Poly[[diaqua-deca-μ-cyanido-hexa-cyanidobis-(4-cyano-pyridine)di-μ-pyrimidine-tricopper(II)ditungsten(V)] dihydrate].

In the polymeric title compound, {[Cu(3)W(2)(CN)(16)(C(4)H(4)N(2))(2)(C(6)H(4)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), the coordination geometry of W is an eight-coordinated bicapped trigonal prism. Five of the CN groups of [W(CN)(8)] are bridged to Cu ions. The coordination geometries of the Cu atoms are each pseudo-octa-hedral; one Cu atom is located on a centre of inversion. The cyano-bridged W-Cu layers are linked by Cu-containing pillars, to form a three-dimensional network with cavities occupied by noncoordinated water and 4-cyano-pyridine mol-ecules.

Related literature

For general background, see: Arimoto et al. (2003 ▶); Catala et al. (2005 ▶); Hozumi et al. (2003 ▶); Leipoldt et al. (1994 ▶); Ohkoshi et al. (2006 ▶, 2008 ▶); Pilkington & Decurtins (2000 ▶); Zhong et al. (2000 ▶). For related structures, see: Garde et al. (1999 ▶); Ohkoshi et al. (2003 ▶, 2007 ▶).

Experimental

Crystal data

[Cu3W2(CN)16(C4H4N2)2(C6H4N2)2(H2O)2]·2H2O

M = 1407.02

Monoclinic,

a = 7.2475 (6) Å

b = 15.4532 (12) Å

c = 20.8560 (16) Å

β = 90.057 (2)°

V = 2335.8 (3) Å3

Z = 2

Mo Kα radiation

μ = 6.32 mm−1

T = 90 (2) K

0.44 × 0.17 × 0.04 mm

Data collection

Rigaku R-AXIS RAPID diffractometer

Absorption correction: numerical (ABSCOR; Higashi, 1995 ▶) T min = 0.297, T max = 0.791

22562 measured reflections

5345 independent reflections

4975 reflections with I > 2σ(I)

R int = 0.095

Refinement

R[F 2 > 2σ(F 2)] = 0.039

wR(F 2) = 0.093

S = 1.09

5345 reflections

314 parameters

H-atom parameters constrained

Δρmax = 2.97 e Å−3

Δρmin = −1.45 e Å−3

Data collection: PROCESS-AUTO (Rigaku, 1998 ▶); cell refinement: PROCESS-AUTO; data reduction: CrystalStructure (Rigaku Americas & Rigaku, 2007 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and PyMOLWin (DeLano, 2007 ▶); software used to prepare material for publication: CrystalStructure.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808032947/tk2308sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808032947/tk2308Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu3W2(CN)16(C4H4N2)2(C6H4N2)2(H2O)2]·2H2O	F(000) = 1334
Mr = 1407.02	Dx = 2.000 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71075 Å
Hall symbol: -P 2yn	Cell parameters from 15466 reflections
a = 7.2475 (6) Å	θ = 3.1–27.5°
b = 15.4532 (12) Å	µ = 6.32 mm−1
c = 20.8560 (16) Å	T = 90 K
β = 90.057 (2)°	Plate, green
V = 2335.8 (3) Å3	0.44 × 0.17 × 0.04 mm
Z = 2

Rigaku R-AXIS RAPID diffractometer	5345 independent reflections
Radiation source: sealed tube	4975 reflections with I > 2σ(I)
sealed tube	Rint = 0.095
Detector resolution: 10.00 pixels mm-1	θmax = 27.5°, θmin = 3.1°
ω scans	h = −9→9
Absorption correction: numerical (ABSCOR; Higashi, 1995)	k = −20→17
Tmin = 0.297, Tmax = 0.791	l = −27→26
22562 measured reflections

Refinement on F2	0 constraints
Least-squares matrix: full	Secondary atom site location: structure-invariant direct methods
R[F2 > 2σ(F2)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.093	H-atom parameters constrained
S = 1.09	w = 1/[σ2(Fo2) + 6.8782P] where P = (Fo2 + 2Fc2)/3
5345 reflections	(Δ/σ)max = 0.002
314 parameters	Δρmax = 2.97 e Å−3
0 restraints	Δρmin = −1.45 e Å−3

Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).

	x	y	z	Uiso*/Ueq
W(1)	0.79222 (2)	0.682386 (11)	0.301091 (8)	0.00933 (7)
Cu(1)	0.5000	0.5000	0.5000	0.01726 (18)
Cu(2)	0.24342 (7)	0.43738 (4)	0.23347 (3)	0.01074 (13)
O(1)	0.6198 (4)	0.3863 (2)	0.50585 (15)	0.0199 (7)
O(2W)	0.4469 (5)	0.2609 (2)	0.44669 (18)	0.0331 (9)
N(8)	0.4520 (5)	0.8223 (2)	0.2839 (2)	0.0171 (8)
N(5)	0.7372 (8)	0.7918 (4)	0.4362 (2)	0.0445 (14)
N(4)	1.1739 (5)	0.6555 (3)	0.3867 (2)	0.0221 (9)
N(6)	1.0499 (5)	0.8542 (2)	0.27039 (19)	0.0155 (8)
N(3P)	0.2076 (5)	0.4190 (2)	0.33127 (19)	0.0139 (7)
N(3)	1.0395 (5)	0.5230 (2)	0.24087 (18)	0.0146 (8)
N(7)	0.7775 (6)	0.7133 (3)	0.1440 (2)	0.0251 (9)
N(1P)	0.3037 (5)	0.4489 (2)	0.43733 (19)	0.0167 (8)
N(1C)	0.2581 (5)	0.4584 (2)	0.13674 (18)	0.0160 (8)
N(2)	0.4536 (5)	0.5548 (2)	0.25142 (19)	0.0159 (8)
N(8C)	0.2655 (15)	0.5073 (7)	−0.1191 (3)	0.108 (3)
N(1)	0.6858 (5)	0.5382 (3)	0.41107 (19)	0.0195 (9)
C(5)	0.7573 (7)	0.7547 (3)	0.3890 (2)	0.0247 (11)
C(8)	0.5679 (6)	0.7718 (3)	0.2897 (2)	0.0131 (8)
C(6)	0.9565 (6)	0.7950 (3)	0.2801 (2)	0.0149 (9)
C(1)	0.7250 (6)	0.5869 (3)	0.3723 (2)	0.0151 (9)
C(3)	0.9483 (5)	0.5780 (3)	0.2595 (2)	0.0117 (8)
C(2)	0.5694 (6)	0.6008 (3)	0.2667 (2)	0.0139 (9)
C(7)	0.7801 (6)	0.7033 (3)	0.1982 (2)	0.0147 (9)
C(4)	1.0445 (6)	0.6656 (3)	0.3562 (2)	0.0145 (9)
C(4P)	0.0484 (6)	0.3870 (3)	0.3537 (2)	0.0208 (10)
C(5P)	0.0114 (6)	0.3841 (4)	0.4186 (2)	0.0250 (11)
C(2P)	0.3299 (6)	0.4475 (3)	0.3738 (2)	0.0158 (9)
C(6C)	0.2623 (8)	0.5390 (3)	0.1143 (2)	0.0286 (12)
C(5C)	0.2606 (10)	0.5585 (4)	0.0505 (3)	0.0468 (19)
C(4C)	0.2565 (9)	0.4902 (6)	0.0079 (3)	0.052 (2)
C(3C)	0.2549 (8)	0.4065 (5)	0.0295 (2)	0.0412 (17)
C(2C)	0.2567 (7)	0.3938 (3)	0.0953 (2)	0.0252 (11)
C(6P)	0.1443 (6)	0.4167 (4)	0.4596 (2)	0.0238 (11)
C(7C)	0.2648 (14)	0.4950 (8)	−0.0622 (4)	0.083 (3)
H(4P)	−0.0415	0.3657	0.3239	0.025*
H(5P)	−0.1017	0.3605	0.4346	0.030*
H(2P)	0.4451	0.4683	0.3579	0.019*
H(6C)	0.2664	0.5859	0.1449	0.035*
H(5C)	0.2618	0.6178	0.0358	0.056*
H(3C)	0.2521	0.3584	−0.0000	0.050*
H(2C)	0.2567	0.3355	0.1117	0.031*
H(6P)	0.1222	0.4165	0.5050	0.028*

	U11	U22	U33	U12	U13	U23
W(1)	0.00709 (11)	0.00851 (13)	0.01238 (11)	−0.00006 (5)	−0.00063 (7)	0.00014 (6)
Cu(1)	0.0109 (3)	0.0285 (5)	0.0123 (3)	−0.0043 (3)	−0.0029 (2)	0.0043 (3)
Cu(2)	0.0096 (2)	0.0105 (2)	0.0121 (2)	0.00227 (19)	−0.00008 (18)	0.0000 (2)
O(1)	0.0141 (16)	0.029 (2)	0.0161 (15)	−0.0006 (13)	−0.0023 (11)	0.0056 (15)
O(2W)	0.029 (2)	0.040 (2)	0.030 (2)	−0.0009 (17)	0.0017 (16)	−0.015 (2)
N(8)	0.016 (2)	0.015 (2)	0.020 (2)	0.0002 (14)	0.0004 (15)	0.0026 (16)
N(5)	0.056 (3)	0.049 (3)	0.029 (2)	0.017 (2)	−0.008 (2)	−0.020 (2)
N(4)	0.019 (2)	0.022 (2)	0.025 (2)	−0.0013 (17)	−0.0066 (16)	0.005 (2)
N(6)	0.0106 (18)	0.015 (2)	0.021 (2)	−0.0015 (15)	−0.0004 (14)	0.0014 (17)
N(3P)	0.0123 (18)	0.013 (2)	0.0160 (18)	0.0003 (14)	0.0009 (13)	0.0001 (16)
N(3)	0.0109 (18)	0.015 (2)	0.0175 (18)	0.0003 (15)	0.0000 (13)	0.0012 (16)
N(7)	0.029 (2)	0.026 (2)	0.021 (2)	0.0002 (19)	0.0035 (16)	0.006 (2)
N(1P)	0.0151 (19)	0.018 (2)	0.0169 (19)	−0.0028 (15)	−0.0023 (14)	0.0050 (17)
N(1C)	0.0145 (19)	0.022 (2)	0.0113 (18)	−0.0018 (15)	0.0007 (13)	0.0037 (17)
N(2)	0.0154 (19)	0.016 (2)	0.0160 (18)	−0.0005 (15)	−0.0012 (14)	−0.0003 (16)
N(8C)	0.145 (9)	0.136 (10)	0.043 (4)	−0.015 (7)	−0.005 (4)	−0.003 (5)
N(1)	0.016 (2)	0.026 (2)	0.0161 (19)	−0.0067 (16)	−0.0049 (14)	0.0059 (19)
C(5)	0.025 (2)	0.023 (2)	0.027 (2)	0.004 (2)	−0.0081 (19)	−0.001 (2)
C(8)	0.012 (2)	0.012 (2)	0.015 (2)	0.0016 (16)	−0.0008 (15)	−0.0019 (18)
C(6)	0.010 (2)	0.016 (2)	0.018 (2)	0.0041 (18)	−0.0037 (15)	0.004 (2)
C(1)	0.012 (2)	0.021 (2)	0.013 (2)	−0.0017 (17)	−0.0036 (15)	−0.003 (2)
C(3)	0.011 (2)	0.014 (2)	0.0102 (19)	−0.0022 (17)	−0.0015 (14)	−0.0006 (18)
C(2)	0.011 (2)	0.012 (2)	0.018 (2)	−0.0003 (17)	−0.0018 (15)	0.0016 (19)
C(7)	0.011 (2)	0.014 (2)	0.019 (2)	−0.0024 (17)	0.0012 (15)	0.003 (2)
C(4)	0.014 (2)	0.013 (2)	0.017 (2)	−0.0028 (17)	−0.0022 (16)	0.0022 (19)
C(4P)	0.013 (2)	0.028 (2)	0.022 (2)	−0.0076 (19)	−0.0006 (17)	−0.002 (2)
C(5P)	0.016 (2)	0.039 (3)	0.020 (2)	−0.007 (2)	0.0037 (17)	0.002 (2)
C(2P)	0.012 (2)	0.017 (2)	0.018 (2)	0.0001 (17)	0.0005 (16)	−0.0006 (19)
C(6C)	0.042 (3)	0.024 (2)	0.020 (2)	−0.012 (2)	−0.007 (2)	0.010 (2)
C(5C)	0.061 (4)	0.047 (4)	0.032 (3)	−0.032 (3)	−0.018 (2)	0.028 (3)
C(4C)	0.032 (3)	0.100 (6)	0.024 (3)	−0.024 (3)	−0.008 (2)	0.028 (3)
C(3C)	0.034 (3)	0.070 (5)	0.020 (2)	−0.001 (3)	0.005 (2)	−0.012 (3)
C(2C)	0.027 (2)	0.029 (3)	0.020 (2)	0.004 (2)	0.0005 (19)	−0.003 (2)
C(6P)	0.014 (2)	0.041 (3)	0.016 (2)	−0.004 (2)	0.0004 (17)	0.003 (2)
C(7C)	0.086 (7)	0.110 (9)	0.054 (5)	−0.016 (6)	0.010 (4)	0.005 (5)

W(1)—C(5)	2.162 (5)	N(3P)—C(2P)	1.328 (6)
W(1)—C(8)	2.146 (4)	N(3)—C(3)	1.145 (6)
W(1)—C(6)	2.153 (4)	N(7)—C(7)	1.141 (6)
W(1)—C(1)	2.149 (4)	N(1P)—C(2P)	1.339 (6)
W(1)—C(3)	2.153 (4)	N(1P)—C(6P)	1.341 (6)
W(1)—C(2)	2.170 (4)	N(1C)—C(6C)	1.331 (7)
W(1)—C(7)	2.173 (4)	N(1C)—C(2C)	1.322 (6)
W(1)—C(4)	2.174 (4)	N(2)—C(2)	1.145 (6)
Cu(1)—O(1)	1.964 (3)	N(8C)—C(7C)	1.202 (12)
Cu(1)—O(1)i	1.964 (3)	N(1)—C(1)	1.141 (6)
Cu(1)—N(1P)	2.086 (3)	C(4P)—C(5P)	1.381 (6)
Cu(1)—N(1P)i	2.086 (3)	C(5P)—C(6P)	1.383 (7)
Cu(1)—N(1)	2.368 (3)	C(6C)—C(5C)	1.364 (8)
Cu(1)—N(1)i	2.368 (3)	C(5C)—C(4C)	1.380 (11)
Cu(2)—N(8)ii	2.301 (4)	C(4C)—C(3C)	1.368 (12)
Cu(2)—N(6)iii	1.975 (3)	C(4C)—C(7C)	1.465 (11)
Cu(2)—N(3P)	2.076 (4)	C(3C)—C(2C)	1.386 (7)
Cu(2)—N(3)iv	1.990 (3)	C(4P)—H(4P)	0.958
Cu(2)—N(1C)	2.046 (3)	C(5P)—H(5P)	0.958
Cu(2)—N(2)	2.399 (4)	C(2P)—H(2P)	0.955
N(8)—C(8)	1.154 (6)	C(6C)—H(6C)	0.965
N(5)—C(5)	1.149 (7)	C(5C)—H(5C)	0.967
N(4)—C(4)	1.143 (6)	C(3C)—H(3C)	0.965
N(6)—C(6)	1.157 (6)	C(2C)—H(2C)	0.964
N(3P)—C(4P)	1.340 (6)	C(6P)—H(6P)	0.960
O(1)···O(2W)	2.615 (5)	N(8C)···C(3)vii	3.564 (10)
O(1)···N(4)v	2.770 (5)	N(8C)···C(6C)vii	3.498 (12)
O(2W)···O(1)	2.615 (5)	C(3)···N(8C)vii	3.564 (10)
O(2W)···N(5)i	2.901 (6)	C(2P)···O(2W)	3.367 (6)
O(2W)···N(7)iii	2.849 (5)	C(6C)···N(8C)vii	3.498 (12)
O(2W)···N(1P)	3.090 (6)	C(5C)···O(2W)x	3.472 (8)
O(2W)···C(2P)	3.367 (6)	C(5C)···N(5)ix	3.326 (9)
O(2W)···C(5C)ii	3.472 (8)	C(5C)···C(7C)vii	3.546 (13)
O(2W)···C(6P)	3.268 (7)	C(4C)···C(4C)vii	3.559 (9)
N(5)···O(2W)i	2.901 (6)	C(6P)···O(2W)	3.268 (7)
N(5)···N(8C)vi	3.318 (13)	C(7C)···N(5)ix	3.301 (14)
N(5)···C(5C)vi	3.326 (9)	C(7C)···C(5C)vii	3.546 (13)
N(5)···C(7C)vi	3.301 (14)	O(2W)···H(5C)ii	2.705
N(4)···O(1)v	2.770 (5)	O(2W)···H(3C)xi	3.087
N(3)···N(8C)vii	3.398 (10)	O(2W)···H(6P)	3.578
N(7)···O(2W)viii	2.849 (5)	N(5)···H(5C)vi	2.510
N(7)···N(8C)vii	3.462 (13)	N(7)···H(3C)vii	3.207
N(1P)···O(2W)	3.090 (6)	C(6P)···H(6P)xii	3.304
N(1C)···N(8C)vii	3.513 (11)	H(5C)···O(2W)x	2.705
N(2)···N(8C)vii	3.563 (10)	H(5C)···N(5)ix	2.510
N(8C)···N(5)ix	3.318 (13)	H(3C)···O(2W)xiii	3.087
N(8C)···N(3)vii	3.398 (10)	H(3C)···N(7)vii	3.207
N(8C)···N(7)vii	3.462 (13)	H(6P)···O(2W)	3.578
N(8C)···N(1C)vii	3.513 (11)	H(6P)···C(6P)xii	3.304
N(8C)···N(2)vii	3.563 (10)	H(6P)···H(6P)xii	3.136
C(5)—W(1)—C(8)	70.83 (18)	N(3P)—Cu(2)—N(2)	91.72 (14)
C(5)—W(1)—C(6)	79.62 (19)	N(3)iv—Cu(2)—N(1C)	90.59 (16)
C(5)—W(1)—C(1)	75.05 (19)	N(3)iv—Cu(2)—N(2)	87.51 (14)
C(5)—W(1)—C(3)	142.29 (18)	N(1C)—Cu(2)—N(2)	90.00 (15)
C(5)—W(1)—C(2)	119.52 (18)	Cu(2)x—N(8)—C(8)	171.0 (3)
C(5)—W(1)—C(7)	139.15 (19)	Cu(2)viii—N(6)—C(6)	165.0 (3)
C(5)—W(1)—C(4)	73.28 (18)	Cu(2)—N(3P)—C(4P)	120.1 (3)
C(8)—W(1)—C(6)	82.92 (17)	Cu(2)—N(3P)—C(2P)	121.8 (3)
C(8)—W(1)—C(1)	110.23 (17)	C(4P)—N(3P)—C(2P)	117.6 (4)
C(8)—W(1)—C(3)	146.68 (16)	Cu(2)xiv—N(3)—C(3)	161.7 (3)
C(8)—W(1)—C(2)	76.94 (17)	Cu(1)—N(1P)—C(2P)	121.9 (3)
C(8)—W(1)—C(7)	76.43 (17)	Cu(1)—N(1P)—C(6P)	120.7 (3)
C(8)—W(1)—C(4)	140.49 (17)	C(2P)—N(1P)—C(6P)	117.4 (4)
C(6)—W(1)—C(1)	145.12 (17)	Cu(2)—N(1C)—C(6C)	119.7 (3)
C(6)—W(1)—C(3)	103.42 (17)	Cu(2)—N(1C)—C(2C)	121.7 (3)
C(6)—W(1)—C(2)	144.47 (17)	C(6C)—N(1C)—C(2C)	118.5 (4)
C(6)—W(1)—C(7)	72.62 (17)	Cu(2)—N(2)—C(2)	168.1 (3)
C(6)—W(1)—C(4)	74.85 (17)	Cu(1)—N(1)—C(1)	149.5 (3)
C(1)—W(1)—C(3)	83.36 (17)	W(1)—C(5)—N(5)	178.7 (5)
C(1)—W(1)—C(2)	70.17 (17)	W(1)—C(8)—N(8)	177.4 (4)
C(1)—W(1)—C(7)	140.87 (18)	W(1)—C(6)—N(6)	177.4 (3)
C(1)—W(1)—C(4)	75.16 (17)	W(1)—C(1)—N(1)	177.8 (4)
C(3)—W(1)—C(2)	79.79 (16)	W(1)—C(3)—N(3)	175.2 (3)
C(3)—W(1)—C(7)	74.54 (17)	W(1)—C(2)—N(2)	176.2 (4)
C(3)—W(1)—C(4)	71.47 (16)	W(1)—C(7)—N(7)	178.4 (4)
C(2)—W(1)—C(7)	74.36 (17)	W(1)—C(4)—N(4)	177.8 (4)
C(2)—W(1)—C(4)	136.94 (17)	N(3P)—C(4P)—C(5P)	121.5 (4)
C(7)—W(1)—C(4)	124.99 (16)	C(4P)—C(5P)—C(6P)	117.4 (4)
O(1)—Cu(1)—O(1)i	180.00 (18)	N(3P)—C(2P)—N(1P)	124.8 (4)
O(1)—Cu(1)—N(1P)	90.05 (15)	N(1C)—C(6C)—C(5C)	123.3 (5)
O(1)—Cu(1)—N(1P)i	89.95 (15)	C(6C)—C(5C)—C(4C)	117.4 (6)
O(1)—Cu(1)—N(1)	91.15 (14)	C(5C)—C(4C)—C(3C)	120.7 (6)
O(1)—Cu(1)—N(1)i	88.85 (14)	C(5C)—C(4C)—C(7C)	127.1 (8)
O(1)i—Cu(1)—N(1P)	89.95 (15)	C(3C)—C(4C)—C(7C)	112.1 (8)
O(1)i—Cu(1)—N(1P)i	90.05 (15)	C(4C)—C(3C)—C(2C)	117.3 (6)
O(1)i—Cu(1)—N(1)	88.85 (14)	N(1C)—C(2C)—C(3C)	122.7 (5)
O(1)i—Cu(1)—N(1)i	91.15 (14)	N(1P)—C(6P)—C(5P)	121.3 (4)
N(1P)—Cu(1)—N(1P)i	180.0 (2)	N(8C)—C(7C)—C(4C)	173.5 (12)
N(1P)—Cu(1)—N(1)	89.52 (14)	N(3P)—C(4P)—H(4P)	119.1
N(1P)—Cu(1)—N(1)i	90.48 (14)	C(5P)—C(4P)—H(4P)	119.5
N(1P)i—Cu(1)—N(1)	90.48 (14)	C(4P)—C(5P)—H(5P)	121.4
N(1P)i—Cu(1)—N(1)i	89.52 (14)	C(6P)—C(5P)—H(5P)	121.2
N(1)—Cu(1)—N(1)i	180.0 (2)	N(3P)—C(2P)—H(2P)	117.6
N(8)ii—Cu(2)—N(6)iii	87.57 (15)	N(1P)—C(2P)—H(2P)	117.6
N(8)ii—Cu(2)—N(3P)	88.40 (15)	N(1C)—C(6C)—H(6C)	118.1
N(8)ii—Cu(2)—N(3)iv	93.94 (15)	C(5C)—C(6C)—H(6C)	118.6
N(8)ii—Cu(2)—N(1C)	89.99 (15)	C(6C)—C(5C)—H(5C)	121.2
N(8)ii—Cu(2)—N(2)	178.55 (14)	C(4C)—C(5C)—H(5C)	121.4
N(6)iii—Cu(2)—N(3P)	92.69 (15)	C(4C)—C(3C)—H(3C)	121.2
N(6)iii—Cu(2)—N(3)iv	177.57 (16)	C(2C)—C(3C)—H(3C)	121.5
N(6)iii—Cu(2)—N(1C)	91.31 (16)	N(1C)—C(2C)—H(2C)	118.3
N(6)iii—Cu(2)—N(2)	90.98 (15)	C(3C)—C(2C)—H(2C)	119.0
N(3P)—Cu(2)—N(3)iv	85.46 (15)	N(1P)—C(6P)—H(6P)	119.2
N(3P)—Cu(2)—N(1C)	175.62 (15)	C(5P)—C(6P)—H(6P)	119.5
C(5)—W(1)—C(8)—N(8)	63 (8)	N(1P)i—Cu(1)—N(1)—C(1)	−91.9 (7)
C(8)—W(1)—C(5)—N(5)	105 (22)	N(1)—Cu(1)—N(1P)i—C(2P)i	177.7 (3)
C(5)—W(1)—C(6)—N(6)	75 (9)	N(1)—Cu(1)—N(1P)i—C(6P)i	−3.0 (4)
C(6)—W(1)—C(5)—N(5)	−169 (18)	N(1P)i—Cu(1)—N(1)i—C(1)i	−88.1 (7)
C(5)—W(1)—C(1)—N(1)	34 (10)	N(1)i—Cu(1)—N(1P)i—C(2P)i	−2.3 (3)
C(1)—W(1)—C(5)—N(5)	−13 (21)	N(1)i—Cu(1)—N(1P)i—C(6P)i	177.0 (4)
C(5)—W(1)—C(3)—N(3)	−14 (4)	N(8)ii—Cu(2)—N(6)iii—C(6)iii	22.8 (14)
C(3)—W(1)—C(5)—N(5)	−70 (22)	N(6)iii—Cu(2)—N(8)ii—C(8)ii	162 (2)
C(5)—W(1)—C(2)—N(2)	−68 (6)	N(8)ii—Cu(2)—N(3P)—C(4P)	−30.3 (3)
C(2)—W(1)—C(5)—N(5)	43 (22)	N(8)ii—Cu(2)—N(3P)—C(2P)	157.6 (3)
C(5)—W(1)—C(7)—N(7)	132 (16)	N(3P)—Cu(2)—N(8)ii—C(8)ii	70 (2)
C(7)—W(1)—C(5)—N(5)	144 (22)	N(8)ii—Cu(2)—N(3)iv—C(3)iv	131.3 (12)
C(5)—W(1)—C(4)—N(4)	64 (11)	N(3)iv—Cu(2)—N(8)ii—C(8)ii	−16 (2)
C(4)—W(1)—C(5)—N(5)	−92 (22)	N(8)ii—Cu(2)—N(1C)—C(6C)	141.8 (4)
C(8)—W(1)—C(6)—N(6)	147 (9)	N(8)ii—Cu(2)—N(1C)—C(2C)	−35.7 (3)
C(6)—W(1)—C(8)—N(8)	−19 (8)	N(1C)—Cu(2)—N(8)ii—C(8)ii	−106 (2)
C(8)—W(1)—C(1)—N(1)	−29 (10)	N(8)ii—Cu(2)—N(2)—C(2)	−42 (6)
C(1)—W(1)—C(8)—N(8)	128 (8)	N(2)—Cu(2)—N(8)ii—C(8)ii	164 (4)
C(8)—W(1)—C(3)—N(3)	174 (4)	N(6)iii—Cu(2)—N(3P)—C(4P)	−117.8 (4)
C(3)—W(1)—C(8)—N(8)	−123 (8)	N(6)iii—Cu(2)—N(3P)—C(2P)	70.2 (3)
C(8)—W(1)—C(2)—N(2)	−127 (6)	N(3P)—Cu(2)—N(6)iii—C(6)iii	111.1 (14)
C(2)—W(1)—C(8)—N(8)	−169 (8)	N(6)iii—Cu(2)—N(3)iv—C(3)iv	3(4)
C(8)—W(1)—C(7)—N(7)	169 (16)	N(3)iv—Cu(2)—N(6)iii—C(6)iii	151 (3)
C(7)—W(1)—C(8)—N(8)	−93 (8)	N(6)iii—Cu(2)—N(1C)—C(6C)	−130.7 (4)
C(8)—W(1)—C(4)—N(4)	89 (11)	N(6)iii—Cu(2)—N(1C)—C(2C)	51.9 (3)
C(4)—W(1)—C(8)—N(8)	37 (8)	N(1C)—Cu(2)—N(6)iii—C(6)iii	−67.1 (14)
C(6)—W(1)—C(1)—N(1)	78 (10)	N(6)iii—Cu(2)—N(2)—C(2)	−40.2 (17)
C(1)—W(1)—C(6)—N(6)	31 (9)	N(2)—Cu(2)—N(6)iii—C(6)iii	−157.2 (14)
C(6)—W(1)—C(3)—N(3)	76 (4)	N(3P)—Cu(2)—N(3)iv—C(3)iv	43.2 (12)
C(3)—W(1)—C(6)—N(6)	−66 (9)	N(3)iv—Cu(2)—N(3P)—C(4P)	63.8 (3)
C(6)—W(1)—C(2)—N(2)	176 (5)	N(3)iv—Cu(2)—N(3P)—C(2P)	−108.3 (3)
C(2)—W(1)—C(6)—N(6)	−158 (9)	N(3P)—Cu(2)—N(1C)—C(6C)	73 (2)
C(6)—W(1)—C(7)—N(7)	82 (16)	N(3P)—Cu(2)—N(1C)—C(2C)	−104 (2)
C(7)—W(1)—C(6)—N(6)	−135 (9)	N(1C)—Cu(2)—N(3P)—C(4P)	38 (2)
C(6)—W(1)—C(4)—N(4)	147 (11)	N(1C)—Cu(2)—N(3P)—C(2P)	−134 (2)
C(4)—W(1)—C(6)—N(6)	−0(8)	N(3P)—Cu(2)—N(2)—C(2)	52.5 (17)
C(1)—W(1)—C(3)—N(3)	−69 (4)	N(2)—Cu(2)—N(3P)—C(4P)	151.1 (3)
C(3)—W(1)—C(1)—N(1)	−178 (9)	N(2)—Cu(2)—N(3P)—C(2P)	−20.9 (3)
C(1)—W(1)—C(2)—N(2)	−10 (6)	N(3)iv—Cu(2)—N(1C)—C(6C)	47.8 (4)
C(2)—W(1)—C(1)—N(1)	−96 (10)	N(3)iv—Cu(2)—N(1C)—C(2C)	−129.6 (3)
C(1)—W(1)—C(7)—N(7)	−86 (16)	N(1C)—Cu(2)—N(3)iv—C(3)iv	−138.7 (12)
C(7)—W(1)—C(1)—N(1)	−122 (10)	N(3)iv—Cu(2)—N(2)—C(2)	137.8 (17)
C(1)—W(1)—C(4)—N(4)	−15 (11)	N(2)—Cu(2)—N(3)iv—C(3)iv	−48.7 (12)
C(4)—W(1)—C(1)—N(1)	110 (10)	N(1C)—Cu(2)—N(2)—C(2)	−131.6 (17)
C(3)—W(1)—C(2)—N(2)	77 (6)	N(2)—Cu(2)—N(1C)—C(6C)	−39.7 (3)
C(2)—W(1)—C(3)—N(3)	−140 (4)	N(2)—Cu(2)—N(1C)—C(2C)	142.9 (3)
C(3)—W(1)—C(7)—N(7)	−28 (16)	Cu(2)x—N(8)—C(8)—W(1)	29 (10)
C(7)—W(1)—C(3)—N(3)	144 (4)	Cu(2)viii—N(6)—C(6)—W(1)	8(10)
C(3)—W(1)—C(4)—N(4)	−103 (11)	Cu(2)—N(3P)—C(4P)—C(5P)	−171.8 (4)
C(4)—W(1)—C(3)—N(3)	8(4)	Cu(2)—N(3P)—C(2P)—N(1P)	170.1 (3)
C(2)—W(1)—C(7)—N(7)	−111 (16)	C(4P)—N(3P)—C(2P)—N(1P)	−2.1 (7)
C(7)—W(1)—C(2)—N(2)	154 (6)	C(2P)—N(3P)—C(4P)—C(5P)	0.6 (7)
C(2)—W(1)—C(4)—N(4)	−52 (11)	Cu(2)xiv—N(3)—C(3)—W(1)	−3(5)
C(4)—W(1)—C(2)—N(2)	29 (6)	Cu(1)—N(1P)—C(2P)—N(3P)	−177.2 (3)
C(7)—W(1)—C(4)—N(4)	−157 (11)	Cu(1)—N(1P)—C(6P)—C(5P)	178.7 (4)
C(4)—W(1)—C(7)—N(7)	26 (16)	C(2P)—N(1P)—C(6P)—C(5P)	−0.6 (8)
O(1)—Cu(1)—N(1P)—C(2P)	−88.9 (3)	C(6P)—N(1P)—C(2P)—N(3P)	2.1 (7)
O(1)—Cu(1)—N(1P)—C(6P)	91.8 (4)	Cu(2)—N(1C)—C(6C)—C(5C)	−175.8 (5)
O(1)—Cu(1)—N(1P)i—C(2P)i	−91.1 (3)	Cu(2)—N(1C)—C(2C)—C(3C)	175.9 (4)
O(1)—Cu(1)—N(1P)i—C(6P)i	88.2 (4)	C(6C)—N(1C)—C(2C)—C(3C)	−1.6 (7)
O(1)—Cu(1)—N(1)—C(1)	178.2 (7)	C(2C)—N(1C)—C(6C)—C(5C)	1.7 (8)
O(1)—Cu(1)—N(1)i—C(1)i	1.8 (7)	Cu(2)—N(2)—C(2)—W(1)	−20 (7)
O(1)i—Cu(1)—N(1P)—C(2P)	91.1 (3)	Cu(1)—N(1)—C(1)—W(1)	9(10)
O(1)i—Cu(1)—N(1P)—C(6P)	−88.2 (4)	N(3P)—C(4P)—C(5P)—C(6P)	0.8 (8)
O(1)i—Cu(1)—N(1P)i—C(2P)i	88.9 (3)	C(4P)—C(5P)—C(6P)—N(1P)	−0.7 (8)
O(1)i—Cu(1)—N(1P)i—C(6P)i	−91.8 (4)	N(1C)—C(6C)—C(5C)—C(4C)	−0.8 (9)
O(1)i—Cu(1)—N(1)—C(1)	−1.8 (7)	C(6C)—C(5C)—C(4C)—C(3C)	−0.3 (7)
O(1)i—Cu(1)—N(1)i—C(1)i	−178.2 (7)	C(6C)—C(5C)—C(4C)—C(7C)	−176.1 (7)
N(1P)—Cu(1)—N(1)—C(1)	88.1 (7)	C(5C)—C(4C)—C(3C)—C(2C)	0.3 (7)
N(1)—Cu(1)—N(1P)—C(2P)	2.3 (3)	C(5C)—C(4C)—C(7C)—N(8C)	−22 (10)
N(1)—Cu(1)—N(1P)—C(6P)	−177.0 (4)	C(3C)—C(4C)—C(7C)—N(8C)	161 (9)
N(1P)—Cu(1)—N(1)i—C(1)i	91.9 (7)	C(7C)—C(4C)—C(3C)—C(2C)	176.8 (6)
N(1)i—Cu(1)—N(1P)—C(2P)	−177.7 (3)	C(4C)—C(3C)—C(2C)—N(1C)	0.6 (8)
N(1)i—Cu(1)—N(1P)—C(6P)	3.0 (4)