A one-dimensional Ag coordination polymer: catena-poly[[[[N'-(4-cyano-benzyl-idene)nicotinohydrazide]silver(I)]-μ-N'-(4-cyano-benzyl-idene)nicotino-hydrazide] trifluoro-methane-sulfonate].

In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3)}(n), the unique Ag(I) ion is coordinated by two N atoms from two pyridine rings of two independent N'-(4-cyano-benzyl-idene)nicotinohydrazide ligands and one N atom of a carbonitrile group of a symmetry-related N'-(4-cyano-benzyl-idene)nicotino-hydrazide ligand, forming a distorted T-shaped coordination environment. One of the independent ligands acts as a bridge connecting Ag(I) ions, forming chains along the a axis. In the crystal structure, two neighbouring anti-parallel chains are connected through N-H⋯O hydrogen bonds. In addition, there are relatively short Ag⋯O contacts of 2.723 (3) Å, which connect the chains into a three-dimensional structure.

Related literature

For a related structure, see: Niu et al. (2007 ▶).

Experimental

Crystal data

[Ag(C14H10N4O)2]CF3SO3

M = 757.46

Monoclinic,

a = 24.966 (2) Å

b = 13.9529 (13) Å

c = 17.6976 (16) Å

β = 98.437 (2)°

V = 6098.3 (10) Å3

Z = 8

Mo Kα radiation

μ = 0.80 mm−1

T = 173 (2) K

0.51 × 0.32 × 0.27 mm

Data collection

Siemens SMART CCD diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.685, T max = 0.813

19396 measured reflections

6990 independent reflections

5059 reflections with I > 2σ(I)

R int = 0.030

Refinement

R[F 2 > 2σ(F 2)] = 0.049

wR(F 2) = 0.148

S = 1.03

6990 reflections

432 parameters

22 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 1.47 e Å−3

Δρmin = −0.79 e Å−3

Data collection: SMART (Siemens, 1996 ▶); cell refinement: SAINT (Siemens, 1996 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 2005 ▶); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808034685/lh2709sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808034685/lh2709Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C14H10N4O)2]CF3SO3	F(000) = 3040
Mr = 757.46	Dx = 1.650 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 5153 reflections
a = 24.966 (2) Å	θ = 2.1–27.5°
b = 13.9529 (13) Å	µ = 0.80 mm−1
c = 17.6976 (16) Å	T = 173 K
β = 98.437 (2)°	Prism, colourless
V = 6098.3 (10) Å3	0.51 × 0.32 × 0.27 mm
Z = 8

Siemens SMART CCD diffractometer	6990 independent reflections
Radiation source: fine-focus sealed tube	5059 reflections with I > 2σ(I)
graphite	Rint = 0.031
φ and ω scans	θmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −28→32
Tmin = 0.685, Tmax = 0.813	k = −18→17
19396 measured reflections	l = −22→15

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.049	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.148	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ2(Fo2) + (0.0766P)2 + 8.964P] where P = (Fo2 + 2Fc2)/3
6990 reflections	(Δ/σ)max < 0.001
432 parameters	Δρmax = 1.47 e Å−3
22 restraints	Δρmin = −0.79 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Ag1	0.177461 (13)	0.31617 (2)	0.21259 (2)	0.05965 (14)
N1	0.16489 (13)	0.4710 (2)	0.22045 (18)	0.0481 (7)
N2	0.19741 (12)	0.17730 (19)	0.16389 (17)	0.0421 (6)
N3	0.25625 (13)	0.6644 (2)	0.10836 (19)	0.0488 (7)
N4	0.29258 (12)	0.7215 (2)	0.07857 (19)	0.0497 (7)
N5	0.5169 (2)	0.9140 (4)	−0.1204 (3)	0.1027 (17)
N6	0.32032 (13)	0.1492 (2)	0.02428 (18)	0.0480 (7)
N7	0.35916 (12)	0.1432 (2)	−0.02381 (18)	0.0491 (7)
N8	0.60476 (14)	0.2456 (3)	−0.2154 (2)	0.0662 (10)
S1	0.35594 (5)	0.41766 (7)	0.11529 (6)	0.0575 (3)
O1	0.23222 (12)	0.78306 (19)	0.18438 (17)	0.0603 (7)
O2	0.28597 (11)	0.0026 (2)	−0.01063 (16)	0.0589 (7)
O3	0.33416 (17)	0.3230 (2)	0.1160 (2)	0.0852 (11)
O4	0.32654 (16)	0.4890 (3)	0.1495 (2)	0.0886 (11)
O5	0.37379 (17)	0.4448 (2)	0.04515 (19)	0.0852 (11)
F1	0.4489 (2)	0.3413 (5)	0.1600 (3)	0.180 (2)
F2	0.40950 (15)	0.3851 (3)	0.2507 (2)	0.1073 (11)
F3	0.4445 (2)	0.4874 (4)	0.1883 (3)	0.180 (2)
C1	0.12856 (16)	0.5082 (3)	0.2610 (2)	0.0548 (10)
H1	0.1059	0.4658	0.2839	0.066*
C2	0.12275 (17)	0.6049 (3)	0.2707 (3)	0.0611 (11)
H2	0.0966	0.6289	0.2998	0.073*
C3	0.15543 (18)	0.6664 (3)	0.2376 (3)	0.0562 (10)
H3	0.1524	0.7336	0.2444	0.067*
C4	0.19279 (14)	0.6307 (2)	0.19433 (19)	0.0410 (7)
C5	0.19597 (15)	0.5322 (3)	0.1878 (2)	0.0452 (8)
H5	0.2216	0.5065	0.1585	0.054*
C6	0.22824 (15)	0.6994 (2)	0.1618 (2)	0.0437 (8)
C7	0.32028 (16)	0.6787 (3)	0.0335 (2)	0.0497 (9)
H7	0.3143	0.6126	0.0226	0.060*
C8	0.36060 (15)	0.7304 (3)	−0.0009 (2)	0.0492 (9)
C9	0.39393 (18)	0.6808 (3)	−0.0440 (3)	0.0629 (11)
H9	0.3893	0.6137	−0.0514	0.075*
C10	0.43334 (18)	0.7280 (4)	−0.0756 (3)	0.0657 (11)
H10	0.4556	0.6936	−0.1054	0.079*
C11	0.44089 (18)	0.8263 (3)	−0.0643 (3)	0.0610 (11)
C12	0.40796 (18)	0.8751 (3)	−0.0220 (3)	0.0624 (11)
H12	0.4131	0.9420	−0.0139	0.075*
C13	0.36835 (17)	0.8298 (3)	0.0086 (2)	0.0549 (10)
H13	0.3455	0.8654	0.0367	0.066*
C14	0.4834 (2)	0.8750 (4)	−0.0962 (3)	0.0731 (13)
C15	0.18030 (14)	0.0956 (3)	0.1923 (2)	0.0434 (8)
H15	0.1556	0.0994	0.2283	0.052*
C16	0.19682 (16)	0.0068 (3)	0.1717 (2)	0.0496 (9)
H16	0.1842	−0.0494	0.1936	0.060*
C17	0.23172 (15)	0.0003 (2)	0.1192 (2)	0.0440 (8)
H17	0.2436	−0.0606	0.1042	0.053*
C18	0.24964 (13)	0.0833 (2)	0.08797 (19)	0.0390 (7)
C19	0.23178 (14)	0.1700 (2)	0.1127 (2)	0.0408 (7)
H19	0.2445	0.2273	0.0924	0.049*
C20	0.28677 (14)	0.0743 (2)	0.0289 (2)	0.0421 (8)
C21	0.38690 (16)	0.2191 (3)	−0.0263 (2)	0.0513 (9)
H21	0.3784	0.2739	0.0016	0.062*
C22	0.43167 (14)	0.2241 (3)	−0.0711 (2)	0.0470 (8)
C23	0.45139 (15)	0.1431 (3)	−0.1041 (2)	0.0496 (9)
H23	0.4343	0.0828	−0.1004	0.059*
C24	0.49545 (16)	0.1502 (3)	−0.1419 (2)	0.0516 (9)
H24	0.5091	0.0949	−0.1639	0.062*
C25	0.52007 (14)	0.2387 (3)	−0.1478 (2)	0.0481 (8)
C26	0.50079 (18)	0.3193 (3)	−0.1168 (3)	0.0615 (11)
H26	0.5176	0.3796	−0.1218	0.074*
C27	0.45664 (18)	0.3123 (3)	−0.0780 (3)	0.0590 (11)
H27	0.4433	0.3678	−0.0559	0.071*
C28	0.56767 (15)	0.2436 (3)	−0.1854 (2)	0.0524 (9)
C29	0.4169 (2)	0.4087 (4)	0.1813 (4)	0.0870 (16)
H28	0.3208 (14)	0.1991 (18)	0.0520 (17)	0.034 (9)*
H29	0.2522 (16)	0.6077 (15)	0.088 (2)	0.077 (15)*

	U11	U22	U33	U12	U13	U23
Ag1	0.0648 (2)	0.03572 (18)	0.0846 (3)	0.00461 (12)	0.03151 (17)	−0.00623 (14)
N1	0.0518 (17)	0.0365 (16)	0.0593 (18)	0.0005 (13)	0.0199 (14)	−0.0055 (13)
N2	0.0429 (15)	0.0342 (15)	0.0533 (17)	0.0026 (12)	0.0204 (13)	0.0006 (12)
N3	0.0516 (18)	0.0351 (17)	0.062 (2)	−0.0037 (13)	0.0157 (15)	−0.0009 (14)
N4	0.0453 (17)	0.0426 (17)	0.0613 (19)	−0.0032 (13)	0.0087 (14)	0.0035 (15)
N5	0.097 (3)	0.080 (3)	0.145 (5)	0.001 (3)	0.067 (3)	0.018 (3)
N6	0.0516 (18)	0.0436 (17)	0.0556 (18)	−0.0025 (14)	0.0308 (14)	−0.0074 (15)
N7	0.0481 (17)	0.0516 (18)	0.0530 (17)	0.0022 (14)	0.0257 (14)	0.0003 (15)
N8	0.055 (2)	0.083 (3)	0.067 (2)	−0.0100 (19)	0.0293 (17)	−0.003 (2)
S1	0.0696 (6)	0.0462 (5)	0.0620 (6)	0.0057 (5)	0.0276 (5)	−0.0020 (5)
O1	0.0777 (19)	0.0316 (13)	0.0750 (19)	−0.0016 (13)	0.0223 (15)	−0.0033 (13)
O2	0.0707 (18)	0.0435 (15)	0.0692 (18)	−0.0031 (13)	0.0324 (14)	−0.0152 (13)
O3	0.116 (3)	0.066 (2)	0.081 (2)	−0.0313 (19)	0.039 (2)	−0.0132 (17)
O4	0.107 (3)	0.085 (3)	0.078 (2)	0.038 (2)	0.029 (2)	−0.0101 (19)
O5	0.129 (3)	0.063 (2)	0.073 (2)	0.010 (2)	0.048 (2)	0.0106 (17)
F1	0.107 (3)	0.242 (6)	0.198 (5)	0.086 (3)	0.042 (3)	0.023 (4)
F2	0.105 (2)	0.118 (3)	0.094 (2)	−0.018 (2)	0.0007 (19)	0.033 (2)
F3	0.157 (4)	0.179 (5)	0.188 (4)	−0.111 (4)	−0.028 (3)	0.067 (4)
C1	0.051 (2)	0.047 (2)	0.072 (3)	−0.0022 (17)	0.0272 (19)	−0.0071 (19)
C2	0.061 (2)	0.050 (2)	0.080 (3)	0.0048 (19)	0.034 (2)	−0.014 (2)
C3	0.063 (2)	0.038 (2)	0.073 (3)	0.0095 (17)	0.024 (2)	−0.0100 (18)
C4	0.0428 (18)	0.0347 (18)	0.0459 (18)	0.0056 (14)	0.0082 (14)	−0.0045 (14)
C5	0.0493 (19)	0.0372 (18)	0.052 (2)	0.0074 (15)	0.0164 (16)	−0.0047 (15)
C6	0.0469 (19)	0.0330 (18)	0.051 (2)	0.0038 (14)	0.0069 (16)	−0.0007 (14)
C7	0.048 (2)	0.043 (2)	0.058 (2)	0.0004 (16)	0.0065 (17)	0.0016 (17)
C8	0.0431 (19)	0.053 (2)	0.051 (2)	−0.0008 (16)	0.0067 (16)	0.0048 (17)
C9	0.060 (3)	0.059 (3)	0.073 (3)	−0.001 (2)	0.020 (2)	−0.010 (2)
C10	0.061 (3)	0.072 (3)	0.069 (3)	0.004 (2)	0.027 (2)	−0.005 (2)
C11	0.052 (2)	0.067 (3)	0.065 (3)	0.0033 (19)	0.012 (2)	0.012 (2)
C12	0.066 (3)	0.049 (2)	0.076 (3)	−0.0001 (19)	0.025 (2)	0.011 (2)
C13	0.056 (2)	0.047 (2)	0.064 (2)	0.0069 (17)	0.0162 (19)	0.0032 (18)
C14	0.065 (3)	0.070 (3)	0.091 (3)	0.006 (2)	0.032 (3)	0.012 (3)
C15	0.0481 (19)	0.0362 (18)	0.0500 (19)	−0.0016 (14)	0.0212 (16)	−0.0007 (15)
C16	0.063 (2)	0.0335 (18)	0.057 (2)	−0.0047 (16)	0.0237 (18)	0.0053 (16)
C17	0.054 (2)	0.0294 (16)	0.052 (2)	−0.0002 (14)	0.0169 (16)	−0.0006 (14)
C18	0.0390 (17)	0.0349 (17)	0.0456 (18)	0.0005 (13)	0.0141 (14)	−0.0002 (14)
C19	0.0425 (18)	0.0305 (17)	0.053 (2)	−0.0001 (13)	0.0196 (15)	0.0028 (14)
C20	0.0427 (18)	0.0383 (18)	0.0485 (19)	0.0036 (14)	0.0172 (15)	0.0025 (15)
C21	0.054 (2)	0.050 (2)	0.056 (2)	−0.0010 (17)	0.0284 (18)	−0.0037 (18)
C22	0.0435 (19)	0.051 (2)	0.050 (2)	−0.0004 (16)	0.0188 (16)	0.0042 (17)
C23	0.047 (2)	0.047 (2)	0.058 (2)	−0.0052 (16)	0.0204 (17)	0.0013 (18)
C24	0.052 (2)	0.051 (2)	0.056 (2)	0.0028 (17)	0.0228 (17)	0.0001 (18)
C25	0.0424 (19)	0.059 (2)	0.0463 (19)	−0.0018 (16)	0.0185 (15)	0.0042 (17)
C26	0.059 (2)	0.057 (3)	0.076 (3)	−0.0119 (19)	0.033 (2)	0.001 (2)
C27	0.060 (2)	0.050 (2)	0.074 (3)	−0.0063 (18)	0.034 (2)	−0.0062 (19)
C28	0.047 (2)	0.065 (3)	0.048 (2)	−0.0058 (18)	0.0171 (16)	−0.0006 (18)
C29	0.071 (3)	0.080 (4)	0.115 (4)	−0.009 (3)	0.032 (3)	0.026 (3)

Ag1—N1	2.190 (3)	C7—C8	1.444 (5)
Ag1—N2	2.207 (3)	C7—H7	0.9500
Ag1—N8i	2.518 (3)	C8—C9	1.392 (6)
N1—C5	1.341 (5)	C8—C13	1.407 (6)
N1—C1	1.341 (5)	C9—C10	1.370 (6)
N2—C19	1.340 (4)	C9—H9	0.9500
N2—C15	1.340 (4)	C10—C11	1.396 (7)
N3—C6	1.348 (5)	C10—H10	0.9500
N3—N4	1.370 (4)	C11—C12	1.372 (6)
N3—H29	0.869 (14)	C11—C14	1.442 (6)
N4—C7	1.278 (5)	C12—C13	1.351 (6)
N5—C14	1.133 (6)	C12—H12	0.9500
N6—C20	1.348 (5)	C13—H13	0.9500
N6—N7	1.383 (4)	C15—C16	1.372 (5)
N6—H28	0.852 (18)	C15—H15	0.9500
N7—C21	1.270 (5)	C16—C17	1.367 (5)
N8—C28	1.134 (5)	C16—H16	0.9500
N8—Ag1ii	2.518 (3)	C17—C18	1.385 (5)
S1—O4	1.424 (3)	C17—H17	0.9500
S1—O5	1.430 (3)	C18—C19	1.382 (5)
S1—O3	1.429 (3)	C18—C20	1.501 (4)
S1—C29	1.782 (6)	C19—H19	0.9500
O1—C6	1.232 (4)	C21—C22	1.464 (5)
O2—C20	1.220 (4)	C21—H21	0.9500
F1—C29	1.324 (8)	C22—C23	1.395 (6)
F2—C29	1.311 (6)	C22—C27	1.392 (5)
F3—C29	1.292 (7)	C23—C24	1.372 (5)
C1—C2	1.370 (6)	C23—H23	0.9500
C1—H1	0.9500	C24—C25	1.390 (6)
C2—C3	1.374 (6)	C24—H24	0.9500
C2—H2	0.9500	C25—C26	1.369 (6)
C3—C4	1.383 (5)	C25—C28	1.446 (5)
C3—H3	0.9500	C26—C27	1.385 (6)
C4—C5	1.382 (5)	C26—H26	0.9500
C4—C6	1.478 (5)	C27—H27	0.9500
C5—H5	0.9500
N1—Ag1—N2	158.96 (11)	C12—C11—C14	121.0 (4)
N1—Ag1—N8i	100.66 (12)	C10—C11—C14	119.9 (4)
N2—Ag1—N8i	96.76 (12)	C13—C12—C11	121.3 (4)
C5—N1—C1	117.6 (3)	C13—C12—H12	119.4
C5—N1—Ag1	120.3 (2)	C11—C12—H12	119.4
C1—N1—Ag1	122.1 (3)	C12—C13—C8	120.6 (4)
C19—N2—C15	117.4 (3)	C12—C13—H13	119.7
C19—N2—Ag1	122.3 (2)	C8—C13—H13	119.7
C15—N2—Ag1	119.8 (2)	N5—C14—C11	179.1 (6)
C6—N3—N4	120.0 (3)	N2—C15—C16	122.9 (3)
C6—N3—H29	125.3 (15)	N2—C15—H15	118.5
N4—N3—H29	114.6 (15)	C16—C15—H15	118.5
C7—N4—N3	114.7 (3)	C17—C16—C15	119.2 (3)
C20—N6—N7	119.3 (3)	C17—C16—H16	120.4
C20—N6—H28	124 (2)	C15—C16—H16	120.4
N7—N6—H28	117 (2)	C16—C17—C18	119.4 (3)
C21—N7—N6	114.0 (3)	C16—C17—H17	120.3
C28—N8—Ag1ii	158.1 (4)	C18—C17—H17	120.3
O4—S1—O5	115.5 (2)	C19—C18—C17	117.8 (3)
O4—S1—O3	115.0 (2)	C19—C18—C20	123.7 (3)
O5—S1—O3	114.8 (2)	C17—C18—C20	118.5 (3)
O4—S1—C29	102.4 (3)	N2—C19—C18	123.3 (3)
O5—S1—C29	104.0 (3)	N2—C19—H19	118.3
O3—S1—C29	102.7 (3)	C18—C19—H19	118.3
N1—C1—C2	122.8 (4)	O2—C20—N6	124.0 (3)
N1—C1—H1	118.6	O2—C20—C18	120.5 (3)
C2—C1—H1	118.6	N6—C20—C18	115.5 (3)
C1—C2—C3	118.7 (4)	N7—C21—C22	121.4 (4)
C1—C2—H2	120.6	N7—C21—H21	119.3
C3—C2—H2	120.6	C22—C21—H21	119.3
C2—C3—C4	120.1 (3)	C23—C22—C27	119.3 (3)
C2—C3—H3	119.9	C23—C22—C21	122.2 (4)
C4—C3—H3	119.9	C27—C22—C21	118.4 (4)
C3—C4—C5	117.1 (3)	C24—C23—C22	120.2 (4)
C3—C4—C6	118.2 (3)	C24—C23—H23	119.9
C5—C4—C6	124.6 (3)	C22—C23—H23	119.9
N1—C5—C4	123.6 (3)	C23—C24—C25	119.7 (4)
N1—C5—H5	118.2	C23—C24—H24	120.1
C4—C5—H5	118.2	C25—C24—H24	120.1
O1—C6—N3	123.1 (4)	C26—C25—C24	120.9 (3)
O1—C6—C4	120.8 (3)	C26—C25—C28	120.5 (4)
N3—C6—C4	116.1 (3)	C24—C25—C28	118.6 (4)
N4—C7—C8	120.3 (4)	C25—C26—C27	119.5 (4)
N4—C7—H7	119.9	C25—C26—H26	120.2
C8—C7—H7	119.9	C27—C26—H26	120.2
C9—C8—C13	118.2 (4)	C26—C27—C22	120.3 (4)
C9—C8—C7	119.5 (4)	C26—C27—H27	119.8
C13—C8—C7	122.3 (4)	C22—C27—H27	119.8
C10—C9—C8	120.5 (4)	N8—C28—C25	178.6 (5)
C10—C9—H9	119.7	F3—C29—F2	105.7 (6)
C8—C9—H9	119.7	F3—C29—F1	107.3 (6)
C9—C10—C11	120.2 (4)	F2—C29—F1	105.2 (5)
C9—C10—H10	119.9	F3—C29—S1	113.3 (4)
C11—C10—H10	119.9	F2—C29—S1	114.0 (4)
C12—C11—C10	119.1 (4)	F1—C29—S1	110.8 (5)
N2—Ag1—N1—C5	−34.0 (5)	C19—N2—C15—C16	0.6 (5)
N8i—Ag1—N1—C5	−179.4 (3)	Ag1—N2—C15—C16	−171.5 (3)
N2—Ag1—N1—C1	149.7 (3)	N2—C15—C16—C17	−0.9 (6)
N8i—Ag1—N1—C1	4.4 (3)	C15—C16—C17—C18	0.0 (6)
N1—Ag1—N2—C19	27.7 (5)	C16—C17—C18—C19	1.0 (5)
N8i—Ag1—N2—C19	173.4 (3)	C16—C17—C18—C20	−178.4 (3)
N1—Ag1—N2—C15	−160.7 (3)	C15—N2—C19—C18	0.6 (5)
N8i—Ag1—N2—C15	−14.9 (3)	Ag1—N2—C19—C18	172.4 (3)
C6—N3—N4—C7	174.1 (3)	C17—C18—C19—N2	−1.4 (5)
C20—N6—N7—C21	177.1 (4)	C20—C18—C19—N2	178.0 (3)
C5—N1—C1—C2	−0.9 (6)	N7—N6—C20—O2	−4.8 (6)
Ag1—N1—C1—C2	175.5 (3)	N7—N6—C20—C18	174.3 (3)
N1—C1—C2—C3	0.1 (7)	C19—C18—C20—O2	−153.1 (4)
C1—C2—C3—C4	1.0 (7)	C17—C18—C20—O2	26.3 (5)
C2—C3—C4—C5	−1.2 (6)	C19—C18—C20—N6	27.7 (5)
C2—C3—C4—C6	−178.1 (4)	C17—C18—C20—N6	−152.9 (3)
C1—N1—C5—C4	0.6 (6)	N6—N7—C21—C22	176.8 (3)
Ag1—N1—C5—C4	−175.8 (3)	N7—C21—C22—C23	−9.6 (6)
C3—C4—C5—N1	0.4 (6)	N7—C21—C22—C27	173.2 (4)
C6—C4—C5—N1	177.1 (3)	C27—C22—C23—C24	1.0 (6)
N4—N3—C6—O1	2.4 (6)	C21—C22—C23—C24	−176.2 (4)
N4—N3—C6—C4	−176.0 (3)	C22—C23—C24—C25	−0.6 (6)
C3—C4—C6—O1	14.1 (5)	C23—C24—C25—C26	−0.4 (6)
C5—C4—C6—O1	−162.6 (4)	C23—C24—C25—C28	177.7 (4)
C3—C4—C6—N3	−167.4 (4)	C24—C25—C26—C27	1.0 (7)
C5—C4—C6—N3	15.9 (5)	C28—C25—C26—C27	−177.0 (4)
N3—N4—C7—C8	−179.1 (3)	C25—C26—C27—C22	−0.6 (7)
N4—C7—C8—C9	173.9 (4)	C23—C22—C27—C26	−0.4 (7)
N4—C7—C8—C13	−4.9 (6)	C21—C22—C27—C26	176.9 (4)
C13—C8—C9—C10	0.4 (6)	O4—S1—C29—F3	−62.1 (6)
C7—C8—C9—C10	−178.4 (4)	O5—S1—C29—F3	58.4 (6)
C8—C9—C10—C11	0.7 (7)	O3—S1—C29—F3	178.4 (5)
C9—C10—C11—C12	−0.8 (7)	O4—S1—C29—F2	58.8 (5)
C9—C10—C11—C14	178.4 (4)	O5—S1—C29—F2	179.4 (4)
C10—C11—C12—C13	−0.3 (7)	O3—S1—C29—F2	−60.7 (5)
C14—C11—C12—C13	−179.4 (4)	O4—S1—C29—F1	177.3 (4)
C11—C12—C13—C8	1.5 (7)	O5—S1—C29—F1	−62.2 (5)
C9—C8—C13—C12	−1.5 (6)	O3—S1—C29—F1	57.8 (5)
C7—C8—C13—C12	177.3 (4)

D—H···A	D—H	H···A	D···A	D—H···A
N3—H29···O2iii	0.87 (1)	2.18 (2)	2.999 (4)	156 (4)
N6—H28···O3	0.85 (2)	2.07 (2)	2.911 (5)	171 (3)

Ag1—N1	2.190 (3)
Ag1—N2	2.207 (3)
Ag1—N8i	2.518 (3)

N1—Ag1—N2	158.96 (11)
N1—Ag1—N8i	100.66 (12)
N2—Ag1—N8i	96.76 (12)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N3—H29⋯O2ii	0.869 (14)	2.18 (2)	2.999 (4)	156 (4)
N6—H28⋯O3	0.852 (18)	2.07 (2)	2.911 (5)	171 (3)

Symmetry code: (ii) .