Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(2,2'-bipyridine-κN,N')copper(I)] bis-(tetra-fluoro-borate).

The centrosymmetric title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(25)H(22)P(2))(2)](BF(4))(2), consists of discrete dinuclear cations and tetra-fluoro-borate anions. The two Cu(I) centers are bridged by the phosphine ligands to form an eight-membered ring. The Cu(I) center exhibits a tetra-hedral coordination as it is chelated by the N-heterocycle.

Related literature

For general background to binuclear metal complexes containing n class="Chemical">bis(diphenylphosphino)methane, see: Stockland et al. (2001 ▶); Jin et al. (2008 ▶). For their photochemical and photophysical properties, see: Armaroli (2001 ▶); Yam et al. (1997 ▶). For related structures, see: Diez et al. (1987 ▶); Ho & Bau (1983 ▶); Kuang et al. (2002 ▶). For the synthesis, see: Jia et al. (2005 ▶).

Experimental

Crystal data

[Cu2(C10n class="Species">H8N2)2(C25H22P2)2](BF4)2

M = 1381.80

Triclinic,

a = 11.5601 (11) Å

b = 12.1936 (13) Å

c = 13.1022 (18) Å

α = 64.603 (1)°

β = 75.781 (2)°

γ = 75.120 (2)°

V = 1592.9 (3) Å3

Z = 1

Mo Kα radiation

μ = 0.84 mm−1

T = 298 K

0.35 × 0.29 × 0.17 mm

Data collection

Bruker SMART diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.758, T max = 0.871

8214 measured reflections

5497 independent reflections

3264 reflections with I > 2σ(I)

R int = 0.052

Refinement

R[F 2 > 2σ(F 2)] = 0.078

wR(F 2) = 0.216

S = 1.12

5497 reflections

434 parameters

H-atom parameters constrained

Δρmax = 1.44 e Å−3

Δρmin = −0.80 e Å−3

Data collection: SMART (Bruker, 1997 ▶); cell refinement: SAINT (Bruker, 1997 ▶); data reduction: SAIn class="Chemical">NT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809038252/ng2640sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809038252/ng2640Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu2(C10H8N2)2(C25H22P2)2](BF4)2	Z = 1
Mr = 1381.80	F(000) = 708
Triclinic, P1	Dx = 1.440 Mg m−3
a = 11.5601 (11) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.1936 (13) Å	Cell parameters from 1867 reflections
c = 13.1022 (18) Å	θ = 2.3–22.2°
α = 64.603 (1)°	µ = 0.84 mm−1
β = 75.781 (2)°	T = 298 K
γ = 75.120 (2)°	Prism, yellow
V = 1592.9 (3) Å3	0.35 × 0.29 × 0.17 mm

Bruker SMART diffractometer	5497 independent reflections
Radiation source: fine-focus sealed tube	3264 reflections with I > 2σ(I)
graphite	Rint = 0.052
φ and ω scans	θmax = 25.0°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −13→11
Tmin = 0.758, Tmax = 0.871	k = −14→14
8214 measured reflections	l = −15→12

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.078	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.216	H-atom parameters constrained
S = 1.12	w = 1/[σ2(Fo2) + (0.0959P)2] where P = (Fo2 + 2Fc2)/3
5497 reflections	(Δ/σ)max = 0.001
434 parameters	Δρmax = 1.44 e Å−3
0 restraints	Δρmin = −0.80 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cu1	0.50912 (7)	0.43927 (7)	0.35411 (6)	0.0397 (3)
B1	0.7558 (10)	0.8853 (10)	0.1027 (8)	0.067 (3)
F1	0.7993 (5)	0.9609 (5)	0.1329 (4)	0.0951 (16)
F2	0.645 (5)	0.941 (8)	0.066 (9)	0.079 (10)	0.6 (3)
F3	0.839 (5)	0.868 (9)	0.011 (6)	0.087 (8)	0.6 (3)
F4	0.749 (11)	0.773 (6)	0.193 (5)	0.087 (14)	0.6 (3)
F2'	0.666 (12)	0.955 (10)	0.035 (9)	0.078 (12)	0.4 (3)
F3'	0.701 (16)	0.801 (12)	0.203 (4)	0.090 (16)	0.4 (3)
F4'	0.845 (5)	0.822 (19)	0.047 (16)	0.09 (2)	0.4 (3)
N1	0.5285 (5)	0.2987 (5)	0.2966 (5)	0.0493 (14)
N2	0.5743 (5)	0.5269 (5)	0.1790 (4)	0.0447 (13)
P1	0.68607 (14)	0.38802 (15)	0.42487 (13)	0.0363 (4)
P2	0.31095 (14)	0.47660 (14)	0.41841 (13)	0.0347 (4)
C1	0.5006 (7)	0.1871 (7)	0.3560 (7)	0.060 (2)
H1	0.4710	0.1653	0.4336	0.072*
C2	0.5126 (8)	0.1007 (8)	0.3098 (9)	0.079 (3)
H2	0.4918	0.0234	0.3549	0.094*
C3	0.5562 (9)	0.1334 (9)	0.1957 (10)	0.093 (3)
H3	0.5648	0.0785	0.1612	0.111*
C4	0.5874 (8)	0.2486 (9)	0.1322 (8)	0.084 (3)
H4	0.6173	0.2719	0.0545	0.101*
C5	0.5737 (6)	0.3292 (7)	0.1850 (6)	0.0530 (18)
C6	0.6058 (6)	0.4537 (7)	0.1216 (6)	0.0478 (17)
C7	0.6681 (8)	0.4930 (9)	0.0094 (6)	0.072 (2)
H7	0.6900	0.4411	−0.0300	0.086*
C8	0.6957 (8)	0.6078 (9)	−0.0406 (7)	0.083 (3)
H8	0.7371	0.6351	−0.1151	0.100*
C9	0.6636 (8)	0.6832 (9)	0.0169 (7)	0.079 (3)
H9	0.6821	0.7623	−0.0170	0.095*
C10	0.6031 (6)	0.6396 (7)	0.1266 (6)	0.0568 (19)
H10	0.5811	0.6910	0.1665	0.068*
C11	0.7495 (6)	0.4990 (5)	0.4462 (5)	0.0388 (15)
H11A	0.7360	0.5779	0.3828	0.047*
H11B	0.8365	0.4719	0.4426	0.047*
C12	0.8068 (6)	0.3515 (6)	0.3173 (5)	0.0410 (15)
C13	0.8772 (6)	0.4376 (7)	0.2381 (5)	0.0519 (18)
H13	0.8689	0.5132	0.2430	0.062*
C14	0.9579 (7)	0.4115 (9)	0.1541 (6)	0.073 (2)
H14	1.0053	0.4695	0.1024	0.087*
C15	0.9717 (7)	0.3019 (9)	0.1431 (6)	0.070 (2)
H15	1.0289	0.2853	0.0855	0.084*
C16	0.8997 (7)	0.2156 (8)	0.2183 (7)	0.068 (2)
H16	0.9049	0.1427	0.2094	0.081*
C17	0.8198 (6)	0.2406 (7)	0.3070 (6)	0.0503 (17)
H17	0.7743	0.1817	0.3604	0.060*
C18	0.7024 (6)	0.2477 (6)	0.5546 (5)	0.0434 (16)
C19	0.6008 (7)	0.2131 (7)	0.6317 (6)	0.0568 (19)
H19	0.5247	0.2569	0.6144	0.068*
C20	0.6108 (11)	0.1126 (9)	0.7358 (7)	0.084 (3)
H20	0.5419	0.0916	0.7889	0.101*
C21	0.7213 (12)	0.0459 (8)	0.7592 (8)	0.086 (3)
H21	0.7279	−0.0225	0.8276	0.103*
C22	0.8256 (9)	0.0790 (7)	0.6813 (7)	0.074 (2)
H22	0.9015	0.0329	0.6972	0.088*
C23	0.8146 (7)	0.1794 (6)	0.5820 (6)	0.0549 (18)
H23	0.8842	0.2030	0.5310	0.066*
C24	0.2196 (5)	0.6013 (6)	0.3136 (5)	0.0378 (14)
C25	0.2751 (6)	0.6778 (6)	0.2144 (5)	0.0461 (16)
H25	0.3593	0.6671	0.2001	0.055*
C26	0.2088 (7)	0.7724 (7)	0.1330 (6)	0.059 (2)
H26	0.2483	0.8256	0.0661	0.071*
C27	0.0844 (7)	0.7861 (7)	0.1526 (7)	0.066 (2)
H27	0.0390	0.8474	0.0984	0.079*
C28	0.0279 (7)	0.7079 (7)	0.2535 (7)	0.066 (2)
H28	−0.0562	0.7167	0.2667	0.080*
C29	0.0928 (6)	0.6180 (7)	0.3343 (6)	0.0580 (19)
H29	0.0530	0.5678	0.4030	0.070*
C30	0.2459 (5)	0.3410 (6)	0.4496 (5)	0.0387 (15)
C31	0.2526 (6)	0.2395 (6)	0.5525 (5)	0.0486 (17)
H31	0.2842	0.2428	0.6097	0.058*
C32	0.2132 (7)	0.1342 (7)	0.5712 (6)	0.060 (2)
H32	0.2182	0.0675	0.6410	0.072*
C33	0.1666 (7)	0.1261 (7)	0.4878 (7)	0.066 (2)
H33	0.1394	0.0552	0.5006	0.079*
C34	0.1615 (7)	0.2254 (7)	0.3860 (7)	0.066 (2)
H34	0.1317	0.2208	0.3284	0.079*
C35	0.1991 (7)	0.3318 (7)	0.3662 (6)	0.0581 (19)
H35	0.1932	0.3983	0.2964	0.070*

	U11	U22	U33	U12	U13	U23
Cu1	0.0353 (5)	0.0503 (5)	0.0409 (5)	−0.0031 (4)	−0.0079 (3)	−0.0260 (4)
B1	0.068 (7)	0.088 (8)	0.054 (6)	0.001 (6)	−0.027 (5)	−0.035 (6)
F1	0.088 (4)	0.112 (4)	0.103 (4)	−0.009 (3)	−0.028 (3)	−0.056 (3)
F2	0.055 (13)	0.12 (2)	0.06 (2)	0.003 (10)	−0.013 (14)	−0.04 (2)
F3	0.065 (11)	0.12 (2)	0.068 (16)	0.019 (12)	−0.018 (9)	−0.044 (19)
F4	0.09 (3)	0.093 (17)	0.078 (11)	−0.021 (16)	−0.044 (16)	−0.014 (9)
F2'	0.06 (3)	0.12 (2)	0.04 (2)	0.000 (19)	−0.017 (18)	−0.03 (2)
F3'	0.09 (4)	0.12 (2)	0.062 (12)	−0.01 (3)	−0.031 (17)	−0.027 (14)
F4'	0.067 (11)	0.13 (5)	0.09 (4)	0.03 (2)	−0.038 (18)	−0.07 (4)
N1	0.039 (3)	0.057 (4)	0.058 (4)	−0.006 (3)	−0.004 (3)	−0.031 (3)
N2	0.034 (3)	0.060 (4)	0.045 (3)	−0.007 (3)	−0.004 (2)	−0.027 (3)
P1	0.0317 (9)	0.0466 (10)	0.0361 (9)	−0.0026 (7)	−0.0063 (6)	−0.0230 (8)
P2	0.0334 (9)	0.0424 (9)	0.0345 (8)	−0.0041 (7)	−0.0087 (6)	−0.0201 (8)
C1	0.055 (5)	0.054 (5)	0.074 (5)	−0.005 (4)	−0.004 (4)	−0.033 (4)
C2	0.076 (6)	0.058 (5)	0.120 (8)	0.001 (4)	−0.015 (5)	−0.059 (6)
C3	0.100 (8)	0.087 (7)	0.121 (9)	−0.003 (6)	−0.010 (6)	−0.080 (7)
C4	0.083 (7)	0.115 (8)	0.091 (7)	−0.018 (6)	−0.001 (5)	−0.081 (7)
C5	0.041 (4)	0.080 (5)	0.063 (5)	−0.002 (4)	−0.012 (3)	−0.054 (4)
C6	0.035 (4)	0.073 (5)	0.049 (4)	−0.005 (3)	−0.008 (3)	−0.038 (4)
C7	0.076 (6)	0.110 (7)	0.050 (5)	−0.026 (5)	−0.001 (4)	−0.048 (5)
C8	0.099 (7)	0.115 (8)	0.042 (5)	−0.046 (6)	0.010 (4)	−0.032 (5)
C9	0.090 (7)	0.091 (6)	0.051 (5)	−0.043 (5)	−0.011 (4)	−0.008 (5)
C10	0.053 (5)	0.063 (5)	0.056 (5)	−0.010 (4)	−0.002 (3)	−0.027 (4)
C11	0.040 (4)	0.045 (4)	0.037 (3)	−0.009 (3)	−0.005 (3)	−0.021 (3)
C12	0.038 (4)	0.050 (4)	0.037 (3)	0.011 (3)	−0.015 (3)	−0.025 (3)
C13	0.051 (4)	0.070 (5)	0.040 (4)	−0.007 (4)	−0.005 (3)	−0.029 (4)
C14	0.065 (6)	0.102 (7)	0.051 (5)	−0.015 (5)	0.001 (4)	−0.034 (5)
C15	0.061 (5)	0.101 (7)	0.047 (5)	0.009 (5)	−0.003 (4)	−0.044 (5)
C16	0.068 (5)	0.086 (6)	0.065 (5)	0.027 (5)	−0.022 (4)	−0.060 (5)
C17	0.043 (4)	0.064 (5)	0.050 (4)	0.000 (3)	−0.011 (3)	−0.032 (4)
C18	0.053 (4)	0.046 (4)	0.041 (4)	−0.010 (3)	−0.008 (3)	−0.025 (3)
C19	0.066 (5)	0.066 (5)	0.047 (4)	−0.023 (4)	−0.006 (4)	−0.025 (4)
C20	0.132 (9)	0.085 (7)	0.050 (5)	−0.069 (7)	0.001 (5)	−0.021 (5)
C21	0.146 (10)	0.053 (5)	0.060 (6)	−0.025 (6)	−0.042 (7)	−0.005 (5)
C22	0.101 (7)	0.057 (5)	0.066 (5)	0.013 (5)	−0.036 (5)	−0.030 (5)
C23	0.067 (5)	0.052 (4)	0.049 (4)	0.000 (4)	−0.019 (4)	−0.022 (4)
C24	0.036 (4)	0.045 (4)	0.042 (4)	−0.004 (3)	−0.012 (3)	−0.023 (3)
C25	0.041 (4)	0.049 (4)	0.045 (4)	0.004 (3)	−0.011 (3)	−0.020 (3)
C26	0.076 (6)	0.053 (4)	0.037 (4)	−0.003 (4)	−0.002 (4)	−0.015 (4)
C27	0.059 (5)	0.065 (5)	0.073 (5)	0.011 (4)	−0.034 (4)	−0.024 (5)
C28	0.046 (5)	0.073 (5)	0.069 (5)	−0.002 (4)	−0.027 (4)	−0.011 (5)
C29	0.045 (4)	0.070 (5)	0.052 (4)	−0.008 (4)	−0.009 (3)	−0.017 (4)
C30	0.031 (3)	0.045 (4)	0.043 (4)	−0.005 (3)	−0.009 (3)	−0.019 (3)
C31	0.056 (4)	0.054 (4)	0.042 (4)	−0.011 (3)	−0.012 (3)	−0.022 (4)
C32	0.070 (5)	0.053 (5)	0.055 (5)	−0.018 (4)	−0.009 (4)	−0.015 (4)
C33	0.070 (6)	0.049 (5)	0.088 (6)	−0.024 (4)	−0.012 (5)	−0.029 (5)
C34	0.077 (6)	0.066 (5)	0.081 (6)	−0.017 (4)	−0.033 (4)	−0.038 (5)
C35	0.072 (5)	0.063 (5)	0.049 (4)	−0.010 (4)	−0.022 (4)	−0.026 (4)

Cu1—N1	2.094 (5)	C13—C14	1.351 (9)
Cu1—N2	2.106 (5)	C13—H13	0.9300
Cu1—P2	2.2384 (17)	C14—C15	1.371 (11)
Cu1—P1	2.2830 (18)	C14—H14	0.9300
B1—F4'	1.38 (5)	C15—C16	1.388 (11)
B1—F4	1.38 (3)	C15—H15	0.9300
B1—F2	1.38 (6)	C16—C17	1.389 (9)
B1—F1	1.381 (11)	C16—H16	0.9300
B1—F2'	1.39 (10)	C17—H17	0.9300
B1—F3'	1.40 (6)	C18—C19	1.373 (9)
B1—F3	1.40 (3)	C18—C23	1.386 (9)
N1—C1	1.325 (8)	C19—C20	1.395 (11)
N1—C5	1.344 (8)	C19—H19	0.9300
N2—C6	1.329 (8)	C20—C21	1.354 (13)
N2—C10	1.336 (8)	C20—H20	0.9300
P1—C18	1.830 (7)	C21—C22	1.396 (13)
P1—C11	1.840 (6)	C21—H21	0.9300
P1—C12	1.840 (6)	C22—C23	1.358 (10)
P2—C30	1.837 (6)	C22—H22	0.9300
P2—C24	1.847 (6)	C23—H23	0.9300
P2—C11i	1.860 (6)	C24—C25	1.352 (8)
C1—C2	1.387 (10)	C24—C29	1.402 (9)
C1—H1	0.9300	C25—C26	1.396 (9)
C2—C3	1.368 (13)	C25—H25	0.9300
C2—H2	0.9300	C26—C27	1.377 (10)
C3—C4	1.380 (12)	C26—H26	0.9300
C3—H3	0.9300	C27—C28	1.377 (10)
C4—C5	1.385 (10)	C27—H27	0.9300
C4—H4	0.9300	C28—C29	1.364 (10)
C5—C6	1.479 (9)	C28—H28	0.9300
C6—C7	1.401 (10)	C29—H29	0.9300
C7—C8	1.353 (11)	C30—C35	1.387 (9)
C7—H7	0.9300	C30—C31	1.388 (8)
C8—C9	1.354 (11)	C31—C32	1.375 (9)
C8—H8	0.9300	C31—H31	0.9300
C9—C10	1.370 (10)	C32—C33	1.379 (10)
C9—H9	0.9300	C32—H32	0.9300
C10—H10	0.9300	C33—C34	1.366 (10)
C11—P2i	1.860 (6)	C33—H33	0.9300
C11—H11A	0.9700	C34—C35	1.374 (9)
C11—H11B	0.9700	C34—H34	0.9300
C12—C17	1.382 (9)	C35—H35	0.9300
C12—C13	1.390 (9)
N1—Cu1—N2	78.6 (2)	P2i—C11—H11A	108.1
N1—Cu1—P2	104.72 (15)	P1—C11—H11B	108.1
N2—Cu1—P2	119.60 (15)	P2i—C11—H11B	108.1
N1—Cu1—P1	101.00 (16)	H11A—C11—H11B	107.3
N2—Cu1—P1	99.03 (15)	C17—C12—C13	118.7 (6)
P2—Cu1—P1	136.81 (6)	C17—C12—P1	119.3 (5)
F4'—B1—F4	86 (5)	C13—C12—P1	121.6 (5)
F4'—B1—F2	122 (3)	C14—C13—C12	120.0 (7)
F4—B1—F2	112 (2)	C14—C13—H13	120.0
F4'—B1—F1	113 (4)	C12—C13—H13	120.0
F4—B1—F1	109.9 (18)	C13—C14—C15	121.7 (8)
F2—B1—F1	111 (3)	C13—C14—H14	119.1
F4'—B1—F2'	111 (4)	C15—C14—H14	119.1
F4—B1—F2'	126 (4)	C14—C15—C16	119.7 (7)
F2—B1—F2'	17 (3)	C14—C15—H15	120.2
F1—B1—F2'	109 (5)	C16—C15—H15	120.2
F4'—B1—F3'	109 (4)	C15—C16—C17	118.6 (7)
F4—B1—F3'	24 (3)	C15—C16—H16	120.7
F2—B1—F3'	91 (4)	C17—C16—H16	120.7
F1—B1—F3'	107 (2)	C12—C17—C16	121.2 (7)
F2'—B1—F3'	107 (4)	C12—C17—H17	119.4
F4'—B1—F3	23 (6)	C16—C17—H17	119.4
F4—B1—F3	110 (2)	C19—C18—C23	118.4 (7)
F2—B1—F3	108.1 (18)	C19—C18—P1	119.1 (6)
F1—B1—F3	106.7 (18)	C23—C18—P1	122.4 (5)
F2'—B1—F3	93 (3)	C18—C19—C20	120.6 (8)
F3'—B1—F3	131 (3)	C18—C19—H19	119.7
C1—N1—C5	117.9 (6)	C20—C19—H19	119.7
C1—N1—Cu1	128.0 (5)	C21—C20—C19	119.7 (8)
C5—N1—Cu1	114.1 (5)	C21—C20—H20	120.1
C6—N2—C10	118.2 (6)	C19—C20—H20	120.1
C6—N2—Cu1	114.5 (4)	C20—C21—C22	120.5 (8)
C10—N2—Cu1	126.4 (5)	C20—C21—H21	119.8
C18—P1—C11	104.8 (3)	C22—C21—H21	119.8
C18—P1—C12	103.4 (3)	C23—C22—C21	119.1 (8)
C11—P1—C12	100.2 (3)	C23—C22—H22	120.5
C18—P1—Cu1	116.5 (2)	C21—C22—H22	120.5
C11—P1—Cu1	122.8 (2)	C22—C23—C18	121.7 (7)
C12—P1—Cu1	106.3 (2)	C22—C23—H23	119.2
C30—P2—C24	102.6 (3)	C18—C23—H23	119.2
C30—P2—C11i	100.2 (3)	C25—C24—C29	118.9 (6)
C24—P2—C11i	104.2 (3)	C25—C24—P2	120.0 (5)
C30—P2—Cu1	108.4 (2)	C29—C24—P2	121.1 (5)
C24—P2—Cu1	115.4 (2)	C24—C25—C26	121.4 (7)
C11i—P2—Cu1	123.3 (2)	C24—C25—H25	119.3
N1—C1—C2	124.1 (8)	C26—C25—H25	119.3
N1—C1—H1	117.9	C27—C26—C25	119.3 (7)
C2—C1—H1	117.9	C27—C26—H26	120.3
C3—C2—C1	117.6 (8)	C25—C26—H26	120.3
C3—C2—H2	121.2	C26—C27—C28	119.3 (7)
C1—C2—H2	121.2	C26—C27—H27	120.4
C2—C3—C4	119.3 (8)	C28—C27—H27	120.4
C2—C3—H3	120.3	C29—C28—C27	121.2 (8)
C4—C3—H3	120.3	C29—C28—H28	119.4
C3—C4—C5	119.5 (8)	C27—C28—H28	119.4
C3—C4—H4	120.2	C28—C29—C24	119.8 (7)
C5—C4—H4	120.2	C28—C29—H29	120.1
N1—C5—C4	121.4 (7)	C24—C29—H29	120.1
N1—C5—C6	116.5 (6)	C35—C30—C31	117.6 (6)
C4—C5—C6	122.1 (7)	C35—C30—P2	120.7 (5)
N2—C6—C7	121.2 (7)	C31—C30—P2	121.5 (5)
N2—C6—C5	115.7 (5)	C32—C31—C30	121.1 (6)
C7—C6—C5	123.1 (7)	C32—C31—H31	119.5
C8—C7—C6	118.8 (8)	C30—C31—H31	119.5
C8—C7—H7	120.6	C31—C32—C33	120.9 (7)
C6—C7—H7	120.6	C31—C32—H32	119.6
C7—C8—C9	120.5 (7)	C33—C32—H32	119.6
C7—C8—H8	119.8	C34—C33—C32	118.1 (7)
C9—C8—H8	119.8	C34—C33—H33	121.0
C8—C9—C10	118.1 (8)	C32—C33—H33	121.0
C8—C9—H9	121.0	C33—C34—C35	121.8 (7)
C10—C9—H9	121.0	C33—C34—H34	119.1
N2—C10—C9	123.2 (7)	C35—C34—H34	119.1
N2—C10—H10	118.4	C34—C35—C30	120.6 (7)
C9—C10—H10	118.4	C34—C35—H35	119.7
P1—C11—P2i	116.7 (3)	C30—C35—H35	119.7
P1—C11—H11A	108.1
N2—Cu1—N1—C1	−177.1 (6)	Cu1—P1—C11—P2i	83.5 (4)
P2—Cu1—N1—C1	−59.2 (6)	C18—P1—C12—C17	48.0 (6)
P1—Cu1—N1—C1	85.8 (6)	C11—P1—C12—C17	156.0 (5)
N2—Cu1—N1—C5	2.0 (5)	Cu1—P1—C12—C17	−75.2 (5)
P2—Cu1—N1—C5	119.9 (4)	C18—P1—C12—C13	−138.8 (5)
P1—Cu1—N1—C5	−95.1 (5)	C11—P1—C12—C13	−30.8 (6)
N1—Cu1—N2—C6	−5.9 (4)	Cu1—P1—C12—C13	98.0 (5)
P2—Cu1—N2—C6	−106.4 (4)	C17—C12—C13—C14	−0.9 (10)
P1—Cu1—N2—C6	93.6 (4)	P1—C12—C13—C14	−174.2 (6)
N1—Cu1—N2—C10	−175.2 (6)	C12—C13—C14—C15	0.9 (12)
P2—Cu1—N2—C10	84.3 (6)	C13—C14—C15—C16	1.3 (13)
P1—Cu1—N2—C10	−75.7 (6)	C14—C15—C16—C17	−3.5 (12)
N1—Cu1—P1—C18	−69.1 (3)	C13—C12—C17—C16	−1.3 (10)
N2—Cu1—P1—C18	−149.1 (3)	P1—C12—C17—C16	172.1 (5)
P2—Cu1—P1—C18	56.7 (2)	C15—C16—C17—C12	3.5 (11)
N1—Cu1—P1—C11	159.5 (3)	C11—P1—C18—C19	108.9 (5)
N2—Cu1—P1—C11	79.5 (3)	C12—P1—C18—C19	−146.6 (5)
P2—Cu1—P1—C11	−74.6 (2)	Cu1—P1—C18—C19	−30.4 (6)
N1—Cu1—P1—C12	45.4 (3)	C11—P1—C18—C23	−66.6 (6)
N2—Cu1—P1—C12	−34.6 (3)	C12—P1—C18—C23	38.0 (6)
P2—Cu1—P1—C12	171.2 (2)	Cu1—P1—C18—C23	154.1 (5)
N1—Cu1—P2—C30	21.0 (3)	C23—C18—C19—C20	1.0 (10)
N2—Cu1—P2—C30	106.0 (3)	P1—C18—C19—C20	−174.6 (5)
P1—Cu1—P2—C30	−103.7 (2)	C18—C19—C20—C21	−2.5 (11)
N1—Cu1—P2—C24	−93.3 (3)	C19—C20—C21—C22	1.9 (13)
N2—Cu1—P2—C24	−8.3 (3)	C20—C21—C22—C23	0.3 (13)
P1—Cu1—P2—C24	142.1 (2)	C21—C22—C23—C18	−1.9 (11)
N1—Cu1—P2—C11i	137.2 (3)	C19—C18—C23—C22	1.2 (10)
N2—Cu1—P2—C11i	−137.8 (3)	P1—C18—C23—C22	176.7 (5)
P1—Cu1—P2—C11i	12.5 (3)	C30—P2—C24—C25	−129.9 (5)
C5—N1—C1—C2	−1.4 (11)	C11i—P2—C24—C25	126.0 (5)
Cu1—N1—C1—C2	177.7 (6)	Cu1—P2—C24—C25	−12.4 (6)
N1—C1—C2—C3	0.0 (13)	C30—P2—C24—C29	49.5 (6)
C1—C2—C3—C4	0.8 (14)	C11i—P2—C24—C29	−54.6 (6)
C2—C3—C4—C5	−0.1 (15)	Cu1—P2—C24—C29	167.1 (5)
C1—N1—C5—C4	2.0 (10)	C29—C24—C25—C26	0.1 (10)
Cu1—N1—C5—C4	−177.2 (6)	P2—C24—C25—C26	179.5 (5)
C1—N1—C5—C6	−179.1 (6)	C24—C25—C26—C27	−1.8 (10)
Cu1—N1—C5—C6	1.7 (8)	C25—C26—C27—C28	1.5 (11)
C3—C4—C5—N1	−1.3 (13)	C26—C27—C28—C29	0.5 (12)
C3—C4—C5—C6	179.9 (8)	C27—C28—C29—C24	−2.2 (12)
C10—N2—C6—C7	0.3 (10)	C25—C24—C29—C28	1.9 (10)
Cu1—N2—C6—C7	−169.9 (6)	P2—C24—C29—C28	−177.6 (6)
C10—N2—C6—C5	178.7 (6)	C24—P2—C30—C35	32.0 (6)
Cu1—N2—C6—C5	8.5 (7)	C11i—P2—C30—C35	139.2 (6)
N1—C5—C6—N2	−6.9 (9)	Cu1—P2—C30—C35	−90.5 (6)
C4—C5—C6—N2	172.0 (7)	C24—P2—C30—C31	−154.5 (5)
N1—C5—C6—C7	171.4 (7)	C11i—P2—C30—C31	−47.3 (6)
C4—C5—C6—C7	−9.7 (11)	Cu1—P2—C30—C31	83.1 (5)
N2—C6—C7—C8	−0.2 (12)	C35—C30—C31—C32	−0.5 (9)
C5—C6—C7—C8	−178.5 (8)	P2—C30—C31—C32	−174.2 (5)
C6—C7—C8—C9	0.0 (14)	C30—C31—C32—C33	0.4 (11)
C7—C8—C9—C10	0.2 (14)	C31—C32—C33—C34	0.5 (12)
C6—N2—C10—C9	−0.1 (11)	C32—C33—C34—C35	−1.2 (12)
Cu1—N2—C10—C9	168.8 (6)	C33—C34—C35—C30	1.1 (12)
C8—C9—C10—N2	−0.1 (13)	C31—C30—C35—C34	−0.2 (10)
C18—P1—C11—P2i	−52.5 (4)	P2—C30—C35—C34	173.6 (6)
C12—P1—C11—P2i	−159.4 (3)