catena-Poly[[(1,10-phenanthroline-κN,N')copper(I)]-μ-thiocyanato-κN:S-[(1,10-phenanthroline-κN,N')copper(I)]-μ-cyanido-κN:C].

In the title complex, [Cu(2)(CN)(NCS)(C(12)H(8)N(2))(2)], which was synthesized under hydro-thermal conditions, both Cu(I) atoms have a slightly distorted tetra-hedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thio-cyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along [01].

Related literature

For related literature, see: Cheng et al. (2006 ▶); Greig & Philp (2001 ▶); Luan et al. (2006 ▶); Piguet et al. (1997 ▶).

Experimental

Crystal data

[Cu2(CN)(NCS)(C12H8N2)2]

M = 571.59

Monoclinic,

a = 13.046 (7) Å

b = 13.470 (7) Å

c = 13.538 (7) Å

β = 90.044 (9)°

V = 2379 (2) Å3

Z = 4

Mo Kα radiation

μ = 1.90 mm−1

T = 293 (2) K

0.30 × 0.15 × 0.12 mm

Data collection

Bruker SMART CCD diffractometer

Absorption correction: multi-scan SADABS (Sheldrick, 1996 ▶) T min = 0.599, T max = 0.804

15496 measured reflections

4959 independent reflections

3662 reflections with I > 2σ(I)

R int = 0.081

Refinement

R[F 2 > 2σ(F 2)] = 0.061

wR(F 2) = 0.164

S = 1.00

4959 reflections

316 parameters

H-atom parameters constrained

Δρmax = 0.47 e Å−3

Δρmin = −0.57 e Å−3

Data collection: SMART (Bruker, 1997 ▶); cell refinement: SAINT (Bruker, 1997 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, New_Global_Publ_Block. DOI: 10.1107/S1600536808037744/bt2813sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808037744/bt2813Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu2(CN)(NCS)(C12H8N2)2]	F000 = 1152
Mr = 571.59	Dx = 1.596 Mg m−3
Monoclinic, P21/n	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 2103 reflections
a = 13.046 (7) Å	θ = 2.2–27.5º
b = 13.470 (7) Å	µ = 1.90 mm−1
c = 13.538 (7) Å	T = 293 (2) K
β = 90.044 (9)º	Prism, red
V = 2379 (2) Å3	0.30 × 0.15 × 0.12 mm
Z = 4

Bruker SMART CCD diffractometer	4959 independent reflections
Radiation source: fine-focus sealed tube	3662 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.081
Detector resolution: 13.6612 pixels mm-1	θmax = 27.5º
T = 293(2) K	θmin = 2.2º
CCD Profile fitting scans	h = −15→16
Absorption correction: multi-scanSADABS (Sheldrick, 1996)	k = −17→15
Tmin = 0.599, Tmax = 0.804	l = −17→17
15496 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.061	H-atom parameters constrained
wR(F2) = 0.164	w = 1/[σ2(Fo2) + (0.0669P)2 + 0.4979P] where P = (Fo2 + 2Fc2)/3
S = 1.00	(Δ/σ)max = 0.001
4959 reflections	Δρmax = 0.47 e Å−3
316 parameters	Δρmin = −0.57 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cu1	0.08441 (4)	0.73813 (3)	0.04132 (4)	0.06012 (19)
Cu2	0.45032 (3)	0.76203 (3)	−0.04863 (3)	0.05589 (18)
C1	0.3089 (3)	0.7520 (2)	−0.0233 (3)	0.0502 (8)
N2	0.5019 (2)	0.8164 (2)	−0.1747 (2)	0.0623 (7)
N3	−0.0405 (2)	0.73312 (19)	−0.0551 (2)	0.0557 (7)
N4	0.0024 (2)	0.86301 (19)	0.0898 (2)	0.0524 (6)
N5	0.54334 (18)	0.8232 (2)	0.06500 (19)	0.0501 (6)
N6	0.5591 (2)	0.64667 (19)	−0.02813 (19)	0.0515 (6)
N1	0.2232 (2)	0.74724 (19)	−0.0059 (2)	0.0619 (8)
C2	0.5338 (2)	0.8478 (2)	−0.2473 (2)	0.0505 (7)
C3	−0.0636 (3)	0.6686 (3)	−0.1262 (3)	0.0712 (10)
H3A	−0.0226	0.6125	−0.1325	0.085*
C4	−0.1433 (4)	0.6793 (3)	−0.1905 (4)	0.0901 (14)
H4A	−0.1549	0.6324	−0.2397	0.108*
C5	−0.2064 (4)	0.7608 (3)	−0.1815 (4)	0.0854 (15)
H5A	−0.2610	0.7697	−0.2248	0.103*
C6	−0.1878 (2)	0.8295 (2)	−0.1071 (3)	0.0609 (9)
C7	−0.2500 (3)	0.9176 (3)	−0.0924 (3)	0.0709 (10)
H7A	−0.3060	0.9296	−0.1333	0.085*
C8	−0.2269 (3)	0.9819 (3)	−0.0200 (3)	0.0662 (10)
H8A	−0.2675	1.0380	−0.0119	0.079*
C9	−0.1417 (2)	0.9670 (2)	0.0451 (3)	0.0523 (7)
C10	−0.1156 (3)	1.0327 (2)	0.1207 (3)	0.0597 (9)
H10A	−0.1545	1.0896	0.1311	0.072*
C11	−0.0333 (3)	1.0133 (3)	0.1790 (3)	0.0682 (10)
H11A	−0.0155	1.0563	0.2299	0.082*
C12	0.0254 (3)	0.9263 (3)	0.1610 (2)	0.0625 (9)
H12A	0.0820	0.9135	0.2008	0.075*
C13	−0.0798 (2)	0.8824 (2)	0.0330 (2)	0.0473 (7)
C14	−0.1038 (2)	0.8128 (2)	−0.0458 (2)	0.0502 (7)
C15	0.5371 (3)	0.9102 (3)	0.1122 (3)	0.0639 (9)
H15A	0.4849	0.9536	0.0943	0.077*
C16	0.6044 (3)	0.9392 (3)	0.1865 (3)	0.0747 (10)
H16A	0.5968	1.0008	0.2167	0.090*
C17	0.6812 (3)	0.8776 (3)	0.2149 (3)	0.0733 (10)
H17A	0.7253	0.8954	0.2659	0.088*
C18	0.6929 (3)	0.7856 (3)	0.1653 (3)	0.0559 (8)
C19	0.7759 (3)	0.7185 (3)	0.1877 (3)	0.0692 (10)
H19A	0.8219	0.7332	0.2382	0.083*
C20	0.7865 (3)	0.6345 (3)	0.1351 (3)	0.0696 (10)
H20A	0.8424	0.5937	0.1478	0.084*
C21	0.7157 (2)	0.6058 (2)	0.0611 (3)	0.0581 (8)
C22	0.7226 (3)	0.5174 (3)	0.0063 (3)	0.0743 (12)
H22A	0.7770	0.4740	0.0168	0.089*
C23	0.6491 (3)	0.4955 (3)	−0.0622 (3)	0.0783 (12)
H23A	0.6530	0.4370	−0.0985	0.094*
C24	0.5680 (3)	0.5616 (3)	−0.0775 (3)	0.0641 (9)
H24A	0.5182	0.5455	−0.1240	0.077*
C25	0.6313 (2)	0.6691 (2)	0.0399 (2)	0.0471 (7)
C26	0.6224 (3)	0.7617 (2)	0.0929 (2)	0.0468 (7)
S1	0.58145 (8)	0.89734 (6)	−0.34839 (7)	0.0644 (3)

	U11	U22	U33	U12	U13	U23
Cu1	0.0442 (3)	0.0592 (3)	0.0770 (4)	0.01178 (17)	0.0058 (2)	0.00483 (19)
Cu2	0.0407 (3)	0.0623 (3)	0.0646 (3)	0.00543 (17)	−0.0032 (2)	0.00538 (18)
C1	0.0387 (17)	0.0418 (15)	0.070 (2)	0.0058 (12)	0.0049 (15)	0.0057 (13)
N2	0.0498 (15)	0.0711 (19)	0.0659 (18)	−0.0020 (14)	−0.0025 (13)	0.0112 (15)
N3	0.0468 (16)	0.0429 (14)	0.077 (2)	0.0043 (11)	0.0045 (15)	−0.0008 (12)
N4	0.0538 (14)	0.0452 (13)	0.0582 (15)	0.0046 (12)	0.0092 (12)	0.0053 (12)
N5	0.0421 (13)	0.0504 (14)	0.0577 (15)	0.0087 (11)	0.0024 (11)	−0.0010 (12)
N6	0.0503 (14)	0.0457 (14)	0.0584 (15)	0.0028 (11)	0.0049 (12)	0.0001 (12)
N1	0.0516 (19)	0.0502 (16)	0.084 (2)	0.0083 (12)	0.0027 (16)	0.0065 (14)
C2	0.0389 (14)	0.0447 (16)	0.068 (2)	0.0002 (13)	−0.0035 (14)	−0.0008 (14)
C3	0.061 (2)	0.056 (2)	0.097 (3)	0.0088 (17)	−0.003 (2)	−0.023 (2)
C4	0.084 (3)	0.067 (3)	0.119 (4)	0.008 (2)	−0.017 (3)	−0.036 (3)
C5	0.060 (3)	0.069 (3)	0.127 (4)	0.0007 (19)	−0.027 (3)	−0.022 (2)
C6	0.0396 (15)	0.0487 (17)	0.094 (3)	−0.0007 (14)	−0.0049 (16)	−0.0069 (17)
C7	0.0495 (18)	0.0507 (19)	0.113 (3)	0.0065 (16)	−0.0176 (19)	−0.005 (2)
C8	0.0518 (19)	0.0413 (17)	0.106 (3)	0.0098 (15)	−0.0004 (19)	0.0024 (18)
C9	0.0471 (16)	0.0394 (15)	0.071 (2)	0.0027 (13)	0.0081 (15)	0.0049 (14)
C10	0.067 (2)	0.0431 (17)	0.069 (2)	0.0091 (15)	0.0118 (18)	0.0027 (15)
C11	0.089 (3)	0.056 (2)	0.060 (2)	0.006 (2)	0.004 (2)	0.0001 (16)
C12	0.071 (2)	0.060 (2)	0.0563 (19)	0.0092 (18)	−0.0005 (16)	0.0008 (16)
C13	0.0384 (14)	0.0383 (15)	0.0653 (18)	0.0014 (12)	0.0091 (13)	0.0044 (13)
C14	0.0395 (14)	0.0389 (15)	0.072 (2)	0.0000 (12)	0.0074 (14)	0.0024 (14)
C15	0.0590 (19)	0.060 (2)	0.072 (2)	0.0170 (17)	0.0047 (17)	−0.0110 (17)
C16	0.078 (2)	0.074 (2)	0.072 (2)	0.011 (2)	−0.001 (2)	−0.023 (2)
C17	0.071 (2)	0.085 (3)	0.065 (2)	−0.006 (2)	−0.0035 (18)	−0.016 (2)
C18	0.0430 (17)	0.066 (2)	0.0590 (19)	−0.0033 (16)	−0.0031 (14)	0.0115 (17)
C19	0.049 (2)	0.086 (3)	0.072 (2)	0.003 (2)	−0.0150 (17)	0.017 (2)
C20	0.0497 (18)	0.073 (2)	0.086 (3)	0.0160 (18)	−0.0044 (18)	0.030 (2)
C21	0.0468 (17)	0.0500 (18)	0.077 (2)	0.0118 (14)	0.0091 (16)	0.0149 (16)
C22	0.072 (3)	0.052 (2)	0.099 (3)	0.0215 (19)	0.020 (2)	0.013 (2)
C23	0.092 (3)	0.047 (2)	0.097 (3)	0.012 (2)	0.021 (3)	−0.005 (2)
C24	0.075 (2)	0.0519 (18)	0.065 (2)	0.0020 (17)	0.0054 (17)	−0.0055 (16)
C25	0.0397 (14)	0.0446 (15)	0.0570 (17)	0.0076 (12)	0.0079 (13)	0.0080 (13)
C26	0.0429 (17)	0.0476 (16)	0.0500 (17)	0.0051 (12)	0.0054 (14)	0.0045 (12)
S1	0.0725 (6)	0.0491 (5)	0.0717 (6)	−0.0137 (4)	0.0150 (5)	−0.0022 (4)

Cu1—N1	1.924 (3)	C8—H8A	0.9300
Cu1—N3	2.089 (3)	C9—C10	1.395 (5)
Cu1—N4	2.099 (3)	C9—C13	1.406 (4)
Cu1—S1i	2.3581 (13)	C10—C11	1.358 (5)
Cu2—C1	1.882 (3)	C10—H10A	0.9300
Cu2—N2	1.976 (3)	C11—C12	1.420 (5)
Cu2—N6	2.123 (3)	C11—H11A	0.9300
Cu2—N5	2.125 (3)	C12—H12A	0.9300
C1—N1	1.145 (5)	C13—C14	1.454 (5)
N2—C2	1.148 (4)	C15—C16	1.391 (5)
N3—C3	1.331 (5)	C15—H15A	0.9300
N3—C14	1.360 (4)	C16—C17	1.356 (6)
N4—C12	1.322 (4)	C16—H16A	0.9300
N4—C13	1.345 (4)	C17—C18	1.417 (5)
N5—C15	1.336 (4)	C17—H17A	0.9300
N5—C26	1.376 (4)	C18—C26	1.382 (5)
N6—C24	1.331 (4)	C18—C19	1.443 (5)
N6—C25	1.351 (4)	C19—C20	1.343 (6)
C2—S1	1.645 (3)	C19—H19A	0.9300
C3—C4	1.363 (6)	C20—C21	1.416 (5)
C3—H3A	0.9300	C20—H20A	0.9300
C4—C5	1.377 (6)	C21—C22	1.406 (5)
C4—H4A	0.9300	C21—C25	1.421 (4)
C5—C6	1.390 (6)	C22—C23	1.366 (6)
C5—H5A	0.9300	C22—H22A	0.9300
C6—C14	1.392 (5)	C23—C24	1.399 (5)
C6—C7	1.452 (5)	C23—H23A	0.9300
C7—C8	1.341 (5)	C24—H24A	0.9300
C7—H7A	0.9300	C25—C26	1.444 (4)
C8—C9	1.433 (5)	S1—Cu1ii	2.3581 (13)
N1—Cu1—N3	121.90 (14)	C9—C10—H10A	120.1
N1—Cu1—N4	122.18 (11)	C10—C11—C12	119.1 (3)
N3—Cu1—N4	79.83 (11)	C10—C11—H11A	120.5
N1—Cu1—S1i	105.99 (9)	C12—C11—H11A	120.5
N3—Cu1—S1i	110.96 (8)	N4—C12—C11	122.4 (3)
N4—Cu1—S1i	114.43 (8)	N4—C12—H12A	118.8
C1—Cu2—N2	121.25 (14)	C11—C12—H12A	118.8
C1—Cu2—N6	125.39 (12)	N4—C13—C9	123.2 (3)
N2—Cu2—N6	98.99 (11)	N4—C13—C14	117.7 (3)
C1—Cu2—N5	117.10 (13)	C9—C13—C14	119.0 (3)
N2—Cu2—N5	106.65 (12)	N3—C14—C6	123.4 (3)
N6—Cu2—N5	78.93 (11)	N3—C14—C13	116.6 (3)
N1—C1—Cu2	178.3 (4)	C6—C14—C13	120.1 (3)
C2—N2—Cu2	178.7 (3)	N5—C15—C16	123.6 (3)
C3—N3—C14	116.5 (3)	N5—C15—H15A	118.2
C3—N3—Cu1	130.5 (2)	C16—C15—H15A	118.2
C14—N3—Cu1	112.9 (2)	C17—C16—C15	119.9 (4)
C12—N4—C13	118.2 (3)	C17—C16—H16A	120.1
C12—N4—Cu1	129.0 (2)	C15—C16—H16A	120.1
C13—N4—Cu1	112.6 (2)	C16—C17—C18	118.8 (4)
C15—N5—C26	116.2 (3)	C16—C17—H17A	120.6
C15—N5—Cu2	130.6 (2)	C18—C17—H17A	120.6
C26—N5—Cu2	113.1 (2)	C26—C18—C17	117.9 (3)
C24—N6—C25	118.3 (3)	C26—C18—C19	120.1 (4)
C24—N6—Cu2	128.5 (3)	C17—C18—C19	122.0 (4)
C25—N6—Cu2	113.0 (2)	C20—C19—C18	119.6 (4)
C1—N1—Cu1	172.5 (4)	C20—C19—H19A	120.2
N2—C2—S1	177.3 (3)	C18—C19—H19A	120.2
N3—C3—C4	124.4 (4)	C19—C20—C21	122.5 (3)
N3—C3—H3A	117.8	C19—C20—H20A	118.7
C4—C3—H3A	117.8	C21—C20—H20A	118.7
C3—C4—C5	118.9 (4)	C22—C21—C20	124.2 (3)
C3—C4—H4A	120.5	C22—C21—C25	116.8 (4)
C5—C4—H4A	120.5	C20—C21—C25	118.9 (3)
C4—C5—C6	119.4 (4)	C23—C22—C21	119.7 (3)
C4—C5—H5A	120.3	C23—C22—H22A	120.1
C6—C5—H5A	120.3	C21—C22—H22A	120.1
C14—C6—C5	117.5 (3)	C22—C23—C24	119.5 (4)
C14—C6—C7	119.4 (3)	C22—C23—H23A	120.2
C5—C6—C7	123.1 (4)	C24—C23—H23A	120.2
C8—C7—C6	120.1 (3)	N6—C24—C23	122.7 (4)
C8—C7—H7A	119.9	N6—C24—H24A	118.7
C6—C7—H7A	119.9	C23—C24—H24A	118.7
C7—C8—C9	122.2 (3)	N6—C25—C21	122.9 (3)
C7—C8—H8A	118.9	N6—C25—C26	118.4 (3)
C9—C8—H8A	118.9	C21—C25—C26	118.7 (3)
C10—C9—C13	117.4 (3)	N5—C26—C18	123.6 (3)
C10—C9—C8	123.4 (3)	N5—C26—C25	116.4 (3)
C13—C9—C8	119.1 (3)	C18—C26—C25	120.0 (3)
C11—C10—C9	119.7 (3)	C2—S1—Cu1ii	102.69 (12)
C11—C10—H10A	120.1
N2—Cu2—C1—N1	−122 (11)	Cu1—N4—C13—C14	4.5 (3)
N6—Cu2—C1—N1	107 (11)	C10—C9—C13—N4	−0.5 (4)
N5—Cu2—C1—N1	11 (11)	C8—C9—C13—N4	179.1 (3)
C1—Cu2—N2—C2	178 (100)	C10—C9—C13—C14	−179.2 (3)
N6—Cu2—N2—C2	−41 (13)	C8—C9—C13—C14	0.3 (4)
N5—Cu2—N2—C2	40 (13)	C3—N3—C14—C6	−1.2 (5)
N1—Cu1—N3—C3	59.4 (4)	Cu1—N3—C14—C6	175.1 (3)
N4—Cu1—N3—C3	−178.9 (3)	C3—N3—C14—C13	178.9 (3)
S1i—Cu1—N3—C3	−66.5 (3)	Cu1—N3—C14—C13	−4.8 (4)
N1—Cu1—N3—C14	−116.3 (2)	C5—C6—C14—N3	−0.3 (5)
N4—Cu1—N3—C14	5.5 (2)	C7—C6—C14—N3	−179.0 (3)
S1i—Cu1—N3—C14	117.9 (2)	C5—C6—C14—C13	179.6 (4)
N1—Cu1—N4—C12	−58.1 (3)	C7—C6—C14—C13	0.9 (5)
N3—Cu1—N4—C12	−179.6 (3)	N4—C13—C14—N3	0.2 (4)
S1i—Cu1—N4—C12	71.9 (3)	C9—C13—C14—N3	179.0 (3)
N1—Cu1—N4—C13	116.1 (2)	N4—C13—C14—C6	−179.7 (3)
N3—Cu1—N4—C13	−5.3 (2)	C9—C13—C14—C6	−0.9 (4)
S1i—Cu1—N4—C13	−113.87 (19)	C26—N5—C15—C16	−0.8 (5)
C1—Cu2—N5—C15	−55.7 (3)	Cu2—N5—C15—C16	179.4 (3)
N2—Cu2—N5—C15	83.8 (3)	N5—C15—C16—C17	−0.3 (6)
N6—Cu2—N5—C15	−180.0 (3)	C15—C16—C17—C18	2.0 (6)
C1—Cu2—N5—C26	124.4 (2)	C16—C17—C18—C26	−2.6 (5)
N2—Cu2—N5—C26	−96.0 (2)	C16—C17—C18—C19	176.6 (4)
N6—Cu2—N5—C26	0.2 (2)	C26—C18—C19—C20	2.5 (5)
C1—Cu2—N6—C24	67.3 (3)	C17—C18—C19—C20	−176.7 (4)
N2—Cu2—N6—C24	−71.8 (3)	C18—C19—C20—C21	−3.5 (6)
N5—Cu2—N6—C24	−177.2 (3)	C19—C20—C21—C22	−178.3 (4)
C1—Cu2—N6—C25	−117.6 (2)	C19—C20—C21—C25	1.4 (5)
N2—Cu2—N6—C25	103.2 (2)	C20—C21—C22—C23	178.7 (3)
N5—Cu2—N6—C25	−2.1 (2)	C25—C21—C22—C23	−0.9 (5)
Cu2—C1—N1—Cu1	−39 (13)	C21—C22—C23—C24	0.3 (6)
N3—Cu1—N1—C1	−177 (2)	C25—N6—C24—C23	−0.6 (5)
N4—Cu1—N1—C1	85 (2)	Cu2—N6—C24—C23	174.2 (3)
S1i—Cu1—N1—C1	−49 (2)	C22—C23—C24—N6	0.5 (6)
Cu2—N2—C2—S1	−66 (17)	C24—N6—C25—C21	−0.2 (4)
C14—N3—C3—C4	2.1 (6)	Cu2—N6—C25—C21	−175.7 (2)
Cu1—N3—C3—C4	−173.4 (3)	C24—N6—C25—C26	179.4 (3)
N3—C3—C4—C5	−1.3 (8)	Cu2—N6—C25—C26	3.9 (3)
C3—C4—C5—C6	−0.3 (8)	C22—C21—C25—N6	0.9 (5)
C4—C5—C6—C14	1.1 (7)	C20—C21—C25—N6	−178.7 (3)
C4—C5—C6—C7	179.7 (4)	C22—C21—C25—C26	−178.7 (3)
C14—C6—C7—C8	−0.4 (6)	C20—C21—C25—C26	1.7 (4)
C5—C6—C7—C8	−179.0 (4)	C15—N5—C26—C18	0.1 (5)
C6—C7—C8—C9	−0.2 (6)	Cu2—N5—C26—C18	180.0 (2)
C7—C8—C9—C10	179.7 (4)	C15—N5—C26—C25	−178.1 (3)
C7—C8—C9—C13	0.2 (5)	Cu2—N5—C26—C25	1.8 (3)
C13—C9—C10—C11	−0.1 (5)	C17—C18—C26—N5	1.6 (5)
C8—C9—C10—C11	−179.7 (3)	C19—C18—C26—N5	−177.7 (3)
C9—C10—C11—C12	0.6 (5)	C17—C18—C26—C25	179.7 (3)
C13—N4—C12—C11	−0.2 (5)	C19—C18—C26—C25	0.5 (5)
Cu1—N4—C12—C11	173.8 (2)	N6—C25—C26—N5	−3.8 (4)
C10—C11—C12—N4	−0.4 (5)	C21—C25—C26—N5	175.8 (3)
C12—N4—C13—C9	0.6 (4)	N6—C25—C26—C18	177.9 (3)
Cu1—N4—C13—C9	−174.3 (2)	C21—C25—C26—C18	−2.5 (4)
C12—N4—C13—C14	179.4 (3)	N2—C2—S1—Cu1ii	163 (6)