (13)
N22	0.0101 (16)	0.0163 (16)	0.0148 (17)	−0.0048 (12)	−0.0013 (14)	−0.0020 (14)
N23	0.0176 (17)	0.0144 (16)	0.0103 (16)	−0.0007 (13)	−0.0013 (14)	−0.0003 (14)
O21	0.0161 (14)	0.0144 (14)	0.0095 (14)	−0.0014 (11)	0.0025 (11)	0.0012 (11)
O22	0.0164 (14)	0.0139 (14)	0.0202 (15)	0.0009 (11)	0.0064 (12)	0.0014 (12)
O23	0.0185 (15)	0.0166 (14)	0.0130 (15)	0.0031 (11)	−0.0027 (12)	−0.0022 (12)
O24	0.0146 (15)	0.0318 (18)	0.034 (2)	0.0028 (12)	−0.0097 (14)	−0.0080 (15)
O25	0.0163 (14)	0.0130 (14)	0.0133 (14)	0.0019 (11)	−0.0037 (12)	−0.0006 (11)
O26	0.0136 (14)	0.0102 (13)	0.0197 (15)	−0.0007 (10)	0.0038 (12)	−0.0048 (11)
C21	0.016 (2)	0.0158 (19)	0.0072 (18)	−0.0027 (15)	0.0010 (15)	−0.0052 (15)
C22	0.017 (2)	0.018 (2)	0.014 (2)	0.0015 (16)	0.0035 (17)	−0.0061 (17)
C23	0.018 (2)	0.020 (2)	0.0105 (19)	−0.0059 (16)	0.0012 (17)	0.0003 (17)
C24	0.017 (2)	0.016 (2)	0.014 (2)	−0.0064 (15)	−0.0006 (17)	−0.0004 (17)
C25	0.016 (2)	0.014 (2)	0.015 (2)	−0.0009 (15)	−0.0052 (17)	0.0031 (16)
C26	0.014 (2)	0.0134 (19)	0.0118 (19)	−0.0017 (14)	−0.0033 (16)	−0.0011 (16)
C27	0.0155 (19)	0.0154 (19)	0.013 (2)	−0.0046 (14)	0.0017 (16)	−0.0016 (16)
C28	0.0121 (19)	0.0119 (19)	0.0122 (19)	0.0024 (15)	0.0004 (16)	0.0007 (15)
C29	0.010 (2)	0.028 (2)	0.015 (2)	−0.0014 (16)	−0.0020 (16)	−0.0045 (17)
C30	0.018 (2)	0.0094 (18)	0.022 (2)	−0.0006 (14)	−0.0025 (18)	−0.0039 (16)
C31	0.016 (2)	0.0107 (19)	0.015 (2)	0.0041 (14)	−0.0009 (17)	0.0030 (16)
C32	0.0125 (19)	0.0163 (19)	0.0131 (19)	0.0000 (15)	0.0081 (16)	0.0014 (16)
Cl1P	0.0172 (5)	0.0118 (4)	0.0201 (5)	0.0008 (4)	0.0043 (4)	0.0007 (4)
Cl2P	0.0179 (5)	0.0190 (5)	0.0250 (6)	−0.0022 (4)	−0.0024 (4)	0.0056 (4)
Cl3P	0.0173 (5)	0.0157 (5)	0.0264 (6)	−0.0003 (4)	−0.0004 (4)	−0.0019 (4)
O1P	0.0213 (15)	0.0160 (15)	0.0302 (18)	−0.0028 (12)	−0.0018 (13)	−0.0033 (13)
O2P	0.0113 (15)	0.0157 (14)	0.0376 (19)	−0.0009 (11)	0.0024 (13)	0.0032 (13)
O3P	0.0133 (14)	0.0142 (15)	0.0322 (17)	0.0006 (11)	−0.0025 (13)	−0.0011 (13)
O4P	0.041 (2)	0.0296 (18)	0.0256 (17)	0.0040 (15)	−0.0028 (15)	−0.0033 (15)
O5P	0.0209 (15)	0.0348 (16)	0.0236 (16)	0.0103 (12)	0.0060 (15)	0.0010 (15)
O6P	0.040 (2)	0.0317 (18)	0.0178 (16)	0.0064 (14)	0.0047 (15)	0.0021 (14)
O7P	0.0225 (15)	0.0153 (13)	0.0211 (15)	0.0024 (11)	−0.0027 (14)	0.0028 (13)
O8P	0.0323 (19)	0.0170 (16)	0.048 (2)	−0.0055 (13)	0.0015 (16)	0.0053 (15)
O9P	0.0257 (17)	0.0278 (17)	0.0384 (19)	−0.0113 (13)	−0.0034 (15)	0.0137 (15)
O10P	0.093 (3)	0.054 (3)	0.026 (2)	0.006 (2)	−0.011 (2)	−0.0121 (19)
O11P	0.0185 (17)	0.0303 (19)	0.085 (3)	0.0005 (14)	0.0062 (18)	0.022 (2)
O12P	0.0276 (18)	0.0225 (17)	0.041 (2)	−0.0039 (13)	−0.0087 (15)	0.0138 (14)
C1S	0.041 (3)	0.032 (3)	0.032 (3)	0.005 (2)	−0.002 (2)	0.001 (2)
O1S	0.0243 (17)	0.0277 (17)	0.0193 (16)	0.0010 (13)	0.0058 (14)	−0.0048 (13)
Na1	0.0106 (7)	0.0141 (8)	0.0140 (8)	−0.0015 (6)	−0.0006 (6)	0.0006 (6)
Na2	0.0176 (8)	0.0149 (8)	0.0216 (8)	0.0011 (6)	0.0059 (7)	−0.0020 (7)
Na3	0.0161 (8)	0.0166 (8)	0.0198 (9)	0.0007 (6)	−0.0018 (7)	−0.0064 (7)
Na4	0.0157 (8)	0.0149 (8)	0.0130 (8)	0.0000 (6)	0.0011 (6)	−0.0036 (6)
Na5	0.0136 (8)	0.0104 (7)	0.0124 (8)	−0.0001 (5)	−0.0012 (6)	−0.0002 (6)

Zn1—O5	2.027 (3)	O24—Na5	2.913 (3)
Zn1—O1	2.062 (2)	O25—C32	1.280 (4)
Zn1—O3	2.066 (2)	O25—Na4	2.388 (3)
Zn1—N2	2.160 (3)	O25—Na3	3.005 (3)
Zn1—N3	2.172 (3)	O26—C32	1.251 (4)
Zn1—N1	2.189 (3)	O26—Na1v	2.291 (3)
N1—C7	1.475 (5)	O26—Na4	2.460 (3)
N1—C1	1.477 (5)	C21—C22	1.524 (5)
N1—C6	1.483 (5)	C21—H21A	0.9900
N2—C9	1.475 (5)	C21—H21B	0.9900
N2—C3	1.495 (5)	C22—H22A	0.9900
N2—C2	1.495 (5)	C22—H22B	0.9900
N3—C11	1.467 (5)	C23—C24	1.519 (5)
N3—C4	1.476 (5)	C23—H23A	0.9900
N3—C5	1.485 (5)	C23—H23B	0.9900
O1—C8	1.276 (4)	C24—H24A	0.9900
O1—Na4i	2.289 (3)	C24—H24B	0.9900
O2—C8	1.244 (4)	C25—C26	1.523 (5)
O2—Na5ii	2.268 (3)	C25—H25A	0.9900
O2—Na2i	2.461 (3)	C25—H25B	0.9900
O3—C10	1.291 (4)	C26—H26A	0.9900
O3—Na3i	2.399 (3)	C26—H26B	0.9900
O3—Na4i	2.564 (3)	C27—C28	1.536 (5)
O4—C10	1.228 (4)	C27—H27A	0.9900
O4—Na5i	2.252 (3)	C27—H27B	0.9900
O4—Na3i	2.501 (3)	C29—C30	1.516 (6)
O5—C12	1.271 (4)	C29—H29A	0.9900
O5—Na1iii	2.390 (3)	C29—H29B	0.9900
O6—C12	1.246 (4)	C30—Na5	2.957 (4)
O6—Na5	2.275 (3)	C31—C32	1.508 (5)
O6—Na2iii	2.495 (3)	C31—H31A	0.9900
O6—Na1iii	2.501 (3)	C31—H31B	0.9900
C1—C2	1.533 (6)	C32—Na4	2.753 (4)
C1—H1A	0.9900	Cl1P—O8P	1.435 (3)
C1—H1B	0.9900	Cl1P—O6P	1.437 (3)
C2—H2A	0.9900	Cl1P—O5P	1.440 (3)
C2—H2B	0.9900	Cl1P—O7P	1.444 (3)
C3—C4	1.527 (5)	Cl2P—O11P	1.425 (3)
C3—H3A	0.9900	Cl2P—O12P	1.430 (3)
C3—H3B	0.9900	Cl2P—O10P	1.431 (4)
C4—H4A	0.9900	Cl2P—O9P	1.442 (3)
C4—H4B	0.9900	Cl3P—O1P	1.435 (3)
C5—C6	1.507 (5)	Cl3P—O3P	1.440 (3)
C5—H5A	0.9900	Cl3P—O4P	1.442 (3)
C5—H5B	0.9900	Cl3P—O2P	1.443 (3)
C6—H6A	0.9900	Cl3P—Na3i	3.0957 (17)
C6—H6B	0.9900	Cl3P—Na4	3.3378 (18)
C7—C8	1.527 (5)	O1P—Na2	2.385 (3)
C7—H7A	0.9900	O1P—Na3i	2.526 (3)
C7—H7B	0.9900	O2P—Na5	2.463 (3)
C8—Na2i	3.083 (4)	O2P—Na4	2.478 (3)
C9—C10	1.516 (5)	O3P—Na1iii	2.451 (3)
C9—H9A	0.9900	O3P—Na3i	2.574 (3)
C9—H9B	0.9900	O5P—Na3i	2.409 (4)
C10—Na3i	2.727 (4)	O7P—Na2	2.404 (3)
C11—C12	1.516 (5)	C1S—O1S	1.398 (6)
C11—H11A	0.9900	C1S—H1S1	0.9800
C11—H11B	0.9900	C1S—H1S2	0.9800
C12—Na1iii	2.742 (4)	C1S—H1S3	0.9800
Zn2—O23	2.047 (3)	O1S—Na4	2.409 (3)
Zn2—O21	2.057 (3)	O1S—Na2	2.572 (3)
Zn2—O25	2.072 (3)	O1S—H1S	0.85 (5)
Zn2—N22	2.198 (3)	Na1—O24vi	2.247 (3)
Zn2—N21	2.201 (3)	Na1—O26vii	2.291 (3)
Zn2—N23	2.201 (3)	Na1—O22i	2.313 (3)
Zn2—Na3	3.6439 (16)	Na1—O5vi	2.390 (3)
N21—C27	1.460 (5)	Na1—O3Pvi	2.451 (3)
N21—C21	1.477 (5)	Na1—O6vi	2.501 (3)
N21—C26	1.496 (5)	Na1—C12vi	2.742 (4)
N22—C29	1.465 (5)	Na2—O22i	2.312 (3)
N22—C22	1.476 (5)	Na2—O2iv	2.461 (3)
N22—C23	1.490 (5)	Na2—O6vi	2.495 (3)
N23—C31	1.467 (5)	Na2—C8iv	3.083 (4)
N23—C24	1.473 (5)	Na3—O3iv	2.399 (3)
N23—C25	1.480 (5)	Na3—O5Piv	2.409 (4)
O21—C28	1.265 (4)	Na3—O4iv	2.501 (3)
O21—Na3	2.297 (3)	Na3—O1Piv	2.526 (3)
O22—C28	1.237 (4)	Na3—O3Piv	2.574 (3)
O22—Na2iv	2.312 (3)	Na3—C10iv	2.727 (4)
O22—Na1iv	2.313 (3)	Na3—Cl3Piv	3.0957 (17)
O23—C30	1.269 (5)	Na4—O1iv	2.289 (3)
O23—Na5	2.364 (3)	Na4—O3iv	2.564 (3)
O24—C30	1.257 (5)	Na5—O4iv	2.252 (3)
O24—Na1iii	2.247 (3)	Na5—O2viii	2.268 (3)
O5—Zn1—O1	92.38 (10)	N23—C24—H24A	109.1
O5—Zn1—O3	93.47 (10)	C23—C24—H24A	109.1
O1—Zn1—O3	87.04 (10)	N23—C24—H24B	109.1
O5—Zn1—N2	153.25 (11)	C23—C24—H24B	109.1
O1—Zn1—N2	112.82 (11)	H24A—C24—H24B	107.8
O3—Zn1—N2	79.63 (11)	N23—C25—C26	110.5 (3)
O5—Zn1—N3	78.72 (11)	N23—C25—H25A	109.6
O1—Zn1—N3	152.26 (11)	C26—C25—H25A	109.6
O3—Zn1—N3	119.42 (11)	N23—C25—H25B	109.6
N2—Zn1—N3	82.29 (12)	C26—C25—H25B	109.6
O5—Zn1—N1	112.96 (11)	H25A—C25—H25B	108.1
O1—Zn1—N1	77.94 (11)	N21—C26—C25	111.5 (3)
O3—Zn1—N1	149.83 (11)	N21—C26—H26A	109.3
N2—Zn1—N1	82.32 (12)	C25—C26—H26A	109.3
N3—Zn1—N1	81.47 (12)	N21—C26—H26B	109.3
O5—Zn1—Na4i	83.44 (8)	C25—C26—H26B	109.3
O1—Zn1—Na4i	40.66 (8)	H26A—C26—H26B	108.0
O3—Zn1—Na4i	48.41 (7)	N21—C27—C28	111.2 (3)
N2—Zn1—Na4i	109.47 (9)	N21—C27—H27A	109.4
N3—Zn1—Na4i	157.82 (9)	C28—C27—H27A	109.4
N1—Zn1—Na4i	117.97 (9)	N21—C27—H27B	109.4
C7—N1—C1	111.8 (3)	C28—C27—H27B	109.4
C7—N1—C6	113.8 (3)	H27A—C27—H27B	108.0
C1—N1—C6	113.9 (3)	O22—C28—O21	126.0 (4)
C7—N1—Zn1	104.7 (2)	O22—C28—C27	117.5 (3)
C1—N1—Zn1	101.6 (2)	O21—C28—C27	116.5 (3)
C6—N1—Zn1	109.9 (2)	N22—C29—C30	111.2 (3)
C9—N2—C3	111.2 (3)	N22—C29—H29A	109.4
C9—N2—C2	114.0 (3)	C30—C29—H29A	109.4
C3—N2—C2	112.9 (3)	N22—C29—H29B	109.4
C9—N2—Zn1	106.2 (2)	C30—C29—H29B	109.4
C3—N2—Zn1	102.3 (2)	H29A—C29—H29B	108.0
C2—N2—Zn1	109.4 (2)	O24—C30—O23	123.3 (4)
C11—N3—C4	114.9 (3)	O24—C30—C29	118.8 (4)
C11—N3—C5	109.8 (3)	O23—C30—C29	117.8 (3)
C4—N3—C5	113.0 (3)	O24—C30—Na5	75.7 (2)
C11—N3—Zn1	105.3 (2)	O23—C30—Na5	50.56 (19)
C4—N3—Zn1	109.7 (2)	C29—C30—Na5	156.9 (3)
C5—N3—Zn1	103.2 (2)	N23—C31—C32	111.2 (3)
C8—O1—Zn1	114.3 (2)	N23—C31—H31A	109.4
C8—O1—Na4i	137.8 (2)	C32—C31—H31A	109.4
Zn1—O1—Na4i	103.41 (11)	N23—C31—H31B	109.4
C8—O2—Na5ii	141.8 (2)	C32—C31—H31B	109.4
C8—O2—Na2i	108.1 (2)	H31A—C31—H31B	108.0
Na5ii—O2—Na2i	96.39 (10)	O26—C32—O25	122.9 (4)
C10—O3—Zn1	115.6 (2)	O26—C32—C31	119.3 (3)
C10—O3—Na3i	90.2 (2)	O25—C32—C31	117.7 (3)
Zn1—O3—Na3i	145.57 (12)	O26—C32—Na4	63.3 (2)
C10—O3—Na4i	107.2 (2)	O25—C32—Na4	60.11 (19)
Zn1—O3—Na4i	94.54 (9)	C31—C32—Na4	173.9 (3)
Na3i—O3—Na4i	99.25 (10)	O8P—Cl1P—O6P	110.1 (2)
C10—O4—Na5i	138.8 (2)	O8P—Cl1P—O5P	110.33 (19)
C10—O4—Na3i	86.9 (2)	O6P—Cl1P—O5P	108.4 (2)
Na5i—O4—Na3i	109.63 (12)	O8P—Cl1P—O7P	109.66 (18)
C12—O5—Zn1	116.9 (2)	O6P—Cl1P—O7P	109.42 (18)
C12—O5—Na1iii	91.8 (2)	O5P—Cl1P—O7P	108.90 (18)
Zn1—O5—Na1iii	142.31 (13)	O11P—Cl2P—O12P	111.1 (2)
C12—O6—Na5	145.5 (2)	O11P—Cl2P—O10P	107.9 (3)
C12—O6—Na2iii	119.2 (2)	O12P—Cl2P—O10P	108.8 (2)
Na5—O6—Na2iii	95.30 (10)	O11P—Cl2P—O9P	108.29 (19)
C12—O6—Na1iii	87.4 (2)	O12P—Cl2P—O9P	110.07 (19)
Na5—O6—Na1iii	97.50 (11)	O10P—Cl2P—O9P	110.7 (2)
Na2iii—O6—Na1iii	84.29 (9)	O1P—Cl3P—O3P	107.20 (16)
N1—C1—C2	111.8 (3)	O1P—Cl3P—O4P	111.07 (19)
N1—C1—H1A	109.3	O3P—Cl3P—O4P	110.22 (18)
C2—C1—H1A	109.3	O1P—Cl3P—O2P	109.51 (18)
N1—C1—H1B	109.3	O3P—Cl3P—O2P	110.08 (17)
C2—C1—H1B	109.3	O4P—Cl3P—O2P	108.74 (18)
H1A—C1—H1B	107.9	O1P—Cl3P—Na3i	53.68 (12)
N2—C2—C1	110.6 (3)	O3P—Cl3P—Na3i	55.65 (11)
N2—C2—H2A	109.5	O4P—Cl3P—Na3i	113.53 (14)
C1—C2—H2A	109.5	O2P—Cl3P—Na3i	137.71 (13)
N2—C2—H2B	109.5	O1P—Cl3P—Na4	86.08 (12)
C1—C2—H2B	109.5	O3P—Cl3P—Na4	152.71 (13)
H2A—C2—H2B	108.1	O4P—Cl3P—Na4	85.68 (13)
N2—C3—C4	112.2 (3)	O2P—Cl3P—Na4	42.67 (11)
N2—C3—H3A	109.2	Na3i—Cl3P—Na4	139.04 (5)
C4—C3—H3A	109.2	Cl3P—O1P—Na2	148.54 (18)
N2—C3—H3B	109.2	Cl3P—O1P—Na3i	99.08 (15)
C4—C3—H3B	109.2	Na2—O1P—Na3i	109.71 (11)
H3A—C3—H3B	107.9	Cl3P—O2P—Na5	128.06 (16)
N3—C4—C3	111.3 (3)	Cl3P—O2P—Na4	114.08 (15)
N3—C4—H4A	109.4	Na5—O2P—Na4	112.04 (11)
C3—C4—H4A	109.4	Cl3P—O3P—Na1iii	134.07 (16)
N3—C4—H4B	109.4	Cl3P—O3P—Na3i	96.85 (13)
C3—C4—H4B	109.4	Na1iii—O3P—Na3i	127.71 (11)
H4A—C4—H4B	108.0	Cl1P—O5P—Na3i	135.67 (19)
N3—C5—C6	113.1 (3)	Cl1P—O7P—Na2	131.63 (17)
N3—C5—H5A	109.0	O1S—C1S—H1S1	109.5
C6—C5—H5A	109.0	O1S—C1S—H1S2	109.5
N3—C5—H5B	109.0	H1S1—C1S—H1S2	109.5
C6—C5—H5B	109.0	O1S—C1S—H1S3	109.5
H5A—C5—H5B	107.8	H1S1—C1S—H1S3	109.5
N1—C6—C5	111.2 (3)	H1S2—C1S—H1S3	109.5
N1—C6—H6A	109.4	C1S—O1S—Na4	121.1 (3)
C5—C6—H6A	109.4	C1S—O1S—Na2	126.1 (3)
N1—C6—H6B	109.4	Na4—O1S—Na2	107.33 (12)
C5—C6—H6B	109.4	C1S—O1S—H1S	110 (3)
H6A—C6—H6B	108.0	Na4—O1S—H1S	90 (3)
N1—C7—C8	111.1 (3)	Na2—O1S—H1S	91 (3)
N1—C7—H7A	109.4	O24vi—Na1—O26vii	114.58 (12)
C8—C7—H7A	109.4	O24vi—Na1—O22i	95.52 (12)
N1—C7—H7B	109.4	O26vii—Na1—O22i	103.68 (11)
C8—C7—H7B	109.4	O24vi—Na1—O5vi	144.28 (12)
H7A—C7—H7B	108.0	O26vii—Na1—O5vi	98.30 (10)
O2—C8—O1	123.3 (3)	O22i—Na1—O5vi	89.56 (11)
O2—C8—C7	118.9 (3)	O24vi—Na1—O3Pvi	86.63 (11)
O1—C8—C7	117.8 (3)	O26vii—Na1—O3Pvi	84.76 (10)
O2—C8—Na2i	49.36 (18)	O22i—Na1—O3Pvi	169.35 (12)
O1—C8—Na2i	93.7 (2)	O5vi—Na1—O3Pvi	82.72 (10)
C7—C8—Na2i	128.1 (2)	O24vi—Na1—O6vi	91.09 (11)
N2—C9—C10	111.6 (3)	O26vii—Na1—O6vi	149.84 (11)
N2—C9—H9A	109.3	O22i—Na1—O6vi	88.43 (10)
C10—C9—H9A	109.3	O5vi—Na1—O6vi	53.64 (9)
N2—C9—H9B	109.3	O3Pvi—Na1—O6vi	81.09 (10)
C10—C9—H9B	109.3	O22i—Na2—O1P	83.69 (11)
H9A—C9—H9B	108.0	O22i—Na2—O7P	118.49 (11)
O4—C10—O3	122.5 (3)	O1P—Na2—O7P	82.05 (11)
O4—C10—C9	119.8 (3)	O22i—Na2—O2iv	139.51 (11)
O3—C10—C9	117.7 (3)	O1P—Na2—O2iv	124.75 (11)
O4—C10—Na3i	66.3 (2)	O7P—Na2—O2iv	95.57 (10)
O3—C10—Na3i	61.58 (18)	O22i—Na2—O6vi	88.60 (10)
C9—C10—Na3i	156.8 (3)	O1P—Na2—O6vi	160.03 (11)
N3—C11—C12	109.9 (3)	O7P—Na2—O6vi	85.54 (10)
N3—C11—H11A	109.7	O2iv—Na2—O6vi	71.91 (9)
C12—C11—H11A	109.7	O22i—Na2—O1S	100.97 (11)
N3—C11—H11B	109.7	O1P—Na2—O1S	75.38 (11)
C12—C11—H11B	109.7	O7P—Na2—O1S	131.66 (11)
H11A—C11—H11B	108.2	O2iv—Na2—O1S	65.65 (10)
O6—C12—O5	122.7 (4)	O6vi—Na2—O1S	124.31 (11)
O6—C12—C11	119.9 (3)	O21—Na3—O5Piv	125.00 (12)
O5—C12—C11	117.4 (3)	O3iv—Na3—O5Piv	85.47 (10)
O6—C12—Na1iii	65.6 (2)	O21—Na3—O4iv	107.40 (10)
O5—C12—Na1iii	60.57 (19)	O3iv—Na3—O4iv	53.55 (8)
C11—C12—Na1iii	159.4 (2)	O5Piv—Na3—O4iv	76.41 (10)
O23—Zn2—O21	93.15 (11)	O21—Na3—O1Piv	81.67 (11)
O23—Zn2—O25	93.30 (10)	O3iv—Na3—O1Piv	130.54 (10)
O21—Zn2—O25	89.92 (10)	O5Piv—Na3—O1Piv	79.32 (11)
O23—Zn2—N22	78.54 (11)	O4iv—Na3—O1Piv	154.94 (12)
O21—Zn2—N22	150.85 (11)	O21—Na3—O3Piv	101.30 (11)
O25—Zn2—N22	118.18 (11)	O3iv—Na3—O3Piv	87.80 (9)
O23—Zn2—N21	116.44 (11)	O5Piv—Na3—O3Piv	107.67 (11)
O21—Zn2—N21	78.35 (11)	O4iv—Na3—O3Piv	141.14 (10)
O25—Zn2—N21	148.30 (11)	O1Piv—Na3—O3Piv	53.95 (9)
N22—Zn2—N21	80.53 (11)	O21—Na3—C10iv	131.52 (12)
O23—Zn2—N23	150.03 (12)	O3iv—Na3—C10iv	28.26 (9)
O21—Zn2—N23	115.34 (11)	O5Piv—Na3—C10iv	73.33 (11)
O25—Zn2—N23	78.41 (11)	O4iv—Na3—C10iv	26.73 (9)
N22—Zn2—N23	80.23 (12)	O1Piv—Na3—C10iv	145.51 (12)
N21—Zn2—N23	80.27 (12)	O3Piv—Na3—C10iv	115.66 (11)
O23—Zn2—Na3	87.28 (8)	O21—Na3—O25	65.18 (9)
O21—Zn2—Na3	35.31 (8)	O3iv—Na3—O25	81.04 (9)
O25—Zn2—Na3	55.57 (8)	O5Piv—Na3—O25	164.93 (10)
N22—Zn2—Na3	164.36 (9)	O4iv—Na3—O25	90.11 (9)
N21—Zn2—Na3	112.10 (8)	O1Piv—Na3—O25	114.70 (10)
N23—Zn2—Na3	110.23 (9)	O3Piv—Na3—O25	78.61 (9)
C27—N21—C21	114.3 (3)	C10iv—Na3—O25	91.59 (10)
C27—N21—C26	110.4 (3)	O21—Na3—Cl3Piv	87.13 (8)
C21—N21—C26	113.4 (3)	O3iv—Na3—Cl3Piv	112.97 (8)
C27—N21—Zn2	104.8 (2)	O5Piv—Na3—Cl3Piv	97.78 (9)
C21—N21—Zn2	110.2 (2)	O4iv—Na3—Cl3Piv	165.21 (9)
C26—N21—Zn2	102.8 (2)	O1Piv—Na3—Cl3Piv	27.24 (7)
C29—N22—C22	110.3 (3)	O3Piv—Na3—Cl3Piv	27.50 (6)
C29—N22—C23	113.3 (3)	C10iv—Na3—Cl3Piv	138.69 (9)
C22—N22—C23	113.7 (3)	O25—Na3—Cl3Piv	93.66 (7)
C29—N22—Zn2	105.1 (2)	O1iv—Na4—O25	152.16 (11)
C22—N22—Zn2	102.9 (2)	O1iv—Na4—O1S	81.39 (10)
C23—N22—Zn2	110.6 (2)	O25—Na4—O1S	114.02 (11)
C31—N23—C24	110.2 (3)	O1iv—Na4—O26	105.71 (10)
C31—N23—C25	113.2 (3)	O25—Na4—O26	54.58 (9)
C24—N23—C25	113.8 (3)	O1S—Na4—O26	88.20 (11)
C31—N23—Zn2	105.6 (2)	O1iv—Na4—O2P	109.63 (11)
C24—N23—Zn2	102.2 (2)	O25—Na4—O2P	92.77 (10)
C25—N23—Zn2	110.9 (2)	O1S—Na4—O2P	94.51 (11)
C28—O21—Zn2	117.5 (2)	O26—Na4—O2P	144.57 (11)
C28—O21—Na3	129.0 (2)	O1iv—Na4—O3iv	71.43 (9)
Zn2—O21—Na3	113.50 (12)	O25—Na4—O3iv	91.22 (10)
C28—O22—Na2iv	138.5 (2)	O1S—Na4—O3iv	152.81 (11)
C28—O22—Na1iv	127.0 (2)	O26—Na4—O3iv	99.40 (10)
Na2iv—O22—Na1iv	92.88 (11)	O2P—Na4—O3iv	94.12 (10)
C30—O23—Zn2	116.8 (2)	O1iv—Na4—C32	131.19 (12)
C30—O23—Na5	104.9 (2)	O25—Na4—C32	27.70 (10)
Zn2—O23—Na5	129.88 (13)	O1S—Na4—C32	100.22 (12)
C30—O24—Na1iii	164.3 (3)	O26—Na4—C32	27.03 (10)
C30—O24—Na5	79.6 (2)	O2P—Na4—C32	118.75 (12)
Na1iii—O24—Na5	87.28 (11)	O3iv—Na4—C32	98.08 (11)
C32—O25—Zn2	116.6 (2)	O1iv—Na4—Cl3P	106.80 (8)
C32—O25—Na4	92.2 (2)	O25—Na4—Cl3P	100.27 (8)
Zn2—O25—Na4	150.14 (13)	O1S—Na4—Cl3P	71.34 (8)
C32—O25—Na3	108.3 (2)	O26—Na4—Cl3P	138.03 (9)
Zn2—O25—Na3	89.79 (9)	O2P—Na4—Cl3P	23.25 (7)
Na4—O25—Na3	88.28 (9)	O3iv—Na4—Cl3P	115.65 (7)
C32—O26—Na1v	122.2 (2)	C32—Na4—Cl3P	120.02 (9)
C32—O26—Na4	89.6 (2)	O4iv—Na5—O2viii	94.98 (11)
Na1v—O26—Na4	117.22 (12)	O4iv—Na5—O6	118.54 (12)
N21—C21—C22	111.3 (3)	O2viii—Na5—O6	79.66 (10)
N21—C21—H21A	109.4	O4iv—Na5—O23	114.38 (11)
C22—C21—H21A	109.4	O2viii—Na5—O23	94.71 (11)
N21—C21—H21B	109.4	O6—Na5—O23	127.05 (11)
C22—C21—H21B	109.4	O4iv—Na5—O2P	84.12 (10)
H21A—C21—H21B	108.0	O2viii—Na5—O2P	174.83 (12)
N22—C22—C21	112.1 (3)	O6—Na5—O2P	96.27 (10)
N22—C22—H22A	109.2	O23—Na5—O2P	90.30 (11)
C21—C22—H22A	109.2	O4iv—Na5—O24	157.10 (11)
N22—C22—H22B	109.2	O2viii—Na5—O24	101.07 (10)
C21—C22—H22B	109.2	O6—Na5—O24	80.68 (10)
H22A—C22—H22B	107.9	O23—Na5—O24	48.48 (9)
N22—C23—C24	109.9 (3)	O2P—Na5—O24	81.29 (10)
N22—C23—H23A	109.7	O4iv—Na5—C30	134.93 (12)
C24—C23—H23A	109.7	O2viii—Na5—C30	102.99 (11)
N22—C23—H23B	109.7	O6—Na5—C30	105.29 (11)
C24—C23—H23B	109.7	O23—Na5—C30	24.50 (10)
H23A—C23—H23B	108.2	O2P—Na5—C30	81.10 (11)
N23—C24—C23	112.5 (3)	O24—Na5—C30	24.72 (9)

Table 1

Selected bond lengths (Å)

Zn1—O5	2.027 (3)
Zn1—O1	2.062 (2)
Zn1—O3	2.066 (2)
Zn1—N2	2.160 (3)
Zn1—N3	2.172 (3)
Zn1—N1	2.189 (3)
Zn2—O23	2.047 (3)
Zn2—O21	2.057 (3)
Zn2—O25	2.072 (3)
Zn2—N22	2.198 (3)
Zn2—N21	2.201 (3)
Zn2—N23	2.201 (3)