Literature DB >> 21580570

N'-[(E)-4-(Diethyl-amino)benzyl-idene]-4-nitro-benzohydrazide monohydrate.

Tanveer Ahmad, Muhammad Zia-Ur-Rehman, Hamid Latif Siddiqui, Syed Umar Farooq Rizvi, Masood Parvez.   

Abstract

In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methyl-idenehydrazide fragment, which is fully extended with C-C-N-N, C-N-N=C and N-N=C-C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic rings is 7.01 (8)°. In the crystal structure, the n class="Chemical">water of hydration is involved in extensive hydrogen bonding. Inter-molecular O-H⋯O, N-H⋯O and O-H⋯N hydrogen bonds link the components of the structure into a two-dimensional network and additional stabilization is provided by weak inter-molecular C-H⋯O hydrogen bonds.

Entities:  

Year:  2010        PMID: 21580570      PMCID: PMC2983899          DOI: 10.1107/S1600536810011554

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  7 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  A facile synthesis of novel biologically active 4-hydroxy-N'-(benzylidene)-2H-benzo[e][1,2]thiazine-3-carbohydrazide 1,1-dioxides.

Authors:  Muhammad Zia-ur-Rehman; Jamil Anwar Choudary; Mark Robert James Elsegood; Hamid Latif Siddiqui; Khalid Mohammad Khan
Journal:  Eur J Med Chem       Date:  2008-08-13       Impact factor: 6.514

3.  Anti-genotoxic hydrazide from Crinum defixum.

Authors:  Manobjyoti Bordoloi; Rumi Kotoky; Jiban J Mahanta; Tarun C Sarma; Purnendu B Kanjilal
Journal:  Eur J Med Chem       Date:  2008-10-07       Impact factor: 6.514

4.  Anti-oxidant and anti-bacterial activities of novel N'-arylmethylidene-2-(3, 4-dimethyl-5, 5-dioxidopyrazolo[4,3-c][1,2]benzothiazin-2(4H)-yl) acetohydrazides.

Authors:  Matloob Ahmad; Hamid Latif Siddiqui; Muhammad Zia-ur-Rehman; Masood Parvez
Journal:  Eur J Med Chem       Date:  2009-11-11       Impact factor: 6.514

5.  N'-[(Z)-4-(Dimethyl-amino)benzyl-idene]-4-nitro-benzohydrazide mono-hydrate.

Authors:  Hoong-Kun Fun; Samuel Robinson Jebas; K V Sujith; P S Patil; B Kalluraya
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-13

6.  Synthesis, characterization and biological activity of Ni, Cu and Zn complexes of isatin hydrazones.

Authors:  Maria C Rodríuez-Argüelles; Marisa Belicchi errari; Franco Bisceglie; Corrado Pelizzi; Giorgio Pelosi; Silvana Pinelli; Monica Sassi
Journal:  J Inorg Biochem       Date:  2004-02       Impact factor: 4.155

7.  New transition metal ion complexes with benzimidazole-5-carboxylic acid hydrazides with antitumor activity.

Authors:  Shadia A Galal; Khaled H Hegab; Ahmed S Kassab; Mireya L Rodriguez; Sean M Kerwin; Abdel-Mo'men A el-Khamry; Hoda I el-Diwani
Journal:  Eur J Med Chem       Date:  2008-07-19       Impact factor: 6.514

  7 in total

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