{1,3-Bis[(diphenyl-phosphanyl-κP)-oxy]prop-2-yl-κC}iodido(trimethyl-phosphane)cobalt(II).

The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo-butane to a solution of the parent cobalt complex {1,3-bis-[(diphenyl-phosphan-yl)-oxy]prop-2-yl}bis-(trimethyl-phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of inter-nal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh(2) groups and a metallated Csp(3) atom. The Co(II) atom is centered in a trigonal-bipyramidal configuration.

Related literature

For general background to transition metal complexes with PCP pincer ligands and their preparation, see: Boom & Milstein (2003 ▶); Pandarus et al. (2008 ▶); Xu et al. (2009 ▶); Zheng et al. (2009 ▶). For Co—Csp 3 bond lengths, see: Klein et al. (2003 ▶).

Experimental

Crystal data

[Co(C27H25O2P2)I(C3H9P)]

M = 705.31

Orthorhombic,

a = 15.161 (3) Å

b = 18.194 (4) Å

c = 21.410 (4) Å

V = 5906 (2) Å3

Z = 8

Mo Kα radiation

μ = 1.82 mm−1

T = 293 K

0.20 × 0.15 × 0.10 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 2004 ▶) T min = 0.713, T max = 0.876

35496 measured reflections

6237 independent reflections

5551 reflections with I > 2σ(I)

R int = 0.071

Refinement

R[F 2 > 2σ(F 2)] = 0.024

wR(F 2) = 0.061

S = 1.04

6237 reflections

357 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.57 e Å−3

Δρmin = −0.54 e Å−3

Data collection: SMART (Bruker, 1997 ▶); cell refinement: SAINT (Bruker, 1997 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810013747/zq2034sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810013747/zq2034Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Co(C27H25O2P2)I(C3H9P)]	F(000) = 2840
Mr = 705.31	Dx = 1.587 Mg m−3
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 13063 reflections
a = 15.161 (3) Å	θ = 2.0–26.9°
b = 18.194 (4) Å	µ = 1.82 mm−1
c = 21.410 (4) Å	T = 293 K
V = 5906 (2) Å3	Block, red
Z = 8	0.20 × 0.15 × 0.10 mm

Bruker SMART CCD area-detector diffractometer	6237 independent reflections
Radiation source: fine-focus sealed tube	5551 reflections with I > 2σ(I)
graphite	Rint = 0.071
phi and ω scans	θmax = 26.7°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)	h = −19→18
Tmin = 0.713, Tmax = 0.876	k = −23→23
35496 measured reflections	l = −27→20

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.024	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.061	H atoms treated by a mixture of independent and constrained refinement
S = 1.04	w = 1/[σ2(Fo2) + (0.0293P)2 + 1.1856P] where P = (Fo2 + 2Fc2)/3
6237 reflections	(Δ/σ)max = 0.004
357 parameters	Δρmax = 0.57 e Å−3
0 restraints	Δρmin = −0.54 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
I1	0.657194 (9)	0.086157 (8)	0.506996 (6)	0.02926 (5)
Co2	0.644969 (16)	0.062554 (12)	0.387635 (11)	0.01625 (6)
P1	0.75443 (3)	0.14172 (2)	0.37052 (2)	0.02092 (10)
P2	0.54174 (3)	0.10487 (2)	0.32815 (2)	0.01924 (10)
P3	0.70421 (3)	−0.03885 (2)	0.35418 (2)	0.01858 (10)
O1	0.48603 (9)	0.03615 (7)	0.30021 (7)	0.0249 (3)
O2	0.65551 (9)	−0.10523 (7)	0.39172 (7)	0.0247 (3)
C1	0.79921 (15)	0.15169 (11)	0.29188 (10)	0.0300 (4)
H1A	0.8427	0.1900	0.2916	0.045*
H1B	0.7525	0.1640	0.2635	0.045*
H1C	0.8260	0.1063	0.2792	0.045*
C2	0.85631 (13)	0.12727 (12)	0.41438 (11)	0.0302 (4)
H2A	0.8833	0.0821	0.4012	0.045*
H2B	0.8431	0.1247	0.4582	0.045*
H2C	0.8960	0.1674	0.4068	0.045*
C3	0.72818 (15)	0.23686 (10)	0.39039 (10)	0.0291 (4)
H3A	0.7813	0.2655	0.3906	0.044*
H3B	0.7014	0.2385	0.4310	0.044*
H3C	0.6880	0.2565	0.3600	0.044*
C4	0.55196 (12)	0.16068 (10)	0.25779 (9)	0.0235 (4)
C5	0.56173 (14)	0.12717 (12)	0.20005 (10)	0.0297 (4)
H5	0.5582	0.0763	0.1968	0.036*
C6	0.57680 (15)	0.16956 (14)	0.14697 (11)	0.0380 (5)
H6	0.5825	0.1469	0.1083	0.046*
C7	0.58336 (16)	0.24521 (14)	0.15141 (13)	0.0437 (6)
H7	0.5942	0.2733	0.1160	0.052*
C8	0.57375 (18)	0.27844 (13)	0.20852 (13)	0.0424 (6)
H8	0.5788	0.3292	0.2117	0.051*
C9	0.55662 (16)	0.23727 (11)	0.26161 (11)	0.0330 (5)
H9	0.5482	0.2606	0.2998	0.040*
C10	0.45903 (13)	0.15345 (10)	0.37462 (9)	0.0240 (4)
C11	0.48287 (15)	0.20811 (11)	0.41667 (11)	0.0327 (5)
H11	0.5416	0.2224	0.4196	0.039*
C12	0.42052 (18)	0.24143 (12)	0.45408 (12)	0.0417 (6)
H12	0.4372	0.2786	0.4815	0.050*
C13	0.33319 (18)	0.21962 (14)	0.45081 (13)	0.0458 (7)
H13	0.2910	0.2420	0.4760	0.055*
C14	0.30906 (17)	0.16476 (15)	0.41022 (14)	0.0449 (6)
H14	0.2505	0.1497	0.4084	0.054*
C15	0.37125 (15)	0.13148 (12)	0.37182 (11)	0.0332 (5)
H15	0.3542	0.0946	0.3443	0.040*
C16	0.49139 (13)	−0.02708 (10)	0.34158 (10)	0.0236 (4)
C17	0.54239 (12)	−0.01073 (9)	0.40104 (9)	0.0207 (4)
C18	0.57921 (13)	−0.08121 (10)	0.42799 (10)	0.0243 (4)
C19	0.81877 (13)	−0.05789 (9)	0.37445 (10)	0.0229 (4)
C20	0.88739 (14)	−0.05669 (10)	0.33109 (10)	0.0261 (4)
H20	0.8749	−0.0501	0.2889	0.031*
C21	0.97401 (14)	−0.06518 (12)	0.35030 (12)	0.0337 (5)
H21	1.0193	−0.0644	0.3211	0.040*
C22	0.99311 (16)	−0.07482 (13)	0.41270 (13)	0.0400 (5)
H22	1.0513	−0.0806	0.4254	0.048*
C23	0.92562 (17)	−0.07593 (14)	0.45670 (12)	0.0428 (6)
H23	0.9387	−0.0820	0.4988	0.051*
C24	0.83859 (15)	−0.06791 (12)	0.43761 (12)	0.0333 (5)
H24	0.7934	−0.0692	0.4670	0.040*
C25	0.69869 (13)	−0.07007 (10)	0.27348 (9)	0.0216 (4)
C26	0.71675 (14)	−0.02226 (10)	0.22455 (10)	0.0272 (4)
H26	0.7265	0.0273	0.2328	0.033*
C27	0.72045 (14)	−0.04749 (12)	0.16343 (10)	0.0313 (4)
H27	0.7343	−0.0153	0.1312	0.038*
C28	0.70351 (14)	−0.12086 (12)	0.15053 (10)	0.0299 (4)
H28	0.7070	−0.1382	0.1097	0.036*
C29	0.68137 (16)	−0.16818 (11)	0.19879 (11)	0.0336 (5)
H29	0.6677	−0.2169	0.1901	0.040*
C30	0.67953 (16)	−0.14335 (10)	0.25967 (11)	0.0302 (4)
H30	0.6654	−0.1757	0.2918	0.036*
H18	0.5970 (16)	−0.0751 (11)	0.4712 (12)	0.021 (5)*
H31	0.5038 (15)	0.0134 (12)	0.4328 (11)	0.023 (5)*
H16	0.5197 (16)	−0.0676 (12)	0.3174 (11)	0.025 (6)*
H17	0.4303 (17)	−0.0420 (13)	0.3517 (12)	0.029 (6)*
H19	0.5380 (17)	−0.1227 (13)	0.4249 (12)	0.032 (6)*

	U11	U22	U33	U12	U13	U23
I1	0.03046 (8)	0.03908 (9)	0.01822 (7)	−0.00978 (5)	0.00190 (5)	−0.00184 (5)
Co2	0.01717 (12)	0.01357 (11)	0.01801 (12)	−0.00099 (8)	0.00126 (9)	−0.00041 (8)
P1	0.0226 (2)	0.0175 (2)	0.0227 (2)	−0.00525 (17)	0.00225 (19)	−0.00124 (17)
P2	0.0203 (2)	0.01627 (19)	0.0211 (2)	0.00030 (16)	−0.00108 (18)	−0.00069 (16)
P3	0.0197 (2)	0.01471 (19)	0.0214 (2)	0.00055 (16)	0.00333 (18)	0.00018 (16)
O1	0.0270 (7)	0.0225 (6)	0.0252 (7)	−0.0043 (5)	−0.0052 (6)	−0.0015 (5)
O2	0.0255 (7)	0.0170 (6)	0.0317 (8)	0.0013 (5)	0.0089 (6)	0.0035 (5)
C1	0.0343 (12)	0.0263 (9)	0.0293 (11)	−0.0095 (8)	0.0085 (9)	−0.0016 (8)
C2	0.0243 (10)	0.0310 (10)	0.0353 (12)	−0.0068 (8)	0.0002 (9)	−0.0028 (9)
C3	0.0342 (11)	0.0187 (8)	0.0343 (11)	−0.0064 (8)	0.0039 (9)	−0.0033 (8)
C4	0.0192 (9)	0.0259 (9)	0.0254 (10)	0.0026 (7)	−0.0018 (8)	0.0041 (7)
C5	0.0265 (10)	0.0345 (10)	0.0281 (11)	−0.0025 (8)	−0.0002 (8)	−0.0009 (8)
C6	0.0299 (12)	0.0571 (14)	0.0270 (11)	−0.0026 (10)	0.0011 (9)	0.0020 (10)
C7	0.0361 (13)	0.0555 (14)	0.0394 (13)	0.0018 (11)	0.0003 (10)	0.0241 (11)
C8	0.0496 (15)	0.0306 (10)	0.0470 (15)	0.0057 (10)	0.0002 (12)	0.0160 (10)
C9	0.0395 (12)	0.0258 (9)	0.0336 (12)	0.0066 (8)	0.0006 (9)	0.0047 (8)
C10	0.0228 (9)	0.0240 (8)	0.0252 (10)	0.0056 (7)	0.0012 (8)	0.0043 (7)
C11	0.0331 (12)	0.0293 (10)	0.0357 (12)	0.0050 (8)	0.0050 (9)	−0.0045 (8)
C12	0.0542 (16)	0.0340 (11)	0.0369 (13)	0.0121 (10)	0.0130 (11)	−0.0027 (9)
C13	0.0475 (15)	0.0459 (13)	0.0439 (15)	0.0244 (11)	0.0223 (12)	0.0124 (11)
C14	0.0257 (12)	0.0579 (15)	0.0512 (16)	0.0097 (10)	0.0101 (11)	0.0150 (13)
C15	0.0258 (11)	0.0377 (11)	0.0362 (12)	0.0044 (9)	0.0003 (9)	0.0065 (9)
C16	0.0218 (9)	0.0185 (8)	0.0304 (10)	−0.0045 (7)	0.0002 (8)	−0.0020 (7)
C17	0.0202 (9)	0.0171 (7)	0.0249 (9)	−0.0031 (7)	0.0048 (7)	−0.0006 (7)
C18	0.0243 (10)	0.0193 (8)	0.0293 (11)	−0.0020 (7)	0.0073 (8)	0.0035 (7)
C19	0.0239 (9)	0.0159 (8)	0.0290 (10)	0.0026 (7)	0.0016 (8)	0.0015 (7)
C20	0.0253 (10)	0.0263 (9)	0.0268 (10)	0.0023 (7)	0.0020 (8)	0.0006 (8)
C21	0.0251 (11)	0.0352 (11)	0.0409 (13)	0.0045 (8)	0.0074 (9)	0.0023 (9)
C22	0.0263 (11)	0.0475 (13)	0.0462 (15)	0.0067 (9)	−0.0053 (10)	0.0096 (11)
C23	0.0346 (13)	0.0601 (15)	0.0339 (13)	0.0081 (11)	−0.0046 (10)	0.0128 (11)
C24	0.0295 (12)	0.0401 (11)	0.0302 (11)	0.0053 (9)	0.0034 (9)	0.0080 (9)
C25	0.0193 (9)	0.0213 (8)	0.0243 (10)	0.0019 (7)	0.0022 (7)	−0.0034 (7)
C26	0.0305 (11)	0.0245 (9)	0.0266 (10)	−0.0063 (8)	0.0024 (8)	−0.0025 (7)
C27	0.0300 (11)	0.0371 (11)	0.0268 (11)	−0.0089 (9)	0.0038 (9)	−0.0008 (8)
C28	0.0270 (10)	0.0357 (10)	0.0269 (11)	0.0002 (8)	0.0013 (8)	−0.0096 (8)
C29	0.0428 (13)	0.0224 (9)	0.0355 (12)	0.0005 (8)	−0.0020 (10)	−0.0074 (8)
C30	0.0424 (12)	0.0182 (9)	0.0300 (11)	0.0015 (8)	0.0000 (9)	−0.0002 (8)

I1—Co2	2.5980 (6)	C11—C12	1.379 (3)
Co2—C17	2.0685 (18)	C11—H11	0.9300
Co2—P2	2.1597 (6)	C12—C13	1.384 (4)
Co2—P3	2.1734 (6)	C12—H12	0.9300
Co2—P1	2.2278 (6)	C13—C14	1.373 (4)
P1—C1	1.824 (2)	C13—H13	0.9300
P1—C3	1.8263 (19)	C14—C15	1.390 (3)
P1—C2	1.827 (2)	C14—H14	0.9300
P2—O1	1.6231 (13)	C15—H15	0.9300
P2—C4	1.823 (2)	C16—C17	1.519 (3)
P2—C10	1.829 (2)	C16—H16	1.00 (2)
P3—O2	1.6278 (14)	C16—H17	0.99 (2)
P3—C25	1.821 (2)	C17—C18	1.513 (3)
P3—C19	1.823 (2)	C17—H31	1.00 (2)
O1—C16	1.454 (2)	C18—H18	0.97 (3)
O2—C18	1.460 (2)	C18—H19	0.98 (2)
C1—H1A	0.9600	C19—C20	1.394 (3)
C1—H1B	0.9600	C19—C24	1.397 (3)
C1—H1C	0.9600	C20—C21	1.385 (3)
C2—H2A	0.9600	C20—H20	0.9300
C2—H2B	0.9600	C21—C22	1.378 (4)
C2—H2C	0.9600	C21—H21	0.9300
C3—H3A	0.9600	C22—C23	1.391 (4)
C3—H3B	0.9600	C22—H22	0.9300
C3—H3C	0.9600	C23—C24	1.389 (3)
C4—C5	1.386 (3)	C23—H23	0.9300
C4—C9	1.398 (3)	C24—H24	0.9300
C5—C6	1.392 (3)	C25—C26	1.389 (3)
C5—H5	0.9300	C25—C30	1.396 (3)
C6—C7	1.383 (4)	C26—C27	1.388 (3)
C6—H6	0.9300	C26—H26	0.9300
C7—C8	1.372 (4)	C27—C28	1.387 (3)
C7—H7	0.9300	C27—H27	0.9300
C8—C9	1.386 (3)	C28—C29	1.386 (3)
C8—H8	0.9300	C28—H28	0.9300
C9—H9	0.9300	C29—C30	1.380 (3)
C10—C11	1.389 (3)	C29—H29	0.9300
C10—C15	1.391 (3)	C30—H30	0.9300
C17—Co2—P2	76.51 (6)	C12—C11—C10	120.8 (2)
C17—Co2—P3	79.01 (5)	C12—C11—H11	119.6
P2—Co2—P3	114.06 (2)	C10—C11—H11	119.6
C17—Co2—P1	178.47 (6)	C11—C12—C13	120.0 (2)
P2—Co2—P1	102.26 (2)	C11—C12—H12	120.0
P3—Co2—P1	100.77 (2)	C13—C12—H12	120.0
C17—Co2—I1	91.36 (6)	C14—C13—C12	119.7 (2)
P2—Co2—I1	124.951 (18)	C14—C13—H13	120.2
P3—Co2—I1	115.788 (17)	C12—C13—H13	120.2
P1—Co2—I1	90.104 (16)	C13—C14—C15	120.7 (2)
C1—P1—C3	101.64 (10)	C13—C14—H14	119.7
C1—P1—C2	100.03 (11)	C15—C14—H14	119.7
C3—P1—C2	101.59 (10)	C14—C15—C10	119.9 (2)
C1—P1—Co2	119.56 (7)	C14—C15—H15	120.0
C3—P1—Co2	114.34 (7)	C10—C15—H15	120.0
C2—P1—Co2	116.88 (7)	O1—C16—C17	112.58 (14)
O1—P2—C4	99.72 (8)	O1—C16—H16	107.0 (14)
O1—P2—C10	102.47 (9)	C17—C16—H16	111.2 (14)
C4—P2—C10	103.81 (9)	O1—C16—H17	107.3 (14)
O1—P2—Co2	108.65 (5)	C17—C16—H17	110.3 (15)
C4—P2—Co2	128.62 (7)	H16—C16—H17	108.3 (19)
C10—P2—Co2	110.39 (7)	C18—C17—C16	109.96 (15)
O2—P3—C25	102.49 (8)	C18—C17—Co2	108.77 (13)
O2—P3—C19	99.99 (8)	C16—C17—Co2	113.12 (13)
C25—P3—C19	102.15 (9)	C18—C17—H31	109.3 (13)
O2—P3—Co2	106.24 (5)	C16—C17—H31	111.0 (13)
C25—P3—Co2	123.96 (6)	Co2—C17—H31	104.6 (12)
C19—P3—Co2	118.45 (6)	O2—C18—C17	110.07 (15)
C16—O1—P2	110.85 (12)	O2—C18—H18	108.7 (14)
C18—O2—P3	113.57 (11)	C17—C18—H18	111.6 (13)
P1—C1—H1A	109.5	O2—C18—H19	103.7 (15)
P1—C1—H1B	109.5	C17—C18—H19	113.0 (14)
H1A—C1—H1B	109.5	H18—C18—H19	109 (2)
P1—C1—H1C	109.5	C20—C19—C24	119.07 (19)
H1A—C1—H1C	109.5	C20—C19—P3	123.31 (16)
H1B—C1—H1C	109.5	C24—C19—P3	117.39 (16)
P1—C2—H2A	109.5	C21—C20—C19	120.5 (2)
P1—C2—H2B	109.5	C21—C20—H20	119.7
H2A—C2—H2B	109.5	C19—C20—H20	119.7
P1—C2—H2C	109.5	C22—C21—C20	120.1 (2)
H2A—C2—H2C	109.5	C22—C21—H21	120.0
H2B—C2—H2C	109.5	C20—C21—H21	120.0
P1—C3—H3A	109.5	C21—C22—C23	120.2 (2)
P1—C3—H3B	109.5	C21—C22—H22	119.9
H3A—C3—H3B	109.5	C23—C22—H22	119.9
P1—C3—H3C	109.5	C24—C23—C22	119.9 (2)
H3A—C3—H3C	109.5	C24—C23—H23	120.1
H3B—C3—H3C	109.5	C22—C23—H23	120.1
C5—C4—C9	119.02 (19)	C23—C24—C19	120.2 (2)
C5—C4—P2	120.07 (15)	C23—C24—H24	119.9
C9—C4—P2	120.74 (17)	C19—C24—H24	119.9
C4—C5—C6	120.1 (2)	C26—C25—C30	118.65 (19)
C4—C5—H5	119.9	C26—C25—P3	120.75 (14)
C6—C5—H5	119.9	C30—C25—P3	120.55 (16)
C7—C6—C5	120.4 (2)	C27—C26—C25	120.79 (18)
C7—C6—H6	119.8	C27—C26—H26	119.6
C5—C6—H6	119.8	C25—C26—H26	119.6
C8—C7—C6	119.5 (2)	C28—C27—C26	119.9 (2)
C8—C7—H7	120.3	C28—C27—H27	120.1
C6—C7—H7	120.3	C26—C27—H27	120.1
C7—C8—C9	120.8 (2)	C29—C28—C27	119.6 (2)
C7—C8—H8	119.6	C29—C28—H28	120.2
C9—C8—H8	119.6	C27—C28—H28	120.2
C8—C9—C4	120.0 (2)	C30—C29—C28	120.38 (19)
C8—C9—H9	120.0	C30—C29—H29	119.8
C4—C9—H9	120.0	C28—C29—H29	119.8
C11—C10—C15	118.9 (2)	C29—C30—C25	120.6 (2)
C11—C10—P2	121.34 (16)	C29—C30—H30	119.7
C15—C10—P2	119.59 (16)	C25—C30—H30	119.7
P2—Co2—P1—C1	−60.80 (9)	C4—P2—C10—C11	−89.34 (18)
P3—Co2—P1—C1	56.98 (9)	Co2—P2—C10—C11	51.66 (18)
I1—Co2—P1—C1	173.28 (9)	O1—P2—C10—C15	−7.46 (18)
P2—Co2—P1—C3	59.95 (8)	C4—P2—C10—C15	95.97 (17)
P3—Co2—P1—C3	177.72 (8)	Co2—P2—C10—C15	−123.03 (16)
I1—Co2—P1—C3	−65.97 (8)	C15—C10—C11—C12	−1.5 (3)
P2—Co2—P1—C2	178.41 (8)	P2—C10—C11—C12	−176.23 (18)
P3—Co2—P1—C2	−63.81 (9)	C10—C11—C12—C13	1.1 (4)
I1—Co2—P1—C2	52.49 (8)	C11—C12—C13—C14	0.0 (4)
C17—Co2—P2—O1	−34.20 (8)	C12—C13—C14—C15	−0.8 (4)
P3—Co2—P2—O1	37.03 (6)	C13—C14—C15—C10	0.4 (4)
P1—Co2—P2—O1	144.87 (6)	C11—C10—C15—C14	0.7 (3)
I1—Co2—P2—O1	−116.27 (6)	P2—C10—C15—C14	175.55 (18)
C17—Co2—P2—C4	−154.04 (10)	P2—O1—C16—C17	3.5 (2)
P3—Co2—P2—C4	−82.82 (9)	O1—C16—C17—C18	−155.92 (16)
P1—Co2—P2—C4	25.02 (9)	O1—C16—C17—Co2	−34.09 (19)
I1—Co2—P2—C4	123.89 (8)	P2—Co2—C17—C18	160.80 (14)
C17—Co2—P2—C10	77.43 (9)	P3—Co2—C17—C18	42.53 (12)
P3—Co2—P2—C10	148.66 (7)	I1—Co2—C17—C18	−73.49 (13)
P1—Co2—P2—C10	−103.50 (7)	P2—Co2—C17—C16	38.31 (12)
I1—Co2—P2—C10	−4.64 (7)	P3—Co2—C17—C16	−79.97 (13)
C17—Co2—P3—O2	−27.71 (8)	I1—Co2—C17—C16	164.01 (12)
P2—Co2—P3—O2	−97.41 (6)	P3—O2—C18—C17	23.9 (2)
P1—Co2—P3—O2	153.84 (6)	C16—C17—C18—O2	75.7 (2)
I1—Co2—P3—O2	58.45 (6)	Co2—C17—C18—O2	−48.69 (18)
C17—Co2—P3—C25	90.18 (10)	O2—P3—C19—C20	135.14 (16)
P2—Co2—P3—C25	20.48 (8)	C25—P3—C19—C20	29.91 (18)
P1—Co2—P3—C25	−88.28 (8)	Co2—P3—C19—C20	−110.13 (16)
I1—Co2—P3—C25	176.33 (7)	O2—P3—C19—C24	−50.42 (17)
C17—Co2—P3—C19	−139.02 (9)	C25—P3—C19—C24	−155.65 (16)
P2—Co2—P3—C19	151.28 (7)	Co2—P3—C19—C24	64.31 (17)
P1—Co2—P3—C19	42.53 (8)	C24—C19—C20—C21	−0.1 (3)
I1—Co2—P3—C19	−52.86 (8)	P3—C19—C20—C21	174.23 (15)
C4—P2—O1—C16	162.61 (13)	C19—C20—C21—C22	−0.1 (3)
C10—P2—O1—C16	−90.78 (14)	C20—C21—C22—C23	−0.1 (4)
Co2—P2—O1—C16	26.04 (13)	C21—C22—C23—C24	0.5 (4)
C25—P3—O2—C18	−122.07 (14)	C22—C23—C24—C19	−0.7 (4)
C19—P3—O2—C18	132.99 (14)	C20—C19—C24—C23	0.5 (3)
Co2—P3—O2—C18	9.27 (15)	P3—C19—C24—C23	−174.15 (18)
O1—P2—C4—C5	−35.28 (18)	O2—P3—C25—C26	166.52 (16)
C10—P2—C4—C5	−140.81 (17)	C19—P3—C25—C26	−90.21 (17)
Co2—P2—C4—C5	88.23 (17)	Co2—P3—C25—C26	46.88 (19)
O1—P2—C4—C9	149.46 (17)	O2—P3—C25—C30	−15.99 (19)
C10—P2—C4—C9	43.93 (19)	C19—P3—C25—C30	87.28 (18)
Co2—P2—C4—C9	−87.03 (18)	Co2—P3—C25—C30	−135.62 (15)
C9—C4—C5—C6	0.6 (3)	C30—C25—C26—C27	−3.5 (3)
P2—C4—C5—C6	−174.71 (17)	P3—C25—C26—C27	174.08 (17)
C4—C5—C6—C7	0.9 (3)	C25—C26—C27—C28	1.8 (3)
C5—C6—C7—C8	−0.8 (4)	C26—C27—C28—C29	1.2 (3)
C6—C7—C8—C9	−0.7 (4)	C27—C28—C29—C30	−2.6 (3)
C7—C8—C9—C4	2.2 (4)	C28—C29—C30—C25	0.9 (4)
C5—C4—C9—C8	−2.2 (3)	C26—C25—C30—C29	2.1 (3)
P2—C4—C9—C8	173.15 (18)	P3—C25—C30—C29	−175.47 (18)
O1—P2—C10—C11	167.23 (17)