catena-Poly[neodymium(III)-bis-[μ-N-(dimorpholinophosphor-yl)benzene-sulfonamidato]-sodium(I)-bis-[μ-N-(dimorpholinophosphor-yl)benzene-sulfonamidato]].

The cubic crystal structure of the title compound, [NaNd(C(14)H(21)N(3)O(5)PS)(4)](n), is composed of one-dimensional polymeric chains propagating in [100], built up from [Nd(C(14)H(21)N(3)O(5)PS)(4)](-) anions and sodium cations functioning as linkers. In the complex anion, the Nd(3+) ion has an eightfold coordination environment formed by the sulfonyl and phosphoryl O atoms of four bidentate chelating N-(dimorpholinophosphor-yl)benzene-sulfonamidate ligands: the resulting NdO(8) polyhedron can be described as inter-mediate between dodeca-hedral and square anti-prismatic. The sodium ion adopts an NaO(4) tetra-hedral geometry arising from four monodentate benzene-sulfonamidate ligands. The resulting crystal structure is unusual because it contains substantial voids (800 Å(3) per unit cell), within which there is no evidence of included solvent.

Related literature

For general background to the use of bidentate ligands in ring closure in coordination compounds, see: Casas et al. (1995 ▶); Amirkhanov et al. (1997 ▶); Ly & Woollins (1998 ▶). For applications of the chelates formed, see: Zazybin et al. (2006 ▶); Karande et al. (2003 ▶); Morgalyuk et al. (2005 ▶); Xu & Angell (2000 ▶). For lanthanide compounds of general formula Na[Ln(L 1)4] where HL 1 is C6H5S(O)2NHPO(OCH3)2, see: Moroz et al. (2007 ▶). For the synthesis of the ligand, see: Kirsanov & Shevchenko (1954 ▶); Oyamada & Morimura (1960 ▶). For inter­pretation of coordination polyhedra, see: Porai-Koshits & Aslanov (1972 ▶). For bond lengths in similar compounds, see: Sokolov et al. (2007 ▶); Sokolnicki et al. (1998 ▶).

Experimental

Crystal data

[NaNd(C14H21N3O5PS)4]

M = 1664.72

Cubic,

a = 22.943 (5) Å

V = 12077 (5) Å3

Z = 6

Mo Kα radiation

μ = 0.90 mm−1

T = 293 K

0.60 × 0.40 × 0.30 mm

Data collection

Oxford Diffraction KM-4 Xcalibur diffractometer with a Sapphire3 detector

Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006 ▶) T min = 0.614, T max = 0.774

66051 measured reflections

5883 independent reflections

3713 reflections with I > 2σ(I)

R int = 0.113

Refinement

R[F 2 > 2σ(F 2)] = 0.095

wR(F 2) = 0.178

S = 1.42

5883 reflections

174 parameters

1 restraint

H-atom parameters constrained

Δρmax = 1.17 e Å−3

Δρmin = −0.75 e Å−3

Absolute structure: Flack (1983 ▶), 2727 Friedel pairs

Flack parameter: 0.05 (3)

Data collection: CrysAlis CCD (Oxford Diffraction, 2006 ▶); cell refinement: CrysAlis RED (Oxford Diffraction, 2006 ▶); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810008214/hb5339sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810008214/hb5339Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[NaNd(C14H21N3O5PS)4]	Mo Kα radiation, λ = 0.71069 Å
Mr = 1664.72	Cell parameters from 68542 reflections
Cubic, P43n	θ = 2.8–32.1°
a = 22.943 (5) Å	µ = 0.90 mm−1
V = 12077 (5) Å3	T = 293 K
Z = 6	Block, light violet
F(000) = 5154	0.60 × 0.40 × 0.30 mm
Dx = 1.373 Mg m−3

Oxford Diffraction KM-4 Xcalibur diffractometer with a Sapphire3 detector	5883 independent reflections
Radiation source: fine-focus sealed tube	3713 reflections with I > 2σ(I)
graphite	Rint = 0.113
Detector resolution: 16.1827 pixels mm-1	θmax = 30.0°, θmin = 2.8°
ω scans	h = −31→32
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006)	k = −30→32
Tmin = 0.614, Tmax = 0.774	l = −32→32
66051 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.095	H-atom parameters constrained
wR(F2) = 0.178	w = 1/[σ2(Fo2) + (0.0311P)2 + 27.6297P] where P = (Fo2 + 2Fc2)/3
S = 1.42	(Δ/σ)max = 0.053
5883 reflections	Δρmax = 1.17 e Å−3
174 parameters	Δρmin = −0.74 e Å−3
1 restraint	Absolute structure: Flack (1983), 2727 Friedel pairs
Primary atom site location: structure-invariant direct methods	Flack parameter: 0.05 (3)

Experimental. CrysAlis RED, (Oxford Diffraction Ltd., 2007) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Nd1	0.2500	0.0000	0.5000	0.03890 (11)
Na1	0.5000	0.0000	0.5000	0.0591 (11)
P1	0.34264 (7)	−0.11150 (8)	0.56551 (8)	0.0580 (4)
S1	0.38783 (6)	−0.07841 (7)	0.45680 (7)	0.0542 (4)
C1	0.3831 (3)	−0.1414 (3)	0.4113 (3)	0.0561 (17)
N1	0.3939 (2)	−0.1001 (3)	0.5188 (2)	0.0784 (19)
N2	0.3754 (2)	−0.1023 (3)	0.6282 (3)	0.0907 (14)
N3	0.3220 (3)	−0.1790 (3)	0.5648 (4)	0.126 (2)
O2	0.33520 (14)	−0.04482 (17)	0.44606 (16)	0.0497 (10)
O3	0.44068 (16)	−0.0500 (2)	0.4378 (2)	0.0719 (13)
O1	0.28838 (15)	−0.07562 (17)	0.55946 (17)	0.0526 (11)
O4	0.4251 (3)	−0.0792 (4)	0.7367 (2)	0.134 (2)
O5	0.2927 (4)	−0.2972 (3)	0.5510 (4)	0.163 (3)
C2	0.4310 (3)	−0.1778 (3)	0.4091 (3)	0.076 (2)
H2A	0.4651	−0.1699	0.4296	0.092*
C3	0.4246 (4)	−0.2277 (3)	0.3737 (4)	0.108 (3)
H3A	0.4562	−0.2528	0.3701	0.129*
C4	0.3754 (5)	−0.2411 (4)	0.3447 (4)	0.112 (3)
H4A	0.3734	−0.2741	0.3212	0.135*
C5	0.3306 (5)	−0.2067 (4)	0.3505 (4)	0.111 (3)
H5A	0.2960	−0.2167	0.3321	0.133*
C6	0.3325 (4)	−0.1552 (3)	0.3833 (3)	0.079 (2)
H6A	0.3000	−0.1311	0.3859	0.095*
C7	0.4355 (3)	−0.0977 (4)	0.6373 (3)	0.0907 (14)
H7A	0.4509	−0.1370	0.6396	0.109*
H7B	0.4521	−0.0800	0.6026	0.109*
C8	0.4565 (5)	−0.0675 (5)	0.6845 (4)	0.134 (2)
H8A	0.4546	−0.0260	0.6763	0.161*
H8B	0.4972	−0.0776	0.6903	0.161*
C9	0.3442 (3)	−0.1124 (4)	0.6830 (3)	0.0907 (14)
H9A	0.3032	−0.1036	0.6778	0.109*
H9B	0.3477	−0.1531	0.6939	0.109*
C10	0.3674 (4)	−0.0770 (6)	0.7282 (4)	0.134 (2)
H10A	0.3569	−0.0368	0.7201	0.161*
H10B	0.3484	−0.0878	0.7644	0.161*
C12	0.2463 (4)	−0.2556 (2)	0.5500 (5)	0.163 (3)
H12A	0.2280	−0.2535	0.5880	0.196*
H12B	0.2171	−0.2673	0.5218	0.196*
C11	0.2713 (3)	−0.1964 (2)	0.5334 (5)	0.126 (2)
H11A	0.2807	−0.1969	0.4922	0.151*
H11B	0.2414	−0.1671	0.5393	0.151*
C13	0.3666 (4)	−0.2253 (3)	0.5699 (5)	0.126 (2)
H13A	0.3873	−0.2288	0.5332	0.151*
H13B	0.3946	−0.2145	0.5997	0.151*
C14	0.3422 (5)	−0.2777 (4)	0.5838 (6)	0.163 (3)
H14A	0.3308	−0.2761	0.6245	0.196*
H14B	0.3723	−0.3072	0.5805	0.196*

	U11	U22	U33	U12	U13	U23
Nd1	0.02596 (19)	0.04536 (15)	0.04536 (15)	0.000	0.000	0.000
Na1	0.0368 (17)	0.078 (3)	0.063 (2)	0.000	0.000	0.000
P1	0.0465 (8)	0.0611 (9)	0.0663 (10)	0.0090 (8)	−0.0157 (8)	−0.0007 (8)
S1	0.0324 (6)	0.0678 (9)	0.0624 (9)	0.0034 (7)	−0.0001 (7)	−0.0180 (8)
C1	0.049 (3)	0.065 (4)	0.055 (3)	0.001 (3)	0.016 (3)	−0.010 (3)
N1	0.054 (3)	0.113 (4)	0.069 (4)	0.041 (3)	−0.004 (3)	−0.008 (3)
N2	0.052 (2)	0.154 (4)	0.066 (2)	−0.005 (3)	−0.0010 (19)	0.018 (3)
N3	0.091 (3)	0.067 (3)	0.219 (6)	0.007 (2)	−0.064 (3)	0.010 (3)
O2	0.0341 (17)	0.059 (2)	0.056 (2)	−0.0013 (18)	0.0033 (18)	−0.009 (2)
O3	0.0338 (19)	0.085 (3)	0.097 (3)	0.001 (2)	0.007 (2)	−0.027 (3)
O1	0.0365 (18)	0.060 (2)	0.061 (2)	0.0045 (18)	0.0008 (18)	0.017 (2)
O4	0.119 (4)	0.212 (5)	0.071 (3)	−0.029 (4)	−0.014 (3)	0.000 (3)
O5	0.194 (6)	0.080 (3)	0.216 (6)	−0.016 (3)	−0.067 (5)	0.034 (4)
C2	0.073 (4)	0.067 (4)	0.090 (5)	0.009 (4)	0.023 (4)	−0.002 (4)
C3	0.143 (7)	0.073 (5)	0.106 (6)	0.021 (5)	0.074 (5)	−0.001 (4)
C4	0.159 (9)	0.077 (5)	0.100 (6)	−0.018 (6)	0.034 (6)	−0.031 (5)
C5	0.137 (8)	0.106 (6)	0.091 (6)	−0.034 (6)	0.003 (6)	−0.041 (5)
C6	0.086 (5)	0.082 (5)	0.070 (4)	−0.009 (4)	−0.007 (4)	−0.009 (4)
C7	0.052 (2)	0.154 (4)	0.066 (2)	−0.005 (3)	−0.0010 (19)	0.018 (3)
C8	0.119 (4)	0.212 (5)	0.071 (3)	−0.029 (4)	−0.014 (3)	0.000 (3)
C9	0.052 (2)	0.154 (4)	0.066 (2)	−0.005 (3)	−0.0010 (19)	0.018 (3)
C10	0.119 (4)	0.212 (5)	0.071 (3)	−0.029 (4)	−0.014 (3)	0.000 (3)
C12	0.194 (6)	0.080 (3)	0.216 (6)	−0.016 (3)	−0.067 (5)	0.034 (4)
C11	0.091 (3)	0.067 (3)	0.219 (6)	0.007 (2)	−0.064 (3)	0.010 (3)
C13	0.091 (3)	0.067 (3)	0.219 (6)	0.007 (2)	−0.064 (3)	0.010 (3)
C14	0.194 (6)	0.080 (3)	0.216 (6)	−0.016 (3)	−0.067 (5)	0.034 (4)

Nd1—O1i	2.376 (4)	O5—C12	1.429 (10)
Nd1—O1ii	2.376 (4)	O5—C14	1.434 (13)
Nd1—O1	2.376 (4)	C2—C3	1.413 (10)
Nd1—O1iii	2.376 (4)	C2—H2A	0.9300
Nd1—O2ii	2.532 (4)	C3—C4	1.345 (13)
Nd1—O2	2.532 (4)	C3—H3A	0.9300
Nd1—O2iii	2.532 (4)	C4—C5	1.302 (13)
Nd1—O2i	2.532 (4)	C4—H4A	0.9300
Na1—O3	2.282 (4)	C5—C6	1.400 (11)
Na1—O3iv	2.282 (4)	C5—H5A	0.9300
Na1—O3v	2.282 (4)	C6—H6A	0.9300
Na1—O3ii	2.282 (4)	C7—C8	1.374 (12)
Na1—S1	3.2926 (16)	C7—H7A	0.9700
Na1—S1v	3.2926 (16)	C7—H7B	0.9700
Na1—S1iv	3.2926 (16)	C8—H8A	0.9700
Na1—S1ii	3.2926 (16)	C8—H8B	0.9700
P1—O1	1.499 (4)	C9—C10	1.421 (13)
P1—N1	1.613 (6)	C9—H9A	0.9700
P1—N3	1.619 (7)	C9—H9B	0.9700
P1—N2	1.637 (7)	C10—H10A	0.9700
S1—O3	1.444 (4)	C10—H10B	0.9700
S1—O2	1.453 (4)	C12—C11	1.524 (5)
S1—N1	1.513 (6)	C12—H12A	0.9700
S1—C1	1.787 (6)	C12—H12B	0.9700
C1—C6	1.365 (10)	C11—H11A	0.9700
C1—C2	1.380 (9)	C11—H11B	0.9700
N2—C7	1.400 (9)	C13—C14	1.364 (12)
N2—C9	1.465 (9)	C13—H13A	0.9700
N3—C11	1.425 (11)	C13—H13B	0.9700
N3—C13	1.478 (10)	C14—H14A	0.9700
O4—C10	1.340 (11)	C14—H14B	0.9700
O4—C8	1.424 (10)
O1i—Nd1—O1ii	97.89 (6)	S1—N1—P1	127.6 (3)
O1i—Nd1—O1	97.89 (6)	C7—N2—C9	111.4 (6)
O1ii—Nd1—O1	136.50 (17)	C7—N2—P1	126.4 (5)
O1i—Nd1—O1iii	136.50 (17)	C9—N2—P1	120.7 (5)
O1ii—Nd1—O1iii	97.89 (6)	C11—N3—C13	113.8 (7)
O1—Nd1—O1iii	97.89 (6)	C11—N3—P1	120.7 (5)
O1i—Nd1—O2ii	151.18 (12)	C13—N3—P1	119.0 (6)
O1ii—Nd1—O2ii	72.42 (12)	S1—O2—Nd1	140.7 (2)
O1—Nd1—O2ii	74.32 (13)	S1—O3—Na1	122.6 (3)
O1iii—Nd1—O2ii	72.30 (12)	P1—O1—Nd1	139.6 (2)
O1i—Nd1—O2	72.30 (12)	C10—O4—C8	111.7 (7)
O1ii—Nd1—O2	74.32 (13)	C12—O5—C14	112.9 (8)
O1—Nd1—O2	72.42 (12)	C1—C2—C3	115.3 (7)
O1iii—Nd1—O2	151.18 (12)	C1—C2—H2A	122.4
O2ii—Nd1—O2	78.92 (16)	C3—C2—H2A	122.4
O1i—Nd1—O2iii	74.32 (13)	C4—C3—C2	123.9 (8)
O1ii—Nd1—O2iii	151.18 (12)	C4—C3—H3A	118.1
O1—Nd1—O2iii	72.30 (12)	C2—C3—H3A	118.1
O1iii—Nd1—O2iii	72.42 (12)	C5—C4—C3	118.2 (9)
O2ii—Nd1—O2iii	126.59 (10)	C5—C4—H4A	120.9
O2—Nd1—O2iii	126.59 (10)	C3—C4—H4A	120.9
O1i—Nd1—O2i	72.42 (12)	C4—C5—C6	122.8 (9)
O1ii—Nd1—O2i	72.30 (12)	C4—C5—H5A	118.6
O1—Nd1—O2i	151.18 (12)	C6—C5—H5A	118.6
O1iii—Nd1—O2i	74.32 (13)	C1—C6—C5	118.3 (8)
O2ii—Nd1—O2i	126.59 (10)	C1—C6—H6A	120.8
O2—Nd1—O2i	126.59 (10)	C5—C6—H6A	120.8
O2iii—Nd1—O2i	78.92 (16)	C8—C7—N2	120.1 (8)
O3—Na1—O3iv	119.6 (2)	C8—C7—H7A	107.3
O3—Na1—O3v	102.5 (2)	N2—C7—H7A	107.3
O3iv—Na1—O3v	106.8 (2)	C8—C7—H7B	107.3
O3—Na1—O3ii	106.8 (2)	N2—C7—H7B	107.3
O3iv—Na1—O3ii	102.5 (2)	H7A—C7—H7B	106.9
O3v—Na1—O3ii	119.6 (2)	C7—C8—O4	113.0 (9)
O3—Na1—S1	21.69 (11)	C7—C8—H8A	109.0
O3iv—Na1—S1	112.32 (11)	O4—C8—H8A	109.0
O3v—Na1—S1	123.55 (12)	C7—C8—H8B	109.0
O3ii—Na1—S1	89.82 (10)	O4—C8—H8B	109.0
O3—Na1—S1v	123.55 (12)	H8A—C8—H8B	107.8
O3iv—Na1—S1v	89.82 (10)	C10—C9—N2	110.7 (7)
O3v—Na1—S1v	21.69 (11)	C10—C9—H9A	109.5
O3ii—Na1—S1v	112.32 (11)	N2—C9—H9A	109.5
S1—Na1—S1v	144.97 (6)	C10—C9—H9B	109.5
O3—Na1—S1iv	112.32 (11)	N2—C9—H9B	109.5
O3iv—Na1—S1iv	21.69 (11)	H9A—C9—H9B	108.1
O3v—Na1—S1iv	89.82 (10)	O4—C10—C9	117.0 (9)
O3ii—Na1—S1iv	123.55 (12)	O4—C10—H10A	108.1
S1—Na1—S1iv	113.77 (6)	C9—C10—H10A	108.1
S1v—Na1—S1iv	77.18 (5)	O4—C10—H10B	108.1
O3—Na1—S1ii	89.82 (10)	C9—C10—H10B	108.1
O3iv—Na1—S1ii	123.55 (12)	H10A—C10—H10B	107.3
O3v—Na1—S1ii	112.32 (11)	O5—C12—C11	108.6 (7)
O3ii—Na1—S1ii	21.69 (11)	O5—C12—H12A	110.0
S1—Na1—S1ii	77.18 (5)	C11—C12—H12A	110.0
S1v—Na1—S1ii	113.77 (6)	O5—C12—H12B	110.0
S1iv—Na1—S1ii	144.97 (6)	C11—C12—H12B	110.0
O1—P1—N1	117.1 (3)	H12A—C12—H12B	108.3
O1—P1—N3	106.4 (3)	N3—C11—C12	115.6 (7)
N1—P1—N3	111.2 (4)	N3—C11—H11A	108.4
O1—P1—N2	113.1 (3)	C12—C11—H11A	108.4
N1—P1—N2	103.2 (3)	N3—C11—H11B	108.4
N3—P1—N2	105.4 (4)	C12—C11—H11B	108.4
O3—S1—O2	114.0 (3)	H11A—C11—H11B	107.5
O3—S1—N1	110.8 (3)	C14—C13—N3	111.6 (8)
O2—S1—N1	114.2 (3)	C14—C13—H13A	109.3
O3—S1—C1	103.8 (3)	N3—C13—H13A	109.3
O2—S1—C1	106.2 (3)	C14—C13—H13B	109.3
N1—S1—C1	106.8 (3)	N3—C13—H13B	109.3
O3—S1—Na1	35.73 (19)	H13A—C13—H13B	108.0
O2—S1—Na1	114.25 (17)	C13—C14—O5	118.5 (10)
N1—S1—Na1	79.9 (2)	C13—C14—H14A	107.7
C1—S1—Na1	131.7 (2)	O5—C14—H14A	107.7
C6—C1—C2	121.4 (6)	C13—C14—H14B	107.7
C6—C1—S1	121.0 (5)	O5—C14—H14B	107.7
C2—C1—S1	117.5 (5)	H14A—C14—H14B	107.1
O3iv—Na1—S1—O3	−114.4 (4)	O3—S1—O2—Nd1	−121.0 (4)
O3v—Na1—S1—O3	15.9 (4)	N1—S1—O2—Nd1	7.8 (5)
O3ii—Na1—S1—O3	142.1 (2)	C1—S1—O2—Nd1	125.3 (4)
S1v—Na1—S1—O3	11.0 (3)	Na1—S1—O2—Nd1	−81.7 (3)
S1iv—Na1—S1—O3	−90.9 (3)	O1i—Nd1—O2—S1	−126.9 (4)
S1ii—Na1—S1—O3	124.3 (3)	O1ii—Nd1—O2—S1	129.2 (4)
O3—Na1—S1—O2	−98.0 (4)	O1—Nd1—O2—S1	−22.3 (3)
O3iv—Na1—S1—O2	147.6 (2)	O1iii—Nd1—O2—S1	51.6 (5)
O3v—Na1—S1—O2	−82.1 (2)	O2ii—Nd1—O2—S1	54.6 (3)
O3ii—Na1—S1—O2	44.1 (2)	O2iii—Nd1—O2—S1	−73.1 (3)
S1v—Na1—S1—O2	−86.97 (18)	O2i—Nd1—O2—S1	−177.7 (3)
S1iv—Na1—S1—O2	171.15 (19)	O2—S1—O3—Na1	98.6 (3)
S1ii—Na1—S1—O2	26.33 (17)	N1—S1—O3—Na1	−31.9 (4)
O3—Na1—S1—N1	149.9 (4)	C1—S1—O3—Na1	−146.2 (3)
O3iv—Na1—S1—N1	35.5 (2)	O3iv—Na1—O3—S1	75.7 (3)
O3v—Na1—S1—N1	165.7 (2)	O3v—Na1—O3—S1	−166.5 (4)
O3ii—Na1—S1—N1	−68.0 (2)	O3ii—Na1—O3—S1	−39.9 (2)
S1v—Na1—S1—N1	160.9 (2)	S1v—Na1—O3—S1	−172.4 (2)
S1iv—Na1—S1—N1	59.0 (2)	S1iv—Na1—O3—S1	98.4 (3)
S1ii—Na1—S1—N1	−85.8 (2)	S1ii—Na1—O3—S1	−53.7 (3)
O3—Na1—S1—C1	46.3 (4)	N1—P1—O1—Nd1	−1.5 (5)
O3iv—Na1—S1—C1	−68.1 (3)	N3—P1—O1—Nd1	−126.5 (5)
O3v—Na1—S1—C1	62.2 (3)	N2—P1—O1—Nd1	118.3 (4)
O3ii—Na1—S1—C1	−171.6 (3)	O1i—Nd1—O1—P1	86.0 (3)
S1v—Na1—S1—C1	57.3 (3)	O1ii—Nd1—O1—P1	−24.3 (3)
S1iv—Na1—S1—C1	−44.6 (3)	O1iii—Nd1—O1—P1	−134.7 (4)
S1ii—Na1—S1—C1	170.6 (3)	O2ii—Nd1—O1—P1	−65.6 (4)
O3—S1—C1—C6	−131.8 (6)	O2—Nd1—O1—P1	17.5 (4)
O2—S1—C1—C6	−11.2 (6)	O2iii—Nd1—O1—P1	156.7 (4)
N1—S1—C1—C6	111.1 (6)	O2i—Nd1—O1—P1	153.6 (3)
Na1—S1—C1—C6	−157.6 (4)	C6—C1—C2—C3	3.4 (10)
O3—S1—C1—C2	53.1 (6)	S1—C1—C2—C3	178.5 (5)
O2—S1—C1—C2	173.7 (5)	C1—C2—C3—C4	−1.8 (12)
N1—S1—C1—C2	−64.0 (6)	C2—C3—C4—C5	−1.3 (14)
Na1—S1—C1—C2	27.4 (7)	C3—C4—C5—C6	2.9 (14)
O3—S1—N1—P1	154.8 (4)	C2—C1—C6—C5	−2.0 (11)
O2—S1—N1—P1	24.4 (6)	S1—C1—C6—C5	−176.9 (6)
C1—S1—N1—P1	−92.7 (5)	C4—C5—C6—C1	−1.4 (13)
Na1—S1—N1—P1	136.6 (5)	C9—N2—C7—C8	−40.8 (12)
O1—P1—N1—S1	−28.1 (6)	P1—N2—C7—C8	153.3 (8)
N3—P1—N1—S1	94.4 (6)	N2—C7—C8—O4	42.8 (13)
N2—P1—N1—S1	−153.0 (5)	C10—O4—C8—C7	−46.7 (13)
O1—P1—N2—C7	−139.0 (7)	C7—N2—C9—C10	41.8 (11)
N1—P1—N2—C7	−11.5 (8)	P1—N2—C9—C10	−151.4 (7)
N3—P1—N2—C7	105.2 (8)	C8—O4—C10—C9	54.2 (13)
O1—P1—N2—C9	56.4 (8)	N2—C9—C10—O4	−52.2 (12)
N1—P1—N2—C9	−176.2 (7)	C14—O5—C12—C11	49.2 (12)
N3—P1—N2—C9	−59.4 (8)	C13—N3—C11—C12	45.9 (12)
O1—P1—N3—C11	29.9 (9)	P1—N3—C11—C12	−162.7 (7)
N1—P1—N3—C11	−98.7 (8)	O5—C12—C11—N3	−48.4 (12)
N2—P1—N3—C11	150.2 (8)	C11—N3—C13—C14	−44.0 (14)
O1—P1—N3—C13	179.8 (8)	P1—N3—C13—C14	164.1 (9)
N1—P1—N3—C13	51.3 (9)	N3—C13—C14—O5	48.7 (16)
N2—P1—N3—C13	−59.9 (9)	C12—O5—C14—C13	−54.3 (15)

Table 1

Selected bond lengths (Å)

Nd1—O1	2.376 (4)
Nd1—O2	2.532 (4)
Na1—O3	2.282 (4)