Literature DB >> 21580519

[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Primjira P Tadbuppa, Edward R T Tiekink.   

Abstract

The <span n>an class="Chemical">class="Chemical">Au atom in the title compound, [<class="Chemical">span class="Chemical">Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

Entities:  

Year:  2010        PMID： 21580519      PMCID： PMC2983763          DOI： 10.1107/S160053681000975X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For the structural systematin>an class="Chemical">cs and luminescence properties of <span class="Chemical">phosphinegold(I) carbonimidothio­ates, see: Ho et al. (2006 ▶); Ho & Tiekink (2007 ▶); Kuan et al. (2008 ▶). For the synthesis, see Hall et al. (1993 ▶).

Experimental

Crystal data

[<span n>an class="Chemical">class="Chemical">Au(C11H14NOS)(<class="Chemical">span class="Chemical">C18H33P)] M = 685.67 Monopan class="Chemical">clinin>an class="Chemical">c, a = 13.7415 (18) Å b = 13.3528 (18) Å pan class="Chemical">c = 16.788 (2) Å β = 100.308 (3)° V = 3030.7 (7) Å3 Z = 4 Mo Kα radiation μ = 5.00 mm−1 T = 223 K 0.37 × 0.10 × 0.10 mm

Data collection

Bruker SMART pan class="Chemical">Cn>an class="Chemical">CD diffractometer Absorption pan class="Chemical">corren>an class="Chemical">ction: multi-scan (SADABS; Bruker, 2000 ▶) T min = 0.445, T max = 1.000 20885 measured reflepan class="Chemical">ctions 6943 independent reflepan class="Chemical">ctions 5710 reflepan class="Chemical">ctions with I > 2σ(I) R int = 0.031

Refinement

R[F 2 > 2σ(F 2)] = 0.028 wR(F 2) = 0.072 S = 1.03 6943 reflepan class="Chemical">ctions 308 parameters H-atom parameters pan class="Chemical">constrained Δρmax = 1.60 e Å−3 Δρmin = −0.40 e Å−3 Data collen>an class="Chemical">ction: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and <span class="Disease">DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶). pan class="Chemical">Crystal strun>an class="Chemical">cture: contains datablocks global. DOI: 10.1107/S160053681000975X/hg2660sup1.cif Strupan class="Chemical">cture fan>an class="Chemical">ctors: contains datablocks I. DOI: 10.1107/S160053681000975X/hg2660Isup2.hkl Additional supplementary materials: pan class="Chemical">crystallographin>an class="Chemical">c information; 3D view; checkCIF report
[Au(C11H14NOS)(C18H33P)]F(000) = 1384
Mr = 685.67Dx = 1.503 Mg m−3
Monoclinic, P21/cMo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 2ybcCell parameters from 993 reflections
a = 13.7415 (18) Åθ = 2.4–26.7°
b = 13.3528 (18) ŵ = 5.00 mm−1
c = 16.788 (2) ÅT = 223 K
β = 100.308 (3)°Block, colourless
V = 3030.7 (7) Å30.37 × 0.10 × 0.10 mm
Z = 4
Bruker SMART CCD diffractometer6943 independent reflections
Radiation source: fine-focus sealed tube5710 reflections with I > 2σ(I)
graphiteRint = 0.031
ω scansθmax = 27.5°, θmin = 1.5°
Absorption correction: multi-scan (SADABS; Bruker, 2000)h = −17→17
Tmin = 0.445, Tmax = 1.000k = −12→17
20885 measured reflectionsl = −21→20
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.028Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.072H-atom parameters constrained
S = 1.03w = 1/[σ2(Fo2) + (0.0386P)2] where P = (Fo2 + 2Fc2)/3
6943 reflections(Δ/σ)max = 0.001
308 parametersΔρmax = 1.60 e Å−3
0 restraintsΔρmin = −0.40 e Å−3
Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/Ueq
Au0.009245 (9)0.077062 (9)0.342984 (7)0.03840 (5)
S10.16091 (6)0.15458 (6)0.37674 (6)0.0453 (2)
P1−0.13794 (6)−0.00461 (6)0.32160 (5)0.03605 (18)
O10.19821 (19)0.00020 (18)0.29116 (16)0.0534 (6)
N10.3294 (2)0.1077 (2)0.3217 (2)0.0532 (8)
C10.2414 (3)0.0848 (2)0.3270 (2)0.0460 (8)
C20.3764 (2)0.1942 (3)0.3601 (3)0.0531 (9)
C30.3875 (3)0.2088 (3)0.4421 (3)0.0581 (10)
H30.35940.16280.47380.070*
C40.4409 (3)0.2924 (4)0.4799 (3)0.0660 (11)
C50.4820 (3)0.3578 (3)0.4314 (4)0.0733 (13)
H50.51760.41370.45490.088*
C60.4720 (3)0.3428 (4)0.3502 (3)0.0733 (13)
H60.50050.38830.31840.088*
C70.4203 (3)0.2612 (3)0.3142 (3)0.0640 (11)
H70.41480.25090.25820.077*
C80.4511 (4)0.3060 (5)0.5685 (3)0.0981 (17)
H8A0.51650.33170.59010.147*
H8B0.44180.24220.59370.147*
H8C0.40160.35310.57980.147*
C90.2533 (3)−0.0593 (3)0.2416 (3)0.0610 (11)
H90.2894−0.01420.21020.073*
C100.1759 (4)−0.1171 (4)0.1845 (3)0.0847 (15)
H10A0.1317−0.07060.15150.127*
H10B0.1384−0.15870.21550.127*
H10C0.2080−0.15920.14980.127*
C110.3256 (4)−0.1286 (4)0.2928 (3)0.0811 (14)
H11A0.3755−0.08930.32750.122*
H11B0.3572−0.17080.25790.122*
H11C0.2907−0.17010.32580.122*
C12−0.2309 (3)0.0592 (2)0.3696 (2)0.0421 (8)
H12−0.24840.12160.33840.050*
C13−0.1880 (3)0.0913 (3)0.4560 (2)0.0511 (9)
H13A−0.12820.13120.45580.061*
H13B−0.16920.03160.48920.061*
C14−0.2617 (3)0.1526 (3)0.4934 (3)0.0649 (11)
H14A−0.23300.16860.54970.078*
H14B−0.27520.21580.46380.078*
C15−0.3573 (3)0.0959 (4)0.4909 (3)0.0715 (13)
H15A−0.40480.13840.51210.086*
H15B−0.34490.03650.52560.086*
C16−0.4009 (3)0.0637 (4)0.4053 (3)0.0778 (14)
H16A−0.42000.12320.37190.093*
H16B−0.46060.02380.40600.093*
C17−0.3273 (2)0.0023 (3)0.3681 (3)0.0568 (10)
H17A−0.3135−0.06060.39820.068*
H17B−0.3563−0.01440.31200.068*
C18−0.1932 (2)−0.0195 (2)0.21456 (19)0.0404 (7)
H18−0.2501−0.06590.21100.048*
C19−0.2310 (3)0.0793 (3)0.1754 (2)0.0519 (9)
H19A−0.17640.12750.18090.062*
H19B−0.28170.10670.20360.062*
C20−0.2749 (4)0.0657 (3)0.0859 (3)0.0641 (12)
H20A−0.33480.02470.08100.077*
H20B−0.29400.13140.06200.077*
C21−0.2044 (3)0.0170 (3)0.0393 (2)0.0670 (12)
H21A−0.14980.06310.03600.080*
H21B−0.23870.0032−0.01600.080*
C22−0.1630 (4)−0.0807 (3)0.0790 (2)0.0602 (11)
H22A−0.1121−0.10660.05030.072*
H22B−0.2161−0.13050.07420.072*
C23−0.1184 (3)−0.0660 (3)0.1681 (2)0.0485 (9)
H23A−0.0966−0.13080.19220.058*
H23B−0.0603−0.02230.17260.058*
C24−0.1207 (2)−0.1309 (2)0.36852 (19)0.0373 (7)
H24−0.1315−0.12290.42490.045*
C25−0.1948 (2)−0.2105 (2)0.3298 (2)0.0412 (7)
H25A−0.1854−0.22340.27420.049*
H25B−0.2624−0.18600.32780.049*
C26−0.1799 (3)−0.3075 (3)0.3788 (2)0.0490 (8)
H26A−0.1947−0.29550.43300.059*
H26B−0.2260−0.35850.35240.059*
C27−0.0745 (3)−0.3458 (3)0.3862 (2)0.0537 (9)
H27A−0.0660−0.40600.42010.064*
H27B−0.0616−0.36400.33240.064*
C28−0.0008 (3)−0.2657 (3)0.4234 (2)0.0558 (10)
H28A0.0668−0.29030.42530.067*
H28B−0.0096−0.25220.47910.067*
C29−0.0154 (2)−0.1691 (3)0.3743 (2)0.0477 (8)
H29A0.0312−0.11830.40020.057*
H29B−0.0018−0.18140.31980.057*
U11U22U33U12U13U23
Au0.04093 (8)0.03425 (8)0.03913 (8)−0.00328 (5)0.00472 (5)−0.00191 (5)
S10.0431 (4)0.0385 (5)0.0546 (5)−0.0042 (4)0.0096 (4)−0.0074 (4)
P10.0378 (4)0.0335 (4)0.0355 (4)0.0002 (3)0.0028 (3)−0.0008 (3)
O10.0592 (15)0.0424 (14)0.0606 (16)−0.0018 (12)0.0163 (12)−0.0119 (12)
N10.0439 (17)0.0524 (18)0.064 (2)0.0025 (15)0.0108 (15)0.0019 (15)
C10.050 (2)0.039 (2)0.047 (2)0.0068 (15)0.0062 (16)0.0050 (14)
C20.0348 (17)0.051 (2)0.072 (3)0.0081 (16)0.0043 (17)0.0029 (19)
C30.043 (2)0.054 (2)0.076 (3)0.0027 (17)0.0061 (19)0.000 (2)
C40.043 (2)0.071 (3)0.079 (3)0.006 (2)0.001 (2)−0.007 (2)
C50.048 (2)0.054 (3)0.113 (4)0.0004 (19)0.002 (3)0.002 (3)
C60.050 (2)0.065 (3)0.101 (4)−0.002 (2)0.004 (2)0.020 (3)
C70.040 (2)0.066 (3)0.084 (3)0.0013 (19)0.0061 (19)0.016 (2)
C80.080 (3)0.115 (5)0.098 (4)−0.010 (3)0.013 (3)−0.025 (3)
C90.075 (3)0.046 (2)0.066 (3)0.010 (2)0.025 (2)−0.0031 (18)
C100.114 (4)0.063 (3)0.079 (3)0.008 (3)0.022 (3)−0.022 (3)
C110.100 (4)0.068 (3)0.079 (3)0.022 (3)0.026 (3)0.001 (2)
C120.0438 (19)0.0367 (19)0.0438 (19)0.0081 (14)0.0025 (15)−0.0008 (14)
C130.054 (2)0.052 (2)0.048 (2)0.0014 (17)0.0096 (17)−0.0102 (16)
C140.077 (3)0.060 (3)0.062 (3)0.011 (2)0.023 (2)−0.010 (2)
C150.064 (3)0.079 (3)0.077 (3)0.023 (2)0.026 (2)−0.006 (2)
C160.046 (2)0.101 (4)0.089 (4)0.017 (2)0.017 (2)−0.005 (3)
C170.0386 (19)0.067 (3)0.063 (2)0.0069 (18)0.0053 (17)−0.008 (2)
C180.0428 (17)0.0397 (19)0.0358 (17)−0.0096 (14)−0.0004 (13)0.0027 (13)
C190.060 (2)0.045 (2)0.047 (2)−0.0031 (17)0.0004 (17)0.0100 (15)
C200.077 (3)0.055 (3)0.051 (2)−0.015 (2)−0.014 (2)0.0186 (18)
C210.096 (3)0.061 (3)0.039 (2)−0.030 (2)−0.001 (2)0.0029 (18)
C220.092 (3)0.052 (2)0.035 (2)−0.016 (2)0.008 (2)−0.0033 (16)
C230.061 (2)0.046 (2)0.0375 (19)−0.0088 (17)0.0063 (16)−0.0052 (14)
C240.0418 (17)0.0330 (17)0.0365 (17)−0.0006 (14)0.0049 (13)0.0002 (13)
C250.0474 (18)0.0379 (19)0.0371 (17)−0.0019 (15)0.0046 (14)0.0002 (13)
C260.063 (2)0.0391 (19)0.045 (2)−0.0057 (17)0.0084 (17)0.0003 (15)
C270.077 (3)0.0328 (19)0.052 (2)0.0086 (18)0.0120 (19)0.0050 (15)
C280.058 (2)0.044 (2)0.063 (2)0.0100 (18)0.0037 (19)0.0075 (18)
C290.0426 (18)0.041 (2)0.058 (2)0.0021 (15)0.0032 (16)0.0055 (16)
Au—P12.2692 (9)C15—C161.517 (7)
Au—S12.3051 (9)C15—H15A0.9800
S1—C11.766 (4)C15—H15B0.9800
P1—C121.837 (4)C16—C171.521 (5)
P1—C181.832 (3)C16—H16A0.9800
P1—C241.858 (3)C16—H16B0.9800
O1—C11.365 (4)C17—H17A0.9800
O1—C91.456 (5)C17—H17B0.9800
N1—C11.266 (5)C18—C191.524 (5)
N1—C21.420 (5)C18—C231.529 (5)
C2—C31.372 (6)C18—H180.9900
C2—C71.387 (6)C19—C201.527 (5)
C3—C41.421 (6)C19—H19A0.9800
C3—H30.9400C19—H19B0.9800
C4—C51.383 (6)C20—C211.498 (7)
C4—C81.480 (7)C20—H20A0.9800
C5—C61.359 (7)C20—H20B0.9800
C5—H50.9400C21—C221.529 (6)
C6—C71.379 (6)C21—H21A0.9800
C6—H60.9400C21—H21B0.9800
C7—H70.9400C22—C231.525 (5)
C8—H8A0.9700C22—H22A0.9800
C8—H8B0.9700C22—H22B0.9800
C8—H8C0.9700C23—H23A0.9800
C9—C111.509 (6)C23—H23B0.9800
C9—C101.511 (7)C24—C291.522 (4)
C9—H90.9900C24—C251.534 (4)
C10—H10A0.9700C24—H240.9900
C10—H10B0.9700C25—C261.529 (5)
C10—H10C0.9700C25—H25A0.9800
C11—H11A0.9700C25—H25B0.9800
C11—H11B0.9700C26—C271.521 (5)
C11—H11C0.9700C26—H26A0.9800
C12—C171.524 (5)C26—H26B0.9800
C12—C131.527 (5)C27—C281.528 (5)
C12—H120.9900C27—H27A0.9800
C13—C141.522 (5)C27—H27B0.9800
C13—H13A0.9800C28—C291.525 (5)
C13—H13B0.9800C28—H28A0.9800
C14—C151.511 (6)C28—H28B0.9800
C14—H14A0.9800C29—H29A0.9800
C14—H14B0.9800C29—H29B0.9800
P1—Au—S1174.73 (3)C15—C16—H16B109.4
C1—S1—Au105.20 (13)C17—C16—H16B109.4
C12—P1—C18106.37 (16)H16A—C16—H16B108.0
C12—P1—C24106.32 (16)C12—C17—C16111.4 (3)
C18—P1—C24108.42 (15)C12—C17—H17A109.4
C12—P1—Au112.19 (12)C16—C17—H17A109.4
C18—P1—Au114.12 (11)C12—C17—H17B109.4
C24—P1—Au109.07 (10)C16—C17—H17B109.4
C1—O1—C9118.3 (3)H17A—C17—H17B108.0
C1—N1—C2121.8 (3)C19—C18—C23109.9 (3)
N1—C1—O1121.0 (3)C19—C18—P1112.2 (2)
N1—C1—S1126.4 (3)C23—C18—P1110.2 (2)
O1—C1—S1112.7 (3)C19—C18—H18108.1
C3—C2—N1122.1 (4)C23—C18—H18108.1
C3—C2—C7119.0 (4)P1—C18—H18108.1
N1—C2—C7118.7 (4)C18—C19—C20111.4 (3)
C2—C3—C4121.1 (4)C18—C19—H19A109.3
C2—C3—H3119.5C20—C19—H19A109.3
C4—C3—H3119.5C18—C19—H19B109.3
C5—C4—C3117.7 (5)C20—C19—H19B109.3
C5—C4—C8122.7 (5)H19A—C19—H19B108.0
C3—C4—C8119.6 (5)C21—C20—C19112.8 (4)
C6—C5—C4121.3 (5)C21—C20—H20A109.0
C6—C5—H5119.4C19—C20—H20A109.0
C4—C5—H5119.4C21—C20—H20B109.0
C5—C6—C7120.5 (5)C19—C20—H20B109.0
C5—C6—H6119.7H20A—C20—H20B107.8
C7—C6—H6119.7C20—C21—C22111.6 (3)
C6—C7—C2120.5 (5)C20—C21—H21A109.3
C6—C7—H7119.8C22—C21—H21A109.3
C2—C7—H7119.8C20—C21—H21B109.3
C4—C8—H8A109.5C22—C21—H21B109.3
C4—C8—H8B109.5H21A—C21—H21B108.0
H8A—C8—H8B109.5C21—C22—C23111.8 (3)
C4—C8—H8C109.5C21—C22—H22A109.3
H8A—C8—H8C109.5C23—C22—H22A109.3
H8B—C8—H8C109.5C21—C22—H22B109.3
O1—C9—C11111.5 (4)C23—C22—H22B109.3
O1—C9—C10105.2 (4)H22A—C22—H22B107.9
C11—C9—C10111.4 (4)C18—C23—C22111.4 (3)
O1—C9—H9109.5C18—C23—H23A109.4
C11—C9—H9109.5C22—C23—H23A109.4
C10—C9—H9109.5C18—C23—H23B109.4
C9—C10—H10A109.5C22—C23—H23B109.4
C9—C10—H10B109.5H23A—C23—H23B108.0
H10A—C10—H10B109.5C29—C24—C25110.2 (3)
C9—C10—H10C109.5C29—C24—P1112.3 (2)
H10A—C10—H10C109.5C25—C24—P1115.1 (2)
H10B—C10—H10C109.5C29—C24—H24106.2
C9—C11—H11A109.5C25—C24—H24106.2
C9—C11—H11B109.5P1—C24—H24106.2
H11A—C11—H11B109.5C24—C25—C26110.1 (3)
C9—C11—H11C109.5C24—C25—H25A109.6
H11A—C11—H11C109.5C26—C25—H25A109.6
H11B—C11—H11C109.5C24—C25—H25B109.6
C17—C12—C13110.0 (3)C26—C25—H25B109.6
C17—C12—P1115.6 (2)H25A—C25—H25B108.1
C13—C12—P1111.5 (2)C27—C26—C25111.3 (3)
C17—C12—H12106.4C27—C26—H26A109.4
C13—C12—H12106.4C25—C26—H26A109.4
P1—C12—H12106.4C27—C26—H26B109.4
C12—C13—C14111.8 (3)C25—C26—H26B109.4
C12—C13—H13A109.3H26A—C26—H26B108.0
C14—C13—H13A109.3C28—C27—C26110.5 (3)
C12—C13—H13B109.3C28—C27—H27A109.6
C14—C13—H13B109.3C26—C27—H27A109.6
H13A—C13—H13B107.9C28—C27—H27B109.6
C15—C14—C13111.0 (3)C26—C27—H27B109.6
C15—C14—H14A109.4H27A—C27—H27B108.1
C13—C14—H14A109.4C27—C28—C29110.9 (3)
C15—C14—H14B109.4C27—C28—H28A109.5
C13—C14—H14B109.4C29—C28—H28A109.5
H14A—C14—H14B108.0C27—C28—H28B109.5
C14—C15—C16111.3 (4)C29—C28—H28B109.5
C14—C15—H15A109.4H28A—C28—H28B108.0
C16—C15—H15A109.4C24—C29—C28110.5 (3)
C14—C15—H15B109.4C24—C29—H29A109.6
C16—C15—H15B109.4C28—C29—H29A109.6
H15A—C15—H15B108.0C24—C29—H29B109.6
C15—C16—C17111.3 (4)C28—C29—H29B109.6
C15—C16—H16A109.4H29A—C29—H29B108.1
C17—C16—H16A109.4
P1—Au—S1—C1107.5 (3)C13—C14—C15—C16−55.5 (5)
S1—Au—P1—C1274.2 (3)C14—C15—C16—C1755.8 (5)
S1—Au—P1—C18−164.8 (3)C13—C12—C17—C1655.6 (4)
S1—Au—P1—C24−43.3 (3)P1—C12—C17—C16−177.1 (3)
C2—N1—C1—O1−178.5 (3)C15—C16—C17—C12−56.1 (5)
C2—N1—C1—S12.8 (6)C12—P1—C18—C1953.4 (3)
C9—O1—C1—N1−4.5 (5)C24—P1—C18—C19167.4 (3)
C9—O1—C1—S1174.3 (3)Au—P1—C18—C19−70.8 (3)
Au—S1—C1—N1171.7 (3)C12—P1—C18—C23176.2 (2)
Au—S1—C1—O1−7.1 (3)C24—P1—C18—C23−69.8 (3)
C1—N1—C2—C358.2 (5)Au—P1—C18—C2352.0 (2)
C1—N1—C2—C7−127.9 (4)C23—C18—C19—C2055.8 (4)
N1—C2—C3—C4175.5 (3)P1—C18—C19—C20178.8 (3)
C7—C2—C3—C41.6 (5)C18—C19—C20—C21−54.8 (5)
C2—C3—C4—C5−0.6 (6)C19—C20—C21—C2252.5 (4)
C2—C3—C4—C8179.7 (4)C20—C21—C22—C23−52.9 (5)
C3—C4—C5—C6−0.1 (6)C19—C18—C23—C22−56.7 (4)
C8—C4—C5—C6179.5 (4)P1—C18—C23—C22179.2 (2)
C4—C5—C6—C7−0.1 (7)C21—C22—C23—C1855.4 (5)
C5—C6—C7—C21.1 (6)C12—P1—C24—C29−147.5 (2)
C3—C2—C7—C6−1.8 (6)C18—P1—C24—C2998.5 (3)
N1—C2—C7—C6−175.9 (3)Au—P1—C24—C29−26.4 (3)
C1—O1—C9—C1182.5 (5)C12—P1—C24—C2585.2 (3)
C1—O1—C9—C10−156.6 (4)C18—P1—C24—C25−28.8 (3)
C18—P1—C12—C1762.6 (3)Au—P1—C24—C25−153.6 (2)
C24—P1—C12—C17−52.8 (3)C29—C24—C25—C2657.6 (4)
Au—P1—C12—C17−172.0 (2)P1—C24—C25—C26−174.1 (2)
C18—P1—C12—C13−170.8 (2)C24—C25—C26—C27−57.0 (4)
C24—P1—C12—C1373.8 (3)C25—C26—C27—C2856.3 (4)
Au—P1—C12—C13−45.4 (3)C26—C27—C28—C29−56.4 (4)
C17—C12—C13—C14−55.7 (4)C25—C24—C29—C28−58.0 (4)
P1—C12—C13—C14174.7 (3)P1—C24—C29—C28172.1 (3)
C12—C13—C14—C1555.9 (5)C27—C28—C29—C2457.5 (4)
D—H···AD—HH···AD···AD—H···A
C16—H16a···Cgi0.982.983.655 (5)127
Table 1

Selected bond lengths (Å)

Au—P12.2692 (9)
Au—S12.3051 (9)
Table 2

Hydrogen-bond geometry (Å, °)

Cg is the centroid of the C2–C7 ring.

D—H⋯AD—HH⋯AD⋯AD—H⋯A
C16—H16a⋯Cgi0.982.983.655 (5)127

Symmetry code: (i) .

  2 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  Luminescent phosphine gold(I) thiolates: correlation between crystal structure and photoluminescent properties in [R3PAu{SC(OMe)=NC6H4NO2-4}] (R = Et, Cy, Ph) and [(Ph2P-R-PPh2){AuSC(OMe)=NC6H4NO2-4}2] (R = CH2, (CH2)2, (CH2)3, (CH2)4, Fc).

Authors:  Soo Yei Ho; Eddie Chung-Chin Cheng; Edward R T Tiekink; Vivian Wing-Wah Yam
Journal:  Inorg Chem       Date:  2006-10-02       Impact factor: 5.165
  2 in total

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