(Sulfasalazinato-κO)bis-(triphenyl-phosphine-κP)copper(I).

The title mixed-ligand copper(I) complex, [Cu(C(18)H(13)N(4)O(5)S)(C(18)H(15)P)(2)], was synthesized via solvothermal reaction of [Cu(PPh(3))(2)(MeCN)(2)]ClO(4) and sulfasalazine [systematic name: 2-hydr-oxy-5-(2-{4-[(2-pyridylamino)sulfon-yl]phen-yl}diazen-yl)benzoic acid]. The mononuclear complex displays a trigonal coordination geometry for the Cu(I) atom, which is surrounded by two P-atom donors from two different PPh(3) ligands and one O-atom donor from the monodentate carboxyl-ate group of the sulfasalazinate ligand. The latter ligand is found in a zwitterionic form, with a deprotonated amine N atom and a protonated pyridine N atom. Such a feature was previously described for free sulfasalazine. The crystal structure is stabilized by C-H⋯O, C-H⋯N, N-H⋯N and O-H⋯O hydrogen bonds.

Related literature

For applications of n>an class="Chemical">sulfasalazine, see: Neva et al. (2000 ▶); Mansfield et al. (2002 ▶). For crystal structures of metal complexes with sulfasalazine, see: Chen et al. (2003 ▶, 2008 ▶); Kang et al. (2006 ▶, 2008a ▶,b ▶); Wang et al. (2005 ▶); Yuan et al. (2006 ▶). For the crystal structure of free sulfasalazine, see: van der Sluis & Spek (1990 ▶). For the structure of a zwitterion related to sulfasalazine, see: Eliopoulos et al. (1983 ▶). For spectroscopic evidences supporting the presence of a proton­ated pyridine, see: Franklin & Richardson (1980 ▶).

Experimental

Crystal data

[Cu(C18H13N4O5S)(C18H15P)2]

M = 985.46

Tripan class="Chemical">clinipan class="Chemical">c,

a = 14.0126 (5) Å

b = 14.2236 (12) Å

pan class="Chemical">c = 14.2302 (4) Å

α = 81.068 (11)°

β = 61.606 (7)°

γ = 75.011 (10)°

V = 2408.4 (2) Å3

Z = 2

Mo Kα radiation

μ = 0.62 mm−1

T = 193 K

0.40 × 0.30 × 0.10 mm

Data collection

Rigaku pan class="Chemical">Mercury pan class="Chemical">CCD diffractometer

Absorption pan class="Chemical">correction: multi-scan (CrystalClear; Rigaku, 2000 ▶) T min = 0.791, T max = 0.941

24096 measured reflepan class="Chemical">ctions

8763 independent reflepan class="Chemical">ctions

6866 reflepan class="Chemical">ctions with I > 2σ(I)

R int = 0.044

Refinement

R[F 2 > 2σ(F 2)] = 0.054

wR(F 2) = 0.109

S = 1.10

8763 reflepan class="Chemical">ctions

610 parameters

pan class="Disease">H atoms treated by a mixture of independent and pan class="Chemical">constrained refinement

Δρmax = 0.31 e Å−3

Δρmin = −0.33 e Å−3

Data collen>an class="Chemical">ction: CrystalClear (Rigaku, 2000 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

pan class="Chemical">Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810013899/bh2279sup1.cif

Strupan class="Chemical">cture factors: contains datablocks I. DOI: 10.1107/S1600536810013899/bh2279Isup2.hkl

Additional supplementary materials: pan class="Chemical">crystallograpn>hipan class="Chemical">c information; 3D view; checkCIF report

[Cu(C18H13N4O5S)(C18H15P)2]	Z = 2
Mr = 985.46	F(000) = 1020
Triclinic, P1	Dx = 1.359 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71070 Å
a = 14.0126 (5) Å	Cell parameters from 8593 reflections
b = 14.2236 (12) Å	θ = 3.0–25.3°
c = 14.2302 (4) Å	µ = 0.62 mm−1
α = 81.068 (11)°	T = 193 K
β = 61.606 (7)°	Block, orange-red
γ = 75.011 (10)°	0.40 × 0.30 × 0.10 mm
V = 2408.4 (2) Å3

Rigaku Mercury CCD diffractometer	8763 independent reflections
Radiation source: fine-focus sealed tube	6866 reflections with I > 2σ(I)
graphite	Rint = 0.044
Detector resolution: 7.31 pixels mm-1	θmax = 25.4°, θmin = 3.0°
ω scans	h = −15→16
Absorption correction: multi-scan (CrystalClear; Rigaku, 2000)	k = −16→17
Tmin = 0.791, Tmax = 0.941	l = −17→17
24096 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.054	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.109	H atoms treated by a mixture of independent and constrained refinement
S = 1.10	w = 1/[σ2(Fo2) + (0.0333P)2 + 1.5872P] where P = (Fo2 + 2Fc2)/3
8763 reflections	(Δ/σ)max < 0.001
610 parameters	Δρmax = 0.31 e Å−3
0 restraints	Δρmin = −0.33 e Å−3
0 constraints

	x	y	z	Uiso*/Ueq
Cu1	0.45981 (3)	0.41881 (3)	0.23424 (3)	0.03507 (12)
S1	0.98672 (7)	1.04661 (6)	0.28783 (6)	0.0347 (2)
P1	0.59805 (6)	0.29238 (6)	0.21974 (6)	0.0316 (2)
P2	0.28157 (6)	0.44685 (6)	0.35221 (6)	0.02895 (19)
O1	0.50582 (17)	0.52994 (15)	0.12432 (17)	0.0374 (5)
O2	0.52453 (19)	0.56619 (17)	0.25992 (18)	0.0449 (6)
O3	0.58620 (19)	0.61550 (17)	−0.05550 (17)	0.0419 (6)
H3	0.5513	0.5767	−0.0085	0.063*
O4	0.89660 (19)	1.12476 (16)	0.34663 (18)	0.0444 (6)
O5	1.07566 (18)	1.07320 (17)	0.18968 (17)	0.0425 (6)
N1	0.7910 (2)	0.80601 (18)	0.0838 (2)	0.0321 (6)
N2	0.7683 (2)	0.80115 (19)	0.1806 (2)	0.0346 (6)
N3	1.0242 (2)	0.98829 (19)	0.3734 (2)	0.0344 (6)
N4	1.1440 (2)	0.8879 (2)	0.4284 (2)	0.0379 (7)
C1	0.5420 (2)	0.5779 (2)	0.1661 (3)	0.0332 (7)
C2	0.6124 (2)	0.6470 (2)	0.0913 (2)	0.0284 (7)
C3	0.6324 (2)	0.6610 (2)	−0.0162 (2)	0.0323 (7)
C4	0.7023 (2)	0.7211 (2)	−0.0851 (2)	0.0350 (8)
H4	0.7152	0.7306	−0.1574	0.042*
C5	0.7531 (2)	0.7671 (2)	−0.0491 (2)	0.0341 (7)
H5	0.8014	0.8080	−0.0970	0.041*
C6	0.7343 (2)	0.7543 (2)	0.0566 (2)	0.0297 (7)
C7	0.6634 (2)	0.6941 (2)	0.1270 (2)	0.0306 (7)
H7	0.6501	0.6855	0.1994	0.037*
C8	0.8276 (2)	0.8567 (2)	0.2012 (2)	0.0305 (7)
C9	0.9189 (3)	0.8911 (2)	0.1218 (2)	0.0378 (8)
H9	0.9476	0.8753	0.0495	0.045*
C10	0.9677 (3)	0.9485 (2)	0.1486 (2)	0.0369 (8)
H10	1.0292	0.9733	0.0943	0.044*
C11	0.9274 (2)	0.9699 (2)	0.2542 (2)	0.0296 (7)
C12	0.8391 (3)	0.9323 (2)	0.3337 (3)	0.0385 (8)
H12	0.8125	0.9457	0.4063	0.046*
C13	0.7897 (3)	0.8750 (2)	0.3071 (3)	0.0396 (8)
H13	0.7299	0.8484	0.3617	0.047*
C14	1.1221 (3)	0.9230 (2)	0.3448 (3)	0.0357 (8)
C15	1.2032 (3)	0.8868 (3)	0.2444 (3)	0.0481 (9)
H15	1.1942	0.9106	0.1823	0.058*
C16	1.2944 (3)	0.8177 (3)	0.2358 (3)	0.0588 (11)
H16	1.3479	0.7935	0.1675	0.071*
C17	1.3108 (3)	0.7820 (3)	0.3245 (3)	0.0590 (11)
H17	1.3741	0.7331	0.3179	0.071*
C18	1.2341 (3)	0.8186 (3)	0.4208 (3)	0.0516 (10)
H18	1.2434	0.7958	0.4829	0.062*
C19	0.7369 (2)	0.3189 (2)	0.1587 (2)	0.0342 (7)
C20	0.8185 (3)	0.2702 (3)	0.1884 (3)	0.0436 (8)
H20	0.8027	0.2221	0.2449	0.052*
C21	0.9230 (3)	0.2918 (3)	0.1358 (3)	0.0513 (10)
H21	0.9791	0.2576	0.1554	0.062*
C22	0.9461 (3)	0.3628 (3)	0.0550 (3)	0.0499 (9)
H22	1.0180	0.3772	0.0189	0.060*
C23	0.8649 (3)	0.4125 (3)	0.0266 (3)	0.0484 (9)
H23	0.8806	0.4618	−0.0287	0.058*
C24	0.7604 (3)	0.3910 (2)	0.0784 (3)	0.0391 (8)
H24	0.7045	0.4260	0.0588	0.047*
C25	0.6144 (2)	0.1902 (2)	0.1472 (2)	0.0333 (7)
C26	0.5200 (3)	0.1771 (3)	0.1471 (3)	0.0573 (11)
H26	0.4521	0.2230	0.1802	0.069*
C27	0.5235 (4)	0.0976 (3)	0.0991 (4)	0.0774 (15)
H27	0.4578	0.0885	0.1008	0.093*
C28	0.6225 (3)	0.0317 (3)	0.0489 (3)	0.0606 (11)
H28	0.6252	−0.0230	0.0163	0.073*
C29	0.7160 (3)	0.0456 (3)	0.0462 (3)	0.0461 (9)
H29	0.7844	0.0009	0.0103	0.055*
C30	0.7131 (3)	0.1236 (2)	0.0949 (3)	0.0415 (8)
H30	0.7793	0.1318	0.0925	0.050*
C31	0.5741 (2)	0.2396 (2)	0.3525 (2)	0.0354 (8)
C32	0.5958 (3)	0.1413 (3)	0.3768 (3)	0.0493 (9)
H32	0.6305	0.0960	0.3214	0.059*
C33	0.5671 (3)	0.1079 (3)	0.4819 (3)	0.0630 (11)
H33	0.5821	0.0400	0.4981	0.076*
C34	0.5173 (3)	0.1727 (4)	0.5624 (3)	0.0656 (12)
H34	0.4972	0.1495	0.6342	0.079*
C35	0.4962 (3)	0.2710 (4)	0.5395 (3)	0.0643 (12)
H35	0.4634	0.3160	0.5949	0.077*
C36	0.5230 (3)	0.3039 (3)	0.4354 (3)	0.0487 (9)
H36	0.5064	0.3718	0.4200	0.058*
C37	0.2514 (2)	0.4620 (2)	0.4891 (2)	0.0325 (7)
C38	0.3070 (3)	0.5206 (3)	0.5054 (3)	0.0524 (10)
H38	0.3588	0.5518	0.4461	0.063*
C39	0.2872 (4)	0.5338 (3)	0.6076 (3)	0.0711 (13)
H39	0.3248	0.5748	0.6181	0.085*
C40	0.2139 (4)	0.4884 (3)	0.6943 (3)	0.0626 (11)
H40	0.2015	0.4972	0.7644	0.075*
C41	0.1589 (3)	0.4301 (3)	0.6788 (3)	0.0601 (11)
H41	0.1080	0.3985	0.7383	0.072*
C42	0.1772 (3)	0.4175 (3)	0.5771 (3)	0.0481 (9)
H42	0.1381	0.3774	0.5674	0.058*
C43	0.2143 (2)	0.3488 (2)	0.3632 (2)	0.0335 (7)
C44	0.2645 (3)	0.2546 (2)	0.3810 (3)	0.0430 (8)
H44	0.3280	0.2443	0.3924	0.052*
C45	0.2232 (4)	0.1755 (3)	0.3823 (3)	0.0581 (11)
H45	0.2579	0.1114	0.3948	0.070*
C46	0.1319 (4)	0.1906 (4)	0.3653 (3)	0.0652 (13)
H46	0.1038	0.1365	0.3655	0.078*
C47	0.0804 (3)	0.2830 (4)	0.3478 (3)	0.0592 (12)
H47	0.0167	0.2926	0.3367	0.071*
C48	0.1219 (3)	0.3628 (3)	0.3463 (3)	0.0449 (9)
H48	0.0868	0.4268	0.3338	0.054*
C49	0.1983 (2)	0.5553 (2)	0.3211 (2)	0.0330 (7)
C50	0.2246 (3)	0.5793 (3)	0.2144 (3)	0.0470 (9)
H50	0.2866	0.5408	0.1599	0.056*
C51	0.1603 (3)	0.6595 (3)	0.1876 (3)	0.0589 (11)
H51	0.1781	0.6753	0.1146	0.071*
C52	0.0713 (3)	0.7161 (3)	0.2654 (3)	0.0510 (9)
H52	0.0266	0.7700	0.2464	0.061*
C53	0.0469 (3)	0.6953 (3)	0.3702 (3)	0.0462 (9)
H53	−0.0134	0.7361	0.4237	0.055*
C54	0.1094 (3)	0.6151 (2)	0.3990 (3)	0.0397 (8)
H54	0.0916	0.6010	0.4722	0.048*
H1	1.094 (3)	0.918 (3)	0.491 (3)	0.056 (11)*

	U11	U22	U33	U12	U13	U23
Cu1	0.0288 (2)	0.0294 (2)	0.0395 (2)	−0.00721 (16)	−0.01025 (17)	0.00251 (17)
S1	0.0439 (5)	0.0330 (5)	0.0374 (4)	−0.0145 (4)	−0.0237 (4)	−0.0004 (4)
P1	0.0293 (4)	0.0304 (5)	0.0331 (4)	−0.0045 (3)	−0.0130 (3)	−0.0025 (4)
P2	0.0279 (4)	0.0282 (4)	0.0317 (4)	−0.0079 (3)	−0.0129 (3)	−0.0027 (3)
O1	0.0399 (13)	0.0356 (13)	0.0462 (13)	−0.0202 (10)	−0.0229 (11)	0.0044 (10)
O2	0.0499 (14)	0.0508 (15)	0.0358 (13)	−0.0267 (12)	−0.0155 (11)	0.0071 (11)
O3	0.0508 (14)	0.0491 (15)	0.0378 (13)	−0.0297 (11)	−0.0201 (11)	−0.0023 (11)
O4	0.0574 (15)	0.0357 (13)	0.0475 (14)	−0.0035 (11)	−0.0314 (12)	−0.0068 (11)
O5	0.0503 (14)	0.0466 (14)	0.0415 (13)	−0.0276 (11)	−0.0231 (11)	0.0060 (11)
N1	0.0330 (14)	0.0349 (15)	0.0330 (15)	−0.0133 (11)	−0.0163 (12)	0.0007 (12)
N2	0.0392 (15)	0.0382 (16)	0.0343 (15)	−0.0168 (12)	−0.0196 (12)	0.0009 (12)
N3	0.0380 (15)	0.0386 (16)	0.0373 (15)	−0.0115 (12)	−0.0236 (12)	−0.0023 (12)
N4	0.0391 (16)	0.0434 (18)	0.0375 (16)	−0.0070 (13)	−0.0223 (14)	−0.0051 (14)
C1	0.0295 (17)	0.0315 (18)	0.0385 (19)	−0.0083 (13)	−0.0144 (14)	−0.0015 (15)
C2	0.0245 (15)	0.0286 (17)	0.0318 (16)	−0.0101 (12)	−0.0103 (13)	−0.0014 (13)
C3	0.0292 (16)	0.0333 (18)	0.0362 (17)	−0.0114 (13)	−0.0125 (14)	−0.0071 (14)
C4	0.0361 (18)	0.047 (2)	0.0249 (16)	−0.0219 (15)	−0.0100 (14)	−0.0003 (14)
C5	0.0332 (17)	0.042 (2)	0.0287 (17)	−0.0184 (14)	−0.0114 (14)	0.0030 (14)
C6	0.0311 (16)	0.0277 (17)	0.0365 (17)	−0.0111 (13)	−0.0173 (14)	−0.0032 (14)
C7	0.0321 (17)	0.0306 (17)	0.0297 (16)	−0.0104 (13)	−0.0123 (13)	−0.0020 (13)
C8	0.0328 (17)	0.0316 (18)	0.0356 (18)	−0.0123 (13)	−0.0208 (14)	0.0021 (14)
C9	0.0432 (19)	0.050 (2)	0.0280 (17)	−0.0198 (16)	−0.0181 (15)	0.0000 (15)
C10	0.0378 (18)	0.049 (2)	0.0329 (18)	−0.0209 (15)	−0.0192 (15)	0.0046 (15)
C11	0.0326 (17)	0.0302 (17)	0.0337 (17)	−0.0098 (13)	−0.0203 (14)	0.0006 (14)
C12	0.0395 (19)	0.048 (2)	0.0298 (17)	−0.0129 (16)	−0.0140 (15)	−0.0076 (15)
C13	0.0406 (19)	0.049 (2)	0.0352 (18)	−0.0226 (16)	−0.0170 (15)	0.0018 (16)
C14	0.0416 (19)	0.039 (2)	0.0388 (19)	−0.0188 (15)	−0.0224 (16)	−0.0017 (15)
C15	0.050 (2)	0.060 (3)	0.038 (2)	−0.0110 (19)	−0.0214 (17)	−0.0101 (18)
C16	0.047 (2)	0.073 (3)	0.050 (2)	0.001 (2)	−0.0186 (19)	−0.023 (2)
C17	0.050 (2)	0.065 (3)	0.066 (3)	0.0062 (19)	−0.033 (2)	−0.023 (2)
C18	0.051 (2)	0.056 (2)	0.054 (2)	−0.0009 (19)	−0.0325 (19)	−0.0096 (19)
C19	0.0291 (17)	0.0357 (19)	0.0352 (17)	−0.0036 (14)	−0.0123 (14)	−0.0079 (15)
C20	0.0372 (19)	0.040 (2)	0.055 (2)	−0.0057 (15)	−0.0233 (17)	0.0008 (17)
C21	0.034 (2)	0.055 (2)	0.068 (3)	−0.0056 (17)	−0.0276 (18)	−0.005 (2)
C22	0.0301 (19)	0.057 (3)	0.058 (2)	−0.0124 (17)	−0.0122 (17)	−0.010 (2)
C23	0.043 (2)	0.049 (2)	0.044 (2)	−0.0169 (17)	−0.0096 (17)	−0.0014 (17)
C24	0.0353 (19)	0.042 (2)	0.0374 (18)	−0.0070 (15)	−0.0150 (15)	−0.0028 (16)
C25	0.0344 (18)	0.0316 (18)	0.0309 (17)	−0.0025 (14)	−0.0143 (14)	−0.0027 (14)
C26	0.040 (2)	0.061 (3)	0.078 (3)	0.0046 (18)	−0.031 (2)	−0.031 (2)
C27	0.058 (3)	0.079 (3)	0.118 (4)	0.001 (2)	−0.053 (3)	−0.051 (3)
C28	0.066 (3)	0.049 (2)	0.074 (3)	0.003 (2)	−0.038 (2)	−0.026 (2)
C29	0.043 (2)	0.040 (2)	0.049 (2)	−0.0020 (16)	−0.0175 (17)	−0.0120 (17)
C30	0.0349 (18)	0.037 (2)	0.048 (2)	−0.0036 (15)	−0.0163 (16)	−0.0066 (16)
C31	0.0283 (17)	0.042 (2)	0.0374 (18)	−0.0084 (14)	−0.0158 (14)	−0.0012 (15)
C32	0.057 (2)	0.051 (2)	0.041 (2)	−0.0156 (18)	−0.0222 (18)	0.0023 (18)
C33	0.071 (3)	0.067 (3)	0.055 (3)	−0.029 (2)	−0.031 (2)	0.019 (2)
C34	0.052 (2)	0.107 (4)	0.039 (2)	−0.028 (2)	−0.0208 (19)	0.012 (3)
C35	0.055 (2)	0.099 (4)	0.039 (2)	−0.004 (2)	−0.0241 (19)	−0.015 (2)
C36	0.046 (2)	0.058 (2)	0.043 (2)	−0.0033 (18)	−0.0228 (17)	−0.0108 (18)
C37	0.0315 (17)	0.0336 (18)	0.0336 (17)	−0.0065 (14)	−0.0145 (14)	−0.0062 (14)
C38	0.056 (2)	0.060 (3)	0.046 (2)	−0.0306 (19)	−0.0154 (18)	−0.0124 (19)
C39	0.081 (3)	0.090 (3)	0.061 (3)	−0.036 (3)	−0.031 (2)	−0.027 (3)
C40	0.083 (3)	0.070 (3)	0.041 (2)	−0.012 (2)	−0.032 (2)	−0.015 (2)
C41	0.081 (3)	0.064 (3)	0.031 (2)	−0.027 (2)	−0.0165 (19)	−0.0024 (19)
C42	0.058 (2)	0.052 (2)	0.040 (2)	−0.0225 (18)	−0.0208 (18)	−0.0043 (17)
C43	0.0325 (17)	0.041 (2)	0.0241 (16)	−0.0152 (14)	−0.0051 (13)	−0.0076 (14)
C44	0.052 (2)	0.038 (2)	0.0399 (19)	−0.0180 (17)	−0.0166 (16)	−0.0037 (16)
C45	0.077 (3)	0.047 (2)	0.042 (2)	−0.033 (2)	−0.010 (2)	−0.0018 (18)
C46	0.078 (3)	0.074 (3)	0.043 (2)	−0.054 (3)	−0.005 (2)	−0.014 (2)
C47	0.047 (2)	0.094 (4)	0.043 (2)	−0.040 (2)	−0.0090 (18)	−0.018 (2)
C48	0.0364 (19)	0.061 (2)	0.0383 (19)	−0.0210 (17)	−0.0097 (15)	−0.0118 (17)
C49	0.0312 (17)	0.0326 (18)	0.0395 (18)	−0.0074 (13)	−0.0187 (14)	−0.0033 (15)
C50	0.057 (2)	0.046 (2)	0.0367 (19)	0.0030 (17)	−0.0245 (17)	−0.0105 (17)
C51	0.079 (3)	0.053 (3)	0.045 (2)	0.011 (2)	−0.039 (2)	−0.0075 (19)
C52	0.054 (2)	0.039 (2)	0.067 (3)	−0.0006 (17)	−0.037 (2)	−0.0041 (19)
C53	0.0342 (19)	0.040 (2)	0.055 (2)	0.0007 (15)	−0.0155 (17)	−0.0071 (18)
C54	0.0338 (18)	0.040 (2)	0.0388 (19)	−0.0051 (15)	−0.0129 (15)	−0.0001 (16)

Cu1—O1	2.040 (2)	C22—H22	0.9500
Cu1—P2	2.2181 (9)	C23—C24	1.384 (5)
Cu1—P1	2.2276 (9)	C23—H23	0.9500
Cu1—O2	2.624 (2)	C24—H24	0.9500
S1—O5	1.439 (2)	C25—C26	1.383 (5)
S1—O4	1.445 (2)	C25—C30	1.388 (4)
S1—N3	1.587 (3)	C26—C27	1.389 (5)
S1—C11	1.766 (3)	C26—H26	0.9500
P1—C25	1.816 (3)	C27—C28	1.380 (5)
P1—C31	1.825 (3)	C27—H27	0.9500
P1—C19	1.831 (3)	C28—C29	1.357 (5)
P2—C49	1.812 (3)	C28—H28	0.9500
P2—C37	1.822 (3)	C29—C30	1.379 (5)
P2—C43	1.825 (3)	C29—H29	0.9500
O1—C1	1.292 (4)	C30—H30	0.9500
O2—C1	1.229 (4)	C31—C32	1.378 (5)
O3—C3	1.351 (3)	C31—C36	1.390 (5)
O3—H3	0.8400	C32—C33	1.390 (5)
N1—N2	1.253 (3)	C32—H32	0.9500
N1—C6	1.414 (4)	C33—C34	1.372 (6)
N2—C8	1.430 (4)	C33—H33	0.9500
N3—C14	1.355 (4)	C34—C35	1.373 (6)
N4—C18	1.354 (4)	C34—H34	0.9500
N4—C14	1.359 (4)	C35—C36	1.378 (5)
N4—H1	0.91 (4)	C35—H35	0.9500
C1—C2	1.500 (4)	C36—H36	0.9500
C2—C7	1.384 (4)	C37—C42	1.380 (4)
C2—C3	1.409 (4)	C37—C38	1.389 (4)
C3—C4	1.383 (4)	C38—C39	1.378 (5)
C4—C5	1.374 (4)	C38—H38	0.9500
C4—H4	0.9500	C39—C40	1.373 (6)
C5—C6	1.390 (4)	C39—H39	0.9500
C5—H5	0.9500	C40—C41	1.371 (5)
C6—C7	1.396 (4)	C40—H40	0.9500
C7—H7	0.9500	C41—C42	1.377 (5)
C8—C13	1.383 (4)	C41—H41	0.9500
C8—C9	1.389 (4)	C42—H42	0.9500
C9—C10	1.384 (4)	C43—C48	1.386 (4)
C9—H9	0.9500	C43—C44	1.388 (5)
C10—C11	1.384 (4)	C44—C45	1.387 (5)
C10—H10	0.9500	C44—H44	0.9500
C11—C12	1.386 (4)	C45—C46	1.370 (6)
C12—C13	1.386 (4)	C45—H45	0.9500
C12—H12	0.9500	C46—C47	1.375 (6)
C13—H13	0.9500	C46—H46	0.9500
C14—C15	1.407 (4)	C47—C48	1.396 (5)
C15—C16	1.361 (5)	C47—H47	0.9500
C15—H15	0.9500	C48—H48	0.9500
C16—C17	1.386 (5)	C49—C50	1.389 (4)
C16—H16	0.9500	C49—C54	1.391 (4)
C17—C18	1.356 (5)	C50—C51	1.385 (5)
C17—H17	0.9500	C50—H50	0.9500
C18—H18	0.9500	C51—C52	1.369 (5)
C19—C24	1.385 (4)	C51—H51	0.9500
C19—C20	1.388 (4)	C52—C53	1.362 (5)
C20—C21	1.385 (5)	C52—H52	0.9500
C20—H20	0.9500	C53—C54	1.384 (5)
C21—C22	1.378 (5)	C53—H53	0.9500
C21—H21	0.9500	C54—H54	0.9500
C22—C23	1.374 (5)
O1—Cu1—P2	114.45 (7)	C21—C22—H22	120.1
O1—Cu1—P1	114.67 (7)	C22—C23—C24	120.2 (3)
P2—Cu1—P1	130.83 (4)	C22—C23—H23	119.9
O1—Cu1—O2	55.07 (8)	C24—C23—H23	119.9
P2—Cu1—O2	102.07 (6)	C23—C24—C19	120.4 (3)
P1—Cu1—O2	103.67 (6)	C23—C24—H24	119.8
O5—S1—O4	117.01 (14)	C19—C24—H24	119.8
O5—S1—N3	114.63 (14)	C26—C25—C30	118.1 (3)
O4—S1—N3	104.26 (14)	C26—C25—P1	116.8 (2)
O5—S1—C11	106.82 (14)	C30—C25—P1	125.0 (2)
O4—S1—C11	106.23 (14)	C25—C26—C27	120.8 (3)
N3—S1—C11	107.27 (14)	C25—C26—H26	119.6
C25—P1—C31	103.77 (15)	C27—C26—H26	119.6
C25—P1—C19	104.45 (14)	C28—C27—C26	119.9 (4)
C31—P1—C19	105.45 (14)	C28—C27—H27	120.1
C25—P1—Cu1	116.38 (10)	C26—C27—H27	120.1
C31—P1—Cu1	109.53 (10)	C29—C28—C27	119.7 (4)
C19—P1—Cu1	116.06 (11)	C29—C28—H28	120.2
C49—P2—C37	104.22 (14)	C27—C28—H28	120.2
C49—P2—C43	104.55 (15)	C28—C29—C30	120.9 (3)
C37—P2—C43	104.23 (14)	C28—C29—H29	119.6
C49—P2—Cu1	114.07 (10)	C30—C29—H29	119.6
C37—P2—Cu1	115.74 (10)	C29—C30—C25	120.7 (3)
C43—P2—Cu1	112.85 (10)	C29—C30—H30	119.6
C1—O1—Cu1	102.76 (19)	C25—C30—H30	119.6
C1—O2—Cu1	77.43 (18)	C32—C31—C36	118.4 (3)
C3—O3—H3	109.5	C32—C31—P1	124.7 (3)
N2—N1—C6	115.7 (2)	C36—C31—P1	116.7 (3)
N1—N2—C8	112.0 (2)	C31—C32—C33	120.3 (4)
C14—N3—S1	122.1 (2)	C31—C32—H32	119.8
C18—N4—C14	124.2 (3)	C33—C32—H32	119.8
C18—N4—H1	123 (2)	C34—C33—C32	120.2 (4)
C14—N4—H1	113 (2)	C34—C33—H33	119.9
O2—C1—O1	123.2 (3)	C32—C33—H33	119.9
O2—C1—C2	121.0 (3)	C33—C34—C35	120.2 (4)
O1—C1—C2	115.7 (3)	C33—C34—H34	119.9
C7—C2—C3	119.2 (3)	C35—C34—H34	119.9
C7—C2—C1	119.4 (3)	C34—C35—C36	119.4 (4)
C3—C2—C1	121.3 (3)	C34—C35—H35	120.3
O3—C3—C4	118.1 (3)	C36—C35—H35	120.3
O3—C3—C2	121.6 (3)	C35—C36—C31	121.3 (4)
C4—C3—C2	120.3 (3)	C35—C36—H36	119.3
C5—C4—C3	120.1 (3)	C31—C36—H36	119.3
C5—C4—H4	120.0	C42—C37—C38	118.3 (3)
C3—C4—H4	120.0	C42—C37—P2	123.6 (2)
C4—C5—C6	120.5 (3)	C38—C37—P2	118.1 (3)
C4—C5—H5	119.7	C39—C38—C37	120.1 (4)
C6—C5—H5	119.7	C39—C38—H38	120.0
C5—C6—C7	119.8 (3)	C37—C38—H38	120.0
C5—C6—N1	115.0 (3)	C40—C39—C38	121.0 (4)
C7—C6—N1	125.2 (3)	C40—C39—H39	119.5
C2—C7—C6	120.1 (3)	C38—C39—H39	119.5
C2—C7—H7	119.9	C41—C40—C39	119.3 (4)
C6—C7—H7	119.9	C41—C40—H40	120.3
C13—C8—C9	120.1 (3)	C39—C40—H40	120.3
C13—C8—N2	116.2 (3)	C40—C41—C42	120.2 (4)
C9—C8—N2	123.7 (3)	C40—C41—H41	119.9
C10—C9—C8	119.7 (3)	C42—C41—H41	119.9
C10—C9—H9	120.2	C41—C42—C37	121.2 (3)
C8—C9—H9	120.2	C41—C42—H42	119.4
C9—C10—C11	120.2 (3)	C37—C42—H42	119.4
C9—C10—H10	119.9	C48—C43—C44	119.0 (3)
C11—C10—H10	119.9	C48—C43—P2	123.3 (3)
C10—C11—C12	120.0 (3)	C44—C43—P2	117.5 (2)
C10—C11—S1	120.2 (2)	C45—C44—C43	120.9 (4)
C12—C11—S1	119.8 (2)	C45—C44—H44	119.5
C11—C12—C13	120.0 (3)	C43—C44—H44	119.5
C11—C12—H12	120.0	C46—C45—C44	119.4 (4)
C13—C12—H12	120.0	C46—C45—H45	120.3
C8—C13—C12	119.9 (3)	C44—C45—H45	120.3
C8—C13—H13	120.0	C45—C46—C47	121.0 (4)
C12—C13—H13	120.0	C45—C46—H46	119.5
N3—C14—N4	113.2 (3)	C47—C46—H46	119.5
N3—C14—C15	131.0 (3)	C46—C47—C48	119.8 (4)
N4—C14—C15	115.8 (3)	C46—C47—H47	120.1
C16—C15—C14	120.4 (3)	C48—C47—H47	120.1
C16—C15—H15	119.8	C43—C48—C47	120.0 (4)
C14—C15—H15	119.8	C43—C48—H48	120.0
C15—C16—C17	121.4 (3)	C47—C48—H48	120.0
C15—C16—H16	119.3	C50—C49—C54	118.7 (3)
C17—C16—H16	119.3	C50—C49—P2	118.2 (2)
C18—C17—C16	118.3 (4)	C54—C49—P2	123.1 (2)
C18—C17—H17	120.9	C51—C50—C49	120.0 (3)
C16—C17—H17	120.9	C51—C50—H50	120.0
N4—C18—C17	119.9 (4)	C49—C50—H50	120.0
N4—C18—H18	120.1	C52—C51—C50	120.5 (3)
C17—C18—H18	120.1	C52—C51—H51	119.7
C24—C19—C20	119.2 (3)	C50—C51—H51	119.7
C24—C19—P1	117.5 (2)	C53—C52—C51	120.1 (3)
C20—C19—P1	123.3 (3)	C53—C52—H52	120.0
C21—C20—C19	120.0 (3)	C51—C52—H52	120.0
C21—C20—H20	120.0	C52—C53—C54	120.4 (3)
C19—C20—H20	120.0	C52—C53—H53	119.8
C22—C21—C20	120.4 (3)	C54—C53—H53	119.8
C22—C21—H21	119.8	C53—C54—C49	120.3 (3)
C20—C21—H21	119.8	C53—C54—H54	119.9
C23—C22—C21	119.8 (3)	C49—C54—H54	119.9
C23—C22—H22	120.1
O1—Cu1—P1—C25	−97.32 (13)	C25—P1—C19—C20	−84.2 (3)
P2—Cu1—P1—C25	85.50 (12)	C31—P1—C19—C20	24.9 (3)
O2—Cu1—P1—C25	−154.86 (12)	Cu1—P1—C19—C20	146.3 (2)
O1—Cu1—P1—C31	145.44 (13)	C24—C19—C20—C21	−2.0 (5)
P2—Cu1—P1—C31	−31.74 (12)	P1—C19—C20—C21	177.5 (3)
O2—Cu1—P1—C31	87.90 (12)	C19—C20—C21—C22	1.1 (5)
O1—Cu1—P1—C19	26.23 (14)	C20—C21—C22—C23	0.2 (6)
P2—Cu1—P1—C19	−150.95 (11)	C21—C22—C23—C24	−0.5 (5)
O2—Cu1—P1—C19	−31.31 (13)	C22—C23—C24—C19	−0.4 (5)
O1—Cu1—P2—C49	9.54 (13)	C20—C19—C24—C23	1.6 (5)
P1—Cu1—P2—C49	−173.28 (11)	P1—C19—C24—C23	−177.9 (3)
O2—Cu1—P2—C49	66.45 (12)	C31—P1—C25—C26	93.1 (3)
O1—Cu1—P2—C37	−111.38 (13)	C19—P1—C25—C26	−156.7 (3)
P1—Cu1—P2—C37	65.80 (13)	Cu1—P1—C25—C26	−27.3 (3)
O2—Cu1—P2—C37	−54.47 (13)	C31—P1—C25—C30	−85.2 (3)
O1—Cu1—P2—C43	128.67 (13)	C19—P1—C25—C30	25.1 (3)
P1—Cu1—P2—C43	−54.15 (13)	Cu1—P1—C25—C30	154.4 (3)
O2—Cu1—P2—C43	−174.42 (13)	C30—C25—C26—C27	2.2 (6)
P2—Cu1—O1—C1	94.71 (18)	P1—C25—C26—C27	−176.1 (4)
P1—Cu1—O1—C1	−82.94 (18)	C25—C26—C27—C28	−1.4 (7)
O2—Cu1—O1—C1	6.85 (17)	C26—C27—C28—C29	−0.4 (7)
O1—Cu1—O2—C1	−7.20 (18)	C27—C28—C29—C30	1.3 (6)
P2—Cu1—O2—C1	−118.72 (18)	C28—C29—C30—C25	−0.4 (6)
P1—Cu1—O2—C1	103.55 (18)	C26—C25—C30—C29	−1.4 (5)
C6—N1—N2—C8	−179.0 (2)	P1—C25—C30—C29	176.9 (3)
O5—S1—N3—C14	−35.7 (3)	C25—P1—C31—C32	15.9 (3)
O4—S1—N3—C14	−164.9 (2)	C19—P1—C31—C32	−93.6 (3)
C11—S1—N3—C14	82.7 (3)	Cu1—P1—C31—C32	140.8 (3)
Cu1—O2—C1—O1	11.2 (3)	C25—P1—C31—C36	−159.4 (3)
Cu1—O2—C1—C2	−165.9 (3)	C19—P1—C31—C36	91.1 (3)
Cu1—O1—C1—O2	−14.5 (4)	Cu1—P1—C31—C36	−34.5 (3)
Cu1—O1—C1—C2	162.8 (2)	C36—C31—C32—C33	−0.1 (5)
O2—C1—C2—C7	3.6 (4)	P1—C31—C32—C33	−175.3 (3)
O1—C1—C2—C7	−173.7 (3)	C31—C32—C33—C34	−0.2 (6)
O2—C1—C2—C3	−179.8 (3)	C32—C33—C34—C35	−0.6 (6)
O1—C1—C2—C3	2.8 (4)	C33—C34—C35—C36	1.6 (6)
C7—C2—C3—O3	178.9 (3)	C34—C35—C36—C31	−1.9 (6)
C1—C2—C3—O3	2.3 (4)	C32—C31—C36—C35	1.1 (5)
C7—C2—C3—C4	0.0 (4)	P1—C31—C36—C35	176.7 (3)
C1—C2—C3—C4	−176.6 (3)	C49—P2—C37—C42	99.5 (3)
O3—C3—C4—C5	−178.6 (3)	C43—P2—C37—C42	−9.9 (3)
C2—C3—C4—C5	0.4 (5)	Cu1—P2—C37—C42	−134.4 (3)
C3—C4—C5—C6	−0.4 (5)	C49—P2—C37—C38	−81.2 (3)
C4—C5—C6—C7	0.0 (5)	C43—P2—C37—C38	169.4 (3)
C4—C5—C6—N1	−179.7 (3)	Cu1—P2—C37—C38	44.9 (3)
N2—N1—C6—C5	174.7 (3)	C42—C37—C38—C39	−0.3 (6)
N2—N1—C6—C7	−5.0 (4)	P2—C37—C38—C39	−179.7 (3)
C3—C2—C7—C6	−0.3 (4)	C37—C38—C39—C40	1.0 (7)
C1—C2—C7—C6	176.3 (3)	C38—C39—C40—C41	−0.8 (7)
C5—C6—C7—C2	0.3 (4)	C39—C40—C41—C42	0.0 (7)
N1—C6—C7—C2	180.0 (3)	C40—C41—C42—C37	0.6 (6)
N1—N2—C8—C13	165.2 (3)	C38—C37—C42—C41	−0.4 (5)
N1—N2—C8—C9	−15.2 (4)	P2—C37—C42—C41	178.9 (3)
C13—C8—C9—C10	−3.7 (5)	C49—P2—C43—C48	1.7 (3)
N2—C8—C9—C10	176.7 (3)	C37—P2—C43—C48	110.9 (3)
C8—C9—C10—C11	1.3 (5)	Cu1—P2—C43—C48	−122.8 (2)
C9—C10—C11—C12	1.2 (5)	C49—P2—C43—C44	176.5 (2)
C9—C10—C11—S1	−177.9 (3)	C37—P2—C43—C44	−74.4 (3)
O5—S1—C11—C10	−1.2 (3)	Cu1—P2—C43—C44	51.9 (3)
O4—S1—C11—C10	124.4 (3)	C48—C43—C44—C45	−0.2 (5)
N3—S1—C11—C10	−124.5 (3)	P2—C43—C44—C45	−175.1 (3)
O5—S1—C11—C12	179.7 (3)	C43—C44—C45—C46	0.3 (5)
O4—S1—C11—C12	−54.7 (3)	C44—C45—C46—C47	−0.5 (6)
N3—S1—C11—C12	56.4 (3)	C45—C46—C47—C48	0.6 (6)
C10—C11—C12—C13	−1.4 (5)	C44—C43—C48—C47	0.2 (5)
S1—C11—C12—C13	177.6 (3)	P2—C43—C48—C47	174.9 (2)
C9—C8—C13—C12	3.5 (5)	C46—C47—C48—C43	−0.4 (5)
N2—C8—C13—C12	−176.9 (3)	C37—P2—C49—C50	162.7 (3)
C11—C12—C13—C8	−0.9 (5)	C43—P2—C49—C50	−88.2 (3)
S1—N3—C14—N4	173.9 (2)	Cu1—P2—C49—C50	35.5 (3)
S1—N3—C14—C15	−5.7 (5)	C37—P2—C49—C54	−17.5 (3)
C18—N4—C14—N3	176.8 (3)	C43—P2—C49—C54	91.7 (3)
C18—N4—C14—C15	−3.4 (5)	Cu1—P2—C49—C54	−144.6 (2)
N3—C14—C15—C16	−177.6 (3)	C54—C49—C50—C51	−2.4 (5)
N4—C14—C15—C16	2.8 (5)	P2—C49—C50—C51	177.5 (3)
C14—C15—C16—C17	−0.7 (6)	C49—C50—C51—C52	0.7 (6)
C15—C16—C17—C18	−1.0 (6)	C50—C51—C52—C53	1.6 (6)
C14—N4—C18—C17	1.9 (5)	C51—C52—C53—C54	−2.1 (6)
C16—C17—C18—N4	0.4 (6)	C52—C53—C54—C49	0.3 (5)
C25—P1—C19—C24	95.4 (3)	C50—C49—C54—C53	1.9 (5)
C31—P1—C19—C24	−155.6 (2)	P2—C49—C54—C53	−178.0 (3)
Cu1—P1—C19—C24	−34.2 (3)

D—H···A	D—H	H···A	D···A	D—H···A
C46—H46···N3i	0.95	2.59	3.542 (5)	178
C18—H18···O4ii	0.95	2.49	3.042 (4)	117
C5—H5···O5iii	0.95	2.49	3.429 (4)	169
N4—H1···O4ii	0.91 (4)	2.36 (4)	2.957 (4)	123 (3)
N4—H1···N3ii	0.91 (4)	2.20 (4)	3.112 (4)	171 (3)
O3—H3···O1	0.84	1.76	2.510 (3)	147

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C46—H46⋯N3i	0.95	2.59	3.542 (5)	178
C5—H5⋯O5ii	0.95	2.49	3.429 (4)	169
N4—H1⋯N3iii	0.91 (4)	2.20 (4)	3.112 (4)	171 (3)
O3—H3⋯O1	0.84	1.76	2.510 (3)	147

Symmetry codes: (i) ; (ii) ; (iii) .