Tris(tetra-methyl-ammonium) tetra-μ(2)-sulfido-tetra-sulfidocopper(I)dimolyb-denum(VI) N,N-dimethyl-formamide solvate.

The title compound, (C(4)H(12)N)(3)[CuMo(2)S(8)]·C(3)H(7)NO, was obtained from the self-assembly of tetra-thio-molybdate, tetra-methyl-ammonium nitrate and cuprous sulfide in dimethyl-formamide (DMF). The asymmetric unit contains three (NMe(4))(+) cations, one [Mo(2)S(8)Cu](3-) anion and one DMF solvent mol-ecule, and no obvious inter-actions are observed between these species. The trinuclear anion can be viewed as fused [MoS(4)Cu](-) units sharing a copper center. The geometric parameters of the trivalent anion are comparable to those reported for other related salts including isomorphous anions, namely (NEt(4))(2)(PPh(4))[Mo(2)S(8)Cu] (a) and (Ph(3)P=N=PPh(3))(2)(NEt(4))[W(2)S(8)Cu]·2CH(3)CN (b). However, the Mo-Cu-Mo angle is found to be 160.24 (3)° for the title salt, while this angle is 162.97 (2)° in (a) and the W-Cu-W angle is 170.3 (2)° in (b), indicating that the largest deviation from linearity is in the title compound.

Related literature

For related MoVI/CuI and WVI/CuI complexes, see: Niu et al. (2002 ▶); Maiti et al. (2004 ▶); Müller et al. (1989 ▶).

Experimental

Crystal data

(C4H12N)3[CuMo2S8]·C3H7NO

M = 807.43

Monoclinic,

a = 9.4380 (19) Å

b = 20.336 (4) Å

c = 17.718 (4) Å

β = 98.60 (3)°

V = 3362.4 (12) Å3

Z = 4

Mo Kα radiation

μ = 1.87 mm−1

T = 293 (2) K

0.40 × 0.30 × 0.25 mm

Data collection

Bruker APEX CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 1998 ▶) T min = 0.527, T max = 0.618

17155 measured reflections

6625 independent reflections

5061 reflections with I > 2σ(I)

R int = 0.039

Refinement

R[F 2 > 2σ(F 2)] = 0.042

wR(F 2) = 0.136

S = 1.05

6625 reflections

274 parameters

H-atom parameters constrained

Δρmax = 0.93 e Å−3

Δρmin = −0.85 e Å−3

Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT (Bruker, 1998 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808036532/bh2199sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808036532/bh2199Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

(C4H12N)3[CuMo2S8]·C3H7NO	F000 = 1640
Mr = 807.43	Dx = 1.595 Mg m−3
Monoclinic, P21/n	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 7032 reflections
a = 9.4380 (19) Å	θ = 1.2–26.1º
b = 20.336 (4) Å	µ = 1.87 mm−1
c = 17.718 (4) Å	T = 293 (2) K
β = 98.60 (3)º	Polyhedron, black red
V = 3362.4 (12) Å3	0.40 × 0.30 × 0.25 mm
Z = 4

Bruker APEX CCD area-detector diffractometer	6625 independent reflections
Radiation source: fine-focus sealed tube	5061 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.039
T = 293(2) K	θmax = 26.0º
φ and ω scans	θmin = 1.5º
Absorption correction: multi-scan(SADABS; Bruker, 1998)	h = −11→11
Tmin = 0.527, Tmax = 0.618	k = −24→25
17155 measured reflections	l = −21→21

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.042	H-atom parameters constrained
wR(F2) = 0.136	w = 1/[σ2(Fo2) + (0.0646P)2] where P = (Fo2 + 2Fc2)/3
S = 1.05	(Δ/σ)max < 0.001
6625 reflections	Δρmax = 0.93 e Å−3
274 parameters	Δρmin = −0.85 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

	x	y	z	Uiso*/Ueq
Mo1	0.25496 (5)	0.15816 (2)	0.93899 (3)	0.04775 (14)
Mo2	0.31519 (5)	0.05342 (2)	0.66754 (3)	0.04773 (14)
Cu1	0.24065 (7)	0.09541 (3)	0.80223 (4)	0.04912 (18)
S1	0.11495 (15)	0.18682 (7)	0.83342 (8)	0.0494 (3)
S2	0.31587 (15)	0.05454 (7)	0.92589 (8)	0.0489 (3)
S3	0.12487 (15)	0.02298 (7)	0.71839 (8)	0.0483 (3)
S4	0.43472 (16)	0.12836 (7)	0.74081 (8)	0.0514 (3)
S5	0.45325 (16)	−0.03117 (8)	0.65994 (8)	0.0532 (3)
S6	0.24512 (16)	0.09507 (7)	0.55703 (9)	0.0543 (3)
S7	0.44848 (16)	0.21739 (7)	0.95638 (8)	0.0516 (3)
S8	0.13280 (16)	0.16860 (7)	1.03204 (8)	0.0522 (3)
O1	0.1656 (5)	0.1069 (2)	1.2555 (3)	0.0610 (11)
N1	0.2487 (5)	0.1922 (2)	1.3279 (3)	0.0500 (11)
C11	0.2068 (7)	0.1295 (3)	1.3196 (4)	0.0553 (14)
H11A	0.2088	0.1028	1.3624	0.066*
C12	0.2912 (7)	0.2217 (3)	1.4013 (4)	0.0605 (15)
H12A	0.3093	0.1879	1.4393	0.091*
H12B	0.2160	0.2499	1.4133	0.091*
H12C	0.3767	0.2471	1.4006	0.091*
C13	0.2171 (7)	0.2367 (3)	1.2639 (4)	0.0579 (15)
H13A	0.1901	0.2118	1.2179	0.087*
H13B	0.3006	0.2625	1.2592	0.087*
H13C	0.1398	0.2653	1.2719	0.087*
N2	0.7731 (5)	0.1115 (2)	0.5453 (3)	0.0507 (11)
C21	0.8726 (7)	0.1130 (3)	0.4883 (4)	0.0616 (16)
H21A	0.9607	0.0916	0.5089	0.092*
H21B	0.8918	0.1578	0.4761	0.092*
H21C	0.8301	0.0905	0.4429	0.092*
C22	0.8482 (7)	0.1530 (3)	0.6068 (3)	0.0549 (14)
H22A	0.9399	0.1340	0.6254	0.082*
H22B	0.7922	0.1557	0.6476	0.082*
H22C	0.8613	0.1963	0.5873	0.082*
C23	0.6306 (7)	0.1439 (3)	0.5187 (4)	0.0600 (15)
H23A	0.5717	0.1411	0.5583	0.090*
H23B	0.5839	0.1219	0.4738	0.090*
H23C	0.6457	0.1892	0.5070	0.090*
C24	0.7503 (7)	0.0474 (3)	0.5762 (4)	0.0557 (14)
H24A	0.8411	0.0269	0.5931	0.084*
H24B	0.6960	0.0207	0.5376	0.084*
H24C	0.6985	0.0519	0.6186	0.084*
N3	0.7749 (5)	0.0309 (2)	0.8680 (3)	0.0525 (11)
C31	0.9019 (7)	−0.0048 (3)	0.9017 (3)	0.0554 (14)
H31A	0.9818	0.0248	0.9108	0.083*
H31B	0.9224	−0.0389	0.8674	0.083*
H31C	0.8857	−0.0241	0.9491	0.083*
C32	0.7374 (7)	0.0836 (3)	0.9250 (4)	0.0574 (14)
H32A	0.8146	0.1146	0.9350	0.086*
H32B	0.7231	0.0626	0.9719	0.086*
H32C	0.6513	0.1061	0.9036	0.086*
C33	0.7972 (6)	0.0578 (3)	0.7979 (4)	0.0577 (14)
H33A	0.8760	0.0881	0.8061	0.087*
H33B	0.7123	0.0805	0.7751	0.087*
H33C	0.8187	0.0232	0.7645	0.087*
C34	0.6474 (4)	−0.01784 (16)	0.85381 (19)	0.0594 (14)
H34A	0.6675	−0.0512	0.8185	0.089*
H34B	0.5620	0.0054	0.8329	0.089*
H34C	0.6339	−0.0380	0.9012	0.089*
N4	0.2179 (4)	0.32703 (16)	0.67898 (19)	0.0504 (10)
C41	0.2608 (4)	0.27407 (16)	0.63794 (19)	0.0593 (15)
H41A	0.2482	0.2339	0.6647	0.089*
H41B	0.3599	0.2791	0.6325	0.089*
H41C	0.2037	0.2727	0.5883	0.089*
C42	0.3149 (6)	0.3291 (3)	0.7528 (3)	0.0522 (13)
H42A	0.3032	0.2897	0.7811	0.078*
H42B	0.2922	0.3666	0.7816	0.078*
H42C	0.4124	0.3322	0.7436	0.078*
C43	0.2388 (6)	0.3897 (3)	0.6357 (3)	0.0512 (13)
H43A	0.3368	0.3929	0.6276	0.077*
H43B	0.2152	0.4269	0.6647	0.077*
H43C	0.1774	0.3890	0.5873	0.077*
C44	0.0667 (6)	0.3221 (3)	0.6915 (4)	0.0560 (14)
H44A	0.0536	0.2824	0.7190	0.084*
H44B	0.0053	0.3214	0.6432	0.084*
H44C	0.0431	0.3593	0.7206	0.084*

	U11	U22	U33	U12	U13	U23
Mo1	0.0462 (3)	0.0487 (3)	0.0477 (3)	0.00610 (19)	0.00487 (19)	−0.00193 (19)
Mo2	0.0459 (3)	0.0490 (3)	0.0484 (3)	0.00548 (19)	0.00763 (19)	0.00304 (19)
Cu1	0.0491 (4)	0.0505 (4)	0.0476 (4)	0.0071 (3)	0.0065 (3)	−0.0035 (3)
S1	0.0479 (7)	0.0533 (7)	0.0479 (7)	0.0088 (6)	0.0104 (6)	−0.0037 (6)
S2	0.0476 (7)	0.0524 (7)	0.0464 (7)	0.0074 (6)	0.0060 (5)	−0.0030 (6)
S3	0.0467 (7)	0.0504 (7)	0.0484 (7)	0.0073 (5)	0.0092 (6)	0.0045 (6)
S4	0.0545 (8)	0.0472 (7)	0.0531 (7)	0.0107 (6)	0.0103 (6)	0.0061 (6)
S5	0.0503 (8)	0.0580 (8)	0.0526 (7)	0.0073 (6)	0.0124 (6)	0.0045 (6)
S6	0.0538 (8)	0.0518 (8)	0.0567 (8)	0.0112 (6)	0.0069 (6)	−0.0029 (6)
S7	0.0513 (7)	0.0521 (7)	0.0526 (7)	0.0119 (6)	0.0118 (6)	−0.0056 (6)
S8	0.0511 (7)	0.0520 (7)	0.0540 (8)	0.0122 (6)	0.0101 (6)	0.0052 (6)
O1	0.058 (2)	0.069 (3)	0.056 (2)	0.014 (2)	0.0089 (19)	0.022 (2)
N1	0.046 (2)	0.050 (3)	0.055 (3)	−0.0102 (19)	0.011 (2)	0.012 (2)
C11	0.053 (3)	0.053 (3)	0.061 (4)	−0.015 (3)	0.010 (3)	0.015 (3)
C12	0.062 (4)	0.053 (3)	0.068 (4)	−0.014 (3)	0.014 (3)	0.010 (3)
C13	0.063 (3)	0.044 (3)	0.061 (3)	0.009 (3)	−0.006 (3)	−0.015 (3)
N2	0.051 (3)	0.051 (3)	0.051 (3)	−0.005 (2)	0.011 (2)	0.011 (2)
C21	0.060 (4)	0.056 (3)	0.061 (3)	0.017 (3)	−0.015 (3)	0.008 (3)
C22	0.051 (3)	0.067 (4)	0.050 (3)	0.005 (3)	0.017 (2)	0.010 (3)
C23	0.067 (4)	0.051 (3)	0.054 (3)	0.020 (3)	−0.015 (3)	0.008 (3)
C24	0.054 (3)	0.059 (3)	0.055 (3)	0.013 (3)	0.008 (3)	0.008 (3)
N3	0.056 (3)	0.047 (2)	0.054 (3)	−0.004 (2)	0.009 (2)	−0.004 (2)
C31	0.067 (4)	0.049 (3)	0.051 (3)	0.009 (3)	0.011 (3)	0.009 (2)
C32	0.056 (3)	0.063 (4)	0.054 (3)	−0.006 (3)	0.009 (3)	0.015 (3)
C33	0.040 (3)	0.064 (4)	0.070 (4)	−0.005 (2)	0.009 (3)	0.013 (3)
C34	0.059 (4)	0.057 (3)	0.062 (4)	0.004 (3)	0.011 (3)	0.010 (3)
N4	0.049 (3)	0.045 (2)	0.057 (3)	−0.010 (2)	0.006 (2)	0.006 (2)
C41	0.066 (4)	0.063 (4)	0.049 (3)	0.010 (3)	0.009 (3)	0.015 (3)
C42	0.047 (3)	0.057 (3)	0.054 (3)	−0.006 (2)	0.011 (2)	0.011 (3)
C43	0.050 (3)	0.056 (3)	0.050 (3)	−0.015 (2)	0.015 (2)	−0.011 (2)
C44	0.053 (3)	0.051 (3)	0.059 (3)	0.012 (3)	−0.005 (3)	0.009 (3)

Mo1—S8	2.1589 (16)	C23—H23C	0.9600
Mo1—S7	2.1710 (17)	C24—H24A	0.9600
Mo1—S1	2.2013 (16)	C24—H24B	0.9600
Mo1—S2	2.2057 (15)	C24—H24C	0.9600
Mo1—Cu1	2.7241 (9)	N3—C33	1.401 (8)
Mo2—S6	2.1451 (17)	N3—C31	1.453 (8)
Mo2—S5	2.1742 (16)	N3—C32	1.549 (9)
Mo2—S4	2.2006 (17)	N3—C34	1.550 (6)
Mo2—S3	2.2148 (16)	C31—H31A	0.9600
Mo2—Cu1	2.7241 (10)	C31—H31B	0.9600
Cu1—S3	2.2549 (17)	C31—H31C	0.9600
Cu1—S1	2.3161 (15)	C32—H32A	0.9600
Cu1—S2	2.3518 (16)	C32—H32B	0.9600
Cu1—S4	2.3630 (17)	C32—H32C	0.9600
O1—C11	1.232 (8)	C33—H33A	0.9600
N1—C11	1.338 (8)	C33—H33B	0.9600
N1—C12	1.434 (9)	C33—H33C	0.9600
N1—C13	1.447 (8)	C34—H34A	0.9600
C11—H11A	0.9300	C34—H34B	0.9600
C12—H12A	0.9600	C34—H34C	0.9600
C12—H12B	0.9600	N4—C41	1.392 (9)
C12—H12C	0.9600	N4—C42	1.481 (7)
C13—H13A	0.9600	N4—C44	1.481 (7)
C13—H13B	0.9600	N4—C43	1.515 (7)
C13—H13C	0.9600	C41—H41A	0.9600
N2—C24	1.443 (8)	C41—H41B	0.9600
N2—C22	1.473 (8)	C41—H41C	0.9600
N2—C21	1.478 (9)	C42—H42A	0.9600
N2—C23	1.508 (7)	C42—H42B	0.9600
C21—H21A	0.9600	C42—H42C	0.9600
C21—H21B	0.9600	C43—H43A	0.9600
C21—H21C	0.9600	C43—H43B	0.9600
C22—H22A	0.9600	C43—H43C	0.9600
C22—H22B	0.9600	C44—H44A	0.9600
C22—H22C	0.9600	C44—H44B	0.9600
C23—H23A	0.9600	C44—H44C	0.9600
C23—H23B	0.9600
S8—Mo1—S7	111.79 (6)	H22B—C22—H22C	109.5
S8—Mo1—S1	107.55 (6)	N2—C23—H23A	109.5
S7—Mo1—S1	111.04 (6)	N2—C23—H23B	109.5
S8—Mo1—S2	110.59 (6)	H23A—C23—H23B	109.5
S7—Mo1—S2	108.54 (6)	N2—C23—H23C	109.5
S1—Mo1—S2	107.24 (6)	H23A—C23—H23C	109.5
S8—Mo1—Cu1	139.84 (5)	H23B—C23—H23C	109.5
S7—Mo1—Cu1	108.35 (5)	N2—C24—H24A	109.5
S1—Mo1—Cu1	54.87 (4)	N2—C24—H24B	109.5
S2—Mo1—Cu1	55.80 (4)	H24A—C24—H24B	109.5
S6—Mo2—S5	111.20 (6)	N2—C24—H24C	109.5
S6—Mo2—S4	109.02 (6)	H24A—C24—H24C	109.5
S5—Mo2—S4	108.98 (6)	H24B—C24—H24C	109.5
S6—Mo2—S3	108.88 (6)	C33—N3—C31	109.6 (5)
S5—Mo2—S3	109.52 (6)	C33—N3—C32	112.8 (5)
S4—Mo2—S3	109.21 (6)	C31—N3—C32	109.4 (5)
S6—Mo2—Cu1	126.23 (5)	C33—N3—C34	108.8 (4)
S5—Mo2—Cu1	122.54 (5)	C31—N3—C34	108.6 (4)
S4—Mo2—Cu1	56.14 (4)	C32—N3—C34	107.5 (4)
S3—Mo2—Cu1	53.12 (5)	N3—C31—H31A	109.5
S3—Cu1—S1	117.80 (6)	N3—C31—H31B	109.5
S3—Cu1—S2	115.59 (6)	H31A—C31—H31B	109.5
S1—Cu1—S2	98.94 (6)	N3—C31—H31C	109.5
S3—Cu1—S4	102.39 (6)	H31A—C31—H31C	109.5
S1—Cu1—S4	110.01 (6)	H31B—C31—H31C	109.5
S2—Cu1—S4	112.49 (6)	N3—C32—H32A	109.5
S3—Cu1—Mo2	51.78 (4)	N3—C32—H32B	109.5
S1—Cu1—Mo2	132.00 (5)	H32A—C32—H32B	109.5
S2—Cu1—Mo2	128.60 (4)	N3—C32—H32C	109.5
S4—Cu1—Mo2	50.66 (4)	H32A—C32—H32C	109.5
S3—Cu1—Mo1	147.85 (5)	H32B—C32—H32C	109.5
S1—Cu1—Mo1	51.01 (4)	N3—C33—H33A	109.5
S2—Cu1—Mo1	50.87 (4)	N3—C33—H33B	109.5
S4—Cu1—Mo1	109.76 (5)	H33A—C33—H33B	109.5
Mo2—Cu1—Mo1	160.24 (3)	N3—C33—H33C	109.5
Mo1—S1—Cu1	74.13 (5)	H33A—C33—H33C	109.5
Mo1—S2—Cu1	73.34 (5)	H33B—C33—H33C	109.5
Mo2—S3—Cu1	75.09 (5)	N3—C34—H34A	109.5
Mo2—S4—Cu1	73.20 (5)	N3—C34—H34B	109.5
C11—N1—C12	122.4 (5)	H34A—C34—H34B	109.5
C11—N1—C13	119.2 (5)	N3—C34—H34C	109.5
C12—N1—C13	116.6 (5)	H34A—C34—H34C	109.5
O1—C11—N1	120.3 (5)	H34B—C34—H34C	109.5
O1—C11—H11A	119.9	C41—N4—C42	107.0 (3)
N1—C11—H11A	119.9	C41—N4—C44	112.8 (3)
N1—C12—H12A	109.5	C42—N4—C44	110.6 (4)
N1—C12—H12B	109.5	C41—N4—C43	108.4 (3)
H12A—C12—H12B	109.5	C42—N4—C43	108.3 (4)
N1—C12—H12C	109.5	C44—N4—C43	109.5 (4)
H12A—C12—H12C	109.5	N4—C41—H41A	109.5
H12B—C12—H12C	109.5	N4—C41—H41B	109.5
N1—C13—H13A	109.5	H41A—C41—H41B	109.5
N1—C13—H13B	109.5	N4—C41—H41C	109.5
H13A—C13—H13B	109.5	H41A—C41—H41C	109.5
N1—C13—H13C	109.5	H41B—C41—H41C	109.5
H13A—C13—H13C	109.5	N4—C42—H42A	109.5
H13B—C13—H13C	109.5	N4—C42—H42B	109.5
C24—N2—C22	108.6 (5)	H42A—C42—H42B	109.5
C24—N2—C21	115.1 (5)	N4—C42—H42C	109.5
C22—N2—C21	102.0 (4)	H42A—C42—H42C	109.5
C24—N2—C23	109.7 (5)	H42B—C42—H42C	109.5
C22—N2—C23	106.8 (5)	N4—C43—H43A	109.5
C21—N2—C23	113.9 (5)	N4—C43—H43B	109.5
N2—C21—H21A	109.5	H43A—C43—H43B	109.5
N2—C21—H21B	109.5	N4—C43—H43C	109.5
H21A—C21—H21B	109.5	H43A—C43—H43C	109.5
N2—C21—H21C	109.5	H43B—C43—H43C	109.5
H21A—C21—H21C	109.5	N4—C44—H44A	109.5
H21B—C21—H21C	109.5	N4—C44—H44B	109.5
N2—C22—H22A	109.5	H44A—C44—H44B	109.5
N2—C22—H22B	109.5	N4—C44—H44C	109.5
H22A—C22—H22B	109.5	H44A—C44—H44C	109.5
N2—C22—H22C	109.5	H44B—C44—H44C	109.5
H22A—C22—H22C	109.5
S6—Mo2—Cu1—S3	87.24 (8)	S7—Mo1—Cu1—Mo2	3.80 (11)
S5—Mo2—Cu1—S3	−90.96 (7)	S1—Mo1—Cu1—Mo2	107.05 (11)
S4—Mo2—Cu1—S3	176.95 (6)	S2—Mo1—Cu1—Mo2	−96.54 (10)
S6—Mo2—Cu1—S1	−7.91 (9)	S8—Mo1—S1—Cu1	−139.25 (6)
S5—Mo2—Cu1—S1	173.89 (8)	S7—Mo1—S1—Cu1	98.15 (6)
S4—Mo2—Cu1—S1	81.80 (8)	S2—Mo1—S1—Cu1	−20.28 (6)
S3—Mo2—Cu1—S1	−95.15 (8)	S3—Cu1—S1—Mo1	143.57 (6)
S6—Mo2—Cu1—S2	−178.47 (8)	S2—Cu1—S1—Mo1	18.32 (6)
S5—Mo2—Cu1—S2	3.34 (9)	S4—Cu1—S1—Mo1	−99.67 (6)
S4—Mo2—Cu1—S2	−88.76 (8)	Mo2—Cu1—S1—Mo1	−154.22 (5)
S3—Mo2—Cu1—S2	94.29 (8)	S8—Mo1—S2—Cu1	137.04 (6)
S6—Mo2—Cu1—S4	−89.71 (8)	S7—Mo1—S2—Cu1	−99.99 (6)
S5—Mo2—Cu1—S4	92.10 (7)	S1—Mo1—S2—Cu1	20.04 (6)
S3—Mo2—Cu1—S4	−176.95 (6)	S3—Cu1—S2—Mo1	−145.14 (5)
S6—Mo2—Cu1—Mo1	−98.05 (11)	S1—Cu1—S2—Mo1	−18.36 (6)
S5—Mo2—Cu1—Mo1	83.75 (11)	S4—Cu1—S2—Mo1	97.75 (6)
S4—Mo2—Cu1—Mo1	−8.35 (10)	Mo2—Cu1—S2—Mo1	154.55 (4)
S3—Mo2—Cu1—Mo1	174.71 (11)	S6—Mo2—S3—Cu1	−121.63 (6)
S8—Mo1—Cu1—S3	−5.97 (12)	S5—Mo2—S3—Cu1	116.59 (6)
S7—Mo1—Cu1—S3	175.98 (9)	S4—Mo2—S3—Cu1	−2.69 (6)
S1—Mo1—Cu1—S3	−80.77 (10)	S1—Cu1—S3—Mo2	123.21 (6)
S2—Mo1—Cu1—S3	75.63 (10)	S2—Cu1—S3—Mo2	−120.22 (5)
S8—Mo1—Cu1—S1	74.81 (8)	S4—Cu1—S3—Mo2	2.42 (5)
S7—Mo1—Cu1—S1	−103.25 (7)	Mo1—Cu1—S3—Mo2	−176.64 (7)
S2—Mo1—Cu1—S1	156.40 (7)	S6—Mo2—S4—Cu1	121.44 (5)
S8—Mo1—Cu1—S2	−81.60 (8)	S5—Mo2—S4—Cu1	−117.02 (5)
S7—Mo1—Cu1—S2	100.35 (7)	S3—Mo2—S4—Cu1	2.59 (5)
S1—Mo1—Cu1—S2	−156.40 (7)	S3—Cu1—S4—Mo2	−2.46 (5)
S8—Mo1—Cu1—S4	175.01 (7)	S1—Cu1—S4—Mo2	−128.49 (5)
S7—Mo1—Cu1—S4	−3.04 (6)	S2—Cu1—S4—Mo2	122.26 (6)
S1—Mo1—Cu1—S4	100.20 (7)	Mo1—Cu1—S4—Mo2	177.01 (3)
S2—Mo1—Cu1—S4	−103.39 (6)	C12—N1—C11—O1	177.0 (6)
S8—Mo1—Cu1—Mo2	−178.14 (9)	C13—N1—C11—O1	13.0 (9)