Bis[N'-(3-cyano-benzyl-idene)isonicotino-hydrazide-κN]silver(I) trifluoro-methane-sulfonate.

In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N'-3-cyano-benzyl-ideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N inter-actions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (-) anion inter-acts with hydrazone groups of two neighbouring ligands via N-H⋯O hydrogen bonds. These weak inter-molecular inter-actions contribute to the formation of supra-molecular chains. In addition, there are Ag⋯O inter-actions [2.787 (2) Å] between Ag and O atoms from adjacent chains.

Related literature

For the coordination of silver ions and properties of n class="Chemical">silver coordination compounds, see: Dong et al. (2004 ▶); Niu et al. (2008 ▶, 2009 ▶); Sumby & Hardie (2005 ▶); Abu-Youssef et al. (2007 ▶).

Experimental

Crystal data

[Ag(C14H10N4O)2]n class="Chemical">CF3SO3

M = 757.46

Triclinic,

a = 7.5481 (17) Å

b = 14.164 (3) Å

c = 14.175 (3) Å

α = 87.895 (4)°

β = 89.918 (4)°

γ = 81.355 (4)°

V = 1497.2 (6) Å3

Z = 2

Mo Kα radiation

μ = 0.82 mm−1

T = 173 K

0.32 × 0.22 × 0.17 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2005 ▶) T min = 0.780, T max = 0.874

8251 measured reflections

5461 independent reflections

3857 reflections with I > 2σ(I)

R int = 0.023

Refinement

R[F 2 > 2σ(F 2)] = 0.060

wR(F 2) = 0.175

S = 1.03

5461 reflections

433 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 1.04 e Å−3

Δρmin = −0.87 e Å−3

Data collection: APEX2 (Bruker, 2005 ▶); cell refinement: SAINT (Bruker, 2005 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXL97 and DIAMOND (Brandenburg, 2005 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809039579/bh2248sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809039579/bh2248Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C14H10N4O)2]CF3SO3	Z = 2
Mr = 757.46	F(000) = 760
Triclinic, P1	Dx = 1.680 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 7.5481 (17) Å	Cell parameters from 2331 reflections
b = 14.164 (3) Å	θ = 2.0–25.5°
c = 14.175 (3) Å	µ = 0.82 mm−1
α = 87.895 (4)°	T = 173 K
β = 89.918 (4)°	Needle, yellow
γ = 81.355 (4)°	0.32 × 0.22 × 0.17 mm
V = 1497.2 (6) Å3

Bruker APEXII CCD area-detector diffractometer	5461 independent reflections
Radiation source: fine-focus sealed tube	3857 reflections with I > 2σ(I)
graphite	Rint = 0.023
φ and ω scans	θmax = 25.5°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 2005)	h = −8→9
Tmin = 0.780, Tmax = 0.874	k = −15→17
8251 measured reflections	l = −15→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.060	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.175	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ2(Fo2) + (0.0934P)2 + 1.7184P] where P = (Fo2 + 2Fc2)/3
5461 reflections	(Δ/σ)max < 0.001
433 parameters	Δρmax = 1.04 e Å−3
0 restraints	Δρmin = −0.87 e Å−3
0 constraints

	x	y	z	Uiso*/Ueq
Ag1	0.93777 (7)	0.21340 (3)	0.17729 (3)	0.0685 (2)
N1	0.8202 (6)	0.1314 (3)	0.0743 (3)	0.0514 (11)
N2	0.5612 (6)	−0.0094 (4)	−0.2091 (3)	0.0513 (11)
N3	0.5110 (6)	−0.0664 (3)	−0.2783 (3)	0.0521 (11)
N4	0.0251 (8)	0.0449 (4)	−0.7023 (4)	0.0721 (14)
N5	1.0223 (6)	0.3075 (3)	0.2790 (3)	0.0537 (11)
N6	1.2968 (6)	0.4563 (4)	0.5530 (3)	0.0513 (11)
N7	1.3579 (6)	0.5147 (3)	0.6166 (3)	0.0505 (10)
N8	1.8445 (9)	0.4103 (5)	1.0418 (4)	0.0814 (16)
O1	0.7156 (6)	−0.1358 (3)	−0.1262 (3)	0.0635 (11)
O2	1.2202 (6)	0.5775 (3)	0.4444 (3)	0.0660 (11)
O3	0.2036 (7)	0.2847 (3)	0.6588 (3)	0.0823 (14)
O4	0.1417 (11)	0.1451 (4)	0.7472 (4)	0.120 (2)
O5	0.4103 (8)	0.2082 (5)	0.7702 (4)	0.124 (2)
S3	0.2325 (3)	0.22699 (11)	0.74187 (11)	0.0677 (5)
F1	−0.0500 (8)	0.3171 (5)	0.8159 (4)	0.135 (2)
F2	0.1803 (8)	0.3828 (3)	0.8371 (3)	0.1131 (17)
F3	0.1446 (7)	0.2578 (3)	0.9181 (3)	0.0987 (14)
C1	0.8156 (7)	0.0385 (4)	0.0907 (4)	0.0512 (13)
H1	0.8508	0.0115	0.1513	0.061*
C2	0.7630 (7)	−0.0201 (4)	0.0248 (4)	0.0498 (12)
H2	0.7614	−0.0859	0.0398	0.060*
C3	0.7118 (6)	0.0181 (4)	−0.0644 (3)	0.0425 (11)
C4	0.7153 (9)	0.1136 (4)	−0.0820 (4)	0.0589 (15)
H4	0.6811	0.1424	−0.1422	0.071*
C5	0.7688 (9)	0.1674 (4)	−0.0114 (4)	0.0617 (15)
H5	0.7693	0.2336	−0.0243	0.074*
C6	0.6637 (7)	−0.0506 (4)	−0.1360 (4)	0.0471 (12)
C7	0.4229 (7)	−0.0216 (4)	−0.3474 (4)	0.0524 (13)
H7	0.4010	0.0463	−0.3488	0.063*
C8	0.3555 (7)	−0.0722 (4)	−0.4237 (3)	0.0473 (12)
C9	0.3767 (9)	−0.1707 (4)	−0.4261 (4)	0.0662 (16)
H9	0.4402	−0.2080	−0.3765	0.079*
C10	0.3077 (11)	−0.2158 (5)	−0.4991 (5)	0.082 (2)
H10	0.3247	−0.2836	−0.4997	0.098*
C11	0.2132 (10)	−0.1621 (5)	−0.5717 (5)	0.0746 (19)
H11	0.1631	−0.1929	−0.6214	0.089*
C12	0.1925 (8)	−0.0643 (4)	−0.5713 (4)	0.0559 (14)
C13	0.2621 (7)	−0.0184 (4)	−0.4967 (3)	0.0484 (12)
H13	0.2454	0.0494	−0.4962	0.058*
C14	0.0978 (8)	−0.0051 (5)	−0.6452 (4)	0.0572 (14)
C15	1.0095 (7)	0.4007 (4)	0.2630 (4)	0.0520 (13)
H15	0.9526	0.4275	0.2064	0.062*
C16	1.0737 (7)	0.4608 (4)	0.3233 (4)	0.0495 (12)
H16	1.0617	0.5273	0.3079	0.059*
C17	1.1562 (7)	0.4243 (4)	0.4069 (3)	0.0442 (11)
C18	1.1695 (10)	0.3279 (4)	0.4243 (4)	0.0723 (19)
H18	1.2229	0.2998	0.4813	0.087*
C19	1.1061 (11)	0.2720 (4)	0.3597 (5)	0.078 (2)
H19	1.1216	0.2048	0.3721	0.093*
C20	1.2263 (7)	0.4947 (4)	0.4696 (4)	0.0477 (12)
C21	1.4326 (7)	0.4693 (4)	0.6902 (4)	0.0510 (13)
H21	1.4425	0.4016	0.6954	0.061*
C22	1.5024 (7)	0.5212 (4)	0.7661 (4)	0.0490 (12)
C23	1.4820 (8)	0.6210 (4)	0.7655 (4)	0.0575 (14)
H23	1.4170	0.6576	0.7158	0.069*
C24	1.5556 (9)	0.6667 (4)	0.8366 (4)	0.0648 (16)
H24	1.5403	0.7345	0.8364	0.078*
C25	1.6511 (8)	0.6137 (4)	0.9077 (4)	0.0615 (15)
H25	1.7058	0.6451	0.9553	0.074*
C26	1.6686 (7)	0.5153 (4)	0.9106 (4)	0.0535 (13)
C27	1.5949 (7)	0.4690 (4)	0.8391 (4)	0.0504 (12)
H27	1.6082	0.4012	0.8406	0.060*
C28	1.7683 (8)	0.4570 (4)	0.9849 (4)	0.0581 (14)
C29	0.1274 (11)	0.2994 (4)	0.8338 (5)	0.0696 (17)
H28	1.287 (7)	0.397 (4)	0.575 (4)	0.047 (15)*
H29	0.529 (8)	0.051 (4)	−0.217 (4)	0.055 (17)*

	U11	U22	U33	U12	U13	U23
Ag1	0.0727 (4)	0.0744 (4)	0.0628 (3)	−0.0187 (2)	−0.0167 (2)	−0.0289 (2)
N1	0.053 (3)	0.052 (3)	0.052 (3)	−0.012 (2)	−0.017 (2)	−0.010 (2)
N2	0.056 (3)	0.053 (3)	0.044 (2)	−0.004 (2)	−0.014 (2)	−0.015 (2)
N3	0.054 (3)	0.058 (3)	0.045 (2)	−0.010 (2)	−0.011 (2)	−0.017 (2)
N4	0.074 (4)	0.091 (4)	0.055 (3)	−0.024 (3)	−0.020 (3)	0.005 (3)
N5	0.064 (3)	0.052 (3)	0.046 (2)	−0.010 (2)	−0.015 (2)	−0.009 (2)
N6	0.062 (3)	0.053 (3)	0.041 (2)	−0.014 (2)	−0.018 (2)	−0.006 (2)
N7	0.051 (3)	0.060 (3)	0.042 (2)	−0.013 (2)	−0.0110 (19)	−0.009 (2)
N8	0.093 (4)	0.094 (4)	0.059 (3)	−0.016 (3)	−0.029 (3)	−0.005 (3)
O1	0.079 (3)	0.049 (2)	0.064 (2)	−0.013 (2)	−0.029 (2)	−0.0073 (18)
O2	0.090 (3)	0.051 (2)	0.059 (2)	−0.014 (2)	−0.028 (2)	−0.0045 (19)
O3	0.120 (4)	0.075 (3)	0.053 (3)	−0.018 (3)	−0.009 (2)	0.007 (2)
O4	0.200 (7)	0.061 (3)	0.108 (4)	−0.045 (4)	0.000 (4)	−0.006 (3)
O5	0.091 (4)	0.168 (6)	0.099 (4)	0.032 (4)	−0.022 (3)	−0.007 (4)
S3	0.0903 (12)	0.0504 (8)	0.0573 (9)	0.0049 (8)	−0.0142 (8)	0.0033 (7)
F1	0.096 (4)	0.161 (5)	0.134 (5)	0.022 (4)	0.016 (3)	0.014 (4)
F2	0.199 (6)	0.058 (2)	0.087 (3)	−0.033 (3)	0.010 (3)	−0.016 (2)
F3	0.163 (4)	0.074 (2)	0.055 (2)	−0.009 (3)	−0.002 (2)	0.0057 (19)
C1	0.053 (3)	0.061 (3)	0.040 (3)	−0.013 (3)	−0.015 (2)	0.000 (2)
C2	0.056 (3)	0.044 (3)	0.050 (3)	−0.012 (2)	−0.014 (2)	0.004 (2)
C3	0.039 (3)	0.050 (3)	0.040 (3)	−0.012 (2)	−0.011 (2)	−0.002 (2)
C4	0.082 (4)	0.049 (3)	0.046 (3)	−0.013 (3)	−0.027 (3)	0.004 (2)
C5	0.082 (4)	0.046 (3)	0.058 (3)	−0.014 (3)	−0.028 (3)	0.002 (3)
C6	0.045 (3)	0.052 (3)	0.045 (3)	−0.009 (2)	−0.014 (2)	−0.004 (2)
C7	0.054 (3)	0.058 (3)	0.044 (3)	−0.004 (3)	−0.013 (2)	−0.010 (2)
C8	0.047 (3)	0.056 (3)	0.040 (3)	−0.009 (2)	−0.010 (2)	−0.006 (2)
C9	0.079 (4)	0.055 (3)	0.066 (4)	−0.015 (3)	−0.029 (3)	0.000 (3)
C10	0.102 (5)	0.058 (4)	0.088 (5)	−0.016 (4)	−0.037 (4)	−0.009 (3)
C11	0.089 (5)	0.073 (4)	0.066 (4)	−0.023 (4)	−0.033 (3)	−0.013 (3)
C12	0.058 (3)	0.069 (4)	0.045 (3)	−0.021 (3)	−0.012 (2)	−0.008 (3)
C13	0.053 (3)	0.054 (3)	0.040 (3)	−0.011 (2)	−0.009 (2)	−0.008 (2)
C14	0.057 (3)	0.074 (4)	0.044 (3)	−0.023 (3)	−0.013 (3)	−0.004 (3)
C15	0.054 (3)	0.063 (3)	0.038 (3)	−0.004 (3)	−0.020 (2)	−0.009 (2)
C16	0.056 (3)	0.047 (3)	0.045 (3)	−0.005 (2)	−0.015 (2)	0.001 (2)
C17	0.049 (3)	0.054 (3)	0.029 (2)	−0.006 (2)	−0.006 (2)	−0.004 (2)
C18	0.115 (6)	0.051 (3)	0.050 (3)	−0.013 (3)	−0.037 (3)	0.006 (3)
C19	0.131 (6)	0.043 (3)	0.061 (4)	−0.017 (3)	−0.044 (4)	−0.001 (3)
C20	0.047 (3)	0.047 (3)	0.048 (3)	−0.004 (2)	−0.010 (2)	−0.008 (2)
C21	0.058 (3)	0.058 (3)	0.041 (3)	−0.018 (3)	−0.010 (2)	−0.005 (2)
C22	0.048 (3)	0.057 (3)	0.043 (3)	−0.013 (2)	−0.015 (2)	−0.003 (2)
C23	0.057 (3)	0.059 (3)	0.057 (3)	−0.010 (3)	−0.010 (3)	−0.001 (3)
C24	0.077 (4)	0.053 (3)	0.067 (4)	−0.015 (3)	−0.009 (3)	−0.012 (3)
C25	0.062 (4)	0.070 (4)	0.057 (3)	−0.019 (3)	−0.015 (3)	−0.019 (3)
C26	0.051 (3)	0.067 (4)	0.044 (3)	−0.012 (3)	−0.010 (2)	−0.011 (3)
C27	0.056 (3)	0.053 (3)	0.043 (3)	−0.012 (2)	−0.009 (2)	−0.006 (2)
C28	0.059 (4)	0.073 (4)	0.044 (3)	−0.012 (3)	−0.013 (3)	−0.009 (3)
C29	0.098 (5)	0.047 (3)	0.060 (4)	0.000 (3)	−0.015 (3)	0.008 (3)

Ag1—N5	2.160 (4)	C7—H7	0.9500
Ag1—N1	2.169 (4)	C8—C9	1.381 (8)
N1—C1	1.333 (7)	C8—C13	1.390 (7)
N1—C5	1.335 (7)	C9—C10	1.379 (8)
N2—C6	1.354 (7)	C9—H9	0.9500
N2—N3	1.381 (6)	C10—C11	1.389 (9)
N2—H29	0.86 (6)	C10—H10	0.9500
N3—C7	1.278 (7)	C11—C12	1.370 (9)
N4—C14	1.140 (7)	C11—H11	0.9500
N5—C15	1.320 (7)	C12—C13	1.404 (7)
N5—C19	1.351 (8)	C12—C14	1.439 (8)
N6—C20	1.359 (7)	C13—H13	0.9500
N6—N7	1.371 (6)	C15—C16	1.366 (7)
N6—H28	0.90 (5)	C15—H15	0.9500
N7—C21	1.291 (7)	C16—C17	1.386 (7)
N8—C28	1.126 (8)	C16—H16	0.9500
O1—C6	1.215 (6)	C17—C18	1.368 (8)
O2—C20	1.207 (6)	C17—C20	1.513 (7)
O3—S3	1.407 (4)	C18—C19	1.365 (8)
O4—S3	1.432 (6)	C18—H18	0.9500
O5—S3	1.385 (6)	C19—H19	0.9500
S3—C29	1.798 (7)	C21—C22	1.467 (7)
F1—C29	1.347 (9)	C21—H21	0.9500
F2—C29	1.305 (8)	C22—C27	1.377 (7)
F3—C29	1.310 (7)	C22—C23	1.399 (8)
C1—C2	1.371 (7)	C23—C24	1.379 (8)
C1—H1	0.9500	C23—H23	0.9500
C2—C3	1.389 (7)	C24—C25	1.371 (9)
C2—H2	0.9500	C24—H24	0.9500
C3—C4	1.371 (7)	C25—C26	1.380 (8)
C3—C6	1.514 (7)	C25—H25	0.9500
C4—C5	1.377 (7)	C26—C27	1.389 (7)
C4—H4	0.9500	C26—C28	1.452 (8)
C5—H5	0.9500	C27—H27	0.9500
C7—C8	1.453 (7)
N5—Ag1—N1	172.56 (17)	C11—C12—C13	120.4 (5)
C1—N1—C5	116.7 (4)	C11—C12—C14	122.0 (5)
C1—N1—Ag1	120.4 (3)	C13—C12—C14	117.6 (5)
C5—N1—Ag1	122.4 (4)	C8—C13—C12	119.9 (5)
C6—N2—N3	119.1 (5)	C8—C13—H13	120.0
C6—N2—H29	124 (4)	C12—C13—H13	120.0
N3—N2—H29	116 (4)	N4—C14—C12	177.3 (6)
C7—N3—N2	115.2 (5)	N5—C15—C16	123.6 (5)
C15—N5—C19	116.4 (5)	N5—C15—H15	118.2
C15—N5—Ag1	122.6 (3)	C16—C15—H15	118.2
C19—N5—Ag1	120.7 (4)	C15—C16—C17	119.8 (5)
C20—N6—N7	119.2 (5)	C15—C16—H16	120.1
C20—N6—H28	124 (4)	C17—C16—H16	120.1
N7—N6—H28	116 (4)	C18—C17—C16	117.0 (5)
C21—N7—N6	113.5 (4)	C18—C17—C20	126.1 (5)
O5—S3—O3	113.8 (4)	C16—C17—C20	116.9 (4)
O5—S3—O4	114.0 (4)	C19—C18—C17	120.0 (5)
O3—S3—O4	115.9 (3)	C19—C18—H18	120.0
O5—S3—C29	103.2 (4)	C17—C18—H18	120.0
O3—S3—C29	105.1 (3)	N5—C19—C18	123.1 (5)
O4—S3—C29	102.8 (4)	N5—C19—H19	118.4
N1—C1—C2	123.6 (5)	C18—C19—H19	118.4
N1—C1—H1	118.2	O2—C20—N6	124.5 (5)
C2—C1—H1	118.2	O2—C20—C17	120.9 (5)
C1—C2—C3	118.9 (5)	N6—C20—C17	114.5 (4)
C1—C2—H2	120.5	N7—C21—C22	120.6 (5)
C3—C2—H2	120.5	N7—C21—H21	119.7
C4—C3—C2	118.1 (5)	C22—C21—H21	119.7
C4—C3—C6	125.1 (4)	C27—C22—C23	119.4 (5)
C2—C3—C6	116.8 (4)	C27—C22—C21	118.2 (5)
C3—C4—C5	119.1 (5)	C23—C22—C21	122.4 (5)
C3—C4—H4	120.5	C24—C23—C22	120.3 (6)
C5—C4—H4	120.5	C24—C23—H23	119.8
N1—C5—C4	123.6 (5)	C22—C23—H23	119.8
N1—C5—H5	118.2	C25—C24—C23	119.7 (6)
C4—C5—H5	118.2	C25—C24—H24	120.2
O1—C6—N2	124.3 (5)	C23—C24—H24	120.2
O1—C6—C3	120.7 (4)	C24—C25—C26	120.7 (5)
N2—C6—C3	114.9 (4)	C24—C25—H25	119.7
N3—C7—C8	121.4 (5)	C26—C25—H25	119.7
N3—C7—H7	119.3	C25—C26—C27	119.8 (5)
C8—C7—H7	119.3	C25—C26—C28	122.2 (5)
C9—C8—C13	118.7 (5)	C27—C26—C28	118.0 (5)
C9—C8—C7	123.2 (5)	C22—C27—C26	120.1 (5)
C13—C8—C7	118.0 (5)	C22—C27—H27	120.0
C10—C9—C8	121.4 (6)	C26—C27—H27	120.0
C10—C9—H9	119.3	N8—C28—C26	178.7 (6)
C8—C9—H9	119.3	F2—C29—F3	108.7 (6)
C9—C10—C11	119.9 (6)	F2—C29—F1	106.0 (6)
C9—C10—H10	120.0	F3—C29—F1	106.0 (6)
C11—C10—H10	120.0	F2—C29—S3	113.5 (5)
C12—C11—C10	119.6 (5)	F3—C29—S3	113.9 (4)
C12—C11—H11	120.2	F1—C29—S3	108.1 (5)
C10—C11—H11	120.2
C6—N2—N3—C7	−176.3 (5)	C15—C16—C17—C20	179.1 (5)
C20—N6—N7—C21	−175.6 (5)	C16—C17—C18—C19	1.3 (10)
C5—N1—C1—C2	0.4 (8)	C20—C17—C18—C19	−177.5 (6)
Ag1—N1—C1—C2	−172.1 (4)	C15—N5—C19—C18	2.4 (11)
N1—C1—C2—C3	0.3 (8)	Ag1—N5—C19—C18	176.9 (6)
C1—C2—C3—C4	−0.5 (8)	C17—C18—C19—N5	−2.7 (12)
C1—C2—C3—C6	177.1 (5)	N7—N6—C20—O2	3.5 (8)
C2—C3—C4—C5	0.1 (9)	N7—N6—C20—C17	−177.5 (4)
C6—C3—C4—C5	−177.3 (5)	C18—C17—C20—O2	174.2 (6)
C1—N1—C5—C4	−0.9 (9)	C16—C17—C20—O2	−4.5 (8)
Ag1—N1—C5—C4	171.4 (5)	C18—C17—C20—N6	−4.8 (8)
C3—C4—C5—N1	0.7 (10)	C16—C17—C20—N6	176.4 (5)
N3—N2—C6—O1	−0.2 (8)	N6—N7—C21—C22	−178.9 (5)
N3—N2—C6—C3	179.8 (4)	N7—C21—C22—C27	−174.4 (5)
C4—C3—C6—O1	156.7 (6)	N7—C21—C22—C23	4.1 (8)
C2—C3—C6—O1	−20.7 (8)	C27—C22—C23—C24	0.8 (9)
C4—C3—C6—N2	−23.3 (8)	C21—C22—C23—C24	−177.6 (5)
C2—C3—C6—N2	159.3 (5)	C22—C23—C24—C25	0.8 (9)
N2—N3—C7—C8	−177.8 (5)	C23—C24—C25—C26	−2.4 (10)
N3—C7—C8—C9	1.9 (9)	C24—C25—C26—C27	2.5 (9)
N3—C7—C8—C13	−179.5 (5)	C24—C25—C26—C28	−179.8 (6)
C13—C8—C9—C10	0.1 (10)	C23—C22—C27—C26	−0.8 (8)
C7—C8—C9—C10	178.7 (6)	C21—C22—C27—C26	177.7 (5)
C8—C9—C10—C11	−0.6 (12)	C25—C26—C27—C22	−0.9 (8)
C9—C10—C11—C12	1.4 (12)	C28—C26—C27—C22	−178.6 (5)
C10—C11—C12—C13	−1.7 (10)	O5—S3—C29—F2	66.4 (6)
C10—C11—C12—C14	179.2 (7)	O3—S3—C29—F2	−53.2 (6)
C9—C8—C13—C12	−0.4 (8)	O4—S3—C29—F2	−174.8 (5)
C7—C8—C13—C12	−179.1 (5)	O5—S3—C29—F3	−58.8 (7)
C11—C12—C13—C8	1.2 (9)	O3—S3—C29—F3	−178.3 (5)
C14—C12—C13—C8	−179.6 (5)	O4—S3—C29—F3	60.0 (7)
C19—N5—C15—C16	−0.8 (9)	O5—S3—C29—F1	−176.3 (5)
Ag1—N5—C15—C16	−175.2 (4)	O3—S3—C29—F1	64.1 (6)
N5—C15—C16—C17	−0.5 (9)	O4—S3—C29—F1	−57.6 (6)
C15—C16—C17—C18	0.3 (8)

D—H···A	D—H	H···A	D···A	D—H···A
N2—H29···O5i	0.86 (6)	2.27 (6)	3.125 (9)	173 (5)
N6—H28···O3ii	0.90 (5)	2.12 (6)	2.982 (7)	161 (5)

Ag1—N5	2.160 (4)
Ag1—N1	2.169 (4)

N5—Ag1—N1

172.56 (17)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H29⋯O5i	0.86 (6)	2.27 (6)	3.125 (9)	173 (5)
N6—H28⋯O3ii	0.90 (5)	2.12 (6)	2.982 (7)	161 (5)

Symmetry codes: (i) ; (ii) .