Literature DB >> 21578623

Dichlorido[N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide-κN](1,10-phenanthroline-κN,N')cobalt(II) methanol monosolvate.

Yuan Wang1, Zheng Liu, Baoyu Liu.   

Abstract

In the title compound, [CoCl(2)(C(13)H(9)Cl(2)N(3)O(2))(2)(C(12)H(8)N(2))]·CH(3)OH, the Co(II) atom is octahedrally coordinated by two N atoms from the pyridyl rings of the tridentate N'-(3,5-dichloro-2-hydroxy-benzyl-idene)pyridine-4-carbohydrazide (H(2)L) ligand, two N atoms from the 1,10-phenanthroline ligand and two chloride ions. The acyl-hydrazone groups are not involved into the coordination of the metal ion. In the crystal packing an extended three-dimensional network formed by N-H⋯Cl, N-H⋯O, O-H⋯N, O-H⋯N and O-H⋯Cl hydrogen bonds is observed.

Entities:  

Year:  2009        PMID: 21578623      PMCID: PMC2972077          DOI: 10.1107/S1600536809047680

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


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  3 in total

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