Literature DB >> 21574566

Sulfoxide-mediated α-arylation of carbonyl compounds.

Xueliang Huang1, Nuno Maulide.   

Abstract

A novel sulfoxide-mediated α-arylation of carbonyl compounds is reported. This reaction proceeds under very mild conditions at room temperature and does not require any transition-metal promoter or catalyst.

Entities:  

Year:  2011        PMID： 21574566     DOI： 10.1021/ja2031882

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  22 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

2.  Sulfoxide-Directed Metal-Free ortho-Propargylation of Aromatics and Heteroaromatics.

Authors:  Andrew J Eberhart; Harry J Shrives; Estela Álvarez; Amandine Carrër; Yuntong Zhang; David J Procter
Journal:  Chemistry       Date:  2015-03-06       Impact factor: 5.236

3.  Nucleophilic ortho-allylation of pyrroles and pyrazoles: an accelerated Pummerer/thio-Claisen rearrangement sequence.

Authors:  Andrew J Eberhart; Claudio Cicoira; David J Procter
Journal:  Org Lett       Date:  2013-07-15       Impact factor: 6.005

4.  Efficient synthesis of 3H-indoles enabled by the lead-mediated α-arylation of β-ketoesters or γ-lactams using aryl azides.

Authors:  Fei Zhou; Tom G Driver
Journal:  Org Lett       Date:  2014-05-27       Impact factor: 6.005

5.  4-Trifluoromethyl-p-quinols as dielectrophiles: three-component, double nucleophilic addition/aromatization reactions.

Authors:  Jinhuan Dong; Lou Shi; Ling Pan; Xianxiu Xu; Qun Liu
Journal:  Sci Rep       Date:  2016-06-01       Impact factor: 4.379

6.  One-pot sequential synthesis of tetrasubstituted thiophenes via sulfur ylide-like intermediates.

Authors:  Jun Ki Kim; Hwan Jung Lim; Kyung Chae Jeong; Seong Jun Park
Journal:  Beilstein J Org Chem       Date:  2018-01-26       Impact factor: 2.883

7.  Regioselective synthesis of C3 alkylated and arylated benzothiophenes.

Authors:  Harry J Shrives; José A Fernández-Salas; Christin Hedtke; Alexander P Pulis; David J Procter
Journal:  Nat Commun       Date:  2017-03-20       Impact factor: 14.919

8.  Metal-free O-H/C-H difunctionalization of phenols by o-hydroxyarylsulfonium salts in water.

Authors:  Dengfeng Chen; Qingyuan Feng; Yunqin Yang; Xu-Min Cai; Fei Wang; Shenlin Huang
Journal:  Chem Sci       Date:  2016-11-04       Impact factor: 9.825

9.  Dual vicinal functionalisation of heterocycles via an interrupted Pummerer coupling/[3,3]-sigmatropic rearrangement cascade.

Authors:  Mindaugas Šiaučiulis; Selma Sapmaz; Alexander P Pulis; David J Procter
Journal:  Chem Sci       Date:  2017-11-17       Impact factor: 9.825

10.  Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.

Authors:  Michael Brown; Ravi Kumar; Julia Rehbein; Thomas Wirth
Journal:  Chemistry       Date:  2016-01-21       Impact factor: 5.236
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