Literature DB >> 21557626

Enantiocontrolled total syntheses of breviones A, B, and C.

Hiromasa Yokoe1, Chika Mitsuhashi, Yoko Matsuoka, Tomoyuki Yoshimura, Masahiro Yoshida, Kozo Shishido.   

Abstract

Enantiocontrolled total syntheses of the breviones A, B, and C have been accomplished using a highly diastereoselective oxidative coupling of an α-pyrone with a tricyclic diene prepared from an optically pure Wieland-Miescher ketone derivative through the 7-endo-trig mode of acyl radical cyclization.
© 2011 American Chemical Society

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Year:  2011        PMID： 21557626     DOI： 10.1021/ja202874d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

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