Bis[1-(2,6-dichloro-benz-yl)-3-methyl-pyrazin-1-ium] bis-(maleonitrile-dithiol-ato)nickelate(II).

In the crystal structure of the title compound, (C(12)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) complex dianion is located on an inversion centre. The Ni(II) atom is coordinated by four S atoms in a square-planar geometry. In the cation, the dihedral angle between the benzene and pyrazine rings is 85.2 (2)°.

Related literature

For general background, see: Ni et al. (2005 ▶); Nishijo et al. (2000 ▶); Robertson & Cronin (2002 ▶). For related structures, see: Ni et al. (2004 ▶); Ren et al. (2004 ▶).

Experimental

Crystal data

(C12H11Cl2N2)2[Ni(C4N2S2)2]

M = 847.33

Monoclinic,

a = 9.081 (2) Å

b = 20.238 (5) Å

c = 10.489 (2) Å

β = 111.243 (4)°

V = 1796.6 (7) Å3

Z = 2

Mo Kα radiation

μ = 1.11 mm−1

T = 298 (2) K

0.30 × 0.20 × 0.20 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: multi-scan (; Bruker, 2000 ▶) T min = 0.732, T max = 0.809

8822 measured reflections

3159 independent reflections

2170 reflections with I > 2σ(I)

R int = 0.086

Refinement

R[F 2 > 2σ(F 2)] = 0.055

wR(F 2) = 0.114

S = 0.96

3159 reflections

224 parameters

H-atom parameters constrained

Δρmax = 0.51 e Å−3

Δρmin = −0.30 e Å−3

Data collection: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808034776/is2350sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808034776/is2350Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

(C12H11Cl2N2)2[Ni(C4N2S2)2]	F(000) = 860
Mr = 847.33	Dx = 1.566 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 773 reflections
a = 9.081 (2) Å	θ = 2.6–21.2°
b = 20.238 (5) Å	µ = 1.11 mm−1
c = 10.489 (2) Å	T = 298 K
β = 111.243 (4)°	Block, black
V = 1796.6 (7) Å3	0.30 × 0.20 × 0.20 mm
Z = 2

Bruker SMART CCD area-detector diffractometer	3159 independent reflections
Radiation source: fine-focus sealed tube	2170 reflections with I > 2σ(I)
graphite	Rint = 0.086
φ and ω scans	θmax = 25.0°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −10→6
Tmin = 0.732, Tmax = 0.809	k = −24→23
8822 measured reflections	l = −12→12

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.055	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.114	H-atom parameters constrained
S = 0.96	w = 1/[σ2(Fo2) + (0.0362P)2] where P = (Fo2 + 2Fc2)/3
3159 reflections	(Δ/σ)max = 0.001
224 parameters	Δρmax = 0.51 e Å−3
0 restraints	Δρmin = −0.30 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Ni1	0.0000	0.5000	0.0000	0.0410 (2)
C1	0.1965 (5)	0.45625 (18)	−0.1702 (4)	0.0434 (10)
C2	0.3109 (6)	0.45822 (19)	−0.2353 (5)	0.0475 (11)
C3	−0.0857 (5)	0.59184 (19)	0.1944 (4)	0.0445 (11)
C4	−0.0777 (5)	0.6476 (2)	0.2820 (5)	0.0489 (11)
C5	0.5497 (5)	0.67689 (19)	0.7483 (4)	0.0418 (10)
C6	0.4392 (5)	0.6850 (2)	0.6168 (5)	0.0508 (11)
C7	0.3690 (6)	0.7445 (3)	0.5682 (5)	0.0676 (14)
H7	0.2936	0.7477	0.4804	0.081*
C8	0.4110 (6)	0.7986 (2)	0.6501 (6)	0.0735 (16)
H8	0.3661	0.8394	0.6172	0.088*
C9	0.5185 (6)	0.7936 (2)	0.7801 (6)	0.0675 (14)
H9	0.5465	0.8309	0.8356	0.081*
C10	0.5857 (5)	0.7331 (2)	0.8293 (5)	0.0505 (12)
C11	0.6274 (5)	0.61171 (19)	0.7983 (4)	0.0486 (11)
H11A	0.6794	0.6130	0.8970	0.058*
H11B	0.5479	0.5772	0.7759	0.058*
C12	0.7394 (5)	0.53854 (19)	0.6677 (5)	0.0512 (12)
H12	0.6629	0.5071	0.6629	0.061*
C13	0.8486 (6)	0.5274 (2)	0.6073 (4)	0.0524 (12)
H13	0.8429	0.4881	0.5597	0.063*
C14	0.9720 (5)	0.6256 (2)	0.6865 (4)	0.0448 (10)
C15	0.8622 (5)	0.63866 (18)	0.7459 (4)	0.0408 (10)
H15	0.8696	0.6776	0.7949	0.049*
C16	1.1035 (5)	0.6723 (2)	0.7000 (5)	0.0666 (14)
H16A	1.2027	0.6502	0.7430	0.100*
H16B	1.0971	0.7094	0.7547	0.100*
H16C	1.0953	0.6874	0.6109	0.100*
Cl1	0.38504 (16)	0.61665 (7)	0.50983 (14)	0.0775 (4)
Cl2	0.71852 (16)	0.72925 (6)	0.99706 (13)	0.0719 (4)
N1	0.4021 (5)	0.46159 (18)	−0.2871 (4)	0.0651 (12)
N2	−0.0664 (5)	0.69443 (19)	0.3446 (4)	0.0688 (12)
N3	0.7460 (4)	0.59632 (15)	0.7340 (3)	0.0415 (9)
N4	0.9619 (4)	0.57012 (18)	0.6139 (4)	0.0535 (10)
S1	0.20391 (14)	0.51963 (5)	−0.05585 (12)	0.0484 (3)
S2	0.05266 (14)	0.59091 (5)	0.11563 (12)	0.0532 (3)

	U11	U22	U33	U12	U13	U23
Ni1	0.0481 (5)	0.0298 (4)	0.0442 (5)	0.0004 (3)	0.0155 (4)	−0.0004 (3)
C1	0.053 (3)	0.030 (2)	0.048 (3)	0.002 (2)	0.018 (2)	0.0027 (18)
C2	0.058 (3)	0.031 (2)	0.054 (3)	−0.002 (2)	0.021 (3)	0.000 (2)
C3	0.054 (3)	0.034 (2)	0.047 (3)	0.005 (2)	0.020 (2)	−0.0004 (19)
C4	0.056 (3)	0.037 (3)	0.056 (3)	0.001 (2)	0.024 (2)	0.002 (2)
C5	0.040 (3)	0.036 (2)	0.057 (3)	−0.0008 (18)	0.027 (2)	0.006 (2)
C6	0.042 (3)	0.050 (3)	0.066 (3)	−0.005 (2)	0.027 (2)	0.005 (2)
C7	0.049 (3)	0.075 (4)	0.077 (4)	0.015 (3)	0.021 (3)	0.031 (3)
C8	0.075 (4)	0.045 (3)	0.113 (5)	0.025 (3)	0.049 (4)	0.021 (3)
C9	0.079 (4)	0.044 (3)	0.098 (4)	0.008 (3)	0.053 (3)	0.001 (3)
C10	0.051 (3)	0.045 (3)	0.066 (3)	0.005 (2)	0.034 (2)	0.005 (2)
C11	0.055 (3)	0.043 (2)	0.057 (3)	−0.001 (2)	0.031 (2)	0.005 (2)
C12	0.052 (3)	0.033 (2)	0.066 (3)	0.000 (2)	0.019 (2)	0.003 (2)
C13	0.059 (3)	0.041 (3)	0.054 (3)	0.005 (2)	0.016 (2)	−0.004 (2)
C14	0.042 (3)	0.046 (3)	0.046 (3)	0.001 (2)	0.015 (2)	0.003 (2)
C15	0.044 (3)	0.029 (2)	0.047 (3)	−0.0017 (19)	0.014 (2)	0.0026 (18)
C16	0.056 (3)	0.059 (3)	0.089 (4)	−0.011 (2)	0.032 (3)	−0.007 (3)
Cl1	0.0753 (10)	0.0753 (9)	0.0747 (10)	−0.0217 (7)	0.0185 (7)	−0.0094 (7)
Cl2	0.0806 (10)	0.0729 (9)	0.0635 (9)	−0.0026 (7)	0.0276 (7)	−0.0100 (6)
N1	0.070 (3)	0.052 (3)	0.083 (3)	−0.004 (2)	0.040 (3)	−0.001 (2)
N2	0.091 (3)	0.045 (2)	0.076 (3)	−0.004 (2)	0.036 (2)	−0.017 (2)
N3	0.046 (2)	0.0282 (19)	0.049 (2)	0.0030 (15)	0.0164 (17)	0.0058 (15)
N4	0.053 (3)	0.054 (2)	0.053 (2)	0.0067 (19)	0.0196 (19)	−0.0017 (19)
S1	0.0551 (8)	0.0365 (6)	0.0549 (8)	−0.0057 (5)	0.0214 (6)	−0.0049 (5)
S2	0.0621 (8)	0.0388 (6)	0.0658 (8)	−0.0115 (5)	0.0316 (6)	−0.0107 (5)

Ni1—S2	2.1596 (11)	C8—H8	0.9300
Ni1—S2i	2.1596 (11)	C9—C10	1.382 (6)
Ni1—S1i	2.1715 (12)	C9—H9	0.9300
Ni1—S1	2.1715 (12)	C10—Cl2	1.737 (5)
C1—C3i	1.356 (5)	C11—N3	1.496 (5)
C1—C2	1.436 (6)	C11—H11A	0.9700
C1—S1	1.741 (4)	C11—H11B	0.9700
C2—N1	1.145 (5)	C12—N3	1.351 (5)
C3—C1i	1.356 (5)	C12—C13	1.375 (6)
C3—C4	1.441 (6)	C12—H12	0.9300
C3—S2	1.736 (4)	C13—N4	1.326 (5)
C4—N2	1.136 (5)	C13—H13	0.9300
C5—C10	1.387 (5)	C14—N4	1.341 (5)
C5—C6	1.391 (6)	C14—C15	1.379 (5)
C5—C11	1.498 (5)	C14—C16	1.489 (6)
C6—C7	1.370 (6)	C15—N3	1.330 (5)
C6—Cl1	1.737 (4)	C15—H15	0.9300
C7—C8	1.358 (7)	C16—H16A	0.9600
C7—H7	0.9300	C16—H16B	0.9600
C8—C9	1.363 (7)	C16—H16C	0.9600
S2—Ni1—S2i	180.00 (3)	C5—C10—Cl2	120.4 (3)
S2—Ni1—S1i	92.37 (4)	N3—C11—C5	110.5 (3)
S2i—Ni1—S1i	87.63 (4)	N3—C11—H11A	109.6
S2—Ni1—S1	87.63 (4)	C5—C11—H11A	109.6
S2i—Ni1—S1	92.37 (4)	N3—C11—H11B	109.6
S1i—Ni1—S1	180.0	C5—C11—H11B	109.6
C3i—C1—C2	123.1 (4)	H11A—C11—H11B	108.1
C3i—C1—S1	119.9 (3)	N3—C12—C13	118.3 (4)
C2—C1—S1	117.0 (3)	N3—C12—H12	120.8
N1—C2—C1	178.2 (4)	C13—C12—H12	120.8
C1i—C3—C4	123.0 (4)	N4—C13—C12	122.9 (4)
C1i—C3—S2	121.3 (3)	N4—C13—H13	118.5
C4—C3—S2	115.7 (3)	C12—C13—H13	118.5
N2—C4—C3	174.5 (5)	N4—C14—C15	120.4 (4)
C10—C5—C6	115.8 (4)	N4—C14—C16	118.2 (4)
C10—C5—C11	122.1 (4)	C15—C14—C16	121.4 (4)
C6—C5—C11	122.1 (4)	N3—C15—C14	120.9 (4)
C7—C6—C5	123.0 (4)	N3—C15—H15	119.6
C7—C6—Cl1	118.3 (4)	C14—C15—H15	119.6
C5—C6—Cl1	118.7 (3)	C14—C16—H16A	109.5
C8—C7—C6	119.1 (5)	C14—C16—H16B	109.5
C8—C7—H7	120.5	H16A—C16—H16B	109.5
C6—C7—H7	120.5	C14—C16—H16C	109.5
C7—C8—C9	120.6 (5)	H16A—C16—H16C	109.5
C7—C8—H8	119.7	H16B—C16—H16C	109.5
C9—C8—H8	119.7	C15—N3—C12	119.4 (4)
C8—C9—C10	119.9 (5)	C15—N3—C11	120.0 (3)
C8—C9—H9	120.0	C12—N3—C11	120.5 (3)
C10—C9—H9	120.0	C13—N4—C14	117.9 (4)
C9—C10—C5	121.6 (4)	C1—S1—Ni1	103.14 (15)
C9—C10—Cl2	118.0 (4)	C3—S2—Ni1	103.02 (14)
C10—C5—C6—C7	0.1 (6)	C16—C14—C15—N3	−179.5 (4)
C11—C5—C6—C7	−178.7 (4)	C14—C15—N3—C12	2.8 (6)
C10—C5—C6—Cl1	−178.9 (3)	C14—C15—N3—C11	−179.5 (4)
C11—C5—C6—Cl1	2.3 (5)	C13—C12—N3—C15	−3.9 (6)
C5—C6—C7—C8	1.6 (7)	C13—C12—N3—C11	178.4 (4)
Cl1—C6—C7—C8	−179.4 (4)	C5—C11—N3—C15	56.1 (5)
C6—C7—C8—C9	−1.7 (8)	C5—C11—N3—C12	−126.2 (4)
C7—C8—C9—C10	0.1 (8)	C12—C13—N4—C14	2.1 (6)
C8—C9—C10—C5	1.7 (7)	C15—C14—N4—C13	−3.3 (6)
C8—C9—C10—Cl2	−178.5 (4)	C16—C14—N4—C13	177.1 (4)
C6—C5—C10—C9	−1.7 (6)	C3i—C1—S1—Ni1	−4.5 (4)
C11—C5—C10—C9	177.1 (4)	C2—C1—S1—Ni1	175.2 (3)
C6—C5—C10—Cl2	178.5 (3)	S2—Ni1—S1—C1	−175.14 (14)
C11—C5—C10—Cl2	−2.7 (5)	S2i—Ni1—S1—C1	4.86 (14)
C10—C5—C11—N3	−105.5 (4)	C1i—C3—S2—Ni1	−2.9 (4)
C6—C5—C11—N3	73.2 (5)	C4—C3—S2—Ni1	179.2 (3)
N3—C12—C13—N4	1.5 (6)	S1i—Ni1—S2—C3	4.39 (15)
N4—C14—C15—N3	0.9 (6)	S1—Ni1—S2—C3	−175.61 (15)