Literature DB >> 21581474

{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}dimethano-ltrinitratonickel(II)europium(III) methanol disolvate.

Fei Liu1.   

Abstract

The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol mol-ecules, forming a slightly distorted octa-hedral geometry. The Eu(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-anti-prismatic environment. Inter-molecular O-H⋯O hydrogen bonds connect complexes and methanol solvent mol-ecules.

Entities:  

Year:  2008        PMID: 21581474      PMCID: PMC2968012          DOI: 10.1107/S1600536808041445

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  3 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  {μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diyl-bis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)samarium(III) acetone solvate.

Authors:  Jing-Hua Wang; Po Gao; Peng-Fei Yan; Guang-Ming Li; Guang-Feng Hou
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-01-16

3.  {μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate.

Authors:  Fei Liu; Fang Zhang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-03-29
  3 in total

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