Poly[(μ(4)-tetra-zole-1-acetato-κN:N:O:O')silver(I)].

In the title complex, [Ag(C(3)H(3)N(4)O(2))](n), the Ag(I) atom is four-coordinated in a slightly distorted tetra-hedral coordination geometry by two N atoms from two tetra-zole-1-acetate (tza) ligands and two O atoms from the other two tza ligands. The tza ligand bridges two Ag atoms through the carboxyl-ate O atoms and simultaneously binds to the other two Ag atoms through the tetra-zole N atoms, forming a two-dimensional network parallel to (100).

Related literature

For the diverse coordination modes and potential applications of metal complexes with tetra­zole derivatives, see: Stagni et al. (2006 ▶); Ye et al. (2006 ▶).

Experimental

Crystal data

[Ag(C3H3N4O2)]

M = 234.96

Triclinic,

a = 5.1584 (10) Å

b = 7.7805 (16) Å

c = 7.8711 (16) Å

α = 109.40 (3)°

β = 98.87 (3)°

γ = 104.85 (3)°

V = 277.92 (14) Å3

Z = 2

Mo Kα radiation

μ = 3.56 mm−1

T = 293 K

0.25 × 0.23 × 0.21 mm

Data collection

Rigaku/MSC Mercury CCD diffractometer

Absorption correction: multi-scan (REQAB; Jacobson, 1998 ▶) T min = 0.470, T max = 0.522

2722 measured reflections

1267 independent reflections

1150 reflections with I > 2σ(I)

R int = 0.056

Refinement

R[F 2 > 2σ(F 2)] = 0.062

wR(F 2) = 0.177

S = 1.23

1267 reflections

92 parameters

H-atom parameters constrained

Δρmax = 2.15 e Å−3

Δρmin = −0.97 e Å−3

Data collection: CrystalStructure (Rigaku/MSC, 2002 ▶); cell refinement: CrystalStructure; data reduction: CrystalStructure; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEPII (Johnson, 1976 ▶) and DIAMOND (Brandenburg, 1999 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810001236/hy2270sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810001236/hy2270Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C3H3N4O2)]	Z = 2
Mr = 234.96	F(000) = 224
Triclinic, P1	Dx = 2.808 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 5.1584 (10) Å	Cell parameters from 3600 reflections
b = 7.7805 (16) Å	θ = 1.4–28°
c = 7.8711 (16) Å	µ = 3.56 mm−1
α = 109.40 (3)°	T = 293 K
β = 98.87 (3)°	Block, blue
γ = 104.85 (3)°	0.25 × 0.23 × 0.21 mm
V = 277.92 (14) Å3

Rigaku/MSC Mercury CCD diffractometer	1267 independent reflections
Radiation source: fine-focus sealed tube	1150 reflections with I > 2σ(I)
graphite	Rint = 0.056
ω scans	θmax = 27.5°, θmin = 3.2°
Absorption correction: multi-scan (REQAB; Jacobson, 1998)	h = −6→6
Tmin = 0.470, Tmax = 0.522	k = −9→10
2722 measured reflections	l = −10→9

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.062	H-atom parameters constrained
wR(F2) = 0.177	w = 1/[σ2(Fo2) + (0.0519P)2 + 3.2858P] where P = (Fo2 + 2Fc2)/3
S = 1.23	(Δ/σ)max < 0.001
1267 reflections	Δρmax = 2.15 e Å−3
92 parameters	Δρmin = −0.97 e Å−3
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.052 (15)

	x	y	z	Uiso*/Ueq
Ag1	0.61189 (17)	−0.19436 (12)	−0.05077 (10)	0.0387 (5)
O1	0.9281 (15)	0.0639 (10)	0.2082 (10)	0.0365 (16)
O2	0.6195 (14)	0.1949 (12)	0.3227 (10)	0.0360 (16)
N1	0.9120 (16)	0.3243 (11)	0.6770 (10)	0.0277 (16)
N2	0.872 (2)	0.4946 (12)	0.7248 (12)	0.0376 (19)
N3	0.7161 (19)	0.4973 (12)	0.8396 (12)	0.0363 (19)
N4	0.656 (2)	0.3322 (13)	0.8697 (12)	0.0351 (18)
C1	0.8444 (18)	0.1645 (13)	0.3374 (12)	0.0265 (17)
C2	1.0509 (18)	0.2615 (13)	0.5323 (12)	0.0267 (17)
H2A	1.1368	0.1710	0.5545	0.032*
H2B	1.1964	0.3719	0.5373	0.032*
C3	0.781 (2)	0.2254 (15)	0.7646 (14)	0.034 (2)
H3	0.7775	0.1022	0.7545	0.041*

	U11	U22	U33	U12	U13	U23
Ag1	0.0430 (6)	0.0441 (6)	0.0259 (5)	0.0145 (4)	0.0071 (3)	0.0105 (3)
O1	0.033 (3)	0.031 (3)	0.034 (4)	0.013 (3)	0.010 (3)	−0.003 (3)
O2	0.028 (3)	0.055 (4)	0.029 (3)	0.020 (3)	0.008 (3)	0.016 (3)
N1	0.033 (4)	0.030 (4)	0.021 (3)	0.011 (3)	0.008 (3)	0.009 (3)
N2	0.051 (5)	0.027 (4)	0.033 (4)	0.013 (4)	0.017 (4)	0.008 (3)
N3	0.045 (5)	0.030 (4)	0.030 (4)	0.010 (4)	0.012 (4)	0.008 (3)
N4	0.048 (5)	0.034 (4)	0.030 (4)	0.020 (4)	0.017 (4)	0.014 (3)
C1	0.026 (4)	0.028 (4)	0.025 (4)	0.010 (3)	0.005 (3)	0.009 (3)
C2	0.023 (4)	0.032 (4)	0.022 (4)	0.010 (3)	0.003 (3)	0.007 (3)
C3	0.041 (5)	0.033 (5)	0.032 (5)	0.014 (4)	0.013 (4)	0.015 (4)

Ag1—O1	2.330 (7)	N1—C2	1.453 (11)
Ag1—O2i	2.282 (7)	N2—N3	1.297 (12)
Ag1—N3ii	2.494 (9)	N3—N4	1.350 (12)
Ag1—N4iii	2.442 (8)	N4—C3	1.331 (13)
O1—C1	1.270 (11)	C1—C2	1.540 (12)
O2—C1	1.238 (11)	C2—H2A	0.9700
N1—C3	1.324 (12)	C2—H2B	0.9700
N1—N2	1.331 (12)	C3—H3	0.9300
O2i—Ag1—O1	129.2 (3)	C3—N4—N3	105.1 (8)
O2i—Ag1—N4iii	118.7 (3)	C3—N4—Ag1iii	117.8 (6)
O1—Ag1—N4iii	95.0 (3)	N3—N4—Ag1iii	137.0 (6)
O2i—Ag1—N3ii	102.2 (3)	O2—C1—O1	127.3 (9)
O1—Ag1—N3ii	118.0 (3)	O2—C1—C2	117.2 (8)
N4iii—Ag1—N3ii	86.0 (3)	O1—C1—C2	115.5 (8)
C1—O1—Ag1	120.6 (6)	N1—C2—C1	111.1 (7)
C1—O2—Ag1i	121.2 (6)	N1—C2—H2A	109
C3—N1—N2	109.2 (8)	C1—C2—H2A	109
C3—N1—C2	128.9 (8)	N1—C2—H2B	109
N2—N1—C2	121.4 (8)	C1—C2—H2B	109
N3—N2—N1	106.3 (8)	H2A—C2—H2B	108
N2—N3—N4	111.0 (8)	N1—C3—N4	108.4 (9)
N2—N3—Ag1iv	112.1 (6)	N1—C3—H3	126
N4—N3—Ag1iv	136.9 (6)	N4—C3—H3	126

Table 1

Selected bond lengths (Å)

Ag1—O1	2.330 (7)
Ag1—O2i	2.282 (7)
Ag1—N3ii	2.494 (9)
Ag1—N4iii	2.442 (8)

Symmetry codes: (i) ; (ii) ; (iii) .